Polymeric Semiconductors with a Pre-Specified Alternation of Conjugated Bonds and Metal Clusters

In this work the first samples of polymeric semi-conductors of a new structure are produced. Their electric conductivity is of the order ∼10 -2 Ohm -1 . cm -1 and it increases with temperature. Their synthesis includes a stage of radiation grafting of a matrix-type on stretched polyamide films. Conducting molecular circuits in such materials include fragments with conjugated bonds and metal clusters. The alternation of these fragments is determined by the polyamide matrix.