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Abstract Biochar as a highly promising CO2 adsorbent is of great significance in addressing global warming and promoting human health. Research has shown that nitrogen doping improves the CO2 adsorption performance of biochar, but selecting chemical nitrogen sources such as urea and melamine to prepare nitrogen-doped biochar is not conducive to green production and environmental protection. Therefore, it is necessary to identify a new nitrogen source to enhance the emission reduction characteristics of this process. This study selected corn straw as the raw material and cow manure as a representative protein-based nitrogen source to explore its potential as a urea substitute and reveal the hydrothermal carbonization doping mechanism of different nitrogen sources. The results indicated that in raw materials with the same C/N ratio, biochar prepared from cow manure as the nitrogen source had a better doping effect and CO2 adsorption performance. Moreover, a moderate amount of cow manure was beneficial for efficient nitrogen doping and the adsorption of CO2 by biochar, with a maximum CO2 adsorption performance improvement of 32.7%. Due to the different carbon-nitrogen bonds of the different nitrogen sources, urea was more likely to retain amino groups, while macromolecular protein nitrogen sources tended to retain structural nitrogen. The results of this study provide new ideas and theoretical support for preparing other nitrogen-doped carbon materials derived from biomass. Graphical Abstract

Abstract Straw returning is an important strategy for effectively using straw resources to improve soil fertility and quality, but the effects of this process on reactive intermediates (RIs) formation in paddy water are not fully explored. In this study, we conducted a field experiment to explore the effects of straw returning on RIs formation including triplet chromophoric dissolved organic matter (3CDOM*), hydroxyl radicals (•OH), and singlet oxygen (1O2) in paddy water. It was found that straw returning considerably increased the steady-state concentration of RIs, and the application of rice straw with 25% and 75% organic replacement ratio increased RIs concentration by 2.52 and 2.25 times, respectively. The optical spectroscopy, Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) analysis and structural equation model showed that straw returning produces abundant humified and aromatic DOM containing fulvic acid, lignin and protein-like substances, which could induce more RIs under irradiation. In addition, straw returning significantly accelerated imidacloprid (IMD) degradation, yielding degradation products that were highly toxic to aquatic animals (i.e., fish and daphnia) but less toxic to aquatic plants (i.e., green algae). This study would offer an innovative viewpoint on the effects of straw returning on the photochemistry of paddy water and the naturally occurring abiotic degradation pathway of organic contaminants.

Abstract Combined straw and straw-derived biochar input is commonly applied by farmland management in low-fertility soils. Although straw return increases soil organic matter (SOM) contents, it also primes SOM mineralization. The mechanisms by which active microorganisms mineralize SOM and the underlying factors remain unclear for such soils. To address these issues, paddy soil was amended with 13C-labeled straw, with and without biochar (BC) or ferrihydrite (Fh), and incubated for 70 days under flooded conditions. Compound-specific 13C analysis of phospholipid fatty acids (13C-PLFAs) allowed us to identify active microbial communities utilizing the 13C-labeled straw and specific groups involved in SOM mineralization. Cumulative SOM mineralization increased by 61% and 27% in soils amended with Straw + BC and Straw + Fh + BC, respectively, compared to that with straw only. The total PLFA content was independent of the straw and biochar input. However, 13C-PLFAs contents increased by 35–82% after biochar addition, reflecting accelerated microbial turnover. Compared to that in soils without biochar addition, those with biochar had an altered microbial community composition-increased amounts of 13C-labeled gram-positive bacteria (13C-Gram +) and fungi, which were the main active microorganisms mineralizing SOM. Microbial reproduction and growth were susceptible to nutrient availability. 13C-Gram + and 13C-fungi increased with Olsen P but decreased with dissolved organic carbon and $${\text{NO}}_{3}^{ - }$$ NO 3 - contents. In conclusion, biochar acts as an electron shuttle, stimulates iron reduction, and releases organic carbon from soil minerals, which in turn increases SOM mineralization. Gram + and fungi were involved in straw decomposition in response to biochar application and responsible for SOM mineralization. Graphical Abstract

Abstract The study examined the impact of Salicornia supplementation on the biological efficiency and biochemical properties of white Elm oyster mushrooms, Hypsizygus ulmarius. Four substrates were used to cultivate the mushrooms. Wheat straw was used as the main substrate and the Salicornia was used to partially replace the main substrate at the ratios of 5, 10, and 20% while 100% wheat straw was used as the control. The study found that the 20% Salicornia completed the mycelial run earlier (41 days), while the control treatment took the longest (45 days). The 5% Salicornia supplemented treatment and control treatment had the highest and lowest biological efficiencies (126 and 65%) respectively. The elemental concentration was undetectable for Copper (Cu), Lead (Pb), and Cadmium (Cd). The mushrooms from the control had the highest while those from the 20% treatment had the lowest (Zinc (Zn) levels (0.0115 ug/100 g) and 0.0078 ug/100 g). Conversely, Chromium (Cr) levels were highest and lowest in the 20% (0.0022 ug/100 g) and control treatments (0.0007 ug/100 g). Similarly, the total unsaturated fatty acids were highest in the control treatment (78%) and lowest in the 20% treatment (69%) while the opposite was true for the saturated fatty acids (22% and 31%). The mushrooms investigated in this study had higher essential amino acids (44–49%) compared to non-essential amino acids (17–20%). The results from this study suggest that Salicornia is a promising marine resource with the potential to enhance the health-promoting properties of oyster mushrooms.

Abstract In order to understand whether corn straw (CS) and straw-derived biochar (CB) can be used as soil amendments to alleviate soil contaminated with metal oxide nanoparticles, CS and CB prepared by pyrolysis at 300 °C (with a weight ratio of 2% and 5%) were added to two types of soil contaminated with copper oxide nanoparticles (CuO NPs) to study the effects of CS and CB application on soil properties, wheat seedling growth, and metal transport. Our results showed that both 2% and 5% additions of CS and CB enhanced the nitrogen, phosphorus, and potassium fertility of both soils. In red earth (acidic), the addition of 2% and 5% of CB significantly increased soil pH (9.24% ~ 18.4%), wheat growth (12.2% ~ 14.9%), chlorophyll content (significantly increased by 32.3% for 2% CB treatment), and decreased antioxidant enzyme activity and membrane lipid peroxidation. In fluvo-aquic soil (alkaline), CS and CB did not increase soil pH, only 5% of CB significantly promoted wheat growth (by 11.0%), and decreased antioxidant enzyme activity, whereas 2% of CB reduced chlorophyll content (by 22.2%). Furthermore, 2% and 5% of CS and CB affected the transport of Cu in wheat, decreasing the translocation factor in red earth but increasing it in fluvo-aquic soil. Principal component analysis showed that 5% of CB had the best alleviating effect on CuO NPs toxicity in red earth, compared to CS. Taken together, CB obtained by pyrolysis at 300 °C appears to be an effective soil amendment specifically for red earth. Highlights • Corn straw (CS) and straw-derived biochar (CB) were used to mitigate CuO NP toxicity • 5% of CB showed the best mitigation effect on CuO NP toxicity in red earth • CS and CB had no significant mitigation on CuO NP toxicity in fluvo-aquic soil Graphical Abstract

Abstract Reductive dissolution of barium (Ba) sulfate in wetland soils may increase Ba bioavailability in the environment, yet no information is available regarding Ba remediation using biochar. This study investigated the effectiveness of sugarcane (Saccharum officinarum) straw biochar pyrolyzed at 350 °C (BC350), 550 °C (BC550), and 750 °C (BC750) in inhibiting barite dissolution and, consequently, Ba availability in a soil artificially spiked with barite and flooded for 365 days. Increasing pyrolysis temperature alters the carbon structure, and increases dehydration and depolymerization, resulting in more stable biochar that releases less DOC (8.6-fold decrease from BC350 to BC750). Additionally, high-temperature biochar (BC750) had 1.7 times higher carbon (C) content, 2.4 times higher ash content, and a 13.1 times greater specific surface area (SSA) than low-temperature biochar (BC350). Amending soil with BC750 increased pH but did not promote reducing conditions, and thus did not promote barite dissolution. Conversely, greater DOC in low-temperature biochar, particularly BC350, favored reducing conditions and increased barite dissolution by 23%, with BC550 also showing an 18% increase. This enhancement led to a greater pool of Ba sorbed into more labile exchangeable sites. In summary, pyrolysis temperature affects biochar attributes, which in turn influences the soil geochemical environment and Ba speciation. Low-temperature biochar (BC350) shows potential as an amendment to increase the bioavailable Ba pool in assisted remediation programs, such as biochar-assisted phytoremediation. Graphical Abstract

Abstract Aside from being a significant source of highly nutritious and medicinally valuable mushrooms, mushroom cultivation is an important means of environmental remediation. Oyster mushroom (Pleurotus ostreatus) is a versatile mushroom that can be grown in various environmental conditions and non-composted lignocellulosic wastes. The present study was conducted to assess the growth response of oyster mushroom on sesame stalk. Spawn was prepared from a mycelium culture grown on potato dextrose agar. The spawn was inoculated onto sesame stalk and wheat straw substrates and incubated at room temperature in the dark for 21 days. A Completely Randomized Design (CRD) was used with five treatments, including the control (100% wheat straw), which were triplicated. Data was analyzed using Minitab version 19. Significant (P

Abstract Icing of wind turbine blades will seriously hinder the development of the wind power industry, and the use of biomass resources to solve the icing problem is conducive to promoting the synergistic development of biomass and wind energy. In this study, ice-phobic coatings with photothermal and anti-corrosion properties were prepared by surface modification pyrolysis and hydrothermal reaction with rice straw biogas residue as raw material. The erosion of KOH and the surface modification of MoS2 produced a rough structure of the material, and the high-temperature pyrolysis and hydrothermal reaction promoted the dehydrogenation and decarboxylation reactions, which reduced the number of oxygen-containing functional groups and decreased the surface energy of the material. The ice-phobic coating has superhydrophobic properties with a contact angle of 158.32°. Due to the small surface area in contact with water, the coating was able to significantly reduce the icing adhesion strength to 53.23 kPa. The icing wind tunnel test results showed that the icing area and mass were reduced by 10.54% and 30.08%, respectively, when the wind speed was 10 m s−1 and the temperature was − 10 °C. Photothermal performance tests showed that the MoS2-loaded material had light absorption properties, and the coating could rapidly warm up to 58.3 ℃ under xenon lamp irradiation with photothermal cycle stability. The loading of MoS2 acts as a physical barrier, reducing the contact of corrosive media with the substrate, thus improving the anti-corrosion of the coating. This study has practical application value and significance for the development of the anti-icing field under complex environmental conditions. Graphical Abstract

The growing interest in commercial Inland saline aquaculture has taken momentum across the globe due to the available technologies for aquaculture and the abundant resources of saline groundwater. However, the critical problems in inland saline ponds are degraded soil and imbalanced or deficient nutrients. To address these issues, a 75-day experiment was conducted to explore the effects of Paddy Straw Biochar (PSB) as a sediment amendment on sediment quality, water characteristics, growth parameters, and the well-being of Penaeus vannamei reared in inland saline environments. PSB was applied to the nursery ponds at 1 ton/hectare (Treatment, T1) and 2 ton/hectare (Treatment, T2). The findings of water quality parameters showed a significant increase in K + and Mg ++ with a decrease in ammonia-N levels in biochar-applied ponds. Similarly, the addition of biochar to ponds (T2) resulted in improved sediment characteristics with enhanced water holding capacity (24.75%), increased soil organic carbon content (77.94%), pH levels (0.37 units), cation exchange capacity (43.15%), available potassium (16.3%), and lower bulk density (12.61%) compared to ponds subjected to control conditions at the end of the experiment. Over the experiment, improvements in sediment and water quality parameters followed the T2 > T1 > control trend. Growth characteristics showed a significant rise in the percentage of weight gain (12.398 ± 0.12), SGR (11.80 ± 0.01% day -1 ) and PER (2.39 ± 0.01) with reduced FCR (1.19 ± 0.00) in biochar-treated ponds (T2), followed by T1 and control. The digestive enzyme activity (amylase) and metabolic enzymes like hepatopancreatic alanine aminotransferase (ALT) and muscle ALT activities were significantly higher in shrimps raised in the biochar-applied ponds. On the other hand, the oxidative stress enzyme superoxide dismutase (SOD) in gills, muscles, and hepatopancreas (HP) exhibited lower values, suggesting reduced oxidative stress due to the biochar amendment of the pond sediment. Overall, the study recommends incorporating PSB at a rate of 2 t/ha into nursery pond sediment to enhance water quality, physiological status, and the growth of P. vannamei juveniles. Moreover, this approach improves soil and water characteristics in saline soils, making it an effective culture practice in degraded environments., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

The amount of biomass production each year is huge, and microwave-assisted pyrolysis of biomass to obtain biogas, bio-oil, and biochar is a promising method. In this study, silicon carbide (SiC) was selected as the microwave absorber, and the effects of microwave power (400, 450, 500, 550 and 600 W), reactor chamber volume (100, 150, 200, 250, and 300 W), and the mass ratio of SiC and corn straw (0, 0.25, 0.5, 0.75, and 1) on the heating performances of corn straw particles were investigated and presented in this study. When the microwave power increased from 400 to 600 W, the average heating rate of corn straw particles increased from 23.06 ℃ /min to 101.46 ℃ /min, and that of mixture particles of corn straw and SiC increased from 87.00 ℃ /min to 236.88 ℃/min. When the reactor chamber volume increased from 100 to 300 mL, the average heating rate of corn straw particles decreased from 38.21 ℃/min to 22.54 ℃/min, and that of mixture particles of corn straw and SiC decreased from 98.84 ℃/min to 76.01 ℃/min. When the mass ratio of SiC and corn straw increased from 0 to 1, the average heating rate of mixture particles of corn straw and SiC increased from 101.46 ℃/min to 236.88 ℃/min. Some formulae with R 2 values ranged from 0.971 to 0.998 were proposed to determine the transient temperatures of corn straw particles and mixture particles of corn straw and SiC., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

The survival and growth of plant pathogens on crop residues are key factors facilitating the dynamics of crop diseases. Spores (e.g., perithecia, and chlamydospores) and mycelium of pathogenic fungi overwinter on harvest residues, such as straw, and serve as initial inoculum infecting crops in the next growing season. Therefore, targeting overwintering fungi is essential to attaining effective disease control. Beneficial microorganisms offer advantages in controlling pathogens through their ability to colonize and exploit different environmental niches. In this study, we applied qPCR assays to explore the biocontrol performance of locally isolated strains of Clonostachys against various Fusarium pathogens. We proved that prior colonization of wheat straw by Fusarium spp. can be effectively reduced by Clonostachys rosea. We demonstrated that the efficiency of C. rosea to reduce Fusarium inoculum appears to remain at a similar level for most studied strains regardless of the target pathogen and the level of colonization of substrates by pathogens. Efficient performance of local C. rosea strains identifies possible targets for future strategies to control Fusarium diseases in cereals. Our study also highlights the challenge in sequence-based determination of C. rosea, which is crucial for the efficient selection of beneficial strains for biocontrol purposes., (© 2024. The Author(s).)

Abstract Fe-modified biochar (FB) and co-using Chinese milk vetch and rice straw (MR) are two effective ways for mitigating the cadmium (Cd) contamination in paddy fields in southern China. Nevertheless, the effects of FB combined with MR on Cd passivation mechanism remain unclear. In the current study, the strengthening effects of FB induced by MR were found and the mechanisms of the extracted dissolved organic matter (DOM) from the co-decomposition of MR on Cd alleviation were investigated through pot experiment and adsorption experiment. Pot experiment demonstrated that co-incorporating FB and MR decreased available Cd by 23.1% and increased iron plaque concentration by 11.8%, resulting in a 34.7% reduction in Cd concentrations in brown rice compared with addition of FB. Furthermore, co-using FB and MR improved available nutrients in the soil. The molecular characteristics of DOM derived from the decomposition of MR (DOM-MR) were analyzed by fluorescence excitation emission matrix spectroscopy-parallel factor analysis (EEM-PARAFAC) and Fourier transform-ion cyclotron resonance mass spectrometry (FT-ICR MS). Results showed that lignin/carboxylic-rich alicyclic molecules and protein/amino sugar were the main compounds, potentially involved in the Cd binding. Adsorption experiments revealed that the addition of DOM-MR improved the functional groups, specific surface area, and negative charges of FB, inducing the strengthening of both physisorption and chemisorption of Cd(II). The maximum adsorption capacity of Fe-modified biochar after adding DOM-MR was 634 mg g−1, 1.30 times that without the addition of DOM-MR. This study suggested that co-incorporating MR, and FB could serve as an innovative practice for simultaneous Cd remediation and soil fertilization in Cd-polluted paddy fields. It also provided valuable insights and basis that DOM-MR could optimize the performances of Fe-modified biochar and enhance its potential for Cd immobilization. Graphical Abstract

The burning of agricultural straw is a pressing environmental issue, and identifying effective strategies for the rational utilization of straw resources is decisive for achieving sustainable development. Owing to its high carbon content and exceptional stability, straw biochar produced via pyrolysis has emerged as a key focus in multidisciplinary research. However, the efficacy of biochar in mitigating nitrous oxide (N 2 O) emissions from paddy soils is not consistent. A 2-year field experiment was conducted and investigated the impact of biochar derived from two feedstocks (rice straw and wheat straw, pyrolyzed at 450 °C) on N 2 O emissions, global warming potential (GWP), greenhouse gas intensity (GHGI), nitrogen use efficiency (NUE), crop yield, and soil quality. The static chamber technique was used for collecting N 2 O gas samples, and concentrations were analyzed through gas chromatography methods. The treatment combinations included BR0 (control), BR1 (NPK at the recommended dose, 120:60:40 kg ha -1 ), BR2 (wheat straw biochar, 5 t ha -1 ), and BR3 (rice straw biochar, 5 t ha -1 ). The results exhibited that cumulative N 2 O emissions from BR2 and BR3 treatments decreased by 10.55% and 13.75% respectively, compared to BR1. Lower GWP and GHGI were observed under both biochar treatments compared with BR1. The highest rice grain yield (3.48 Mg ha -1 ) and NUE (76.72%) were recorded from BR3, which also exhibited the lowest yield-scaled N 2 O emission. We observed positive correlations between soil nitrate, ammonia and water-filled pore spaces, while NUE showed negative correlations with N 2 O emissions. Significant (p < 0.05) improvements in soil quality were also detected in both the biochar treated plots, indicated by increased soil pH, water holding capacity, porosity, and nutrient contents. Overall, the results suggest that applying biochar at a rate of 5 t ha -1 in paddy soil is a viable nutrient management strategy with the potential to reduce reliance on inorganic fertilizers, mitigate N 2 O emissions, and contribute to sustainable food production., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Abstract Lime is commonly used to neutralize acidic soil in practical farmland management. This study aimed to examine the effect of soil pH change by liming in acidic soil on the mineralization and microbial assimilation of 13C-labelled maize straw-derived hydrophilic and hydrophobic fractions in a 60-d incubation experiment. Our results showed a higher cumulative mineralization of hydrophilic fraction in acidic (34.5%) than neutralized Ferralsol (22.3%), related to lower microbial substrate use efficiency under low soil pH. The cumulative mineralization of hydrophobic fraction was similar between acidic and neutralized Ferralsol. Soil pH affected substrate (hydrophilic and hydrophobic fractions) utilization by actinomycetes and bacteria, but not fungi. The utilization of hydrophilic fraction followed the order: bacteria (57–68%) > actinomycetes (10–19%) > fungi (4.2–5.5%). In contrast, utilization of hydrophobic fraction was the highest for fungi (24–38%), followed by bacteria (21–29%) and actinomycetes (3.2–15%). Actinomycetes showed a greater preference for hydrophilic fraction in neutralized than acidic Ferralsol; bacteria preferred to utilize hydrophilic fraction in both soils, while fungi favored hydrophobic fraction. Also, various substrate uses were found in specific phospholipid fatty acids, which showed that some individual species harbor particular organic C metabolization strategies. In conclusion, soil pH regulates the mineralization of hydrophilic fraction and variously determines the preferential utilization of hydrophilic and hydrophobic fractions by fungi, bacteria, and actinomycetes. Graphical Abstract

This experiment was designed to investigate the effect of feeding wheat-straw based densified complete feed block (DCFB) on daily weight gain, feed intake, digestibility and feed conversion rate in growing heifer calves. Eight weaned F1 Frisian*Borena (Bos taurus × Bos indicus) crossbred calves (92.5 ± 27.5 kg body weight) and 5 months of age were randomly distributed into four groups, each with two animals evaluated under 4 × 4 double Latin Square Design for 240 days. The control treatment was natural pasture hay (NPH) and concentrate mix (CM) fed conventionally in a way that covers 50:50% requirements on dry matter (DM) bases and DCFB prepared by mixing wheat straw (WS) to concentrates mixture in the ratio of 50:50 (T2), 40:60 (T3) and 30:70 (T4), respectively. Each heifer group was fed on each diet for 60 days. At the end of each period the last 7 days were used to collect feed and feacal samples. However, the heifers were weighed each 15 days to estimate daily growth performances. It was found that significant (P < 0.05) differences among groups in average daily gain, feed conversion rate, feed intake and digestibility. The densification of WS and feeding in the form of feed block generally improved feed DM and nutrient intake and digestibility. The increase in the proportion of CM in the DCFBs also increased the DM and nutrient intake and digestibility. Heifer growth rate was higher (P < 0.05) in T1, T3 and T4 diets than T2 groups. Feed conversion ratio was higher (P < 0.05) both in T3 and T4 compared to T1 and T2. The total cost of production per each gram body weight gained was recorded higher (P < 0.05) for calves in the T2 group compared to calves in T1, T3 and T4. In conclusion, maintaining post weaned F1 heifer calves on DCFB composed of wheat straw and a commercial calf's concentrate based diet in the ratio of 40 to 60 would both biologically and economically feasible., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

Phosphate removal from water through green, highly efficient technologies has received much attention. Biochar is an effective adsorbent for phosphate removal. However, adsorption capacity of phosphate on pristine rice straw-based biochar was not optimistic due to low anion exchange capacity. In this study, Fe-modified, Mg-modified and MgFe-modified rice straw-based biochar (Fe-BC, Mg-BC and MgFe-BC) were prepared by combining metal impregnation and biological template methods to improve the adsorption capacity of phosphate. The surface characteristics of biochar and the adsorption behavior of phosphate on biochar were investigated. The modified biochar had the specific surface area of 17.910-39.336 m 2 /g, and their surfaces were rich in a large number of functional groups and metal oxides. Phosphate release was observed on pristine rice straw-based biochar without metal impregnation. The maximum adsorption capacities of phosphate on MgFe-BC, Mg-BC and Fe-BC at 298 K were 6.93, 5.75 and 0.23 mg/g, respectively. Adsorption was a spontaneous endothermic process, while chemical adsorption dominated and electrostatic attraction and pores filling existed simultaneously. Based on the site energy distribution theory study, the standard deviation of MgFe-BC decreased from 6.96 to 4.64 kJ/mol with temperature increasing, which proved that the higher the temperature would cause the lower heterogeneity. Moreover, the effects of pH, humic acid, co-existing ions and ionic strength on phosphate adsorption of MgFe-BC were also discussed. MgFe-BC with fine pores and efficient adsorption sites is an ideal adsorbent for phosphate removal from water., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Highlights Efficiency and mechanisms of Al(III) phytotoxicity mitigation by crop straw biochar varied with their feedstock growing regions. Liming was mainly responsible for mitigation in YBC and HBC. Oxyanion precipitation and pH-induced interactions predominantly governed mitigation in XBC and NBC.

The present study aimed to use poor quality roughages, such as rice and faba bean straw, treated with or without urea, and their impacts on digestibility, rumen fermentation, some blood parameters, and growth performance of lambs. Twenty crossbred male lambs ( 1 / 4  Finland ×¾ Ossimi, 25±1.13kg live body weight) were chosen and divided into four groups. All lambs were fed rations of concentrated feed mixture at 2% of live weight with the following roughages ad libitum: URS (control group, untreated rice straw), TRS (urea-treated rice straw), FBS (faba bean straw), and TRS+FBS (mixture of TRS and FBS, 1:1). Nutrient digestibility and feeding values improved (P<0.05) with TRS+FBS lambs versus FBS, TRS and URS lambs. The highest numerical values of ruminal total volatile fatty acid (VFA) concentration in TRS lambs were recorded 23.9 ml.eq/dl followed by TRS+FBS, URS and FBS. Regarding to the ruminal parameters, there were no differences (P>0.05) among evaluated groups except for NH 3 -N, the highest concentration (P<0.05) was recorded in TRS lambs at 3 h post-feeding. Lambs of TRS, FBS and TRS+FBS showed faster growth (P<0.05) than those of the control (i.e., URS). Intakes of dry matter, total digestible nutrients, and digestible crude protein were numerically increased for TRS, FBS, and TRS+FBS. Feed conversion, as kg dry matter/kg gain, was improved for TRS, FBS, and TRS+FBS lambs versus URS. Daily gain of lambs increased (P<0.05) with lambs of TRS, FBS, and TRS+FBS but URS lambs showed a decrease (P<0.05) in daily gain. Feed conversion as kg dry matter intake/kg gain was improved (P<0.05) by feeding on TRS, FBS and TRS+FBS rations versus URS. The TRS+FBS lambs tended to have the highest economic efficiency versus URS, TRS and FBS lambs. It was concluded that urea-treated rice straw could be used as sole roughage or mixed with faba bean straw (1:1) in growing lambs' ration to improve their performance and economic efficiency without adversely affecting their health.The present study aimed to use poor quality roughages, such as rice and faba bean straw, treated with or without urea, and their impacts on digestibility, rumen fermentation, some blood parameters, and growth performance of lambs. Twenty crossbred male lambs ( 1 / 4  Finland ×¾ Ossimi, 25±1.13kg live body weight) were chosen and divided into four groups. All lambs were fed rations of concentrated feed mixture at 2% of live weight with the following roughages ad libitum: URS (control group, untreated rice straw), TRS (urea-treated rice straw), FBS (faba bean straw), and TRS+FBS (mixture of TRS and FBS, 1:1). Nutrient digestibility and feeding values improved (P<0.05) with TRS+FBS lambs versus FBS, TRS and URS lambs. The highest numerical values of ruminal total volatile fatty acid (VFA) concentration in TRS lambs were recorded 23.9 ml.eq/dl followed by TRS+FBS, URS and FBS. Regarding to the ruminal parameters, there were no differences (P>0.05) among evaluated groups except for NH 3 -N, the highest concentration (P<0.05) was recorded in TRS lambs at 3 h post-feeding. Lambs of TRS, FBS and TRS+FBS showed faster growth (P<0.05) than those of the control (i.e., URS). Intakes of dry matter, total digestible nutrients, and digestible crude protein were numerically increased for TRS, FBS, and TRS+FBS. Feed conversion, as kg dry matter/kg gain, was improved for TRS, FBS, and TRS+FBS lambs versus URS. Daily gain of lambs increased (P<0.05) with lambs of TRS, FBS, and TRS+FBS but URS lambs showed a decrease (P<0.05) in daily gain. Feed conversion as kg dry matter intake/kg gain was improved (P<0.05) by feeding on TRS, FBS and TRS+FBS rations versus URS. The TRS+FBS lambs tended to have the highest economic efficiency versus URS, TRS and FBS lambs. It was concluded that urea-treated rice straw could be used as sole roughage or mixed with faba bean straw (1:1) in growing lambs' ration to improve their performance and economic efficiency without adversely affecting their health., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

Lactic acid (LA) production from sugar mixture derived from lignocellulosic rice straw employing co- culture system of thermotolerant and inhibitor tolerant Bacillus licheniformis DGB and Bacillus sonorenesis DGS15 was carried out. In minimal media, both the strains of Bacillus DGB and DGS15 worked together by efficiently utilising glucose and xylose respectively. Response Surface Methodology (RSM) was used for optimisation of pretreatment of rice straw to achieve maximum yield of 50.852 g/L total reducing sugar (TRS) from 100 gm of rice straw biomass. Pretreatment of rice straw resulted in its delignification, as confirmed by FTIR spectroscopy, since the peak at 1668 cm -1 disappeared due to removal of lignin and scanning electron microscopy (SEM) revealed disruption in structural and morphological features. Crystallinity index ( CrI) of treated rice straw increased by 15.54% in comparison to native biomass. DGB and DGS15 individually yielded 0.64 g/g and 0.82 g/g lactic acid respectively, where as their co-cultivation led to effective utilisation of both glucose and xylose within 15 h (70%) and complete utilisation in 48 h, producing 49.75 g/L LA with a yield of 0.98 g/g and productivity of 1.036 g/L/h, and resulting in reduction in fermentation time. Separate hydrolysis of rice straw and co-fermentation (SHCF) of hydrolysates by Bacillus spp. enhanced the production of lactic acid, can circumvent challenges in biorefining of lignocellulosic biomass., Competing Interests: Conflict of interestThe authors declare that there are no competing interests directly or indirectly related to the work submitted for the publication. The authors declare that there are no financial or non-financial interests that are directly or indirectly related to the work submitted for publication., (© King Abdulaziz City for Science and Technology 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.)

The potential of alkali-assist photocatalytic (AAP) pretreatment to overcome the recalcitrant nature of lignocellulose biomass, i.e. rice straw (RS), was investigated in the present study. Box-Behenken Design (BBD) using standard response surface methodology (RSM) approach was considered to obtain optimal conditions for maximum delignification. The model was designed with three variables: alkali concentration (NaOH, 0-3% w/v), photocatalyst (TiO 2 NPs (titania nanoparticles), 0-1 g/L) and pretreatment time (30-240 min). The availability of cellulose was increased by 96.73%, while the concentration of lignin and hemicellulose decreased by 73.89%, and 71.79%, respectively, at a combination of 1.5% NaOH, 0.5 g/L TiO 2 NPs and 135 min pretreatment time. The structural and morphological alterations in the RS were assessed via Fourier Transform Infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) both before and after AAP pretreatment. The FTIR measurement indicated that the original RS included a significant quantity of lignin, which was eliminated after the pretreatment procedure. The XRD pattern demonstrates that cellulose crystallinity is significantly affected by the pretreatment. The SEM analysis revealed structural distortion and surface porosity from the pretreatment procedure., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Soil amendment is an important strategy for improving soil quality and crop yield. From 2014 to 2019, we conducted a study to investigate the effects of tobacco straw return with lime on soil nutrients, soil microbial community structure, tobacco leaf yield, and quality in southern Anhui, China. A field experiment was conducted with four treatments: straw removed (CK), straw return (St), straw return with dolomite (St + D), and straw return with lime (St + L). Results showed that after 5 years of application, the St + L significantly increased the soil pH by 16.9%, and the contents of soil alkaline nitrogen (N) and available potassium (K) by 17.2% and 23.0%, respectively, compared with the CK. Moreover, the St + L significantly increased tobacco leaf yield (24.0%) and the appearance (9.1%) and sensory (5.9%) quality of flue-cured tobacco leaves. The addition of soil conditioners (straw, dolomite, and lime) increased both the total reads and effective sequences of soil microorganisms. Bacterial diversity was more sensitive to changes in the external environment compared to soil fungi. The application of soil amendments (lime and straw) promoted the growth of beneficial microorganisms in the soil. Additionally, bacterial species had greater competition and limited availability of resources for survival compared to fungi. The results showed that soil microorganisms were significantly influenced by the presence of AK, AN, and pH contents. These findings can provide an effective method for improving the quality of flue-cured tobacco leaves and guiding the amelioration of acidic soil in regions where tobacco-rice rotation is practiced., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Rice straw burning annually (millions of tons) leads to greenhouse gas emissions, and an alternative solution is producing humic acid with high added-value. This study aimed to examine the influence of a microbial consortium and other additives (chicken manure, urea, olive mill waste, zeolite, and biochar) on the composting process of rice straw and the subsequent production of humic acid. Results showed that among the fungal species, Thermoascus aurantiacus exhibited the most prominent impact in expediting maturation and improving compost quality, and Bacillus subtilis was the most abundant bacterial species based on metagenomics analysis. The highest temperature, C/N ratio reduction, and amount of humic acid production (Respectively in lab 61 °C, 54.67%, 298 g kg -1 and in pilot level 65 °C, 72.11%, 310 g kg -1 ) were related to treatments containing these microorganisms and other additives except urea. Consequently, T. aurantiacus and B. subtilis can be employed on an industrial scale as compost additives to further elevate quality. Functional analysis showed that the bacterial enzymes in the treatments had the highest metabolic activities, including carbohydrate and amino acid metabolism compared to the control. The maximum enzymatic activities were in the thermophilic phase in treatments which were significantly higher than that in the control. The research emphasizes the importance of identifying and incorporating enzymatically active strains that are suitable for temperature conditions, alongside the native strains in decomposing materials. This strategy significantly improves the composting process and yields high-quality humic acid during the thermophilic phase., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

Traditional pyrolysis biochar has been widely employed to treat dye wastewater. However, there are some problems in the pyrolysis process, such as the generation of harmful gases and the low content of silico-oxygen functional groups to promote adsorption. Straw biochar (Ac-BC bm ) was prepared by sulfuric acid co-ball milling method. The adsorption performance and adsorption mechanism of rhodamine B (RhB) under different preparation conditions and factors were investigated. The results showed that the adsorption rate of Ac-BC bm on RhB was up to 94.9%, which was 60.5% and 55.8% higher than that of ball-milling straw (ST bm ) and biochar prepared by pyrolysis (STBC600), respectively. The Ac-BC bm had better adaptability under different pH and common interfering ions for remove RhB. Characterization and DFT simulation analysis revealed that the sulfuric acid co-ball milling process promoted the formation of Si-OH and Si-O-CH 3 oxygen-containing functional groups of Si component in straw, which enhanced the hydrogen bonding interactions and effectively improved the adsorption efficiency. This study investigated a new strategy for biochar preparation by sulfuric acid co-ball milling, which provides an additional development direction for the efficient resource utilization of straw., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

In recent years, cadmium pollution in water environment has become an environmental problem that could not be ignored. As a porous carbon rich solid material, biochar is an environment-friendly new material because of its ultra-high adsorption capacity and strong chemical stability. In this study, rice straw biochar (RS-Biochar) was successfully prepared at different temperatures for removal of Cd(II) from aqueous solution. Through a series of characterization and adsorption experiments, the adsorption principle of Cd(II) by RS-Biochar was deeply studied. The results showed that RS-Biochar prepared at 600 °C (BioC600) has high specific surface area (232.6 m 2 /g) and shows high Cd(II) removal rate of 91.23% with the maximum Cd(II) adsorption capacity of 8.62 mg/g. The Langmuir model fit well to describe the adsorption process of Cd(II) on the BioC600. The mechanism analysis showed that hydroxyl and carboxyl groups on the biochar surface were concerned in the removal of Cd(II). The formation of CdCO 3 in the adsorption process was also be proven. Importantly, RS-Biochar could be conveniently produced with needed scale, displaying a promising approach for remediating Cd(II)-contaminated water environment and a huge application potential., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

A thermal synthesis method was employed in this work to prepare CdS/TiO 2 corn straw biochar photocatalytic composite materials suitable for synergistic hydrogen production with the photocatalytic reduction of CO 2 . The structure and synergistic reaction of these composite materials were characterized by its photogenerated electron transfer process. Compared with pure TiO 2 , the energy band gap of the optimal CdS/TiO 2 corn straw biochar composite material was reduced to 2.89 eV. The heterostructure coupling between TiO 2 and CdS in the biochar accelerated the transfer of photogenerated electrons and reduced the recombination rate of photogenerated electrons and holes. Under visible light irradiation, the photocatalytic H 2 yield of this CdS/TiO 2 corn straw-derived biochar composite material was 1200 µmol·h -1 ·g -1 , the CO yield was 150 µmol·h -1 ·g -1 , and the CH 4 yield was 55 µmol·h -1 ·g -1 . The key to this synergistic reaction is the formation of heterojunctions between CdS and TiO 2 as well as the rapid oxidation of holes in the composite material caused by the doping of biochar., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

The lignocellulolytic accessory enzyme, Feruloyl esterase C (FE&#95;5DR), encoded in the genome of thermotolerant Myceliophthora verrucosa was successfully cloned and heterologously expressed in Pichia pastoris . The expressed FE&#95;5DR was purified using UNOsphere™ Q anion exchange chromatography column, exhibiting a homogeneous band of ~ 39 kDa. Its optimum temperature was determined to be 60 °C, with an optimal pH of 6.0. Additionally, the enzyme activity of FE&#95;5DR was significantly enhanced by preincubation in a buffer containing Mg 2+ , Cu 2+ and Ca 2 metal ions. Enzyme kinetic parameters, computed from double reciprocal Lineweaver-Burk plots, yielded observed V max and K m values of 0.758 U/mg and 0.439 mM, respectively. Furthermore, the potential of custom-made cocktails comprising FE&#95;5DR and benchmark cellulase derived from the developed mutant strain of Aspergillus allahabadii MAN 40, as well as the biorefinery-relevant lignocellulolytic enzyme Cellic CTec 3, resulted in improved saccharification of unwashed acid pretreated (UWAP) rice straw slurry and mild alkali deacetylated (MAD) rice straw when compared to benchmark MAN 40 and Cellic CTec 3., Supplementary Information: The online version contains supplementary material available at 10.1007/s13205-024-04013-7., Competing Interests: Conflict of interestIt is declared that no competing interest among all the authors exists., (© King Abdulaziz City for Science and Technology 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.)

In this work, the corn straw (CS) with concentrations of 3%, 6%, and 9% (w/v) were pretreated by rumen fluid (RF) and then used for batched mesophilic biogas production. The results showed that after a 6-day pretreatment, volatile fatty acid (VFAs) production of 3.78, 8.27, and 10.4 g/L could be found in 3%, 6%, and 9%, respectively. When concerning with biogas production, the highest accumulative methane production of 149.1 mL CH 4 /g volatile solid was achieved by 6% pretreated CS, which was 22% and 45% higher than 3% and 9%, respectively. Also, it was 3.6 times higher than the same concentration of unpretreated CS. The results of the microbial community structure analysis revealed that the 6% CS pretreatment not only maintained a microbial community with the highest richness and diversity, but also exhibited the highest relative abundance of Firmicutes (45%) and Euryarchaeota (3.9%). This high abundance was conducive to its elevated production of VFAs and methane. These findings provide scientific reference for the utilization of CS and support the development of agricultural waste resource utilization and environmental protection., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

This study describes the extraction and characterization of the hemicellulosic autohydrolysates (HAHs) derived from rice straw (RS) and vascular aquatic weeds like Typha angustifolia (TA) and Ceretophyllum demersum (CD). It further explores their capacity to sustain the proliferation of selected lactic acid bacteria (i.e., prebiotic activity) isolated from milk samples. To fractionate HAH from RS, TA and CD hot water extraction (HWE) method was used and RS, TA, and CD biomasses yielded 6.8, 4.99 and 2.98% of HAH corresponding to the hemicellulose extraction efficiencies of 26.15 ± 0.8%, 23.76 ± 0.6%, and 18.62 ± 0.4% respectively. The chemical characterization of HAH concentrates through HPLC showed that they comprised galactose, arabinose, xylose and glucose. The total phenol content of the RS, TA and CD-derived HAH concentrates were 37.53, 56.78 and 48.08 mg GAE/g. The five lactic acid bacteria (LAB) isolates Q1B, Q2A, Q3B, G1C and G2B selected for prebiotic activity assays generated mixed responses with the highest growth in RS-HAH for Q2A and the least in TA-HAH for Q3B. Further, the isolates Q2A, Q3B, G1C, and G2B, which showed the highest growth performance, were identified through MALDI-TOF and 16S rRNA sequencing as Lactobacillus brevis. All the tested LAB isolates showed diauxic growth in crude HAH preparations to maximize the utilization of carbon resources for their proliferation. This suggests that the selected LAB isolates are efficient degraders of hemicellulosic sugars. This paves the way for the valorization of lignocellulosic biomass to produce prebiotic hemicellulosic autohydrolysate and consequently enhances environmental sustainability by improving resource efficiency., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

The impact of biogas residual biochar (BRB) on the humification and carbon balance process of co-composting of hog slurry (HGS) and wheat straw (WTS) was examined. The 50-day humification process was significantly enhanced by the addition of BRB, particular of 5% BRB, as indicated by the relatively higher humic acid content (67.28 g/kg) and humification ratio (2.31) than other treatments. The carbon balance calculation indicated that although BRB addition increased 22.16-46.77% of C lost in form of CO 2 -C, but the 5% BRB treatment showed relatively higher C fixation and lower C loss than other treatments. In addition, the BRB addition reshaped the bacterial community structure during composting, resulting in increased abundances of Proteobacteria (25.50%) during the thermophilic phase and Bacteroidetes (33.55%) during the maturation phase. Combined these results with biological mechanism analysis, 5% of BRB was likely an optimal addition for promoting compost humification and carbon fixation in practice., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

This article provides a comprehensive exploration of the imperative necessity for coupling the utilization of low-rank coal, sewage sludge, and straw. It studies the challenges and limitations of individual utilization methods, addressing the unique hurdles associated with feedstocks. It focused on achieving integrated and sustainable resource management, emphasizing efficient resource utilization, waste minimization, and environmental impact reduction. The investigation extends to the intricate details of reaction processes in co-processing, with a specific emphasis on the drying of raw materials to enhance combustion characteristics. The molding and preparation of feedstock are dissected, encompassing raw material selection, mixing, and the crucial addition of additives and binders. The proportions and homogenization of these feedstocks are intricately examined for uniformity and effectiveness. Furthermore, it presents theoretical approaches for investigating the co-combustion of these diverse feedstocks, contributing a solid foundation for future studies in this dynamic field. The findings presented in it offer valuable insights for researchers, practitioners, and policymakers seeking sustainable solutions in the co-disposal technology of these feedstocks. Therefore, it provides a holistic understanding of the challenges and opportunities in coupling the utilization of these selected feedstocks. By addressing individual limitations and emphasizing integrated resource management, the article establishes the groundwork for sustainable and efficient co-processing practices. The exploration of reaction processes gives a comprehensive framework for future research and application in the field of co-combustion technology. The insights gleaned from this study contribute significantly to advancing knowledge in the sustainable utilization of diverse feedstocks, guiding efforts towards environmentally responsible and resource-efficient practices., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

A field trial was performed to carry out an enhanced phytoremediation technique for multi-metal contaminated copper tailings by Sudan grass (Sorghum Sudanese), ryegrass (Lolium perenne L.), and Bermuda grass (Cynodon dactylon), using conditioner (TH-LZ01) and straw combination into composite amendments as soil amendments, aimed to obtain the maximum of phytoremediation effect. The results showed that compared with untreated herbaceous plants, the application of conditioner and straw planted with herbaceous plants reduced the pH and conductivity and increased the organic matter and water content of the copper tailings to different degrees. With the addition of conditioner and straw, the DTPA-Cd, DTPA-Cu, DTPA-Pb, and DTPA-Zn contents in the copper tailings showed a decreasing trend compared with the untreated group. The herbaceous plants were promoted to reduce the percentage contents of acid soluble fractions Cd, Cu, Pb, and Zn and to increase the percentage contents of reducible, oxidizable, and residual fractions heavy metals (Cd, Cu, Pb, and Zn) in the copper tailings to different degrees. The contents of Cd, Cu, Pb, and Zn in the underground part of herbaceous plants were higher than those in the aboveground part, and the contents of Cd, Cu, Pb, and Zn in the aboveground part and underground part decreased after adding conditioner and straw, which indicated that the conditioner and straw inhibited the transport of heavy metals in the plant. Furthermore, the principal component analysis showed that the application of conditioner and straw with planting ryegrass had more potential for improving the physicochemical properties of copper tailings and reducing heavy metal toxicity, followed by Bermuda grass and Sudan grass., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

This work conducted experimental combustion on a closed chamber using two different materials: mixture (1:1) sugarcane bagasse/straw and pre-treated biomass. The sampling method was an Andersen cascade impactor with eight stages. Tests were carried out on untreated biomass varying the velocities observed in the sampling duct (4.18; 5.20, 6.85, and 8.21 m.s -1 ). Pre-treated biomass tests were performed at 4.19 m.s -1 because in this condition there is a higher speed stability inside the duct. During the combustion tests, the concentration of emitted particles was higher for the lower speed range, with an order of 4.19 > 5.40 > 6.85 > 8.21 m.s -1 . The higher speeds observed inside the duct behaved as a dragging agent for particulate material. For the tests at the speed of 8.21 m.s -1 where the flow inside the duct was 0.088 m 3 s -1 , this behavior is more evident. Considering the fine diameter particles (< 2.5 µm), they were emitted in a higher concentration, due to the biomass combustion process, which results in higher emission of ultrafine particles. The emission factors (EFs) obtained for PM 10 for untreated biomass were in the range of 0.414 and 0.840. On the other hand, considering the pre-treated biomass, these factors were 0.70 and 1.51. The EFs of PM from the burning of the pre-treated biomass were higher when compared to untreated biomass, which is mainly due to the higher temperature of the process due to the higher HHV (higher heating value) of this material, caused by the removal of hemicellulose (4.71 times) and a proportional increase in lignin (1.52 times). Biomass combustion has the potential to partially replace fossil fuels in heat and energy generation. Nevertheless, more stringent and comprehensive legislation should be established to ensure that air quality is maintained. Furthermore, the emission factors obtained in this study might be useful as input data for air quality modeling in the context of sugarcane's burning biomass, thus, contributing to the generation of inventories that include emissions of this nature., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

This study investigated the effect of co-ensiled rice straw (RS) with whole sugar beet (SB) on lactating cows' performance. Ensiled rice straw (ERS) as control (CGS) was incorporated with immersed corn grains (CG) for 24 h, while the 2nd and 3rd ensiled RS (LSB and HSB) contained SB substituted of 50 and 100% of CG on an energy basis (total digestible nutrients, TDN), respectively. In the experimental diets, D1, D2, and D3, which include CGS, LSB, and HSB provided ad-libitum, respectively, while a concentrated feed mixture (2% of body weight) was offered. The population of lactic acid bacteria was slightly higher with fed HSB, relative to LSB and CGS. The OM, CP, EE, NFC, and TCH contents of CGS were slightly higher than LSB and HSB, while the opposite happened with the aNDFom, and ADFom contents. The digestibility of DM, OM, aNDFom, and ADFom of the D3 group was higher (P < 0.05) than in D1 and D2. The D3 recorded the highest values (P < 0.05) of silage consumption, and palatability. Milk production, fat-corrected milk (FCM), and energy-corrected milk (ECM) were (P < 0.05) higher for cows fed D3 compared with D1 and D2. Fat, protein, lactose, and total solids were trending on the same track. The feed conversion ratio (FCR) of cows fed diet D3 was better than cows fed D1 diet. The level of glucose in the blood increased (P < 0.05) significantly with feeding on HSB than LSB, which was significantly (P < 0.05) higher compared to CGS. In conclusion, co-ensiling of RS with the whole SB plant consider a good method to improve its nutritional value., (© 2024. The Author(s).)

Globally, more than 5 billion tons of crop residue (mainly rice straw) are produced yearly, and their management results in pollution, which kills microbes and limits soil nutrient recycling. Therefore, on-farm management that boosts degradation speed will improve the practicability of crop residue retention practices. The present study evaluated the 21 microbial isolates ( Pseudomonas, Bacillus , Aspergillus, Trichoderma, Fusarium, and Rhizopus ) from the soil of different agroclimatic zones obtained from rice fields for in situ straw degradation. The microbial diversity of these isolates was analyzed using 16 s rRNA and 18 s rRNA primers from various soil samples. The rice straw was used for degradation from isolated pathogens individually and in combination, and the results were analyzed using FTIR (Fourier transform infrared spectroscopy). The result suggested that the straw's degradation was the maximum with Trichoderma and Aspergillus, followed by the mixture of the isolates ( Pseudomonas, Bacillus , Aspergillus, Trichoderma, Fusarium, and Rhizopus ). Furthermore, SEM (scanning electron microscope) observed the degradation rate on different days of inoculation (7, 14, 28, 56, 70, and 100 DAI). The results showed that 90 DAI caused the highest degradation of rice straw. Therefore, Trichoderma containing microbial consortia could be used for vermicompost production from rice straw in field conditions, and it could increase crop productivity. Overall, our study added knowledge in rice straw management through a microbial consortium for better utilization in predominantly rice-growing countries., Supplementary Information: The online version contains supplementary material available at 10.1007/s13205-024-03982-z., Competing Interests: Conflict of interestsOn behalf of all authors, the corresponding author states that there is no conflict of interest., (© King Abdulaziz City for Science and Technology 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.)

Anaerobic digestion is one of the best options for producing valuable end products (biogas and biofertilizer). The aim of this study was to investigate the influences of thermoalkaline pretreatment of wheat straw on biogas production and digestate characteristics from codigestion with waste-activated sludge. Different alkaline conditions (NaOH, KOH and Na 2 CO 3 ) and pretreatment durations (1, 3 and 5 h) were used for straw pretreatment. Batch anaerobic codigestion of sludge and pretreated straw was conducted under different pretreatment conditions. A feedforward neural network (FFNN) model, logistic model and statistical analysis were applied to the experimental data to predict biogas and investigate the significance and relationships among the variables. NaOH pretreatment for 5 h showed the best treatment conditions: biogas yield was 6.59 times higher than that without treatment. Moreover, the proportions of total solids, total volatile solids, chemical oxygen demand and microbial count removed reached 63.52%, 74.60%, 78.15% and 82.22%, respectively. The methane content was 67.50%, indicating that the biogas had a high quality. The thermoalkaline pretreatment significantly affected biogas production and digestate characteristics, allowing it to be used as a biofertilizer. Experimental data were successfully modelled for predicting biogas production using the applied models. The R 2 values reached 0.985 and 0.999 for the logistic and FFNN models, respectively., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Shaanxi Province is an important agricultural province in western China. Its profit-oriented management of crop residues remains a concern in the agriculture sector. Aiming to accelerate the valorization of agricultural straw and offer potential solutions for profit-oriented use of crop residues in Shaanxi, this study estimated the quantity of resources and collectable amount of crop straw by using the grain-to-straw ratio, analyzed the carbon emission reduction potential considering biochar energy and soil uses with the help of a life cycle assessment (LCA) model, and calculated the economic benefits of biochar production using waste and abandoned straw in Weinan (a city of Shaanxi). The theoretical resources and collectible amount of crop straw in Shaanxi showed an overall growth trend from 1949 to 2021, reaching 1.47 × 10 7 and 1.26 × 10 7  t in 2021 respectively. In 2021, straw from corn, wheat, and other grains accounted for 94.32% of the total straw. Among the 11 cities in Shaanxi, Weinan had the largest straw resources of 2.82 × 10 6  t, Yulin had the largest per capita straw resources of 0.72 t/person, and Yangling had the highest resource density of 7.60 t/hm 2 . The total carbon emission reduction was 3.11 × 10 4  t under scenario A with crop straw used for power generation. The emission reduction ranged from 1.25 × 10 7 to 1.27 × 10 7 CO 2e t under scenario B with biochar production for energy and soil use. By using waste and abandoned straw in Weinan for biochar production, carbon emissions could be reduced by up to 2.07 × 10 5  t CO 2e . In terms of the economic benefit from straw pyrolysis, the actual income was estimated to range from 0.67 × 10 8 to 1.33 × 10 8 ¥/a with different carbon prices. This study sheds light on the economic and environmental benefits of agricultural straw valorization through pyrolysis in Shaanxi, and provided an important basis for promoting the agricultural straw utilization in view of its potential for carbon emission reduction., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

In this work, chili straw (CS) was pretreated by microwave at 250 W, 406 W, 567 W, and 700 W. The pyrolysis characteristics, kinetics, thermodynamic parameters, and solid reaction mechanism were investigated. The maximum weight loss rate increases from  - 24.72%/°C at P0 to  - 28.01%/°C at P700 after microwave pretreatment, and the residual mass decreases from 31.81 at P0 to 26.71% at P700. In addition, microwave pretreatment leads to a decrease in activation energy, ∆H, and ∆G at the end of the pyrolysis (α > 0.7). The solid reaction mechanism of CS pyrolysis is revealed by the Z-master plots method, with un-pretreated CS conforming to P2, D4, F3/2, and F3, respectively. Microwave pretreatment changes the solid reaction mechanism mainly in the third stage, when α = 0.8, the mechanism function changes from f(α) = (1 - α) 3 at P0 to f(α) = (1 - α) at P700, and the number of reaction order is reduced, which is profitable for CS pyrolysis., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Biomass briquetting is a viable densification technique that converts waste biomass materials into useful products and alternative energy. This work explores the characteristics and optimization of hybrid bio-briquette production by combining crop residues (paddy straw) and solid biomass materials (sawdust and sugarcane bagasse). A total number of 20 briquettes were fabricated with three input factors: sawdust (SD), sugarcane bagasse (SB), and paddy straw (PS) based on the faced-centered central composite design (FCCCD) approach in the laboratory to investigate the calorific value (CV) and ash content (AC). The bomb calorimeter technique was used to evaluate the briquette's calorific value and ash content. The proposed work focused on optimizing the briquette input parameters (SD, SB, and PS) and output responses (CV and AC) using analysis of variance (ANOVA) and response surface methodology (RSM) and hybrid artificial neural network-integrated with multi-objective genetic algorithms (ANN-MOGA). This study shows that the MOGA-ANN-based model results in the best value of CV (17.07 MJ/kg) and AC (1.95%) with optimal input parameters SD (39.99 g), SB (29.02 g), and PS (69.02 g). The optimal results observed from the MOGA-ANN model have also been validated experimentally. The Fourier transform infrared (FTIR) spectroscopy investigation reveals that biomass briquettes are the sustainable and environment-friendly option of fossil fuels for power generation and indoor cooking. The study suggests a strategy for minimizing agro-waste, which may be converted into future fuel in the form of briquettes., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

This study investigates the potential of using sewage sludge and low-rank coal for the sustainable production of sulfuric acid, which can then be used for the hydrolysis of straw through ASPEN PLUS simulation. Pyrolysis and gasification processes were used to convert sewage sludge and low-rank coal into syngas, which were then purified and oxidized to produce H 2 SO 4 and NH 3 gas. The pyro-gasification enhanced syngas yield. The effects of key process parameters such as temperature, steam-to-biomass ratio, equivalence ratio, and feedstock composition on the yield and composition of syngas and H 2 SO 4 coupled with minor parameters like pressure were investigated. The simulation was conducted over the temperature and pressure range of 400 - 900°°C and 70 - 150 kPa respectively. While the steam-to-biomass ratio and equivalence ratio were respectively varied from 0.66 - 1.65 and 0.14 - 0.35. Part of the 1012.88 kg/h of H 2 SO 4 produced was used to hydrolyze straw, producing glucose as a valuable feedstock for biorefineries. About 3989.10 kg/h of NH 3 was produced. Results showed that the use of sewage sludge and low-rank coal as feedstocks for syngas production can be a sustainable and cost-effective alternative to traditional fossil fuels. The resulting H 2 SO 4 can also be used for various other applications, such as in the production of fertilizers and detergents. Overall, this study agrees with the literature, demonstrates the potential of integrating biomass and waste resources for the sustainable production of high-value chemicals and fuels, and contributes to the field of sustainable chemical and energy production while addressing environmental and economic considerations., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Farmland has become a significant contributor to greenhouse gas (GHG) emissions, and research has shown that the addition of straw or biochar may be a viable method for mitigating these emissions. However, there is a lack of understanding regarding the comparative biotic and abiotic effects of straw and biochar amendments on GHG emissions. To address this knowledge gap, we conducted a meta-analysis of 100 published papers to quantify the impact of straw and biochar application on GHG emissions. Our findings indicate that straw application significantly increased CO 2 and CH 4 emissions from agricultural ecosystems by 46.2% and 113.5%, respectively, but did not have a significant effect on N 2 O emissions. Conversely, biochar amendment significantly reduced CO 2 , CH 4 , and N 2 O emissions by an average of 11.0%, 31.7%, and 22.8%, respectively. We also found that straw and biochar amendments increased soil pH, soil organic carbon (SOC), and C/N ratio, and there were significant differences between them. Moreover, straw application significantly increased the microbial biomass carbon (MBC) content and microbial quotient by 37.1% and 20.1%, respectively, while biochar application increased the MBC content by 25.0% without a significant effect on the microbial quotient. Furthermore, both straw and biochar applications promoted the nitrification process and increased the abundance of ammonia-oxidizing bacteria (AOB) by 50.7% with straw and by 57.5% and 75.1% with biochar for ammonia-oxidizing archaea (AOA) and AOB, respectively. The denitrification process was also stimulated by straw or biochar amendment, resulting in an increase in the abundance of nirK by 22.9% and 16.8%, respectively. Biochar amendment additionally increased the abundance of nosZ by 29.4%, indicating that the main reason for reducing N 2 O emissions through biochar application is the conversion of NO 3 - . Thus, compared to straw application, biochar application is a more effective method for reducing greenhouse gas emissions.2 . Thus, compared to straw application, biochar application is a more effective method for reducing greenhouse gas emissions., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

The development of sustainable and renewable energy production is in high demand, and bioenergy production via microbial digestion of organic wastes is in prime focus. Biogas produced from the microbial digestion of organic waste is the most promising among existing biofuel options. In this context, biogas production from lignocellulosic biomass is one of the most viable and promising technologies for sustainable biofuel production. In the present review, an assessment and feasibility advancement have been presented towards the sustainable production of biogas from rice straw waste. Rice straw (RS) is abundantly available, contains a high composition of cellulose, and is found under the category of lignocellulosic waste, but it may cause severe environmental issues if not treated. Whereas, due to its high cellulose and inorganic content, lower cost, and huge availability, this waste can be effectively valorized into biogas production at a lower cost on a commercial scale. Therefore, the present review provides existing insight in this area by focusing on the operational parameter's improvement and advancement in the research for the expansion of mass-scale production at a lower cost. Thus, the presented review analyzed the processing parameters status, associated challenges, and positive endnote solutions for more sustainable viability for biogas production., (© 2023. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.)

Co-combustion of coal and biomass has the potential to reduce the cost of power generation in plants. However, because of the high content of the alkali metal of biomass ash, co-combustion of these two fuels leads to unpredictable ash fusion temperature (AFT). This study conducted experiments to measure the AFT of straw, sludge, and herb residue when they were blended with coal at different ratios. Additionally, a machine learning algorithm called tuna swarm optimization (TSO) was employed to optimize the support vector regression (SVR) model to predict the softening temperature (ST) of samples. The results indicate that straw and sludge were found to be suitable for blending in small proportions, while herb residue was suitable for blending in larger proportions. In comparison to the traditional grid search optimization model, the TSO algorithm significantly enhances the prediction accuracy of both training and test sets, and improves the generalization ability of SVR., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

In the last few decades, U(VI) is a significant environmental threat. The innovative and environmentally friendly adsorbent materials for U(VI) removal were urgent. Preparation of the modified biochar from wheat straw by combined composites of MnFe 2 O 4 nanoparticles and chitosan Schiff base (MnFe 2 O 4 @CsSB/BC) was characterized, and adsorption experiments were carried out to investigate the performance and interfacial mechanism of U(VI) removal. The results showed that MnFe 2 O 4 @CsSB/BC exhibited high adsorption capacity of U(VI) compared with BC. The adsorption process of U(VI) removal by MnFe 2 O 4 @CsSB/BC could be ascribed as pseudo-second-order model and Langmuir model. The maximum adsorption capacity of U(VI) removal by MnFe 2 O 4 @CsSB/BC reached 19.57 mg/g at pH4.0, 30 mg/L of U(VI), and 25 °C. The possible mechanism was a chemical adsorption process, and it mainly contained electrostatic attraction and surface complexation. Additionally, it also was an economic and environmental friendly adsorbent., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

2,4,6-Trinitrotoluene (TNT) production processes generate a substantial amount of toxic wastewater. Therefore, it is crucial to identify efficient and sustainable methods for treating this wastewater. This paper explores the application of sustainable biomass-derived carbon produced from rice straw for the adsorption of 2,4,6-trinitrotoluene (TNT) red water. The rice straw-derived biochar (SBC) materials were synthesized by two-step reactions through hydrothermal carbonization and chemical activation with KOH. Characterization of the fabricated biochar was conducted using various techniques. Here, the chemical oxygen demand (COD) was used as an evaluation index for adsorption efficiency. The adsorption kinetics showed a good fit with the pseudo-second-order model, and the adsorption equilibrium was achieved in 30 min. The biochar's high surface area (1319 m 2 /g) and large pore volume (1.058 cm 3 /g) gave it a large adsorption capacity. The Langmuir model exhibited better correlation for equilibrium data analysis, with a maximum adsorption capacity of 173.9 mg/g at 298 K. The SBC was found to have a high removal effect over a wide pH range (from 1 to 13) and showed remarkable stability after undergoing five desorption-adsorption cycles using ethanol and acetone as eluent. The results provide a simple and low-cost method for the efficient treatment of TNT red water., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

A new plastic ban has banned the use of single-use non-degradable plastic drinking straws in China's food and beverage industry by the end of 2020. However, this has caused widespread discussion and complaints on social media. What are consumers' reactions and what factors influence consumers to choose bio-straws (substitutes for plastic straws) are unclear. Therefore, this research collected 4367 effective comments (177,832 words in total) on "bio-straws" from social media and extracted keywords based on grounded theory to generate questionnaires. Structural equation modeling was used to analyze the consumption intention and influencing factors of 348 consumers regarding the ban. The results indicate the following: (1) consumer opinion on straws can be summarized into five main categories, namely, consumers' user experience, consumer subjectivity, policy awareness, policy acceptance, and consumption intention; (2) consumer subjectivity, policy awareness, and policy acceptance directly affect consumption intention significantly, while user experience affects consumption intention indirectly; and (3) user experience and consumer subjectivity play significant roles in mediating these relationships. From the perspective of consumers, this study provides an important basis for policymakers to formulate single-use plastic alternative policies in the future., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

The high value resource utilization of corn straw is a long-term problem at present and in the future. Biochar preparation is an important utilization way of corn straw. The research on city tail water treated by constructed wetland (CW) with biochar was carried out to further increase the wastewater treatment capacity of the CW. Surface characterization, structural characteristics, and adsorption of straw biochar modified by different acids were measured. The study found that the ability of H 2 SO 4 to remove ash from biochar was stronger than other acids and H 2 SO 4 -biochar was easy to be cleaned without H 2 SO 4 residue. The performance of biochar modified by H 2 SO 4 was obviously better than other acids, and the biochar adsorption was enhanced. The modification of biochar substrate modified by H 2 SO 4 in CW reduced the change of electrical conductivity (EC) and promoted denitrification. H 2 SO 4 -modified biochar promoted the absorption of N and P by Iris pseudacorus L. The compound modification effect of straw biochar was obvious. The results revealed the acid modification characteristics of straw biochar, which were beneficial for increasing the wastewater treatment rate by CW. This study will promote the sustainable development of CW., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Biochar amendment can benefit rice growth, but the long-term effects of rice straw carbonized utilization (RSCU, biochar, and biochar-based fertilizer) on rice production in cold areas are still unclear. Herein, we conducted a field experiment over 6 years with four treatments: F (conventional fertilization) as the control, RB1 (biochar, 3 t·ha -1 ), RB2 (biochar, 6 t·ha -1 ), and RBF (biochar-based fertilizer, 0.75 t·ha -1 ). We found that rice straw biochar significantly improved soil physical properties by reducing soil bulk density, increasing soil porosity and liquid and gas phases ratio, and enhancing soil aggregate stability. RSCU also increased soil fertility by improving soil organic carbon (SOC), active organic carbon, and soil nutrients (N, P, K) and their availability, as indicated by an increase in soil C:N and a decrease in soil N:P. Moreover, biochar increased soil microbial biomass carbon (MBC), microbial biomass nitrogen (MBN), and enzyme activities. As a result, RSCU increased rice yield, which was positively correlated with soil total porosity, total phosphorus, available potassium, dissolved organic carbon (DOC), easily oxidizable carbon (EOC), labile fraction of organic carbon (LFOC), and urease activity. RB2 had the highest rice yield (5.94% higher than F). Our study suggests that RSCU can synergistically improve the rice straw utilization rate, soil fertility, and rice productivity in cold areas., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)