Back to Search
Start Over
Formal Total Synthesis of Benzylpedamide: The Right Half of (+)-Pederin.
- Source :
-
Synlett . 2008, Issue 10, p1526-1528. 3p. - Publication Year :
- 2008
-
Abstract
- The right half of (+)-pederin was synthesized through a convenient and efficient asymmetric synthesis in 14 steps with 8.3% overall yield. The key step was an iodine-induced heterocyclization to construct the pyran ring. The chiral centers were constructed separately via asymmetric allylation, substrate-controlled diastereoselective reactions, and Sharpless asymmetric dihydroxylation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09365214
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Synlett
- Publication Type :
- Academic Journal
- Accession number :
- 95202026
- Full Text :
- https://doi.org/10.1055/s-2008-1077788