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To identify a nanocomposite material capable of mitigating surface charge accumulation issues in silicone rubber composite insulators, this paper investigated the surface charge dissipation characteristics of micron-sized Al2O3/silicone rubber composites with different weight percentages under positive dc voltage. Furthermore, this paper investigated the influence of the uncharged and charged silicone rubber on the surface flashover voltage under positive dc voltage. The result show that the addition of micron-sized Al2O3 particles effectively ameliorates the severity of surface charge accumulation. In comparison to pure silicone rubber, the reduction in maximum surface charge density and average surface charge density of different weight percentage Al2O3/silicone rubber composites ranges from 18.60% to 50.60% and from 33.26% to 57.53%, respectively. When there is no surface charge on the silicone rubber surface, the addition of micron-sized Al2O3 particles at different weight percentages results in a decrease in positive dc surface flashover voltage. Conversely, when a positive surface charge is applied to the silicone rubber surface, the greatest reduction in positive dc surface flashover voltage occurs in pure silicone rubber. Furthermore, the positive DC flashover voltage of pure silicone rubber can recover to 86.53% of its value without applied surface charge at a decay time of 60 minutes. In contrast, the addition of micron-sized Al2O3 particles at different weight percentages diminishes the impact of surface charge on the surface flashover voltage, allowing it to recover to 92.03% to 94.18% of its value without applied surface charge.

Silicone rubber (SR) micro nanocomposites formed with micro-ATH and nano-alumina particles have been subjected to different levels of gamma-ray irradiation to understand the characteristic variation in the surface condition of the material through contact angle measurement, Atomic Force Microscopy (AFM) studies, water droplet-initiated corona inception voltage (CIV) measurement and by laser-induced breakdown spectroscopy (LIBS) analysis. It is realized that the recovery rate of silicone rubber micro nanocomposites is less compared with the base SR material. It is observed that, irrespective of the level of irradiation, the contact angle and water droplet initiated CIV of the specimen have shown direct correlation. FTIR analysis clearly indicates variation in methyl group formation on irradiation is less with S2 specimen. It is also observed that fractal dimension calculated by three different techniques for the surface profile data obtained using AFM is in directly in proportion with average surface roughness. In addition, the lacunarity values of the irradiated samples followed the same pattern as that of the average surface roughness. The variation in thermal degradation temperature has been analyzed by adopting thermogravimetric analysis (TGA). The calculated plasma temperature values from laser-induced breakdown spectroscopy and the crater depth formed due to laser ablation have shown inverse relationship. Artificial neural network (ANN) has been employed successfully using LIBS data, to understand the level of irradiation of the SR samples. Overall, the silicone rubber micro-nanocomposite sample S2 filled with micro-ATH and nano Alumina has reflected relatively lesser degradation after being exposed to gamma irradiation, over other test specimens.

Silicone rubber (SR) samples are coated with various types of artificially prepared pollutants, in order to identify and distinguish them by employing laser induced breakdown spectroscopy (LIBS). LIBS analysis is successful in identifying the elemental composition of the various types of pollutants. The presence of copper sulphate as well as carbon-based compounds such as fly ash, coal and calcium-based compounds such as cement and calcium phosphate (fertilizer) have been identified by the increment in the normalized intensity ratio of the copper, carbon and calcium peaks respectively. LIBS spectral data has been used in conjunction with several machine learning (ML) algorithms such as linear discriminant analysis, decision tree, K-nearest neighbors and various gradient boosting techniques to classify seven different types of contaminated SR samples. When compared to the other ML approaches utilized in the present study, classification using the Light gradient boosting technique has reflected better classification accuracy of 97.43% with a reasonable computation time of 5.1 s.

The evaluation of the state of transformer oil-immersed insulation based on the traditional methods becomes unreliable due to the nonuniform aging effect. To address this issue, a novel model for accessing the aging information of transformer oil-immersed insulation at the hotspot is proposed. In this article, frequency-domain spectroscopy (FDS) is selected as the carrier for characterizing the aging states of oil-immersed insulation. The multiobjective function for reversing the FDS of the hotspot is constructed based on the dielectric response equivalent circuit. Then, the nondominated sorting genetic algorithm with the multiconstraint scheme is proposed to solve the multiobjective function, by which the FDS data of the transformer hotspot region are acquired. The verification results indicate that the average standard deviation between the computed FDS of the hotspot region and the measured data is less than 0.26. The contribution of this article is in the exploration of the proposed model as a potential tool to extract the FDS data of the hotspot region. This will promote a more reliable aging evaluation of the transformer oil-immersed paper insulation at the hotspot. [ABSTRACT FROM AUTHOR]

Due to excellent anti-pollution performance, composite insulators have been widely used in transmission lines. However, composite insulators present various failures after long-term outdoor operation under environmental, mechanical, and electrical stress. This paper aims to investigate the mechanical deterioration of silicone rubber exposed to electrical stress in an acidic corrosive environment. This study examines the mechanical properties before and after experiments and uses physicochemical properties to analyze aging causes and mechanisms. The results are as follows: a) Subjected to electrical stress in acid mist, alumina tri-hydrate (ATH) decomposition and polydimethylsiloxane (PDMS) pyrolysis occur on the silicone rubber, and oxidative crosslinking reactions take place. The contents of highly oxidized silicon and oxygen increase, and carbon content decreases. The surface discharge aggravates the above progress. b) The electric field has no obvious effect on the penetration of nitric acid into silicone rubber. The surface discharge becomes intense with the increased energized voltage, resulting in decreased hydrophobicity and degraded surface properties. c) Mechanical properties of silicone rubber exposed to acid conditions continuously degrade. Physical crosslinking of the silicone rubber increases along with corrosion time and nitric acid concentration, increasing hardness, decreasing tensile strength, and elongation at break. This paper investigates the relationship between mechanical and physicochemical properties, and the results can provide references for studying the failure mechanism of silicone rubber in an acid corrosion environment.

In the present study, investigations have been carried out by choosing the nano-sized ATH (30–50 nm) particles as filler content in silicone rubber to acquire a deep insight to understand the use of nano ATH fillers in silicone rubber on its performance, to use it as insulation structure as an outdoor insulator. Variation in the surface condition of silicone rubber nanocomposites due to corona aging and the recovery characteristics analysis carried out through contact angle measurement. Nano ATH added in silicone rubber, up to 3 wt% of filler, shows increased dielectric constant with less loss factor. Water droplet-initiated discharges on silicone rubber nano ATH composites under DC voltage measured using UHF technique and the damage caused zone is analyzed through AFM studies and by surface potential measurement, which indicates higher surface roughness and increased charge trap depth. It is observed that negative DC voltage has higher CIV followed by positive DC and AC voltage. Laser Induced breakdown spectroscopy (LIBS) studies show a direct correlation between plasma temperature and material surface hardness. Also, on laser shining on the surface of the specimen, its temperature was measured on the backside of the specimen through thermal imaging confirming increased diffusivity of temperature. Laser flash analysis shows a direct correlation between filler content in base polymer and thermal conductivity and diffusivity. Higher storage modulus and activation energies measured from the dynamic mechanical analysis indicate the significance of prepared composites as an excellent mechanical support structure for the power system network.

Outdoor oil-filled cable terminations play an important role in power transmission and distribution networks, but their frequent explosions and disintegration accidents in cold environments pose great risks to the stable operation of power systems. In this study, an electric field-temperature multi-physical field simulation model was built based on 220 kV oil-filled cable termination. The dynamic solidification process of the insulating silicone oil was analyzed. It is found that the solidification of silicone oil is a temporal and spatial evolutionary process, which is closely related to the load current and the external environment. The solidification of filled and coated silicone oil will induce air gap defects, which will lead to different electric field distortion at different interfaces, especially at the stress cone/cable insulation interface. So the effects of different states of coated silicone oil on partial discharge at the interface are tested. Compared with the non-coating condition, solidification of coated silicone oil will aggravate partial discharge in cold environments, which is irreversible. The related results indicate the fault mechanism of oil-filled cable terminations subjected to cold environments and provide references for the selection of insulation materials and other measures to improve the reliability of cable terminations considering extreme environments. [ABSTRACT FROM AUTHOR]

This article investigates the filler barrier effect on suppressing the erosion of silicone rubber composites during the dc dry-band arcing, by supplementing main microfillers in silicon rubber, i.e., ground silica and micro-sized alumina trihydrate, with fumed silica and nano-sized alumina trihydrate fillers. A study framework employing simultaneous thermogravimetric-differential thermal analyses (TGA-DTAs), the inclined plane tracking and erosion test, and the dry-arc test is employed. Fumed silica in silicone rubber increases the amount of the crosslinked residue and suppresses silicone rubber depolymerization, whereas nano-sized alumina trihydrate releasing water of hydration may adversely impact the residue coherence and promote combustion. The viability of the filler barrier effect is synergistically achieved by adding fumed silica to the main ground silica filler, thereby maintaining the residue integrity. The inclined plane-tracking erosion test confirms the importance of the filler barrier effect of fumed silica in supplementing the volume effect of ground silica in the suppression of the dc dry-band arcing. These filler effects appear to mainly govern the erosion resistance, with insignificant effect shown for thermal conductivity under dc. The dry-arc resistance test is shown as a useful method to simulate a stable dry-band arcing and obtain reproducible surface erosion patterns that correlate with the outcomes of the dc inclined plane tracking and erosion test. [ABSTRACT FROM AUTHOR]

Silicone rubber (SR) is widely used in external insulation. However, the utilization of either high-temperature vulcanized (HTV) SR or liquid SR (LSR) remains controversial in China because of their differences in tracking and erosion resistance and aging resistance due to various amounts of nonreinforcing fillers. Here, the tracking and erosion behaviors of HTV and LSR during the inclined plane test (IPT) are captured and compared for a detailed comprehension of the difference between the two materials. The results revealed that LSR was easily carbonized and formed electrical tracks initially. Then, the carbonization slowed because of developing a protective ceramic layer. The relatively stable ceramic layer resulted in less frequent rapid erosion but increased the average arc burning time. An energy balance model of dry-band arcing (DBA) was established to evaluate DBA’s energy dissipation and absorption. Then, the emission spectra of DBA were collected to analyze the arc temperature and resistance more accurately. The energy input from the system is dissipated primarily through heating and evaporation of the liquid film, with radiant energy only accounting for a minuscule fraction. In different erosion states, the power absorbed by the surface of samples is different. LSR shows an average absorption power of 19.9 W in the initial carbonization state, which is higher than that of HTV (16.5 W). The average absorption power in the fast erosion state is the same for both samples at about 30 W. The absorption power at 20–25 W is considered the threshold range of relatively stable erosion. [ABSTRACT FROM AUTHOR]

Although the circulating flow of insulating oil can enhance heat dissipation in converter transformers, it can also influence the space charge distribution in oil–paper composite insulation. In this article, the oil–paper composite insulation between flat electrodes was used as the experimental model. Based on the pulsed electroacoustic (PEA) method, we investigated the effect of uncharged flowing oil on the space charge distribution in composite insulation under a dc electric field and polarity reversal. Under a dc electric field, as the oil flow velocity increased, the amount of interface charge between the oil and paper first increased and then decreased. During the polarity reversal process, the field distortion was aggravated at slower oil flows. These experimental results were explained in terms of the effect of oil flow on ionized charges in the oil. [ABSTRACT FROM AUTHOR]

The usage of polymeric insulators in transmission and distribution overhead lines for the last few decades has increased extensively. Silicone rubber (SiR) material is used enormously to make high voltage (HV) polymeric insulators. The SiR insulator provides insulation protection for overhead HV lines. The life span of the SiR insulators is shortened due to the aging effect. The progressive aging ultimately leads to the failure of the insulation system as well as the power supply. Therefore, a regular condition assessment of SiR insulators can help prevent the power system’s failures. A comprehensive study of the various types of aging processes of SiR insulators is reported in this article. Also, the comparative analysis of SiR insulators’ physical, chemical, and electrical properties under the influence of aging is reported here. The usefulness, limitation, and difficulties confronted in the existing methodologies are also reported in this article. This review article would be helpful to implement in future research for applying the HV overhead line insulator. [ABSTRACT FROM AUTHOR]

In order to provide further evidence for the improvement in tracking and erosion resistance of alumina trihydrate (ATH)-free silicone rubbers (SRs) by direct fluorination and to explore the improvement mechanisms, the ATH-free SR samples containing 15-parts per hundred parts of rubber by weight (phr) melamine cyanurate and 18-phr fumed silica were prepared, and then they were surface fluorinated using a $\text{F}_{{2}}/\text{N}_{{2}}$ mixture at 0.1 MPa and 85 °C for 120 min. Inclined plane tracking and erosion tests indicate that at 4.5-kV rms ac, all 15 fluorinated samples passed the test, while 7 of the 15 unfluorinated samples failed the test due to combustion. Analyses of erosion depth, length, and area show that the fluorinated sample, compared to the unfluorinated sample, has a larger average erosion depth but a smaller average erosion length or area. Attenuated total reflection infrared spectroscopy (ATR-IR) and X-ray photoelectron spectroscopy (XPS) analyses indicate that both the SR matrix and the fillers of melamine cyanurate and fumed silica in the surface layer were fluorinated, forming the Si–F, C–F, and N–F bonds. Scanning electron microscopy (SEM) observations show that the fluorinated layer has a thickness of $1.15~\mu \text{m}$ and a rough surface, and the fillers are uniformly dispersed in the matrix. The resistance improvement by the fluorination is attributed to these changes of the surface layer in composition, structure, and interface of the SR matrix and the fillers and is also influenced by the change in surface morphology. [ABSTRACT FROM AUTHOR]

Transformer oil and insulation paper are subject to the combined effects of the electric field and temperature operations, which significantly impact insulation deterioration. This article designs a comparative test of the electro-thermal combined aging to obtain several characteristic parameters for the aging degree of oil-pressboard insulation. Molecular dynamics are used to establish a mixed molecular model of oil-pressboard insulation to simulate the pyrolysis reactions at high temperatures using the ReaxFF force field. The microscopic effects of the electric field on the aging of oil-pressboard insulation are studied. The rationale of the simulation model is verified from experimental results, and the trend of the reactants and products in the reaction process was considered to determine the influence mechanism of electric–thermal coupling on oil-pressboard insulation. The experimental results show that thermal stress remains the most important factor toward cracking in insulation paper. The acid value and furfural formation rate in oil increase, and the polymerization degree of the insulation paper decreases rapidly after the combined electric and thermal aging. In addition, the molecular dynamics simulations show that pyrolysis increases the bond energy, promotes repulsion between atoms, and leads to fractured bonds. The addition of the electric field increases the susceptibility of the chemical bonds in cellulose molecules to breakage. The morphology of the cellulose chain then changes, and the diffusion of small molecules intensifies. This study reveals the mechanism of insulation aging under electro-thermal coupling through combined macroscopic testing and molecular dynamics simulations. [ABSTRACT FROM AUTHOR]

Due to rapid temperature rise and insulation moisture, bubbles can generate in the oil-paper insulation of oil-immersed power transformers, which can reduce the dielectric strength of oil-paper insulation and even bring about the risk of insulation breakdown. In order to accurately evaluate the conditions of bubble formation, the physical process of bubble formation in oil-paper insulation is studied in this article. Considering the effects of water vaporization, gas dissolution in oil, and moisture migration on bubble formation, a bubble formation prediction model is constructed. Based on Henry’s law, the dissolution equilibrium of gas in oil is taken into consideration and the upper boundary of the initial temperature of bubble effect (ITBE) envelope is obtained in this model. Based on the moisture equilibrium in oil-paper insulation, the bubble formation process caused by the emergence and rapid evaporation of free water is analyzed, and then, the lower boundary of the ITBE envelope is obtained in this model. The model results show that the moisture content of the pressboard and the presence of free water have a great impact on ITBE. Specifically, the higher the moisture content, the lower the ITBE value. In addition, with the further increase of moisture content, the upper and lower boundaries of the ITBE envelope gradually tend to be the same. However, once free water is present on the surface of cellulose, ITBE decreases rapidly to below 120 °C. The model built in this article is of great significance to study the temperature limit of the power transformer. Hence the ITBE envelope can provide an important theoretical reference for reducing the risk of bubble formation during power transformer operation. [ABSTRACT FROM AUTHOR]

In this article, silicone rubber (SiR) is filled with industry preferred micro-silica and specialty hexagonal boron nitride (h-BN) nanosheets, by varying the ratio between the two fillers, while keeping the filler to matrix ratio the same in all three composites. The fillers are added to SiR using an electrostatic disperser which aids in homogenizing the filler-polymer mixture by means of shearing force along with elongation. The performance of synthesized silicone composites are evaluated using thermal, erosion resistance, morphological, mechanical, and high-temperature dielectric properties. Addition of as low as 5 wt% h-BN fillers significantly improved the thermal properties; 6%–20% improvement in thermal conductivity and in less than half the weight loss compared to only silica filled composites with laser erosion. The morphological and mechanical analyses showed improved filler dispersion and filler to silicone matrix interaction owing to good filler dispersion achieved through the electrostatic dispersing method. The dielectric properties measured in wide frequency range, between 10−4 and 103 Hz and at elevated temperatures (up to 175 °C) showed a negligible effect of increase in h-BN content. Thus, this article implies that low amounts of h-BN in silica-silicone composites improve thermal conductivity and erosion resistance significantly and not altering the dielectric responses of these hybrid composites even at elevated temperatures. Hence these composites can find applications both in the high voltage industry and as electronic packaging materials. [ABSTRACT FROM AUTHOR]

High-frequency (HF) oil-immersed transformers with small size and light weight have been paid wide attention by researchers. Its oil–paper insulation frequently withstands HF over-voltages at frequencies of several kilohertz and above, resulting in the too early failure of oil–paper insulation. In order to investigate the effect of HF on oil–paper insulation, this article investigates the partial discharge (PD) characteristics of oil–paper insulation under HF stress. The experimental results show that a frequency-induced inflection point is existed near 10 kHz and the PD parameters of HF voltages is much higher than that ac voltages. Besides, the theoretical mechanism is expounded to interpret and understand the formation process of frequency-induced inflection points more easily. It can be found that the change in frequency causes the change in the charge decay time constant and the residual charge on the insulating surface, resulting in the formation of the frequency-induced inflection point at HF. These results might contribute to determine the characteristics of PDs between HF voltages and ac voltages. It can provide references for the research and production of HF transformers. [ABSTRACT FROM AUTHOR]

The intrusion of moisture may induce an abnormal increase in temperature or may even cause fractures in insulation equipment. Therefore, the hygroscopicity of rubber materials must be characterized. However, the existing methods for weighing organic polymer materials, such as silicone rubber, for moisture-absorption tests are time-consuming. In this article, a practical method for testing the moisture-absorption performance of silicone rubber materials for external insulation is proposed. The basic characteristics of the Langmuir diffusion equation for the water-absorption characteristics of silicone rubber are analyzed. A Langmuir curve fitting method based on the contraction–expansion (C–E) algorithm is developed, and its fitting effect is preliminarily verified by combining the experimental errors obtained from the experiment. Results show that the fitting effect has a strong relationship with the initial range of diffusion coefficient, bonding coefficient, and debonding coefficient. The time-consuming process of directly applying the fitting method is reduced from 70 to 50 days. The initial ranges of diffusion, bonding coefficient, and debonding coefficient are determined via the results of molecular simulations and experiments combined with an analysis of the literature. A prediction model is optimized and then validated against the experimental data from the recent literature on the water-absorption characteristics of silicone rubber at different temperatures. The experimental time required to reach saturated water absorption is remarkably reduced from 70 days to 1 day. Therefore, the method developed herein is feasible for engineering applications. Moreover, the entire water-absorption curve can be possibly plotted with an error of not greater than 5% via this prediction method. [ABSTRACT FROM AUTHOR]

Influence mechanism of side group types on the macroscopic electrical properties of silicone rubber (SiR) are analyzed based on the experimental comparison and the molecular simulation. The insulation properties of SiR with different side group types (vinyl, phenyl, and trifluoropropyl), as well as binary compound SiR (vinyl/phenyl and vinyl/trifluoropropyl) are compared and studied experimentally. Further, the effect of side groups on the movement of the molecular chain is analyzed by calculating the free volume, the mean square displacement (MSD), and the end distances. Then the mechanism of its influence on the macroscopic properties of SiR was studied. The experimental results indicated that the resistance and breakdown performance of the phenyl SiR surpasses both vinyl SiR and fluorosilicone rubber owing to the conjugated structure of benzene ring, which has a high electron affinity and reduces free charges and carrier migration rate. Besides, when 10wt% phenyl SiR was mixed into vinyl SiR, the resistivity increased by one order of magnitude, and the breakdown field strength increased by about 8%. In the aspect of dielectric properties, the fluorosilicone rubber is more qualified than the vinyl SiR and the phenyl SiR due to the addition of trifluoropropyl as a polar group to the non-polar dielectric SiR to boost its dielectric constant and dielectric loss. The molecular simulation results indicated that the SiR containing phenyl has a tiny free volume and weak molecular chain movement, the fluorosilicone rubber has the strongest molecular chain movement. The work has important guiding significance for improving and modifying SiR in power equipment. [ABSTRACT FROM AUTHOR]

Insulator leakage current is the primary root cause of pole fires; therefore, it is critical to recognize outdoor insulators as potential cause of wildfires. [ABSTRACT FROM AUTHOR]

The optically segmented single volume scatter camera (OS-SVSC) aims to image neutron sources for nuclear nonproliferation applications using the kinematic reconstruction of elastic double-scatter events. We report on the design, construction, and calibration of one module of a new prototype. The module includes 16 EJ-204 organic plastic scintillating bars individually wrapped in Teflon tape, each measuring $0.5 {\mathrm {cm}}\times 0.5 {\mathrm {cm}}\times 20 {\mathrm {cm}}$. The scintillator array is coupled to two custom silicon photomultiplier (SiPM) boards consisting of a $2\times 8$ array of SensL J-Series-60035 SiPMs, which are read out by a custom 16 channel DRS4 based digitizer board. The electrical crosstalk between SiPMs within the electronics chain is measured as $0.76\% \,\pm \,0.11\%$ among all 16 channels. We report the detector response of one module including interaction position, time, and energy, using two different optical coupling materials: EJ-560 silicone rubber optical coupling pads and EJ-550 optical coupling grease. We present results in terms of the overall mean and standard deviation of the $z$ -position reconstruction and interaction time resolutions for all 16 bars in the module. We observed the $1\sigma z$ -position resolution for gamma interactions in the 0.3–0.4 MeVee range to be 2.24 cm ± 1.10 cm and 1.45 cm ± 0.19 cm for silicone optical coupling pad and optical grease, respectively. The observed $1\sigma $ interaction time resolution is 265 ps ± 29 ps and 235 ps ± 10 ps for silicone optical coupling pad and optical grease, respectively. [ABSTRACT FROM AUTHOR]

Interfacial bonding is significant in determining the mechanical properties and dielectric loss of polymer composites. In this study, NH3 plasma treatment is used to reinforce the interfacial bonding between polyisophthaloyl metaphenylene diamine (PMTA) and the cellulose matrix. The mechanism of modification is investigated via x-ray photoelectron spectroscopy (XPS) and density functional theory (DFT). Additionally, molecular dynamics (MD) simulations are performed to explore the microscopic mechanism of the performance improvement of the composite insulation paper. The experimental results show that the mechanical property is improved and dielectric loss decreased to a certain extent after treatment. According to the results of XPS and DFT, the treatment introduces a polar group, −NH2, into the C18 position of PMTA. PMTA treated with NH3 plasma (T-PMTA) is conducive to form H-bonds with cellulose. It increases the interaction energy and strengthens the interfacial bonding, causing the T-PMTA molecules to penetrate wider and deeper on the cellulose surface. Thus, the mechanical properties are improved. Additionally, the improved interfacial bonding impedes the rotation and movement of molecules at the interface, which reduces the degree of freedom of the dipole steering and the resulting low dielectric loss. This study reveals the mechanism of NH3 plasma treatment and provides insights into the microscopic mechanism of the improvement of properties of composite insulation paper at the molecular level. [ABSTRACT FROM AUTHOR]

Improving the tracking and erosion resistance of silicone rubber (SiR) is of great significance to outdoor SiR insulators. In this work, a feasible method to enhance the antitracking performance of SiR by a ceramifiable system is investigated. Through scanning electron microscope (SEM), energy dispersive spectrometer (EDS), X-ray diffraction (XRD), and other characterization methods, the mechanism that aluminum hydroxide (ATH) and low-melting glass (LMG) powder synergistically improve the tracking resistance of SiR is proposed. In this ceramifiable system, ATH plays a role in absorbing heat and serves as a precursor under the synergy with LMG, which promotes the formulation of dense mullite ceramic layer on the surface of SiR at the high temperature generated by dry band arc discharges, thereby the internal SiR is protected from degradation. Hydrophobicity and mechanical properties of ATH/LMG/SiR composites are also investigated, revealing that ATH/LMG improves the mechanical properties and hydrophobicity compared with one filler filled with the same amount. The ceramifiable system exhibits a good effect that the antitracking performance, mechanical properties, and hydrophobicity of SiR composites are improved at the same time. This system provides a new method for the research of antitracking SiR materials applied in outdoor SiR insulators. [ABSTRACT FROM AUTHOR]

Timely identification of the aging stage of the transformer can effectively ensure the safe operation of the transformer and prevent the aging fault of the transformer. This work proposes the aging diagnosis of transformer using the Raman spectroscopic recurrence plot combined with learning vector quantization (LVQ) neural network. Oil-paper insulation samples at different aging stages are obtained by accelerated thermal aging tests. Acquisition of Raman spectra of insulating oil is from 800 to 3000 cm−1 and converts to the Raman spectroscopic recurrence plot. The gray-level cooccurrence matrix (GLCM) is used to extract the characteristic information of the Raman spectroscopic recurrence plot. The optimal number of neurons in competitive layer of LVQ neural network is determined by the experimental method. A transformer aging diagnosis model based on the Raman spectroscopic recurrence plot is established. The results show that the diagnostic accuracy of the proposed diagnostic model reached 95%. The Raman spectroscopic recurrence plot has more abundant aging “fingerprint” characteristic information and the proposed diagnostic method shows potential for monitoring oil-paper insulation. [ABSTRACT FROM AUTHOR]

The results of breakdown voltages in liquid silicone rubber (LSiR) insulation under stepped polarity reversal voltages at a uniform temperature in a needle-plane electrode system are presented in this article. In the presence of defects such as sharp conductor projections or protrusions in the cable insulation stressed under polarity reversal direct current (dc) voltages, the electric field distribution is far more complex due to nonlinear insulation conductivity and time-dependent field distribution. The electric field distribution and space-charge accumulation are intricate functions of factors such as geometry and nonlinear conduction. In this article, a two-dimensional (2-D) axisymmetric model of a needle-plane geometry is developed using the finite-element method to compute the time-dependent field, space charge, and current density distribution under polarity reversal dc, which apparently did not get much attention until now. Interesting results on the effect of polarity transition time and applied polarity time step on the abovementioned distributions are addressed and presented. The pronounced effects of nonlinear conductivity on the time-dependent field distribution are also demonstrated. Furthermore, from the breakdown experiments conducted on tip-plane electrode system for different tip radii and applied time steps, the results put forward a rational and practical estimate of the breakdown field using the proposed model. [ABSTRACT FROM AUTHOR]

In this article, space charge and partial discharge (PD) behavior and the breakdown strength of silicone rubber under ac and dc voltages are tested in high magnetic field. In the case of ac voltage, the effects of high magnetic field on promoting air gap breakdown result in the decrease in PD inception voltage. Polarization of specimens with higher speed and lower air gap breakdown voltage result in the increase in PD frequency and eventually causes the decrease in breakdown strength. In the case of dc voltage, energy level splitting due to Zeeman effects results in lower interface barrier, considering both the increase in electron affinity and the increase in density deference between donor-like and acceptor-like surface traps. The decrease in interface barrier causes more space charge injection. The electric field distortion caused by local space charge accumulation leads to the decrease in breakdown strength in high magnetic field. [ABSTRACT FROM AUTHOR]

The ecological environment is increasingly damaged due to the impact of mineral oil extraction and leakage. As a kind of sustainable resource, a vegetable oil transformer has bright application prospects in future. However, the stability of vegetable oil has always been a problem to be solved. In addition, the metallic copper inside the transformer has a certain catalytic effect on the deterioration of vegetable oil. In this article, a copper–oil–paper insulation model is established. Based on the molecular dynamics simulation method, the catalytic mechanism of copper on the deterioration of oil-paper insulation is revealed from the microscopic level. Then, the effects of temperature, contact area, and oxygen on the catalytic effect of copper are discussed. The results show that copper could accelerate the decomposition of oil-paper insulation by attracting H atoms and O atoms in oil-paper. The increase in temperature accelerates the progress of the catalytic reaction and aggravates the deterioration of oil-paper insulation. The oxygen concentration has an important influence on the catalytic reaction of copper. As the oxygen concentration increases, the catalytic effect of copper is weakened. The abovementioned research could provide some theoretical reference for further exploration of effective oil-paper insulation deterioration protection technology. [ABSTRACT FROM AUTHOR]

Despite the technical popularity of the dielectric response (DR) methods used for the nonintrusive diagnosis of the cellulose insulation condition, it is still considered a challenging and tough task so far to trustworthily interpret the details of the measurement results for further understanding and tracing the insulation changes behind. From a novel perspective of parametric study on the circuital DR equivalence of cellulosic insulation—extended Debye model (EDM), the new dielectric characteristic quantities and the quantification approach to determine the cellulosic moisture condition are investigated in the present study. First, a kind of tailor-made scale-down bushing model is prepared, with its cellulosic condenser body absorbing differently controlled quantities of water to simulate the dampness of real-life insulation, of which the frequency-domain spectroscopy (FDS) is measured under controlled temperatures. Then, the EDM is employed for a parameterized study on the FDS details with the moisture changes, by identifying the model parameters against the FDS curves, whereby the two time-domain dielectric spectra—polarization/depolarization current and return voltage—are transferred from the FDS so that a set of hybrid time–frequency characteristic quantities is proposed, which is revealed to be indicative of the dampness variations of cellulosic insulation. Finally, the principal component analysis and the feature recognition algorithm based on minimum distance are applied to determine the moisture content of the condenser body, which verifies the holistic effectiveness of the proposed method. [ABSTRACT FROM AUTHOR]

Corona discharges get accelerated at low air pressure conditions leading to severe aging of the polymeric housing material, eventually causing the failure of the insulator. In this article, the effect of ac corona on different silicone rubber (SiR) micro- and nanocomposite samples at low pressure is studied. Micro alumina trihydrate (ATH), nano-titanium dioxide (TiO2), and nano-silica are used as filler materials in varying concentrations. This article compares the filler materials for nanocomposite preparation based on their performance in low-pressure conditions. It is observed that the decrease in pressure results in increased corona discharges and loss of hydrophobicity in the samples. The formation of carboxylic acid is evident from the Fourier transform infrared spectroscopy (FTIR) for the treated samples. The performance of silica nanocomposite with 5 wt% loading is better than the silica nanocomposite with 3 wt% loading. Crack width, surface roughness, and physicochemical changes were significantly reduced in silicone dioxide filled SiR (SSR5%) when compared to other silica and TiO2-filled samples at low pressure. The SiR samples filled with 5 wt% nano-silica perform better in terms of resisting corona-induced degradation at low pressure. [ABSTRACT FROM AUTHOR]

Silicone rubber (SR) insulators have been coated with different concentrations of NaCl to study the contamination level adopting laser-induced breakdown spectroscopy (LIBS) analysis. An elemental study of LIBS spectral data has identified the sodium peaks, thereby indicating the presence of salt deposits. A regression coefficient is used for a better understanding of the direct correlation between the salt deposit density (SDD) and the normalized intensity ratio, at various standoff distances. A marginal decrement in the normalized intensity ratio of the sodium peaks has been noticed in the case of readings taken at morning and midday, compared to those taken at night at different SDD values and different energies of the laser pulse. With increase in SDD, the intensity distribution characteristics have a right shift on the intensity scale. The polluted SR specimens are successfully classified by employing artificial neural network technique. Overall, the LIBS method is successful in identifying the variations in the salt deposition on the surface of the insulator, even at far distances of 15 m and at any time of the day. [ABSTRACT FROM AUTHOR]

A simple, robust, compact, and highly sensitive temperature sensor based on silicone rubber-sealed non-adiabatic tapered fiber (SR-NATF) is proposed and demonstrated. By combining with the fast Fourier transform (FFT) method, an online Vernier reference interferometer (OVRI) is constructed to enhance the temperature sensitivity. The temperature sensitivity is −1.30 nm/°C for the single SR-NATF in the temperature range of 35 °C – 40 °C. After utilizing the FFT method and cascading an OVRI, the temperature sensitivity can obtain 6.26 nm/°C, which is 4.82 times as that of a single SR-NATF. The proposed sensor is robust, soft and easy-fabrication which can be applied in human body temperature detection. In addition, the proposed method is efficient and convenient for the construction of an online reference arm based on Vernier-amplified sensitivity. [ABSTRACT FROM AUTHOR]

In this article, a silicone rubber-based composite material is selected as the test sample, and a 100-h corona aging test is conducted under different environments using multiple pin-plate electrodes to study the corona discharge characteristics of pin-plate under different humidity, salt fog, and haze environments. The corona aging characteristics of silicone rubber material are analyzed by the static contact angle, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and nuclear magnetic resonance (NMR). The results show that, with the increase in the relative humidity (RH), the frequency and energy of corona discharge increase. The discharge frequency under a haze environment is small, but the number and amplitude of the positive half-cycle pulse are larger. With the increase in RH and the deterioration of the environment, the oxidation degree and hydrophobicity loss rate of the material surface are accelerated, and the material surface damage is also aggravated. The aging characteristics of silicone rubber have a positive correlation with the content of water molecules in the air, some hydrophilic -OH, and acidic -COOH appear on the material surface, leading to the insulation performance decrease. As the aging of silicone rubber deepens, its equivalent transverse relaxation time drop increases, the number of H atoms that become low bond energy state inside increases, and the resistance to corona aging decreases. The results of this article can provide some reference for the evaluation, diagnosis, and production of composite insulators in different regions. [ABSTRACT FROM AUTHOR]

To fully understand the distribution network cable accessories’ moisture fault, the variation in insulation parameters of the cable main insulation of cross-linked polyethylene (XLPE) and the cable accessory reinforced insulation of silicone rubber (SIR) under different moisture conditions are studied experimentally. Furthermore, the effects of typical moisture defect forms and moisture positions on electric field distributions are studied by establishing the interface defect model. The experimental results show that the insulation properties of XLPE after water immersion are more seriously reduced than SIR. The resistivity of XLPE and SIR specimens decreases significantly with the increase in moisture time, decreasing by 90.3% and 48.3% after 720 h, respectively. The relative dielectric constants of the two kinds of specimens increase with different degrees after moisture, increasing by 5.16% and 7.83%, respectively, and the breakdown strength decreases by 18.3% and 13.1% after 720 h, respectively. The simulated results show that the moisture form and position have a great influence on electric field distribution. The electric field distortion caused by water trees’ defect is the most serious, followed by water film defects and water droplet defects. Besides, for different types of moisture defects, the position of the maximum distortion electric field is different. [ABSTRACT FROM AUTHOR]

Studying the collision and rebound characteristics between particles and silicone rubber surfaces is the basis of establishing a scientific contamination deposition model for silicone rubber insulators. In this article, high-speed and microscopic imaging techniques are used to set up an experimental platform for tracking and filming the collision and rebound motion of micrometer particles. Key parameters in the semiempirical calculation formula of critical adhesion velocity and tangential and normal rebound coefficients of particles in the collision issue between particles and silicone rubber surface are also obtained in this article by the parameter optimization method based on experimental measurement results. In addition, a probability calculation model for tangent and normal rebound coefficients of particles is proposed based on the statistical analysis method. Findings show that the critical adhesion velocity of particles decreases with the increase of the particle diameter. Influenced by the roughness distribution of the silicone rubber surface, the tangent rebound coefficient and the ratio between the measurement results and the theoretical calculated values of normal rebound coefficients of particles in the oblique collisions obeys normal distributions. This article is valuable for studying the contamination mechanism of silicone rubber insulators. [ABSTRACT FROM AUTHOR]

In this research, the leakage current (LC) and applied voltage waveforms on samples of installed outdoor porcelain and silicone rubber (SIR) insulators were measured by using a storage digital oscilloscope concurrent with humidity, temperature, and illuminance measurements. Essentially, the measurements were conducted daily, every three hours, for thirty days, and the data were analyzed using exponential regressions, box plots, and correlation coefficients. The porcelain and SIR insulator leakage currents varied from 23.7 μA to 28.8 μA and 8.4 μA to 10.35 μA for median values, respectively, while for outlier excluded values, they varied from 20.3 μA to 40.0 μA and 5.1 μA to 17.1 μA, respectively. Both leakage currents slightly increased as the exposure duration of the insulator rose, while the ratio decreased very slightly. Additionally, the leakage currents decreased moderately and slightly as the temperature and illuminance increased, respectively. However, the parabolic leakage currents increased as the humidity rose, especially at high humidity. Therefore, the porcelain insulator was more susceptible than the daily SIR, while the SIR insulator was more highly influenced by aging of the exposure duration. The rainy condition contributed to the highest leakage currents on both insulators, whereas the drizzle condition contributed to the highest leakage current on the SIR insulator. The total harmonic distortion (THD) and phase angle of the porcelain insulator leakage currents experienced differences of 5.8% and 7.8 degrees in the minimum and maximum humidity, respectively, but both quantities were less for the SIR insulator.

Magneto-rheological elastomers (MREs) belong to the class of smart materials whose mechanical properties can be controlled by an external magnetic field. These materials can be integrated into mechatronic systems and submitted to multiple loadings such as temperature, mechanical stress, and magnetic field. Thus, this work is dedicated to the development of a magneto-mechanical bench and on first experimental characterizations of hard MREs taking multiphysics coupling into account. Regarding the mechanical loading, the experimental setup is able to create a uniaxial tensile stress in case of low strain (< 1%) without friction effect. In regards to the magnetic loading, a magnetic circuit made of a strong permanent magnet has been designed to impose a variable and a homogeneous magnetic field strength up to 41 kA/m. Experimental analysis has been performed on silicone rubber filled with 36%vol. of NdFeB particles. The purpose was first to investigate the evolution of the Young modulus with or without magnetic field. Results obtained from measurements show that the developed test bench is able to depict the mechanical behavior and phenomena linked to rubber-like material. [ABSTRACT FROM AUTHOR]

Compared with conventional porcelain bushings, polymeric ones are light and therefore possess improved seismic performance. They are also explosion proof with no scattering when broken and are highly stain resistant. In particular, the polymeric bushings coated with silicone rubber show good voltage resistance performance, even when covered with salt deposits. That is, by covering the surface with silicone rubber, the hydrophobic nature of the polymer bushing becomes excellent. This reduces the risk of the occurrence of surface arc discharges and flashovers. Therefore, as shown in Figure 1, the length of a typical polymer bushing insulated with pressurized SF6 can be reduced significantly compared with a conventional porcelain bushing insulated with oil-impregnated paper (OIP) of the same voltage class. The weight can be reduced drastically as well. [ABSTRACT FROM AUTHOR]

In this communication, the liquid metal alloy (LMA) is utilized to design a metasurface with switchable reflection phases, which serves as the superstrate of an antenna array to manipulate its scattering features. The proposed metasurface is composed of a silicone rubber etched with microfluidic channels. Hence, its electromagnetic properties can be controlled by the filling of LMA. Simulated results reveal that the injection of LMA shifts the phase of waves reflected from the proposed metasurface by 180° ranging from 8 to 32 GHz. Then, the proposed metasurface covers a slot antenna array to regulate its scattering characteristic. By arranging the filling of LMA with various configurations, the scattering pattern can be switched among four different states with a slight influence on its radiation performance. Fulfilling all microfluidic channels with air, the reference antenna has a normal scattering pattern like a metallic plate. Moreover, by switching the filling area of LMA, monostatic radar cross-section (RCS) reduction is realized in three of these four working states. Finally, we had processed and tested a demonstrated prototype of the slot antenna array along with the proposed metasurface superstrate. Measured results are consistent well with the simulation. An implication of this research is the possibility that manipulating the scattering features of an antenna array without influences on its radiation characteristics by employing LMA. [ABSTRACT FROM AUTHOR]

Exposure of insulating systems to strong electric field and other environmental stresses may cause loss of their desired properties. In high-voltage applications, phenomena, such as corona discharges and unexpected flashovers, may deteriorate the surface as well as bulk conditions of an insulating material and thereby affect its lifetime. In this article, several types of corona-exposed HTV-SiR/ethylene propylene diene monomer (EPDM) blends filled with different concentrations of nano-sized boron nitride and silicon carbide particles are evaluated and the induced modifications of their properties are presented and discussed. The diagnosis is based on measured data of surface partial discharge (PD) and volume current. For the latter, experiments were performed at different levels of electric field between 0.5 and 4 kV/mm and ambient temperature ranging from 22 °C to 70 °C. Results of the conducted experiments revealed the degradation of surface properties through an increase in the PD magnitude. It was also observed that corona aging of the samples decreases the threshold electric field particularly at elevated temperatures, above which space charge effect in the materials may become significant. Moreover, it was observed that the blend compositions loaded with nanofillers retard surface PD and bulk deterioration. [ABSTRACT FROM AUTHOR]

The viability of fillers for inhibiting the dry-band arcing damage on high temperature vulcanized silicone rubber under the critical AC and the equivalent DC voltages of inclined plane test is investigated. Alumina tri-hydrate and ground silica are employed in the study as common fillers employed in silicone rubber formulation for outdoor high voltage insulation, and thermal analysis is applied in order to understand the protective mechanisms of the fillers. Filler volume effect plays a role in improving the erosion performance, and the dilution effect of water of hydration is shown advantageous for preventing progressive (directed) erosion. Dilution effect promoted with internal oxidation is found only notable at 50 wt% alumina tri-hydrate in this study. On the other hand, alumina tri-hydrate at 10 or 30 wt% may yield a porous residue, which is conducive to thermo-oxidation (combustion) and consequently erosion. The erosion suppression effects reported for the fillers in the composites employed in this study are found less viable under the equivalent DC as compared to the critical AC voltages of the inclined plane test. This study clarifies common perceptions about the viability of fillers in silicone rubber for AC and DC outdoor insulation applications. [ABSTRACT FROM AUTHOR]

The Joule heat produced by the current in conductor decreases in the radial direction, producing a temperature gradient in the insulation. This existing temperature gradient can affect the electrical tree phenomenon in insulation materials because of the temperature dependence of insulation material, charge migration and tree growth. Different temperature gradients were obtained by controlling the temperature of high voltage (HV) and ground electrode (GD) sides. The electrical tree was recorded by a microscope, while the partial discharge (PD) was observed simultaneously. For better understanding the effects of the temperature gradient on electrical tree inception, the trap distribution in silicone rubber (SIR) with different temperature was analyzed by isothermal discharge current (IDC) method. With the fixed temperature in HV or GD side, it was found that the electrical tree inception voltage decreased linearly with increasing temperature in either side. The IDC results indicate that the increasing temperature contributes to the de-trapping of charges and lowers the inception voltage. Besides, the electrical tree length and accumulated damage gradually increase with the temperature gradient. The observed PD amplitude and quantity also increase with the temperature gradient, which facilitates the growth of electrical trees. These results indicate that the tree growth is promoted with an increase in the temperature gradient of the cable insulation, posing a threat to the safety of the cable system.

Thermal and structural properties of aged silicone rubber composite insulators widely used in high-voltage transmission power systems were characterized by photothermal radiometry (PTR) to evaluate the degree of aging. A two-layer PTR theoretical model was developed to extract the thermal diffusivity and the aged layer thickness from the PTR frequency-scan data. Results show that aging generated an aged layer with a reduced thermal diffusivity at the surface of the composite insulator. Further investigation into the depth dependence of the thermal diffusivity of aged composite insulators found a monotonically increasing thermal diffusivity along the depth direction, approximating to a hyperbolic tangential profile, which indicates a spatially continuous variation from surface to bulk during the aging process. The PTR depth-profiling of thermal and structural properties provides a deeper understanding of the aging process in composite insulators. [ABSTRACT FROM AUTHOR]

In this paper, the electrical tree growth characteristics of silicone rubber (SiR) are studied under impulse superimposed on DC voltage and a temperature gradient (TG) field. The temperature difference between high voltage (HV) and ground (GD) electrodes varies from -90 to 90 °C resulting in a TG field in the samples. The electrical tree morphology, length and accumulated damage are discussed. Experimental results show that with the increase of absolute value of TG, the electrical tree length and accumulated damage continue to increase, and the tree morphology turns from branch-like tree to bush-branch hybrid tree. The positive TG has a more obvious acceleration effect on the tree growth than does the negative TG. Under the TG, the temperature dependent carrier transport results in space charge accumulation and electric field distortion at low temperature side, which is the main reason for the different growth characteristics of electrical tree. Besides, the accumulated damage of DC superimposed with heteropolar impulse voltage is larger than that under DC superimposed with homopolar impulse voltage. It is concluded that the temperature gradient and impulse superimposed on DC voltage promote the electrical tree growth of HVDC cable accessories insulation. [ABSTRACT FROM AUTHOR]

This paper investigates the tracking and erosion of silicone rubber and EPDM insulation in the DC inclined plane tracking and erosion test. Silicone rubber filled with alumina tri-hydrate fails due to combustion in the gas phase or erosion paths, but with no evidence of tracking. EPDM fails due to tracking and surface capturing fire, from dry-band arcing leaving a black residue while impinging the surface. Carbonaceous residue on EPDM gives rise to leakage current magnitude, whereas fused silica-based residue on silicone rubber is shown to promote combustion. A high amount of alumina tri-hydrate replacing the polymeric fuel in the composite is shown as a primary factor preventing failure and changing the nature of the residue in the DC inclined plane tracking and erosion test. Depolymerization is the main degradation mechanism reported for silicone rubber and EPDM, with notable degrees of crosslinking reported only for silicone rubber. Crosslinking reduces the amount of silicone rubber undergoing depolymerization, thus, the amount of fuel prone to combustion is reported to promote a coherent residue shield against the eroding dry-band arcing. [ABSTRACT FROM AUTHOR]

Nanofillers are added to polymeric insulating materials in order to modify the electrical, mechanical and thermal properties. This study investigates silicone rubber filled with hydrophilic and hydrophobic silica nanoparticles with respect to their resistance to laser ablation and to arc discharges, as well as their mechanical properties. The laser ablation is performed with single femtosecond laser pulses at wavelengths of 520 nm and 1040 nm. This way, the influence of the nanoparticles on the ablation by laser pulses with defined energy is investigated. The energy absorbed in the ablated volume is determined by taking into account the absorption for various fluences above the ablation threshold. For the silica nanocomposites, the energy specific ablation volume (ESAV), i.e., the ablated volume per absorbed energy, is significantly reduced compared to the unfilled polymer. The reduction is more pronounced for hydrophilic nanoparticles than for hydrophobic nanoparticles. Furthermore, the resistance to arc discharges and the mechanical strength of the nanocomposites are higher compared to the unfilled polymer. In particular, for nanocomposites with different types of silica filler particles the resistance to laser ablation, expressed by the ESAV, the resistance to arc discharges and the mechanical strength, expressed by Shore A hardness and the Young's modulus, show a strong correlation. From this, it is concluded that the modifications of the material properties are caused by interactions between the polymer and the nanoparticle surface, i.e., an interphase. The different extent of this interphase becomes obvious in the different degrees of impact on various electrical and mechanical properties. [ABSTRACT FROM AUTHOR]

The timely treatment is the crucial element for the survival of patients with brain stroke. Thus, a fast, cost-effective, and portable device is needed for the early and on-the-spot diagnosis of stroke patients. A 3D electromagnetic head imaging system for rapid brain stroke diagnosis with a wearable and lightweight platform is presented. The platform comprises a custom-built flexible cap with a 24-element planar antenna array, and a flexible matching medium layer. The custom-built cap is made out of an engineered polymer-ceramic composite substrate of RTV silicone rubber and aluminum oxide (Al2O3) for enhanced dielectric properties and mechanical flexibility and robustness. The array is arranged into two elliptical rings that are entirely incorporated into the flexible cap. The employed antenna elements within the system are compact with low SAR values over the utilized frequency range of 0.9–2.5 GHz. Moreover, a flexible matching medium layer is introduced on the front of the apertures of the antenna array to enhance the impedance matching with the skin. The detection capability of the system is experimentally verified on 3D realistic head phantoms at multiple imaging scenarios and different types of strokes. The reconstructed 3D and 2D multi-slice images using the beamforming and polar sensitivity encoding (PSE) image processing algorithms indicate the applicability and potential of the system for onsite brain imaging. [ABSTRACT FROM AUTHOR]

Silicone rubber nanocomposites were prepared using 1, 3, 5, and 10 wt% of alumina nanofiller. Corona inception voltage (CIV) due to water droplets was measured using fluorescence technique, and it has decreased for alumina-added silicone rubber nanocomposites and with corona-aged samples. The effect of the corona discharges on the surface morphology characteristics of the nanocomposites was analyzed by measuring contact angle, surface profile measurement using atomic force microscopy (AFM), and characterized by adopting multiresolution signal decomposition (MRSD) technique. The addition of the alumina nanofiller suppressed the surface roughness for the corona-aged nanocomposites and 5-wt% sample observed to have the lowest surface roughness values. Recovery of the surface roughness caused by corona discharges was analyzed at different time intervals, and it was observed that alumina nanoparticle-added silicone rubber showed an incremental reduction in the roughness recovery rate. The laser-induced breakdown spectroscopy (LIBS) technique was adopted to analyze the nanocomposites after the corona aging, and further plasma temperature was evaluated at different recovery times. The addition of an alumina nanofiller increased the plasma temperature, and 5-wt% samples have the lowest plasma temperature recovery rate after corona aging. The analysis of the study indicates that the corona-aged silicone rubber specimen surface properties recover in 8 h of resting time period. [ABSTRACT FROM AUTHOR]

The interface between silicone rubber (SR) and fiber reinforced plastic (FRP) is a weak point in composite insulator, which is easy to be affected by moisture. However, the corresponding evaluation methods and detection means are not complete yet. Based on the newly proposed method for measuring the interface resistivity with a four-electrode system, the influence of liquid type, filler and coupling agent on the interface resistivity are studied in this paper. It is found that the interface resistivity reduced by 2–4 orders of magnitude after permeation by deionized water, saline and low concentration nitric acid, but the variation trend of interface resistivity is specific when permeated in high concentration of nitric acid solution (1 mol/L). The experimental results of samples with and without silicone coupling agent (SCA) are compared and it is found that the interface without silane coupling agent is easier to be penetrated by liquid, and the change of interface resistivity is more obvious. Besides, the influence of moisture-sensitive Alumina Tri-hydrate and SiO2 fillers, which could provide paths for water and hydrated ions to permeate, on interface resistivity are analyzed. The experimental results are of great significance for the selection of the appropriate formula system and the prevention of liquid penetration for composite insulators. [ABSTRACT FROM AUTHOR]

Using an experimental approach, the effectiveness of nonionic surfactant, Triton™-X-100 in dispersing nano Alumina in high temperature vulcanized silicone rubber are studied in detail. Nanocomposites are prepared in varying concentrations of 0, 0.01, 0.05, 0.2, 1, and 5 phr levels by weight of the surfactant. Evidence to moderate dispersion of nano Alumina for composites at 0.01 phr and 0.05 phr weight loadings is gained from SEM pictures. Structural changes observed for the composites in FTIR spectra are examined and peaks identified. Thermogravimetric analysis shows some improvement in thermal resistance. However, an adverse effect on properties, such as volume resistivity, surface resistivity and dissipation factor are observed even at low surfactant loadings. A plausible role of surfactant as a plasticizer is explained with respect to the results of tensile strength. From this work, it can be inferred that surfactant at 0.01 phr may be taken as an optimum loading concentration for a desirable level of electrical properties, without compromising on insulation characteristics of volume resistivity and dissipation factor. Nonetheless, utmost caution needs to be exercised while employing Triton™-X-100 in compositions prepared for insulation applications because of inadequacies in values of volume resistivity, surface resistivity, dissipation factor and dry arc resistance even at low loadings. [ABSTRACT FROM AUTHOR]

In this paper, graphene/silicone rubber (SiR) nanocomposites with filler contents of 0.001–0.005 wt% are prepared to improve electrical tree inhibiting ability under different temperature gradients. The electrical treeing test is performed under three temperature gradients by controlling the temperature of high voltage and ground sides. Experimental results indicate that the SiR sample with 0.003 wt% graphene presents the best performance on electrical tree resistance. The tree length and accumulated damage are both reduced with the increase of graphene content from 0 to 0.003 wt%, but increased with the further increase of filler content from 0.003 to 0.005 wt%. The tree outline tends to be circular in neat SiR under negative temperature gradient, while it is triangular under positive temperature gradient. However, the effect of temperature gradient is weakened when graphene exists. Based on quantum dot models, the role of graphene quantum wells (QWs) in the regulation of charge transport and electrical tree resistance in SiR is revealed. This research provides an effective method to suppress electrical trees of SiR for cable accessories. [ABSTRACT FROM AUTHOR]