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Graphical abstract Enzyme-linked immunosorbent assay (ELISA) is widely used for the detection of disease biomarkers. However, it utilizes time-consuming procedures and expensive instruments, making it infeasible for point-of-care (POC) analysis especially in resource-limited settings. In this work, a multicolorimetric ELISA biosensor integrated on a paper/polymer hybrid microfluidic device was developed for rapid visual detection of disease biomarkers at point of care, without using costly equipment. This multicolormetric ELISA platform was built on multiple distinct color variants resulted from the catalytic oxidation of 3,3′,5,5′-tetramethylbenzidine (TMB) and the etching of gold nanorods (AuNRs). The vivid color changes could be easily distinguished by the naked eye, and their red mean values allowed quantitative biomarker detection, without using any sophisticated instruments. When this multicolorimetric ELISA was integrated on a paper/polymer hybrid analytical device, it not only provided integrated processing and high portability but also enabled fast assays in about 50 min due to the unique advantages of paper/polymer hybrid devices. The limit of detection of 9.1 ng/μL of the hepatitis C virus core antigen, a biomarker for hepatitis C, was achieved using this multicolorimetric ELISA platform. This multicolor ELISA analytical device provides a new versatile, user-friendly, affordable, and portable immunosensing platform with high potential for on-site detections of various viruses, proteins, and biomarkers for low-resource settings such as at home, public venues, rural areas, and developing nations. Supplementary Information The online version contains supplementary material available at 10.1007/s00216-021-03359-8.

A simple electrochemical approach has been strategically developed for in situ generations of ZnO nanoparticles using Zn rods as electrodes and hydrogen peroxide as the oxidant without the formation of any by-product. These ZnO nanoparticles were extended for remediation of pollutants present in paper mill effluents, and separation efficiency was found to be above 90% for hydrocarbons, 92% for lignin, 99% for phenol, and 93% of chemical oxygen demand (COD), as confirmed by gas chromatography-mass spectrometry and COD analysis. It was also observed that the experimental setup could successfully remove 99% of the color from the sample. These ZnO nanoparticles have been proven in the past to be antibacterial and were explored for its ability to inhibit the growth of both Gram-positive and Gram-negative bacteria in the effluent samples after the removal of toxic pollutants. Therefore, we proposed an electrochemical reaction for the in situ synthesis of ZnO nanoparticles for remediation of paper mill effluent as well as inhibit the bacterial growth in the treated effluent sample.

In this study, Taguchi experimental design was used to the optimize operating parameters for the degradation of paper mill effluent using electrochemical (EC) process with two-dimensional concentric aluminum tube electrodes (CATE). For this purpose, four significant experimental factors were used in four levels pH (6–9), electrolysis time (10–40 min), voltage (6–12 V) and surface area (357–624 cm(2)). The process parameters were optimized, through performing L16 orthogonal array of Taguchi technique, for the removal of chemical oxygen demand (COD) and turbidity. The percent COD and turbidity reductions were transferred into an accurate S/N ratio for a larger value is the better (LBT) response. The study presents a unique method of finding optimum combination of process parameters to illustrate their effect on the turbidity and COD reduction. The treatment conditions for the maximum elimination of the pollutants were second level of pH (7), third level of ET (30 min), fourth level of voltage (12 V) and second level of surface area (446 cm(2)). The confirmation experiment results were within the confidence intervals (CI) indicating an acceptable agreement between predicted and observed values. Based on the p-values, the electrolysis time and voltages were found to be the most significant factors for both COD and turbidity reduction. The findings of research indicated, that the Taguchi method can be used successfully for the treatment of paper industry effluent by electrochemical technique.

In this research, simultaneous quantification of cysteine (Cys) and histidine (His) using a paper-based sensor was investigated for the first time. A microfluidic paper-based sensor is a promising amino acid determination tool due to its low cost, low sample consumption, and fast analysis and is easy to make. We used SBA-15 as porous materials that are crystalline compounds formed with surfactants and TEOS as a silica source. The SBA-15 sample was characterized by X-ray diffraction, Fourier transform infrared, and scanning electron microscope techniques. The microfluidic paper-based sensors were fabricated using a wax pen, and the mesoporous SBA-15 modified filter paper. The fabricated sensors for Cys and His determination are operated based on an indicator-displacement assay. A comparative determination study of Cys and His on the sensors was carried out. The results illustrated that the addition of silica nanoporous material led to an immediate and uniform color change. The sensors were successfully exploited in the simultaneous determination of urinary Cys and His levels, thus providing the potential opportunity for clinical diagnosis. The linear range of 1.0 to 90.0 μM and 1.0 to 100 μM for His and Cys was obtained from the calibration data. The detection limits were also calculated (S/N = 3) for His and Cys of 0.5 μM and 1.5 μM, respectively. The proposed method showed a good agreement with the results achieved by a standard method.

This study focused on the applying endo-xylanases to reduce the use of bleaching agent, coupled with the production of xylooligosaccharides (XOs), in mulberry paper making. Paper mulberry pulp (PMP) was consecutively prepared from paper mulberry bark by traditional NaOH-treatment, and two types of thermostable endo-xylanase from Streptomyces thermovulgaris TISTR1948 (wild-type and recombinant endo-xylanases) were employed in the biobleaching of PMP. This process was optimized to achieve maximum XOs yields and the highest PMP quality. The optimal condition was an enzyme dosage of 125 U/g PMP at 12 h of reaction time, both in a 500 mL laboratory bottle and a 150 L reactor. The mixture obtained from the reactor was separated as liquid of XOs derived from PMP (PMP-XOs) and solid biobleached PMP. The PMP-XOs from wild-type endo-xylanase were composed of 31.6% xylopentaose (X5), 30.9% xylohexaose and higher-degree XOs (X ≥ 6), and 11.7% xylobiose (X2), whereas 76.6% of X5 and 8.6% of X2 were the main products from recombinant endo-xylanase. The PMP-XOs derived from both endo-xylanase types exhibited high antioxidant activities, reducing power, phenolic contents, and prebiotic efficacy. In addition, the application of both endo-xylanases enhanced the brightness of PMP by 5.1% and 3.5%, and reduced the kappa number by 9.1% and 3.6%, respectively. Biobleached PMP was subsequently subjected to the NaOCl bleaching step to produce the mulberry paper. This approach could reduce NaOCl consumption by 20–25%, making it an environmentally friendly alternative. The production of valuable prebiotics, such as PMP-XOs, further enhances the economic viability of this approach.

A high-barrier, strong, and antibacterial paper was fabricated by coating the acetylated cellulose solution with different contents of cinnamaldehyde (CIN) on Kraft paper. The antibacterial, antioxidant, mechanical, and barrier properties of coated paper were investigated. When the amount of CIN added in coating reached 6% v/v, the coated paper exhibited excellent antioxidant activity and antibacterial activity against Escherichia coli and Staphylococcus aureus. Notably, the dry and wet tensile strength of paper after coating was increased by 26.4 and 10.6 MPa, respectively. Furthermore, the coated papers' barrier properties against oil, water, water vapor, and oxygen were dramatically improved, especially for the water barrier rate up to 96.4%. Our coated papers with over 6% v/v CIN could extend beef's shelf-life for at least 4 days, which exhibited a promising prospect in eco-friendly antibacterial packaging.

The present study reports the characterization of reverse osmosis (RO) technology at water treatment plant Cogen-2 in paper and Board mills, Pakistan. RO is a commonly used process to obtain de-mineralized water for high-pressure boiler operation in thermal power plants. Scaling and fouling in three-stage RO plants is a major challenge in chemical industry due to the use of raw brackish water in the power plant of paper and board mills. In our study, the feed water quality of RO was changed from soft water to raw water to make it economical. The cleaning frequency was increased three times than normal, which was unsafe for operation and it was required to control scaling and fouling to achieve the desired result. Differential pressures behavior of all stages for 2-month data was observed without acid treatment, and the results of Langelier Saturation Index (LSI) control parameters (temperature, pH, total dissolved solids, calcium hardness, and alkalinity) clearly showed the abnormality. To optimize scaling and fouling of RO, the LSI factor was controlled in total reject water for the next 2 months by acid treatment in feed water. Duration of chemical cleaning and membranes’ life has been extended by fouling and scaling control. Understanding the effect of operational parameters in RO membranes is essential in water process engineering due to its broad applications in drinking water, sanitation, seawater, desalination process, wastewater treatment, and boiler feed water operation. The product flow increased from 18.3 to 19.9 m3/h, and this was due to a decrease in the rejection flow from 8.2 to 6.7 m3/h. The total reject stream pressure also increased from 8.1 to 9 bar. A lower value of LSI of 1.6 is obtained in the reject water stream after the acid treatment.

Rising socioeconomic level and increasing popularity of e-commerce have dramatically increased the use of cardboard packaging materials, and consequent related recycling and wastes. Large amounts of sludge (up to 40% of input mass) is formed through the recycling process, with sludge solids that are very rich in cellulose fibers (~ 75% w/w). To date this sludge is mostly disposed in landfills, resulting in added economic and environmental costs to the recycling process. Short ozonation pretreatment of RPS resulted in enzymatic release of ~ 34% of the cellulosic fraction of the sludge as sugar, and fermentation of these sugars by yeasts resulted in production of ~ 15 g/L ethanol. The solid remnants, were used as a bio-sorbent, efficiently removing dyes from textile wastewater. Recycled paper sludge waste was thus a good source for both energy and water-treatment applications, increasing sustainability and circular economy in the paper and cardboard recycling industry.

Currently, most of the collected waste medium-density fiberboards (MDF) is incinerated or landfilled, as economically viable recycling methods are yet to be developed. By steam refining waste medium-density fiberboards (MDF), it is possible to hydrolyze the incorporated resins and isolate a high yield fiber fraction. Further refining of the steam treated fibers might enable the fibers to be utilized in applications such as paper packaging, facilitating a cascading use of the waste material stream. To this end, intimate knowledge of the material is needed. In this study, the steam refined fibers of two waste MDF samples containing differing amounts of softwood and hardwood underwent refining and beating. The resulting fibers were characterized regarding their morphology and paper test sheets were produced to evaluate their strength (compression-, tensile- and tear-strength). Distinct differences in response to refining between the MDF samples were apparent. For the sample with the higher hardwood share an increase in strength properties with increasing steam treatment severities could be observed and it was possible to produce test sheets with comparable compression strength to recycled pulp for industrial corrugated paperboard. For the sample with a higher share of softwood, the steam treatment severity did not show any influence on fiber morphology or paper properties, and the resulting paper strength was low in comparison to the other steam refined waste MDF sample. Graphic Abstract

The kapok (Ceibapentandra (L.) Gaertn) seed fibre is unicellular with length up to 35 mm, however, it is covered by a hydrophobic waxy layer that limits its application in paper production. In this study, the effect of various pulping methods namely mechanical, chemi-mechanical, semichemical and chemical pulping on kapok fibre properties was investigated. Each kapok pulp was then blended with the secondary fibre recovered from kraftliner board for handsheet making to examine their reinforcing ability on strength properties. The results showed that kapok mechanical pulps (with and without dewaxing (5% (v/v) diluted detergent) and chemimechanical pulp were unable to improve the strength properties of the handsheet. Kapok pulps chemically treated with 18–25% of sodium hydroxide gave a better effect on handsheet strength properties whilst fibre treated with 20% sodium hydroxide showing the highest increment. Although the reinforcing effect of the 4% native cooked starch was slightly higher than that of the 10% kapok pulp blended in recycled paper, the recycling potential of the latter was better as all strength properties retained unchanged after recycling. The findings indicated that kapok chemical pulp is a promising reinforcing fibre source with superior recycling potential.

In traditional deinking process, large amounts of chemicals are required which makes these methods expensive and polluting. Also, application of sustainable material implies the use of green processes to reduce waste and pollution. Green enzymatic deinking processes are alternatives to those technologies that have negative effects on the environment. In this work, we applied response surface methodology for deinking the electrophotography-printed paper based on a systematic experimental pattern. The individual and interactive effects of enzymatic deinking parameters including time, temperature, and enzyme dosage on the handsheet properties were investigated. Different analyses were carried out to determine the best process conditions of enzymatic deinking to optimize the handsheet properties (i.e., tensile, burst, whiteness, and brightness). The obtained responses of an oven-dried fiber at 45 min, 43 °C and the enzyme concentration of 1 mg/15 g were 12.44, 0.65, 72.20, and 87 for tensile strength, burst strength, whiteness, and brightness, respectively. Measuring the optical density of the deinked handset after printing showed that the printability of the deinked paper is in the desired range.

The salivary glands are closely associated with stress conditions and the neuroendocrine system. The concentrations of these salivary biomarkers fluctuate with a person’s disease status. Until now, salivary diagnostics have been promising; however, the analytical tools for detecting salivary biomarkers have remained burdensome due to the lack of user-friendly and cost-effective equipment. In this study, we used a microfluidic starch-coated paper-based chip to isolate ɑ-amylase from human saliva. The concentration of ɑ-amylase on the head and tail sections of the paper-based chip was compared in the presence or absence of starch. We found that ɑ-amylase was highly concentrated only in the head section of the starch-coated paper-based chip through Western blotting (WB) and enzyme-linked immunosorbent assay (ELISA). We expect our designed paper-based chip will aid in α-amylase detection technologies using saliva and small amounts of other biofluids including blood, tears, pancreatic juice, and urine.

In this elucidation, we synthesized novel molecularly imprinted polymers (MIPOH1-4) that were used as organic fillers on bagasse pulp to form cellulosic paper sheets, the formation of MIPOH1-4 from the reaction of enaminone 3 with methyl methacrylate monomer in the presence of ethylene glycol dimethyl acrylate and 2,2’-azobisisobutyronitrile. The obtained MIPOH1-4 was confirmed via FT-IR and SEM with different pore sizes. And we noticed that the increase of template 3 increases the hydrogen bond between monomer and template and gave sponge surface of MIPOH4. Furthermore, the computational energies of the template with different monomers utilize DFT/B3LYP/6-31G (d) level to know the stability of polymers and hydrogen bonding between them. So that we applied that in paper manufacture through the adsorption of MIPOH4 as an organic filler on bagasse pulp to form novel cellulosic paper sheets with different concentrations and these sheets which characteristic through FT-IR, SEM, sizing test, tensile strength, and elucidation their antimicrobial activity with theoretical and docking studies. The MIPOH4 and cellulosic paper sheets showed the thermal stability and high tendency of sizability of these paper sheets and concluded the interaction between cellulose fibers of pulp with MIPOH polymer with physical hydrogen bonding.

Microfluidic paper-based analytical devices (μPADs) have developed rapidly in recent years, because of their advantages, such as small sample volume, rapid detection rates, low cost, and portability. Due to these characteristics, they can be used for in vitro diagnostics in the laboratory, or in the field, for a variety of applications, including food evaluation, disease screening, environmental monitoring, and drug testing. This review will present various detection methods employed by μPADs and their respective applications for the detection of target analytes. These include colorimetry, electrochemistry, chemiluminescence (CL), electrochemiluminescence (ECL), and fluorescence-based methodologies. At the same time, the choice of labeling material and the design of microfluidic channels are also important for detection results. The construction of novel nanocomponents and different smart structures of paper-based devices have improved the performance of μPADs and we will also highlight some of these in this manuscript. Additionally, some key challenges and future prospects for the use of μPADs are briefly discussed.

Thermochemical parameters of A4-sized printing paper (AP), filter paper (FP), newspaper (NP), writing paper (WP), and reed pith (RP) samples were estimated using standard protocol to identify its fuel characteristics, and thermal degradation of the same was studied using thermogravimetric analysis (TGA) and differential thermogravimetric (DTG) techniques in the temperature range of 30–800 °C at the heating rates of 10, 15, and 20 °C/min under nitrogen atmosphere. The curves of TGA and DTG exhibited four significant stages. Maximum weight loss was found to be in the second stage. Kinetic analysis was carried out in the conversion range of 0.1 to 0.7 using iso-conversational models of Flynn-Wall-Ozawa (FWO), Kissinger-Akahira-Sunose (KAS), Vyazovkin, and Vyazovkin AIC (V.AIC). The average activation energies were found to be 139.90, 115.93, 212.52, 257.41, and 241.63 kJ/mol using FWO; 129.73, 103.06, 202.46, 248.38, and 231.55 kJ/mol using KAS; 145.57, 134.00, 195.29, 256, and 241.63 kJ/mol using Vyazovkin; and 140.71, 133.86, 193.14, 247.57, and 190.14 kJ/mol using Vyazovkin AIC model. Thermodynamic parameters (enthalpy change (ΔH), Gibbs free energy change (ΔG), and entropy change (ΔS)) using these models have been evaluated.

All-cellulose paper-based composites with underwater superoleophobicity and high-wet-strength were developed by casting a barrier layer of bacterial cellulose (BC) on a filter paper substrate. To optimize the pore structure of barrier layer, slow gel process of BC dispersion was conducted via acidification and solvent exchange. 1,2,3,4-butanetetracarboxylic acid was used to improve the wet strength and surface hydrophilicity through the crosslinking reaction between fibers. The underwater oil contact angles are higher than 150° in neutral environment, and slightly decrease under acid and alkali conditions. Combined with the micron-sized pore structure of BC barrier layer, the composite papers show good separation performance of oil-in-water emulsion. A denser BC layer can significantly improve the separation efficiency, but also lead to the reduction of flux. During the gelation of BC barrier layer, the increase in the ethanol/water ratio of the dispersion medium is able to increase the flux without obvious negative impact on the separation efficiency. When the ethanol/water ratio is 80%, the separation efficiency and water flux reach 99.2% and 1320 L m−2 h−1·bar−1 for the emulsified soybean oil with the average size of 13 μm, respectively. This type of all-cellulose composite papers provides a new idea for the fabrication of membrane materials for oil–water separation.

A paper-based membrane coated by graphitic carbon nitride (g-C3N4) is prepared via a dip-coating method and used as a separator for sodium metal batteries with merits of low cost and environment-friendliness. Introduction of g-C3N4 effectively improves the ionic conductivity and the structural stability of the separator. Compared with traditional polyethylene separators and Al2O3-coated separators, the g-C3N4-coated separators show better electrolyte wettability, thermal stability, and electrochemical stability. Therefore, Na||Na3V2(PO4)3 battery using the g-C3N4-coated separator exhibits better cycling stability and higher rate capability. These results prove that the g-C3N4-coated paper-based separator is expected to become the next generation of low-cost and high-safety separator in sodium metal batteries.

The present study illustrates the electrocoagulation remediation of paper mill wastewater for multiple response optimization. Multiple response optimization can be combined into one desirability function. All variables and responses varied for a unique global solution. The effect of basic electrocoagulation process variables pH (3–10), conductivity (3.15–10 mS/cm), electrode distance (1–2.5 cm) and current density (5–20 mA/cm2) on four response parameters such as chemical oxygen demand, color, total dissolved solids and total organic carbon has been analyzed experimentally and statistically. The global solution for these variables and responses obtained by software over a hundred design points. For unit desirability function variables conditions were pH 7.49, Conductivity 8.34 mS/cm, electrode distance 2.06 cm and current density 9.32 mA/cm2. In these global variable conditions, responses were observed to be COD 70.19%, Color 75.03%, TDS 70.69% and TOC 71.93%, respectively.

This study investigated the feasibility of utilizing paper sludge (PS) as feedstock in the production of composite boards that are lightweight, durable and environmentally friendly. PS samples were collected from recycled newsprint (RN), corrugated recycled (CR) and virgin pulp (VP) pulping mills in South Africa. The PS was dried and mixed with magnesium phosphate cement to produce boards in a central composite design. Three different fillers including fly ash, calcium carbonate and silica fume were also added to the mix as binder replacement. The PS was characterized before use, and the produced composite board was evaluated for mechanical and physical properties. The boards produced had medium to high density (0.52—1.12 g/cm3) that could be used for non-structural interior applications. The results showed that boards containing RN had the highest mean value for modulus of elasticity (MOE) of 769 MPa. The mean MOE for boards containing CR- and VP-PS was 357 and 411 MPa, respectively. Calcium carbonate had the best effect on the board properties. Techno-economic analysis was simulated for four different types of feedstock scenarios at different locations including a combined scenario. Sensitivity analysis revealed that decreased feedstock cost resulted in decreased minimum required selling price. The analysis also revealed that the combined scenario proved to be the most cost-effective and profitable option for the future.

Compared with a single chemical indicator, the use of multivariate chemical indicators in aging status assessment of transformer cellulose paper insulation can improve the reliability of the evaluation. In this study, a non-destructive method based on multivariate chemical indicators was proposed to evaluate the remaining life of cellulosic paper insulation. The selected chemical indicators closely related to the aging of the insulating paper were analyzed. Additionally, by applying the subjective and objective weighting method, the evaluation information of each indicator was fully extracted to obtain reasonable comprehensive evaluation weights. Besides, the comprehensive evaluation index of multivariate chemical indicators was obtained by using the technique for order preference by similarity to ideal solution method, which is consistent with the deterioration law of paper insulation. Then, the correlation lifespan model between the comprehensive evaluation index of multivariate chemical indicators and the degree of polymerization of insulating paper under different aging stages was established. The effectiveness of the proposed model was verified by experiments. This promising model can increase the accuracy of the condition assessment for the transformer cellulosic paper insulation.

Gelatine sizing was used extensively for western papermaking before the nineteenth century and this technique is still applied nowadays for restoration purposes. Despite its wide use, the relationships between gelatine types, the strength of the size and its distribution inside the paper sheet are still unclear. Different concentrations of three gelatines of various origins and types (A/B) were used to size model papers. The gelatine uptake, the strength of the size and the presence of gelatine at the papers surface were investigated by using a water drop test method and ATR-FTIR spectroscopy. At a given concentration, similar uptakes were found for all gelatines but great variations were observed in terms of size strength and of gelatine ability to cover the surface of paper sheets. In addition, Scanning transmission X-ray microscopy was performed on paper fibres cross sections to map the distribution of the organic compounds (both cellulosic and proteinaceous) on a nanometer scale. This showed that gelatine coats but does not penetrate the fibres. It can be inferred that the different size strengths observed between the tested gelatines are mainly due to different ways of filling holes between fibres inside the paper mat, some gelatines being more prone to go inside the sheet than others which remain mostly distributed near the surface.

Natural cellulose paper is flame retarded using ammonium polyphosphate/montmorillonite (APP/MMT) nanocompound through coating method. Their morphologies are assessed by scanning electron microscopy, chemical components by energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy, chemical structure by Fourier transform infrared, thermal stability by thermo-gravimetric analysis and fire retardancy by 45° horizontal burning test. The results show that the thermal stability and flame retardancy of coated paper samples are enhanced obviously, and all samples are self-extinguishing during the tests due to the char formation reaction between APP/MMT and cellulose. Then the treated paper, AM-18.3, as surface flame retardant treatment for low specific surface area (SSA) polypropylene (PP) specimens (PP@AM-18.3) also is investigated using cone calorimeter. Compared with two controlled samples, PP@AM-18.3 shows significantly increased time to ignition, the lowest fire growth index and highest fire performance index. This may give a new flame retarded approach for low SSA polymer materials with little amount flame retardants.

This study evaluates the use of fermentation to increase nutrient availability in pulp and paper bio-sludge (PPBS) as feed for black soldier fly larvae (BSFL). Rearing of BSFL on fermented PPBS was carried out in a climate chamber in order to assess nutrient availability and larvae survival and growth. The PPBS used came from a chemo-thermomechanical pulp/groundwood pulp mill. The PPBS was fermented at 35 °C and 55 °C, respectively, at initial pH of 10. The effects of sediment and liquid from fermented PPBS on larvae dry weight, survival rate until the prepupae stage, bioconversion, and reduction rate of PPBS were measured. The bioconversion of the liquids (4.1–6.6%) was substantially higher than for both the sediments and untreated PPBS (≤ 0.4%). The survival rate, on the other hand, was substantially lower (26.3–30.9 %) than for the sediments and untreated PPBS (49.5–52.6%). Neither the sediments nor the liquids had significant effects on the larvae weight or on the PPBS reduction rate. The sediments had no significant effect on the survival rate or the bioconversion. This study demonstrates that fermentation dissolves a part of the PPBS and that dissolved substances in the fermentation liquid readily convert to larvae biomass. However, the bulk of the lignocellulose is not dissolved, and most of PPBS nutrients remain unavailable for growth of the larvae. Further research should focus on improved pretreatment of PPBS to increase availability of nutrients and thereby improve the feasibility of BSFL as a recycling method for PPBS.

Lightweight yet strong paper with high toughness is desirable especially for impact protection. Herein we demonstrated electrically conductive and mechanically robust paper (AP/PB-GP) made of reduced graphene oxide via interfacial crosslinking with 1-aminopyrene (AP) and 1-pyrenebutyrat (PB) small molecules. The AP/PB-GP with thickness of over ten micrometer delivers a record-high toughness (∼69.67 ± 15.3 MJ m−3 in average), simultaneously with superior strength (close to 1 GPa), allowing an impressive specific penetration energy absorption (∼0.17 MJ kg−1) at high impact velocities when used for ballistic impact protection. Detailed interfacial and structural analysis reveals that the reinforcement is synergistically determined by π-π interaction and H-bonding linkage between adjacent graphene lamellae. Especially, the defective pores within the graphene platelets benefit the favorable adsorption of the pyrene-containing molecules, which imperatively maximizes the interfacial binding, facilitating deflecting crack and plastic deformation under loading. Density functional theory simulation suggests that the coupling between the polar functional groups, e.g., −COOH, at the edges of graphene platelets and −NH2 and −COOH of AP/PB are critical to the formation of hydrogen bonding network.

In China, Xuan paper has been the paper of choice as artwork support and for conservation, for several centuries. However, little is known about its material properties, especially given the many grades of sized and unsized Xuan paper. In addition, there is a lack of information on its degradation. In this research, a selection of contemporary unsized Xuan papers was investigated, representing diverse raw materials. Seven out of twelve contemporary unsized Xuan papers were determined to be approximately neutral and contain > 2% alkaline reserve, indicating good durability. Viscometry was used to determine the degree of polymerisation (DP) as none of the samples gave significant reactions to the phloroglucinol spot test. The average DP of ten contemporary unsized Xuan papers is ~ 1700, excluding two papers that have presumably been sun-bleached, and that exhibit significantly lower DP. Using X-ray fluorescence, it can be demonstrated that Ca and Si are the dominant elements and interestingly, Ca content is directly correlated with ash content and with alkaline reserve. Accelerated degradation was performed at two sets of environmental conditions, i.e. 90 °C, 30% RH and 60 °C, 70% RH, and the established degradation rates agreed with the Collections Demography model of paper degradation meaning that degradation of Xuan papers proceeds in the same way as other types of paper. This research gives fundamental insights into contemporary unsized Xuan papers, which exhibit good stability during accelerated degradation despite the low starting DP in the context of the samples used in this study. Our findings may inform methods of Xuan paper production, selection of Xuan paper for conservation purposes, as well as preventive conservation of Xuan paper-based artefacts.

Process-monitoring laboratories in the pulp and paper industry generally use a combination of wet chemical analyses and physical measurements to certify the fitness of a production pulp for a specific end-use. These laboratory tests require time and the effort of trained personnel, limiting their utility for real-time process control. Here we show that Raman probes of unrefined cellulosic pulps, well-suited to the online measurement of in-process materials, can predict the quality attributes of manufactured papers. The accuracy of prediction improves when the covariance is modelled in a reduced measurement space selected by a data-driven, feature-selection technique referred to as a Template Oriented Genetic Algorithm (TOGA). TOGA, combined with discrete wavelet transform (DWT), isolates functional-group features that correlate best with mechanical properties paper derived from refined pulp. Paper makers refine market pulps to build sheet strength using a beating process that decreases freeness as it increases fibre-fibre bonding. Methods demonstrated here predict manufactured sheet properties obtainable after any specified degree of refining from the Raman spectrum of an unrefined pulp. This analysis capacity will enable both vendors of market pulp and makers of sheet paper to specify in advance the amount of beating required to produce a desired product, thereby saving cost and conserving resources.

An industry compatible chemo-refining approach was tested for preparation of micro-nanofibrillated cellulose (MNFC) from bleached softwood pulp using sodium meta-periodate and sodium chlorite as oxidizers followed by refining in Valley beater. SEM and FTIR analyses confirmed micro-nano scale fibrillation and chemical functional group modification in laboratory prepared MNFC, respectively. The water retention value, carboxyl content and viscosity of MNFC were found comparable with imported NFC as reference (R-NFC). To evaluate MNFC as strength enhancer for paper properties, 5% MNFC addition to bleached mixed hardwood pulp showed 6% reduction in bulk with 36%, 24% and 97% increment in breaking length, burst index and double fold of the handsheets, respectively without affecting tear index and optical properties than the control. Surface properties were also improved. Pulp drainability (37°SR) after MNFC addition was found suitable for papermaking. These laboratory results confirmed the potential of MNFC as a suitable strength additive for paper quality improvement.

In this study, a microfluidic paper-based analytical device (mu PAD) was integrated with a smartphone app capable of offline (without internet access) image processing and analysis for the rapid colorimetric detection of glucose. A self-inking stamp was used to form hydrophobic channels on a piece of paper-towel due to its superior water absorption efficiency. As demonstrated, the developed sensor was employed for the colorimetric detection of glucose in artificial saliva in the linear scope of 0 - 1 mM with a calculated detection limit of 29.65 mu M. The experimental results show that the quantitative analysis of glucose with the proposed smartphone platform could be completed in less than one minute. The app developed for the smartphone platform is capable of extracting the color-changing area with an embedded image processing tool which could address the problem of color uniformity in the detection zones of mu PAD. The integrated platform has great potential to be used for non-invasive measurements of glucose in body fluids, like tears, sweat and saliva.

The search for non-wood fibers as alternative to the limited wood fiber resources is highly imperative in the pulp and paper-based industries. This is due to growing environmental concern as a result of excessive deforestation. This study aimed at investigating the pulp and paper potentials of pineapple crown (Ananas comosus), sandbox (Hura crepitans), pino macho (Pinus caribaea), elephant grass (Pennissetum purpureum) and teak (Tectona grandis) leaves. Chemical properties (holocellulose, cellulose, hemicellulose, ash contents, hot water and 1% NaOH solubilities) were determined using the relevant TAPPI test and chlorite methods, while the physical properties were determined after the pulping processes. Fourier transform-infrared spectroscopic (FT-IR) analyses of intrinsic functional groups of the paper sheets produced from the pulps of the waste plant leaves were determined. In addition, scanning electron microscope (SEM-EDX) analyses of the morphological characteristic and elemental compositions of the resulting hand sheet surfaces were also examined. P. caribaea has the highest lignin (80.22 ± 0.012%) and cellulose (72.30 ± 0.012%) contents with lowest 1% NaOH solubility (15.20 ± 0.05%) values. A .comosus has the highest hemicellulose (21.73 ± 0.1%) and moisture (75.00 ± 0.12%) contents with lowest ash values (5.01 ± 0.15%). The fibre lengths and the Runkel ratio of the resulting pulps were of the order, A. comosus > P. purpureum > P. caribaea > H. crepitans > T. grandis and A. comosus

The study examines the potential of Mauritian hemp (Furcraea foetida L.), a lignocellulosic non-wood biomass, as a more environmental friendly substitute to virgin wood for printing paper production. The best pulping method for Mauritian hemp was first investigated. A4 sized papers were then produced using 100% Mauritian hemp fibres and mixtures of Mauritian hemp fibres with Elephant grass fibres and wastepaper. Using Standard tests, the physical (thickness, grammage, apparent density, water absorbency) and mechanical (tensile strength, burst strength, crease recovery, abrasion resistance) properties of the papers produced were evaluated and compared with those of an 80 gsm A4 commercial printing paper used as control. Lastly, internal sizing was done by adding different proportions of starch to the paper whose properties were closest to the control (judged most printable) to investigate any property enhancement. Soda cooking with 12% Wt/V NaOH solution at a temperature of 90 °C for 90 min was found best for pulping Mauritian hemp. The 100% Mauritian hemp paper had characteristics closest to the control, with apparent density 141.54 kg/m3, water absorbency time 1.436 s, burst strength 0.323 kPa m2/g, tensile strength 10.97 Nm/g, abrasion resistance 37.5 cycles before rupture and crease recovery angle 34.8°. Increasing the starch content from 10 to 40% caused the 100% Mauritian hemp paper’s characteristics to increasingly approach those of the control, thus showing printability improvement. The methodologies adopted for papermaking and testing demonstrated that Mauritian hemp is a suitable alternative to wood to produce good quality printing paper.

This study aimed to evaluate eggshell wastes, which have the potential to turn into high value-added products in paper industry. Membrane-removed eggshell wastes were subjected to certain processes of washing, drying, grinding, and sieving. The final product of eggshell calcium carbonate (ECC) was used in office paper production as filler, and its possible effect on physical and optical properties of papers was investigated. Mixed office wastes were turned pulp using as raw material of office paper production. Moreover, the effects of ECC was compared with the use of industrial calcium carbonates of ground (GCC) and precipitated (PCC) forms as filler. Breaking lengths of the papers were shown to reduce up to 65.2, 76.6, and 64.1% by a 30% usage of GCC, PCC, and ECC fillers, respectively. PCC and GCC were more effective in improved optical properties of papers than ECC. The brightness values were measured to be 96.8, 98.4, and 93.1 ISO% with a 30% dosage of GCC, PCC, and ECC fillers, respectively. These results suggested that ECC can be used as filler in paper industry.

Pathogen detection is crucial for human, animal, and environmental health; crop protection; and biosafety. Current culture-based methods have long turnaround times and lack sensitivity. Nucleic acid amplification tests offer high specificity and sensitivity. However, their cost and complexity remain a significant hurdle to their applications in resource-limited settings. Thus, point-of-need molecular diagnostic platforms that can be used by minimally trained personnel are needed. The nuclease protection assay (NPA) is a nucleic acid hybridization-based technique that does not rely on amplification, can be paired with other methods to improve specificity, and has the potential to be developed into a point-of-need device. In traditional NPAs, hybridization of an anti-sense probe to the target sequence is followed by single-strand nuclease digestion. The double-stranded target-probe hybrids are protected from nuclease digestion, precipitated, and visualized using autoradiography or other methods. We have developed a paper-based nuclease protection assay (PB-NPA) that can be implemented in field settings as the detection approach requires limited equipment and technical expertise. The PB-NPA uses a lateral flow format to capture the labeled target-probe hybrids onto a nitrocellulose membrane modified with an anti-label antibody. A colorimetric enzyme-substrate pair is used for signal visualization, producing a test line. The nuclease digestion of non-target and mismatched DNA provides high specificity while signal amplification with the reporter enzyme-substrate provides high sensitivity. We have also developed an on-chip sample pretreatment step utilizing chitosan-modified paper to eliminate possible interferents from the reaction and preconcentrate nucleic acids, thereby significantly reducing the need for auxiliary equipment. Graphical abstract.

The study is a first investigation of the feasibility to preserve recycled fillers (e.g. calcium carbonate, kaolin) from deinking paper sludge for newspaper production using an alternative approach respect to the actual methods. Deinking paper sludge was incinerated at 575 °C. The thermal stability of the incinerated sludge (ash) was evaluated by infrared analysis. Subsequently, the resulting ash was bleached by sodium dithionite. The particle size of the ashes was analysed by laser diffraction. The effect of recycled fillers on recycled paper pulp, after blending, was evaluated by the analysis of the physical and optical properties of the obtained paper sheets. Analysis showed the conservation of the calcium carbonate and other fillers’ molecular structure, both after incineration of the sludge and after bleaching. The dithionite treatment of the ashes resulted in ISO brightness levels of more than 70. The brightness was stable over one month. Paper sheets made by blending the bleached ashes with recycled paper showed an improvement of brightness and opacity but a decrease in terms of porosity and breaking length compared to paper sheets made without any filler. The proposed method still requires further studies to evaluate the economical application but offers an opportunity for the recycling of inorganic materials and valorisation of the sludge.

The study describes the preparation of pulp and nanocellulose from non-wood plant materials, as well as an improved properties of paper and cardboard for mass production. The pulps from wheat straw, kenaf and flax fibers were prepared by the environmentally friendly organosolv method—cooking in a solution of isobutanol or peracetic acid. The organosolv pulps used to prepare nanocellulose had traces of lignin and mineral substances. The process of hydrolysis of the investigated organosolv pulps was optimal when carried out under the following conditions: 43% sulfuric acid, temperature 60 °C, hydrolysis time 90 min and ultrasonic treatment 60 min. Using the methods of SEM, XRD, TEM, AFM and TGA, the structure and properties of organosolv pulps and nanocellulose were studied. The use of nanocellulose in bulk and on the surface of mass types of paper and cardboard—paper for corrugation, offset paper, recycled containerboard and cardboard for flat layers of corrugated cardboard were investigated. We established the positive effect of nanocellulose application on the physical and mechanical properties of paper and cardboard. Low consumption of nanocellulose allows production of the paper and cardboard with properties that meet the requirements to appropriate standards and replacement of synthetic reinforcing materials.

Loop-mediated isothermal amplification or LAMP has been identified to be an efficient technology for point-of-care diagnostics. Paper-based LAMP technique has tremendous potential in replacing the existing tube-based technology as the manufacturing cost of a paper-based device is comparatively lower and easy-to-use. LAMP-based paper diagnostic device for Mycobacterium tuberculosis (MTB) detection is of extreme importance as it will help in early and rapid diagnosis of the affected patients. The fabrication of these devices requires assessment of design parameters on the extent of LAMP amplification reaction. Hence, CFD studies would be extremely beneficial from the design perspective. The current work presents an insight into the CFD simulations for LAMP amplification reaction on a porous paper membrane (nitrocellulose membrane). The convection-diffusion-reaction model is solved on a COMSOL Multiphysics 5.0 platform. Studies on effect of pore size, aspect ratio and initial DNA concentration on the extent of DNA amplification reaction have been carried out. The current paper-based technique is effective in detecting a minimum of 5 copies of DNA contrasting the previous semi-quantitative technique which demonstrated the detection of minimum 98 copies. Overall, the simulation results displayed almost 96% enhancement in the DNA amplification rate on paper membrane. Graphical abstract Graphical abstract for the computational study of DNA amplification reaction via LAMP technique on a porous paper membrane.

Maturity of vermicomposted end products obtained from citronella bagasse (CB) and a mixture of citronella bagasse and paper mill sludge (CB + PMS) was determined employing the epigeic earthworm species Eisenia fetida. Two of the primary biological indicators—enzyme assay and germination index—were used for evaluation of vermicompost maturity. The enzyme assay includes the changes in dehydrogenase and urease activities in the final products. The test for germination index was performed on two economically important plant species Abelmoschus esculentus and Solanum melongena. The results revealed a significant increase in dehydrogenase and urease activities in the vermicompost samples over the raw materials and traditional compost. The enhancement was recorded 215.63–225.63% in dehydrogenase and 149.89–249.31% for urease in the end products obtained after 45 days of experimental trials. Further, the higher values of germination index in the vermicompost treatments as against the control confirm the suitability and stability of the vermicomposted final products.

Paper folding-and-punching tests are used to measure spatial abilities in humans. This paper presents a qualitative model for paper folding (QPF) and a computer game (Paper Folding Game) developed to apply and show the reasoning capabilities of the QPF model. This interactive game presents paper-folding activities intended to help users train and understand how to fold a paper to get a specific shape. Then, it presents paper-folding-and-punching tests to the players. The Paper Folding Game can automatically generate paper-folding-and-punching questions with varying degrees of difficulty depending on the number of folds and holes made, thus producing additional levels for training. The reasoning mechanisms in the QPF model are used by the Paper Folding Game to infer the right answer to each paper-folding-and-punching question. This reasoning capability allows the game to provide feedback to the players when they are wrong and also to create other plausible answers automatically, so that random question-answers are shown to the players in the master-mode. The Paper Folding Game has been implemented using Unity engine and it is available to download from GooglePlay and AppleStore for everyone to train their spatial reasoning skills.

A discussion is currently under way in the literature on the sustainable benefits of recycling material, particularly paper, which has high global consumption and polluting capacity. Optimized planning of waste paper recycling networks stimulates sustainable processing efficiency, motivating the investigation of quantitative methods to guide decision-making. The objective of this article is to review papers that present quantitative models for planning waste paper recycling networks considering optimization of the echelons of this process, to analyze the evolution of research, find research opportunities and contribute to future research. The article presents an analysis of five categories of the selected studies: I—evolution of publications; II—echelons considered in different waste paper recycling systems; III—the sustainability pillars considered in the objectives of the formulated model; IV—formulations and techniques used; and V—uncertainty analysis. The proposal for waste paper recycling networks involves summary of the echelons considered in selected articles, to help future analysis. Research suggestions involving sustainability objectives, especially considering social issues, using different solution techniques and considering uncertainty were identified. This study, by reviewing the articles and identifying possibilities for future research, contributes to the development of research using quantitative methods for the efficient management of waste paper recycling networks or similar arrangements.

This study demonstrates a method for patterning paper-based microfluidic devices. An octadecyltrichlorosilane (OTS) solution is used to coat a chromatography paper to make it hydrophobic. A low-temperature (~ 32.9 °C) atmospheric-pressure dielectric-barrier-discharge jet with a shadow mask is then used to pattern hydrophilic stripes on the OTS-coated hydrophobic paper. In this manner, 1-mm-wide hydrophilic stripes are patterned successfully. Liquids are demonstrated to be transported and mixed in the hydrophilic stripes. Water contact angle measurement, X-ray photoelectron spectroscopy, surface profiler, optical emission spectroscopy, and scanning electron microscopy are used to characterize effect of pattering.

In this paper hemicellulose was separated by using 1-ethyl-3-methylimidazolium acetate (EmimAc, an ionic liquid) -water mixtures from a paper grade market bleached hardwood kraft pulp to produce dissolving pulp. Pure EmimAc dissolves pulp fibers completely in 30 min at ambient temperatures. By adding water (as an antisolvent to EmimAc system) the cellulose dissolution decreases and by optimizing the conditions, hemicellulose is largely removed while cellulose remains as the solid residue (dissolving pulp). At optimal conditions: molar ratio of water to EmimAc of 2, 60 °C, an alpha-cellulose content of 92.2%, with a high yield (78 wt%) was obtained. The viscosity of the solvent mixture decreases by increasing water to EmimAc molar ratio, which improves the mobility of ions, thus, facilitating their penetration into pores and lumens of the fibers during the dissolution process. Cellulose purity increases and purified cellulose yield decreases with the increases in temperature and water content (up to 2 wt%) in the mixture. This study implies that the optimal EmimAc/water mixture is an effective system to separate hemicellulose from hemicellulose/cellulose matrix.

The sensitive quantitative analysis of trace heavy metallic elements (Cd, Mn, Cr, and Cu) in aqueous solutions was achieved successfully through the combination of filter paper enrichment with laser-induced breakdown spectroscopy. Filter paper was enriched with 0.4 mL aqueous solutions to form a homogeneous sample layer on the surface of the metallic target. Considering the limits of detection, the values deduced with calibration curves already exhibited the high performance of the proposed method at several hundred or 10 μg/L (Cd 0.165, Mn 0.035, Cr 0.012, and Cu 0.078 mg/L), lower than or comparable to those using other similar methods. The LIBS results agreed reasonably well with those from ICP-MS for real samples. All results showed that our method was suitable and accurate for rapid on-site detection of trace metals in aqueous solutions. This indicates that filter paper enrichment combined with laser-induced breakdown spectroscopy is a feasible approach to wastewater quality monitoring.

Abstract Tissue paper softness relies on two major factors, the bulk softness, which can be indicated by the elasticity of the sheet, and surface softness. Measurement of surface softness is complicated and often requires a multi-step process. A key parameter defining surface softness is the topography of the surface, particularly the crepe structure and its periodicity. Herein, we present a novel approach to measure and quantify the tissue paper surface crepe structure and periodicity based on the detection of waviness along the sample using laser scanning confocal microscopy (LSM) and X-ray tomography (XRT). In addition, field emission scanning electron microscope (FESEM) was used to characterize the tissue paper surface. We demonstrate that surface topography is directly correlated to the erosion of the doctor blade, which is used to remove the dry tissue paper from the Yankee cylinder. Because of its accuracy and simplicity, the laser confocal microscopy method has the potential to be used directly on the production line to monitor the production process of the tissue paper. XRT revealed more structural details of the tissue paper structure in 3D, and it allowed for the reconstruction of the surface and the internal structure of the tissue paper. Graphic abstract

A superhydrophobic paper with excellent robustness was fabricated by roll coating with modified nano-TiO2. First, nano-TiO2 particles were hydrophobically modified by γ-aminopropyltriethoxysilane and 1H, 1H, 2H, 2H-perfluorooctyltriethoxysilane (POTS). Then the paper coating composed of modified nano-TiO2 particles as pigments and epoxy resin (EP) as adhesives was coated on a paper surface to create the desired surface morphology and surface energy. Compared with the uncoated filter paper, the prepared paper showed an improved rough surface morphology owing to the uniform layer of TiO2 microclusters deposited on the fiber network. The superhydrophobic paper exhibited water contact angles (WCA) about 153° ± 1.5°, and water sliding angles (WSA) about 3.5° ± 0.5°, low surface adhesion and excellent bounce ability. The superhydrophobic paper can withstand a variety of wear and tear, such as tape stripping and knife scraping. The as-prepared superhydrophobic paper showed mechanical durability even after 20 wear cycles with sandpaper,thus sustaining excellent superhydrophobicity on the filter paper surface. Moreover, it remains fully functional even in environments with high concentrations of acid and alkali for 96 h. The superhydrophobicity was not affected after storage for 6 months in a natural environment. It was confirmed that the superhydrophobic paper surface exhibited excellent chemical stability, long-term stability and self-cleaning properties. The entire production process was operated under normal environment, without complex equipment; and, as such, has the possibility for large-scale production and application in industry.

A method for treating cellulose paper using the ionic liquid 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) was developed. The treatment was intended to reform the paper structure. Filter paper was immersed in 20 g of molten [BMIM]Cl at 80 °C for 20–80 s and then washed with ethanol and distilled water. The treated paper was then immersed in tert-butyl alcohol before drying in a freeze dryer for 30 min. Next, polyethylene glycol (PG) and trichloromethylsilane were fixed to freeze-dried paper. The paper treated with [BMIM]Cl had a higher specific surface area than that not treated with [BMIM]Cl, and the specific surface area increased as the treatment time increased. The amount of PG fixed to the paper increased as the specific surface area of the paper increased, and PG improved moisture retention. The degree to which the moisture retention was improved was therefore related to the increase in the specific surface area caused by [BMIM]Cl treatment. Addition of trichloromethylsilane to the paper treated with [BMIM]Cl improved the hydrophobicity, and this was caused by the [BMIM]Cl treatment. Overall, [BMIM]Cl treatment was effective for reforming the paper structure and this improved the amount of functional material that could be fixed to the paper.

In the present analysis, a new experimental pilot plant system for exploring resin-impregnated paper (RIP) bushing technology was conducted. Experimental and numerical studies were carried out on the resin infusion and impregnation processes in the paper condenser core of a RIP bushing. An innovative approach for the molding process (named molding method B) of a commercial RIP bushing was implemented. For this method, the homogeneity of the paper winding process was controlled precisely. The filling process was conducted by gravity due to the difference of heights between two vacuumed chambers and from bottom to top in the mold. The flow front position and infusion time were measured experimentally and used to obtain the axial permeability of the paper condenser core analytically and numerically. The results indicate that the molding methods have a significant effect on the RIP bushing quality, homogeneous filling, and impregnating process time. Also, it was found that homogeneity of the paper winding process and, consequently, uniform axial velocity of resin flow in the radial direction is the most effective factor to eject the air. Finally, it was recognized that the determination of axial permeability in the case of transient flow is novel in comparison with conventional procedures such as Darcy relation of steady flows. By decreasing the paper thickness from 0.3 to 0.2 mm, the permeability decreased from 8.84 × 10−10 to 4.52 × 10−10 m2. The microstructure of the core illustrates that the axial permeability of the crepe paper condenser core is considerably affected by the variation of the paper thickness.

We present a high resolution, ultra-frugal printing of paper microfluidic devices using in-house paraffin formulation on a simple filter paper. The patterns printed using an office inkjet printer formed a selective hydrophobic barrier of 4 ± 1 µm thickness with a hydrophilic channel width of 275 µm. These printed patterns effectively confine common aqueous solutions and solvents, which was verified by solvent compatibility studies. SEM analysis reveals that the solvent confinement is due to pore blockage in the filter paper. The fabricated paper-based device was validated for qualitative assessment of Candida albicans (pathogenic fungi) by using a combination of L-proline β-naphthylamide as the substrate and cinnamaldehyde as an indicator. Our studies reveal that the pathogenic fungi can be detected within 10 min with the limit of detection (LOD) of 0.86 × 106 cfu/mL. Owing to its simplicity, this facile method shows high potential and can be scaled up for developing robust paper-based devices for biomarker detection in resource-limited settings. Graphic abstract

Water–oil separation from their emulsions and mixtures has been a prominent topic in fundamental research and in industries. A superhydrophobic/oleophilic membrane (SHP) was obtained by dipping a cellulose filter paper in an acetonitrile solution of toluene diisocyanate (TDI) and in that of N-(2,4-diaminophenyl) maleimide, alternatively and repeatedly for three times, to make the paper coated by maleimide-containing polyurea (PU), which was then reacted with n-dodecanethiol (DAT) through Michael addition to obtain the superhydrophobic porous membrane (SHP). All the involved reactions were confirmed by different techniques. SHP membrane as prepared was demonstrated to be superhydrophobic and oleophilic and of high performance in separation of oil and water from their emulsions and mixtures. This study provides a new route to the fabrication of new materials of high superhydrophobicity and oleophilicity, featured by ease of fabrication, low-cost and versatile availability of the starting materials, both synthetic and natural.

Fluorine-free cellulosic paper was successfully obtained by coating the glassine base paper with eco-friendly cellulosic coating, which was made from dissolving cellulose in 8 wt% NaOH/12 wt% urea aqueous solution. Then the coated paper was severally immersed into CH3COOH, Na2SO4, and H2O solution to coagulate and regenerate. Benefiting from the compact matrix and fully covered surface, the resultant cellulosic paper exhibited favorable barrier properties and mechanical performance. Notably, the paper coagulated with CH3COOH displayed the reduction in water–vapor transmission rate, air permeability, and uptake of organic solvents due to its low porosity (26.8%) and narrow pore size distribution (0.1–0.36 µm). The tensile strength and elongation at break of papers treated by CH3COOH at coating weight of 5 g/m2 were increased by 72.1% and 34.0%, respectively. In summary, the fluorine-free cellulosic paper with high oil and grease resistance is attractive for the development of high-performance materials for food packing applications. Fluorine-free paper was obtained from the glassine base paper coated with eco-friendly, non-fluorinated, and degradable cellulosic coating, then coagulated with CH3COOH, Na2SO4, and H2O solution, respectively. The resultant functional papers displayed enhanced barrier properties (oil, organic solvent, vapor, and gas) and mechanical performance.

The use of nanocelluloses is being conducted for the most diverse applications. Their performance as coating agent has been mainly explored to improve barrier properties, as they emerge as perfect candidate for plastic substitution, but it is also important to explore their potential to improve printing quality. In the present work, the influence of different nanocelluloses, obtained through mechanical, enzymatic, TEMPO-mediated oxidation and carboxymethylation treatments, in the coating process and inkjet printability of office papers was assessed. The results revealed that the cellulose nanofibrils are better for printability than the microfibrils. But the size and charge of the former must be taken into account, since fibrils of very small size penetrate the paper structure, dragging the pigments from the surface, and very anionic nanofibrils can also have negative influence on the optical density. Besides, an interesting synergy between surface-sizing starch and the cellulose nanofibrils was found to occur as the latter closed the paper structure, which prevented starch from penetrating, while potentiating both of their positive effects on ink pigment entrapment. An additional study of characterization of inkjet pigments was also performed.

Chitosan is a biopolymer that has shown promising results for surface treatment of paper to enhance barrier and mechanical properties. Commercially, chitosan is available with a wide range of degree of deacetylation (DD). Herein, effect of DD on performance of chitosan in surface application of paper is investigated. Surface application of chitosan of different DD (77%, 84% and 94%) was done at a dose of 1.0 ± 0.2 g/m2 on kraft paper and comparison in terms of strength, structural, surface and barrier properties of paper was performed. Different DD of chitosan was confirmed by FTIR analysis. Results showed that breaking length of paper maximally increased by 15.2%/26.6% in machine direction (MD)/cross direction (CD), respectively after surface application of 94% DD chitosan followed by 77% DD and 84% DD. The maximum increase in burst index, stretch in MD and TEA in both directions of paper was found after surface application of 94% DD chitosan. Results attained by 77% DD and 84% DD chitosan for improvement in burst index, stretch and tensile energy absorption of paper were also encouraging. Maximum increase in stiffness was observed in CD with application of 84% DD chitosan. Double fold of paper also increased the maximum after surface application of 84% DD chitosan. The best results of contact angle, surface energy, Cobb60 and water vapor transmission rate were attained after surface application with 94% DD chitosan whereas the results attained by 77% DD and 84% DD chitosan for contact angle, surface energy, Cobb60 were also encouraging.