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We present a computational approach for identifying the important descriptors of the ionic conductivities of lithium solid electrolytes. Our approach discriminates the factors of both bulk and grain boundary conductivities, which have been rarely reported. The effects of the interrelated structural (e.g. grain size, phase), material (e.g. Li ratio), chemical (e.g. electronegativity, polarizability) and experimental (e.g. sintering temperature, synthesis method) properties on the bulk and grain boundary conductivities are investigated via machine learning. The data are trained using the bulk and grain boundary conductivities of Li solid conductors at room temperature. The important descriptors are elucidated by their feature importance and predictive performances, as determined by a nonlinear XGBoost algorithm: (i) the experimental descriptors of sintering conditions are significant for both bulk and grain boundary, (ii) the material descriptors of Li site occupancy and Li ratio are the prior descriptors for bulk, (iii) the density and unit cell volume are the prior structural descriptors while the polarizability and electronegativity are the prior chemical descriptors for grain boundary, (iv) the grain size provides physical insights such as the thermodynamic condition and should be considered for determining grain boundary conductance in solid polycrystalline ionic conductors. [ABSTRACT FROM AUTHOR]

The 70-year history of scientific endeavor of solid state ionics research in Japan is reviewed to show the contribution of Japanese scientists to the basic science of solid state ionics and its applications. The term 'solid state ionics' was defined by Takehiko Takahashi of Nagoya University, Japan: it refers to ions in solids, especially solids that exhibit high ionic conductivity at a fairly low temperature below their melting points. During the last few decades of exploration, many ion conducting solids have been discovered in Japan such as the copper-ion conductor Rb4Cu16I7Cl13, proton conductor SrCe1-xYxO3, oxide-ion conductor La0.9Sr0.9Ga0.9Mg0.1O3, and lithium-ion conductor Li10GeP2S12. Rb4Cu16I7Cl13 has a conductivity of 0.33 S cm-1 at 25 °C, which is the highest of all room temperature ion conductive solid electrolytes reported to date, and Li10GeP2S12 has a conductivity of 0.012 S cm-1 at 25 °C, which is the highest among lithium-ion conductors reported to date. Research on high-temperature proton conducting ceramics began in Japan. The history, the discovery of novel ionic conductors and the story behind them are summarized along with basic science and technology. [ABSTRACT FROM AUTHOR]

La0.61Li0.17TiO3 microstructures have been studied by high resolution electron microscopy. A local lattice distortion occurs in the vicinity of the domain boundary region due to the twin with an angle of 89°. The average domain size of La0.61Li0.17TiO3 is greater than 20 nm. The domain size and structures of La0.61Li0.17TiO3 differ greatly from those of La-poor compounds, such as La0.55Li0.35TiO3. At a nanoscopic level, microdomains of 20-100 nm in size construct a two-dimensional structure in La-rich compounds, while microdomains of 5-10 nm in size construct a three-dimensional structure in La-poor compounds. In addition, the Li-ion conduction mechanisms for La-rich and La-poor compounds are two- and three-dimensional, respectively. [ABSTRACT FROM AUTHOR]

The paper presents the results of research of properties of LaLiTiO 3 and β-Al 2 O 3 thin films for miniature thermobiosensors. The available thermoelectric semiconductor converters are not sensitive enough for registration of slight quantities of heat during biochemical reactions in the region of low-potential temperature differences. For this, we prepared new thin-film materials LaLiTiO 3 and β-Al 2 O 3 and studied their thermal and electrical properties. These materials are solid electrolytes with superionic conductivity. The vacuum methods of “explosive” evaporation and magnetron sputtering were used for depositing the films. For the first time thin films of β-Al 2 O 3 and LaLiTiO 3 were used as sensor based electrical converters for measuring the concentration of glucose, urine and heavy metal ions. [ABSTRACT FROM AUTHOR]

We have measured the hole spectra in YSZ:Pr3+ and YSZ:Eu3+ with various Y2O3 concentrations at low temperature. The temperature dependence of the hole width which obtained from the hole spectra in YSZ:Pr3+ and YSZ:Eu3+ was similar to that for disordered materials. However, the Y2O3 concentration dependence of the hole width in YSZ:Pr3+ was contrary to that for YSZ:Eu3+ at low temperature. The hole width was the widest in the case of YSZ:Pr3+ at 10 mol% Y2O3. On the contrary, it was the narrowest in the case of YSZ:Eu3+ at the same concentration of Y2O3. It was found that there are two states in YSZ, in which the degree of ordered differs from each other. Additionally, the Y2O3 concentration dependence of the hole width at low temperature has reflected the ionic conductivity of YSZ at high temperature. It is suggested that the ordering of local structure is responsible for the ionic conduction in YSZ. [Copyright &y& Elsevier]