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Start Over Author "Liu, Degang" Publisher georg thieme verlag stuttgart
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1. Formal Total Synthesis of Benzylpedamide: The Right Half of (+)-Pederin.

Author

Liu, Degang, Xue, Jijun, Xie, Zhixiang, Wei, Liping, Zhang, Xianshu, and Li, Ying

Subjects
*ASYMMETRIC synthesis, *CHEMICAL synthesis, *PYRAN synthesis, *IODINE, *HETEROCYCLIC compounds
Abstract

The right half of (+)-pederin was synthesized through a convenient and efficient asymmetric synthesis in 14 steps with 8.3% overall yield. The key step was an iodine-induced heterocyclization to construct the pyran ring. The chiral centers were constructed separately via asymmetric allylation, substrate-controlled diastereoselective reactions, and Sharpless asymmetric dihydroxylation. [ABSTRACT FROM AUTHOR]

Published
2008
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