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Start Over Author "Laura, Voigt" Publisher elsevier bv
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2. Pentagonal-bipyramidal acetonitrile complexes of the lanthanide(II) iodides

Author

Laura Voigt, Mariusz Kubus, and Kasper S. Pedersen

Subjects
Lanthanide, Chemistry, Divalent lanthanides, 02 engineering and technology, Iodides, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, 0104 chemical sciences, Inorganic Chemistry, Crystallography, chemistry.chemical_compound, Pentagonal bipyramidal molecular geometry, Magnetic properties, Materials Chemistry, Acetonitrile, Physical and Theoretical Chemistry, Isostructural, 0210 nano-technology
Abstract

We report a simple synthesis and the structural characterization of a small, isostructural series of distorted pentagonal-bipyramidal LnI2(CH3CN)5 (Ln = Sm, Eu, Yb) complexes. These complexes could be employed as versatile, labile starting materials in Ln(II) chemistry when the presence of oxygen-containing ligands is undesired.

Published
2020

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