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We report on the study of heavy-ion-induced Si KL x-ray satellite spectra of several 3d, 4d and 5d silicides, with the aim of elucidating the trends in bonding properties of transition metal (TM) silicides. Measurements of the 43 MeV Ne3+-beam-induced Si KL spectra of elemental silicon and compound targets were performed at the Paul Scherrer Institute, Villigen, Switzerland, with a high-resolution von Hamos crystal spectrometer. The interpretation of the data was based on the importance of the effect of the solid and chemical environment on the KL x-ray satellite relative intensities due to the L-vacancy refilling by intra- and inter-atomic electron transitions. Within the framework of a statistical procedure for L-shell vacancy refilling the average L-shell rearrangement probability for each silicide was extracted so that calculated x-ray intensity distributions matched the experimental ones. The results are discussed in terms of the interplay of Si-Si, Si-TM and TM-TM bonding interactions in the studied TM silicides.

The influence of solid and chemical effects on photo-induced x-ray transitions from the valence states was investigated by means of high-resolution x-ray diffractometry. The study was devoted to metallic Mo and , and compounds. A significant enhancement of the emission rate of the 4d - 1s and 4d - 2s quadrupole-allowed transitions was found for the targets studied. The change of the transition probability is interpreted as being due to the mixing of the 4d states with p character orbitals. Further, the effect of exchange interaction between the 4p core level and the

The first experimental results of a high-resolution study of Th and U Lγ-X-rays induced in collisions with 230 MeV and 360 MeV oxygen ions, undertaken to investigate the dynamics of the multiple ionization in M-, N- and O-shells and the structure of M- and N-shell X-ray satellites, are reported. The measurements were performed using the transmission curved- crystal spectrometer installed in DuMond geometry. An instrumental resolution of about 10 eV was achieved for Lγ (L-N,O) X-ray transitions, allowing clear separation of M-shell X-ray satellites for Th and U. Moreover, the N-shell satellite structure in the Lγ6 (L2-O4) X-ray transition was observed for 360-MeV O ion impact on a thorium target. This, to our knowledge, is the first observation of this kind. Other observed Lγ X-ray diagram lines are shifted and widened, with respect to the photoinduced X-ray spectra excited by an X-ray tube, due to the unresolved N-shell and, probable the O-shell, satellite structure.

The Kβ X-ray spectrum of molybdenum bombarded by 28 MeV 4He ions was measured with a transmission curved crystal spectrometer. L and even M satellite lines were observed and resolved. Experimental energies are compared with those calculated with a MCDF program. Satisfactory agreement is found. Measuring the Kβ X-ray spectra with high resolution is a novel technique to also determine the M-shell ionization probability in central collisions. Comparison of the value obtained for Mo with theoretical (SCA) predictions demonstrates the importance of the recoil term.

We report on nonlinear interaction of solid Fe with intense femtosecond hard x-ray free-electron laser (XFEL) pulses. The experiment was performed at the CXI end-station of the Linac Coherent Light Source (LCLS) by means of high- resolution x-ray emission spectroscopy. The focused x-ray beam provided extreme fluence of ~105 photons/A2. Two-photon absorption leading to K-shell hollow atom formation and to single K-shell ionization of solid Fe was investigated.

High energy resolution off-resonant X-ray emission spectroscopy (HEROS) was applied to study one-photon (OPA) and two-photon absorption (TPA) processes in metallic copper generated by ultra-short hard X- ray FEL pulses from the Linac Coherent Light Source (LCLS). The OPA and TPA signals were measured using a multiple-crystal von Hamos diffraction spectrometer allowing observation of both the intermediate and final states in the TPA process. The universal scaling of TPA/OPA cross sections is discussed.

The observation of the enhancement of radiative recombination (RR) into the K-shell for U92+ ions interacting with cooling electrons in x-ray RR experiment performed at the ESR storage ring is reported. From the measured intensities of K-RR x-rays for the electron relative energies in the range 0-1000 meV a clear indication of the recombination enhancement, with respect of the fully relativistic RR calculations, was found for the K-shell for the zero relative electron energy. This results add new aspects to existing interpretations of the enhancement effect emphasizing a role of recombination into high Rydberg states.

The photon energy dependence of the double K-shell ionization cross sections for light atoms and He-like ions is reported. The K-shell double photoionization DPI cross-sections for hollow atom production are compared to those of the corresponding He-like counterparts. The relative contribution of the initial-state correlations and final-state electron-electron interactions to the K-shell DPI is addressed. A semiempirical universal scaling of the double photoionization cross sections with the effective nuclear charge for neutral atoms in the range 2 ≤ Z ≤ 47 is established.