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Green molecular transformation by a B(12)-TiO(2) hybrid catalyst as an alternative to tributyltin hydride.

Authors :
Shimakoshi H
Abiru M
Izumi S
Hisaeda Y
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2009 Nov 14 (42), pp. 6427-9. Date of Electronic Publication: 2009 Sep 09.
Publication Year :
2009

Abstract

The B(12)-TiO(2) hybrid catalyst was effectively used for the radical reactions, such as 1,2-migrations of phenyl groups and acyl groups under irradiation by UV light, and the selectivity of the reaction was controlled by the solvent system.

Details

Language :
English
ISSN :
1364-548X
Issue :
42
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
19841798
Full Text :
https://doi.org/10.1039/b913255d