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1. Green molecular transformation by a B(12)-TiO(2) hybrid catalyst as an alternative to tributyltin hydride.

Author

Shimakoshi H, Abiru M, Izumi S, and Hisaeda Y

Subjects
Catalysis, Ultraviolet Rays, Titanium chemistry, Trialkyltin Compounds chemistry, Vitamin B 12 chemistry
Abstract

The B(12)-TiO(2) hybrid catalyst was effectively used for the radical reactions, such as 1,2-migrations of phenyl groups and acyl groups under irradiation by UV light, and the selectivity of the reaction was controlled by the solvent system.

Published
2009
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