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Made available in DSpace on 2022-04-29T08:31:12Z (GMT). No. of bitstreams: 0 Previous issue date: 2021-10-01 Organization and planning of reverse logistics networks make sustainable processes more efficient. Thus, an important sector for connecting the collection and waste paper recycling echelons is the intermediate center. In this study, a Mixed Integer Linear Programming model, which is multi-objective, multi-product, multi-level and multi-period, was developed to optimize the waste paper logistics processes of intermediate centers. The formulation includes the following echelons: collection, considering vehicle routing with different capacities; inventory of non-baling materials; baling sorted waste and inventory of bales; selling bales; disposal of non-recyclable waste. The aims of the model include: maximizing the collected waste; minimizing distances; maximizing both the production and sale of bales, and minimizing costs. According to research carried out in the literature, the developed model is a new proposal and to implement it, the Weighted Goal Programming and Revised Multi-Choice Goal Programming approaches were used to deal with multiple objectives and incorporate uncertainty into the quantity of waste available for collection. To analyze the proposed model, computational tests were executed with instances based on real data from a Brazilian company in the sector. For all performed tests, General Algebraic Modeling System 23.6.5 modeling language and CPLEX 12.2.0.2 solver were used for modeling and optimization. The results show that this study presents formulation and technological approaches that represent real situations and provide competitive solutions to the problem. Sáo Paulo State University “Júlio de Mesquita Filho” [Universidade Estadual Paulista Júlio de Mesquita Filho] School of Engineering of Guaratinguetá [Faculdade de Engenharia de Guaratinguetá] Production Department, Av. Ariberto Pereira da Cunha, 333, Portal das Colinas Agulhas Negras Military Academy [Academia Militar das Agulhas Negras] Rodovia Presidente Dutra, km 306, s/n Escola Preparatória de Cadetes do Exército Avenida Papa Pio XII 350 Jardim Chapadão Campinas - SP Brazil, Avenida Papa Pio XII, 350, Jardim Chapadão, Campinas - SP Sáo Paulo State University “Júlio de Mesquita Filho” [Universidade Estadual Paulista Júlio de Mesquita Filho] School of Engineering of Guaratinguetá [Faculdade de Engenharia de Guaratinguetá] Production Department, Av. Ariberto Pereira da Cunha, 333, Portal das Colinas

The construction industry had approached a critical limit which led to the increase of cement production. The production of cement would cause a broader environmental implication. Cement production is a major source of carbon dioxide emission. Carbon dioxide gas contributes about 63.33% of global warming since the production of one ton of cement would emit about one ton of carbon dioxide to the environment. To mitigate this issue, the research community has investigated the use of waste materials that possess similar chemical properties with cement content as a material for partial cement replacement. The use of rice husk ash has shown to be a contending candidate in the literature. Therefore, this paper attempts at reviewing the performance of rice husk ash as partial cement replacement. It could be observed from the literature that concrete with 5% up to 15% of rice husk ash showed an equivalent performance to ordinary concrete in compressive, flexural, and tensile strength. Thus, rice husk ash can be used as a material replacement in concrete and reduces pollution that originates from cement production and open burning of rice husk.

Cellulose triacetate (CTA) forward osmosis (FO) membrane from Hydration Technology Innovation (HTI), USA was tested in a locally fabricated FO system to concentrate synthetic and pulp and paper mill wastewater. The industry is among the 17 most polluted industries with intensive water consumption and wastewater generation (MoEFCC, Government of India). The CTA membrane was studied with deionized water as feed solution and 1 M NaCl as draw solution, which resulted into water flux of 5.8 L/m2h and reverse salt flux of 0.2 g/L. A concentration stepping method was used to determine the critical draw concentration with lignin solution as the model feed. There was no deviation in flux between the baseline (deionized water feed) and the lignin solution up to 1.5 M NaCl, but a marginal deviation (8% and 21% respectively at 2 M and 3 M) was seen thereafter. The average water flux after 24 h FO study with synthetic wastewater as feed solution (draw solution 2 M NaCl) was 8 L/m2h, and 80% water recovery. Similar study with pulp and paper wastewater as feed solution (draw solution of 1.5 M NaCl) was 5.4 L/m2h was with 62% water recovery. Lignin and COD rejection in pulp and paper mill wastewater was 90% and 64% respectively. The preliminary results indicate that FO is promising for water and lignin recovery from waste streams.

Virgin pulp is made by splitting up cellulose fibers from the woods by mechanical and chemical process without adding any recycled pulp content. The demand for trees, which are the basic raw material for making virgin pulp, increasing constantly in enormously growing paper manufacturing industry. The paper, which is made from virgin pulp is called as virgin paper and this is considered as better quality paper than the recycled paper. Now there is a need to increase the quality of recycled paper to equalize the quality of virgin paper, to reduce the demand for trees to make virgin pulp. In recycling, dispersive system is responsible for the de-inking process, which is one of the pulp purifying process which removes the printing ink from fibers. Chemicals are added in this deinking process which causes a serious problem by increasing the chemical concentration level of industrial outlet water. In conventional deinking technology, dispersive system is controlled by DCS which is quite complicated to control complex loop of operations. To overcome these problems, the dispersive system operations are controlled by PLC along with sensors which make the process easier and replacing the chemicals with enzymes will reduce the chemical concentration level of industrial outlet water and increases the quality of paper.

Edible oils form an integral component in the human diet as well as in the industrial preparations. Any adulteration in oil is concerning from nutritional as well as economical perspective. Although analytical techniques exist for detection of adulterants in oil, most of them require sophisticated instruments, and trained professionals. Microfluidic based lab-on-a-chip technologies have rapidly progressed over the recent years and offer promising alternatives in this regard. In this work, we report development of a paper-based microfluidic lab-on-a-chip for detection of palm oil contamination in sunflower oil. We use the paper-based microfluidic colorimetric detection approach that indicates the presence of adulteration in a visual manner. The data is analyzed using digitally acquired images along with ultraviolet–visible spectrophotometry. The paper-based microfluidic device is fabricated and tested for 10–50% (v/v) palm oil adulteration in sunflower oil. Further, we employ the device for free fatty acid content tests in oil samples. Visual signal acquired from the device is optimized by varying phenolphthalein proportions. The stability of visual colorimetric signal is examined over time and is found to remain steady over the trial period of six days considered in this work. The integration of the detection device with smartphone imaging can prove to be useful for onsite data collection. We believe the approach presented here can be extended to food quality monitoring portable platforms.

This work investigates the influence of blending waste paper and cement at fixed proportion with varying proportions of chicken feather fiber (CFF) and wood saw dust (WSD) as reinforcements. Samples produced were tested for flexural properties and water absorption potentials. The outcome showed that with increasing CFF content and reducing WSD content, water absorption reduced while flexural strength, modulus of ruptures (MOR) and modulus of elasticity (MOE) increases. MOR and MOE were at peaked when the ratio of CFF to WSD was 3:2 while flexural strength reached it crescendo at 4:1 of CFF to WSD. It was noticed that higher CCF content from 3 to 5 wt% gave better results in most of the investigated properties compared to WSD. Therefore, it was concluded that low quantity of WSD is needed to form a synergy with CFF in order to achieve optimum results. Well dispersed CFF-WSD phase in waste paper-cement based composites was observed to be responsible for the enhancement in the investigated properties.

The waste of paper or the paper dump is a serious problem and its occurrence is widespread in various institutions. Wastepaper can be recycled to produce some important and usable products that are ecological and biodegradable. For example, it is used to extract new paper from the old by chemical decomposition. Other products such as paper plates, paper cups, paper spoons, tiles, toys, crafts, etc. can be formed from the slurry. This project also initiates a mould that makes cups and plates from the wastepaper management circuit. With learning institutions being the main consumers, most paper are usually eliminated after its use. The waste remains undeveloped and unused, although is a valuable resource. Studying the design of a manual, economical and efficient paper recycling machine, it can be surmised that the design uses the integration of the knowledge gained about the recycling technology that exists manually from the paper recycling machines used to form a cheap but effective paper recycling system. The advantages of the machine are not only of recycled paper, but also the advantages of the interaction of the manual drive system, which will also reduce the high cost. As the design is not 100% effective, the transmission, belt and chain transmission correspond to the estimated 90% efficiency using the 90% for the design. The power consumption for the design is 450 W and since an average user can produce 100 W constant, it takes 5 people to drive the machine.

Wastewater containing heavy metal ions is considered as the serious environmental problem in human society. Adsorption as the widely used method plays an important role in wastewater treatment, which is based on the physical interaction between metal ions and sorbents. Drumsticks are reported to have efficient adsorbing property. It has been found that Moringa causes alteration in testosterone levels, preventing testicular damage and hence is capable of protecting against the toxic effect of hazardous material. Based on this phenomenon of adsorption by Moringa species, we are trying to remove heavy metals from aqueous sample. The bio sorption of heavy metals by non-living biomass of plant origin is an innovative and alternative technology for the removal of the pollutants from aqueous solution and offers several advantages such as low-cost bio sorbents, high efficiency, minimization of chemical and/or biological sludge, and regeneration of the bio sorbent. Moringa oleifera (drumsticks) has a number of advantages including low cost, biodegradable sludge production and lower sludge volume, and also it does not affect the pH of the water. Apart from turbidity removal, Moringa oleifera seeds also possess antimicrobial properties. Amount of adsorption is considerably larger when activated charcoal is used. Thus, this work reports preparation of activated charcoal from drumsticks seeds and fibres. These are generally part of kitchen waste; thus, its preparation and utilisation for heavy metal toxicity not only controls water pollution but also help in reduction of kitchen waste. It will serve as an effective, cheap and robust and green tool for toxicity control. The paper reports the removal of heavy metal (Pb, Ni, Cd, As in this study) by application of prepared activated charcoal tablets via MATLAB assisted paper based sensors. These tablets will surely serve as point-of- care devices for removal of heavy metal toxicity.

In recent years there has been increasing interest in the use of recycled paper waste in the production of concrete to reduce environmental pollution. This study aims to investigate the use of raw paper waste to produce lightweight cement mortar and to study the effect of the aluminium sulphate treatment of raw paper waste on the compressive strength, absorption ratio and hardened density of mortar. This study used raw paper waste as a replacement for fine aggregate, with percentages of 5%, 10%, 15%, 20% and 30%. The same percentages were examined for the aluminium-sulphate-treated paper waste. The study aims to achieve a similar workability and fixed flow rate for all mixes; therefore, the water–cement ratios were changed for mixes containing paper waste to balance the water absorbed by the paper waste. The study found that the treatment of paper waste with aluminium sulphate helps to reduce the amount of water absorbed by the paper waste and also reduces the amount of water required to maintain its workability, with a higher paper-waste content requiring a larger water content to achieve a similar workability. It was found that the higher the paper-waste content, the lower the wet and dry densities. The compressive strength at both an early and mature age decreased with the increased content of paper waste. Finally, the treatment of paper waste with aluminium sulphate increases the early age compressive strength for similar replacement percentages of up to 19%.

Cyanide ( CN - ) is a deleterious chemical and can cause serious health effects upon exposure even at low concentrations. Different sensors have been developed to monitor cyanide in water, which, however, suffers from complex mechanisms and high-cost. Curcuma longa or turmeric is a commercially available natural dye (usually in powder form) used as medicine. The phenolic substance curcumin is responsible for its yellow color and is capable of sensing environmentally significant analytes such as CN - . In this study, a colorimetric sensor for cyanide in aqueous solution was fabricated by the immobilization of crude curcumin on ordinary filter paper. The curcumin was extracted from locally available turmeric powder using a simple extraction method. Its successful integration in the filter paper was validated by FT-IR spectroscopy. UV–Vis analysis showed that the curcumin-based paper sensor was sensitive to CN - (down to 5.0 ppm), producing a visual change from yellow to dark red. The fabricated sensor also demonstrated high selectivity towards CN - in the presence of N a + , K + , and F - . Its response time was found to be inversely proportional to the concentration of the CN - in the solution. Assessment of reusability revealed that the sensor was reusable for up 8 cycles before significant changes in colorimetric response were observed. Importantly, the fabricated sensor exhibited applicability for actual cyanide monitoring in real water samples.

Enormous quantities of bagasse are being used as raw material in agro based large integrated pulp and paper mills. Anaerobic technology is an effective means of biodegradation of organic substance in wastewater and energy production of biogas that can be used as an alternative fuel. This study illustrates the effect of HRT on performance of lab scale hybrid upflow anaerobic sludge blanket (HUASB) reactor on treatment of pulp and paper mill bagasse wash water. The lab scale HUASB reactor was designed for an effective volume of 0.013 m3 with bio balls as packing media at the top of reactor and operated under mesophilic condition. After startup period, the reactor was operated with HRTs of 23.55, 15.98, 12.00, 10.03 and 7.97 h for the average influent COD concentrations of 2503.6 mg/L, 3918 mg/L, 5432 mg/L, 6608 mg/L and 7996 mg/L respectively. The results showed that the maximum COD removal efficiencies and TSS removal efficiencies were in the range of 68.60–92.19% and 89.56–94.66% respectively. The minimum and maximum biogas yield of 0.32 and 0.53 m3/kg CODa were obtained at influent concentration of 2503.6 mg/L and 7996 mg/L respectively.

SnO2 nanoparticles @ carbon nanoparticles (SnO2@carbon NPs) were synthesized by a facile route using SnCl2·2H2O and filter paper as precursors for lithium ion battery. The different sized nanoparticles of SnO2@carbon NPs were prepared at different temperatures (400, 450 and 500 °C). From the powder X-ray diffraction study the various size of prepared nanoparticles at different temperatures were found to be 16.5 nm (400 °C), 28.5 nm (450 °C), and 35.6 nm (500 °C). Scanning electron microscope (SEM) study reveals the particle nature of synthesized SnO2@carbon NPs. The presence of individual constituents such as Sn, O and C was confirmed by EDAX analysis. TG/DTA studies give assurance of the presence of carbon nanoparticles. FT-Raman spectral study also confirmed the phase and structure of SnO2 nanoparticles. The band gaps of SnO2@carbon NPs prepared at different temperatures (400, 450 and 500) were found to be 3.64 eV, 3.39 eV, and 3.17 eV, respectively by a UV–Vis spectral study. The capacity of SnO2@ carbon NPs prepared at 500 °C was found to be showing better electrochemical properties.

The application of pulp and paper fibers as reinforcement in thermoplastic composites involves several advantages, such as sustainability, constant fiber quality and high mechanical properties. This work compares three different processing methods for the production of paper-reinforced polypropylene composites. The composites were produced by (i) hot pressing, (ii) injection molding and (iii) a pre-coating process with fiber volume fractions between 10 and 65%. The mechanical properties were investigated by tensile and flexural testing. Furthermore, SEM analysis and porosity determination were carried out. The results were correlated with the according processing method and evaluated towards the highest composite performance. As a result, laminated composites with intact paper layers, showed significantly higher mechanical properties, due to the fiber orientation in the paper sheet and good adhesion between the matrix and the paper fibers. Compounded and injection molded composites showed a high degree of fiber agglomeration and less orientated fibers in the composite leading to reduced mechanical properties.

Eco-friendly oil–water separation substrates are mostly recommended in the present context of the world. In the present work, biodegradable and more economical ultrahydrophobic composite material was synthesized by sol–gel method using silica nanoparticles (SiO2) and poly (methyl methacrylate-co-ethyl acrylate) polymer (PMMA) with 1H,1H,2H,2H Perfluorooctyltrichlorosilane (PFOTS) coupler, and coated on 40-grade cellulose filter paper with a dip-coating method. As-prepared surfaces achieved static contact angle more than 175° and sliding angle 3.8°. The microstructure and chemical composition of ultrahydrophobic filter paper were characterized by scanning electric microscopy (SEM), X-ray spectroscopy (EDX), and Flourier transformation infrared spectroscopy (FTIR), respectively. The coated filter paper accomplished 98% oil–water separation efficiency by filtering different oils. Besides, the SiO2 nanoparticles were enhanced the thermal and UV aging resistance. The coated surfaces also showed excellent chemical inertness, and mechanical durability tested. This research work can be employed yet for domestic and industrial applications at a large scale for oil–water separation and self-cleaning.

Advancements in technology have led to the use of smartphones as biosensor detectors. However, it is difficult to obtain stable color information of colorimetric sensors using multiple smartphones owing to different light conditions and image correction operations. In this study, we attempted color detection of the colorimetric paper chip using smartphone-embedded light-emitting diode (LED) and simple transformation calculation. This method enables the acquisition of stable color information using different smartphones by reducing the influence of external light sources. Moreover, we studied characteristics such as convergence and distinction of detection result details by the manufacturers and smartphones. These findings suggested the necessity of classification criteria for the use of smartphones to achieve optimal detection. In addition, white and black references were used to set the standard for color correction of various light sources. Based on our results, we conclude that this approach presents the possibility of smartphone-based colorimetric detection in practical applications.

Nano-dielectrics, which were discovered more than 20 years ago, were once considered as promising insulators. Adding or hybridizing inorganic oxides into polymer matrices inevitably results in poor compatibility between multiphase materials and thus results in limited breakdown strength improvement (generally lower than 20%). Therefore, we bypassed the traditional nano-doping method and proposed the direct construction of matrix materials on nanostructures, that is, a ceramic fiber-porous silica composite insulating paper. The breakdown strength of prepared dielectric was remarkably improved by 120.5%. To the best of our knowledge, such a high improvement in electrical performance has not been reported in previous studies.

In present investigation, electroless Ni-P-SiC/Ni-P-TiO2-ZrO2 nano-composite platings have been deposited upon mild steel substrate (AISI 1040). A homogeneous and consistent allocation of SiC, TiO2 and ZrO2 nano-particles into EL Ni-P matrix is recognized in as plated and heated (400°C) coupons respectively through SEM and EDAX methods. The investigated coupons exhibited resistance against corrosion in order as: 254SMO > SS2205 > Ni-P-TiO2-ZrO2 as-plated > Ni-P-TiO2-ZrO2 heat treated > Ni-P-SiC as-plated > Ni-P-SiC heat treated > SS316L. The corrosion resistance seems too dependent upon Cr, Mo and N content and hence correlate well with the PRE number of the respective alloys. The conventional materials of construction SS 316L are not suitable for both C and D washers. Avesta 254SMO shows immunity to attack in these environments. On the basis of corrosion resistance, mechanical properties and cost comparison, Avesta 254 SMO seems acceptable material for gaseous phase of C and D washers while duplex stainless steel 2205 and Ni-P-SiC/Ni-P-TiO2-ZrO2 as-plated and heated coatings seems acceptable for the other application in these washers.

A paper-based pressure sensor constructed by sandwiching a piezoresistive film between two pieces of paper substrates with silver electrodes is reported in this work. The resulting devices exhibited rapid response and recovery speed, and the response and recovery times were 0.6 s and 0.2 s, respectively, under a pressure of approximately 1.5 kPa. In addition, the device can be especially sensitive to pressures less than 3 kPa. Finally, the devices were used to monitor physiological signals, including the motions of fingers, vocal cord vibration and wrist pulse. The advantages of paper-based devices, such as low cost, portability and flexibility, will have great potential for expanding the application of resultant sensors in wearable medical devices.

The interest in and use of microfluidic paper-based analytical devices (μPADs) has grown exponentially over the last decade. Cellulose, and modified cellulose, has been used for centuries for making chemical measurements but devices made with this material traditionally suffered from either poor detection limits and/or limited ability to provide quantitative measurements. μPADs address these problems by patterning paper to create microfluidic channel networks that can direct flow to different regions of the device without the need for external pumps used in most traditional microfluidic devices. Furthermore, because the devices are made from cellulose or modified cellulose using inexpensive manufacturing methods, the devices can be inexpensive and disposable. The ability to carry out multiplexed analysis without external pumps using inexpensive, disposable devices makes μPADs ideal for point-of-care (POC) analysis. The interest in μPADs has led to a number of excellent comprehensive reviews in the field; in this review, we do not attempt to reference the entire field but instead seek to highlight major developments as well as areas that will be important for future development of this field.

Epoxide-bearing filter paper was first prepared by surface-initiated reversible addition-fragmentation chain transfer (RAFT) copolymerization of glycidyl methacrylate (GMA) and poly(ethylene glycol)methacrylate (PEGMA). Without the need for activation step, the capture peptide nucleic acid (PNA) probes carrying a C-terminal lysine modification can be directly immobilized on the surface-grafted poly[glycidyl methacrylate-ran-poly(ethylene glycol)methacrylate] (P(GMA-ran-PEGMA)) through ring-opening of epoxide groups in the GMA repeating units by amino groups in the PNA’s structure. The success of P(GMA-ran-PEGMA) grafting on the filter paper and subsequent PNA immobilization was confirmed by fluorescence microscopy, Fourier transform-infrared spectroscopy and X-ray photoelectron spectroscopy. Colorimetric detection with signal amplification upon DNA hybridization relies on sandwich-hybridization assay employing another biotinylated PNA strand as a reporter probe together with streptavidin-horseradish peroxidase conjugate (SA-HRP) and o-phenylenediamine (OPD) substrate. It was found that increasing ionic strength during the DNA hybridization step by addition of NaCl can increase the signal intensity, which can be visualized by naked eye. The sensing platform showed the best performance in preventing non-specific adsorption from the non-complementary DNA and discriminating between complementary and single-mismatched targets of at least 50 fmol without the requirement for stringent hybridization or washing condition. This superior ability to suppress non-specific adsorption of non-target DNA as well as other non-DNA components may be explained as a result of hydrophilic PEGMA repeating units in the surface-grafted copolymer.

Micro-cracks are inherently present in concrete, leads to debilitation of structures. Methods used for managing micro-cracks have a certain degree of toxicity and also possesses certain drawbacks that made them not completely efficient. Bacterial technique when used in fresh concretes results in calcite precipitation in voids and consequently improves the strength and lowers permeability of concrete. Bio- cement is the combination of Bacillus pasteurii 5% and nutrients Urea, Calcium Lactate 95%. In this study by adding 0.5, 1, 1.5 and 2% Bio- cement by weight of cement and observed compressive strength, flexural strength values after 7 and 28 days of curing for M25 grade of concrete.

Paper industry wastewater is the significant source of water and soil contamination due to various unknown residual organic pollutants directly discharged into the environment without proper treatment. Therefore, the study has focused on the detection of residual organic pollutants (N-(1,2,2,2-tetrachloroethyl) trimethylacetamide, octadecane, 1-iodo, Oleic acid, trimethylsilyl ester, eicosane; hexadecane, 2-methyl-; octadecane, docosane; tricosane) from paper industry wastewater sources showed endocrine-disrupting compounds and their toxicity. This experiment were carried out the effect of paper mill sludge amendments with garden soil (25%, 50%, 75%, and 100%) and garden soil was utilized as a control in a pot experiment. This study revealed the growth parameters of Triticum aestivum in seeds germination percentage and germination index values decreased with rising in sludge concentration. Further, soil amended with 25% paper industry sludge slightly reduced the growth in root length, shoot length, biomass, photosynthetic and 50% sludge amended soil had variable effects on the root, shoot, and photosynthetic pigment of T. aestivum. Moreover, the toxicity of paper industry wastewater on tubifex-tubifex worms after 48 h of exposure (>50% concentration), worms showed various changes such as movement; haemoglobin content disappeared, cell bursting, and the back of the body became white with body disintegration at the lethal concentrations of paper industry wastewater. This article has revealed that the toxicity of the organic pollutants in the terrestrial and aquatic life due to paper industry wastewater there is needed to treat adequately prior to discharge.

Writing and presenting results is important for any research work. Publishing is not enough; it should be written clearly and consistently for others to read and cite. We present a review of different techniques, for improving the writing in research papers intended for publishing. These include how to write the title, whether to use active or passive voice, how long sentences should be, how to present the uncertainty, understanding the International System of Units (SI) writing conventions, how to assign authorship, how to effectively use references, how to present the work, and how to publish it in a journal. This paper is a summary of the main and most recent recommendations in the scientific field on how to write a research paper to increase its impact.

An innovative method to quantitatively assess the state of degradation of paper in a non-destructive way has been developed by using THz time-domain spectroscopy (THz-TDS). The method relies on the observation that the hydrolytic and oxidative degradation of cellulose in paper is accompanied with rearrangement of the hydrogen bonds (H-bond) network of cellulose polymers. This gives clear fingerprints in the THz spectral profiles. THz-TDS is a suitable approach to study low-energy vibrational properties of biological materials in a non-destructive way. The THz photon energy range (about 1-40 meV) is particularly suitable to probe the H-bonds between molecules. However, the quantitative assessment of the state of preservation of artworks poses significant challenges, in particular when measurements on low refractive index and thin samples, such as ancient documents and drawings, must be carried out [1]. In the present study, we have successfully solved this problem obtaining a precise determination of the absorption by cellulose fibers in the 0.2-3.5 THz (7-117cm-1) range in single freely standing paper sheets. This has been achieved by developing a new procedure to remove from the experimental signals the spurious interference effects generated by the Fabry-Pérot resonances in the sheet. By using this approach, the THz absorption coefficient of cellulose fibers in ancient and modern samples artificially aged has been obtained. The THz absorption spectra are explained in terms of absorption peaks of the cellulose crystalline phase superimposed to a background contribution due to a disordered H-bonds network [2]. The complex evolution of the spectra as a function of natural and artificial aging is explained with a reduction up to 30% of the H-bond density in the cellulose polymer networks and a parallel increasing of the sample crystallinity evident in the peaks at about 2.1 and 3.1 THz. The comparison with density functional theory ab-initio calculations suggests that the observed THz spectral changes could be related not only to the recrystallization of amorphous regions, but also to the progressive degradation of the external surfaces of crystalline domains. These results demonstrate a significant potential in the non-destructive analysis of the structural modifications of cellulose and paper artifacts by aging, resulting, at a macroscopic scale, in a progressive weakening of the mechanical properties of paper [3]. [1] T. Trafela, M. Mizuno, K. Fukunaga, and M. Strlic, Appl. Phys. A, 111, 2013, 83-90. [2] E. Scarpellini, M. Ortolani, A. Nucara, L. Baldassarre, M. Missori, R. Fastampa, and R. Caminiti, J. Phys. Chem. C 120, 2016, 24088-24097. [3] L. Teodonio, M. Missori, D. Pawcenisc, J. ?ojewskac, F. Valle, Micron 91, 2016, 75-81.

In recent times, it has been witnessed that wireless systems based on IoT-based have developed rapidly in various sectors. The IoT (Internet of Things) is the network in which physical devices, equipment, sensors and other objects can communicate among themselves without human involvement. The WSN (Wireless Sensor Network) is a central component of the IoT, which has proliferated into several different applications in real-time. The IoT and WSNs now have various critical and non-critical applications impacting nearly every area of our everyday life. WSN nodes are usually small and battery-driven machines. Thus, the energy effective data aggregation techniques that increase the lifespan of the network are highly significant. Various approaches and algorithms for energy-efficient data aggregation in IoT-WSN systems were presented. This paper reviews the literature with specific attention to aspects of wireless networking for the preservation of energy and aggregation of data.

Paper recycling is the process of turning waste paper into new paper products. The main objective of the current research work is to analyze the effectiveness of stainless steel based compact paper recycling machines for small scale industries and institutions such as schools, colleges, printing media, etc. At present paper recycling technology is being implemented in large scale industries as it requires enormous space and cost involved. In the current study, an attempt is made to design a compact recycling machine that is affordable for small scale industries and institutions to possess their paper recycling units. The mechanism comprises of hydro pulper, mould box, conveyors, rollers, and driers. It is capable of recycling the used papers and produce papers, cardboards, and egg trays. The thickness of the paper is controlled by setting the distance between the two finishing rollers using a spring set up. The process of recycling is broadly divided into three main categories that include collection of waste, manufacturing of new products, and purchasing. The main advantage of the machine is waste paper be converted into a useful product and thus reduce deforestation. The cost of recycling is reduced and is affordable by small industries. The simplicity of the operation of this machine ensures that a high level of technical skill is not essential for the process. The durability of the machine is high provided if adequately maintained. Since recycling is good for the environment, and if more and more people make use of it, it will address the problem of global warming.

Unsuitable storage conditions or accidents such as floods can present a serious threat for large quantities of book making them prone to attack by harmful microorganisms. The microbiological degradation of archives and book collections can be efficiently inhibited with irradiation processing. Application of EB irradiation to book and archive collections can also be a very effective alternative to the commonly used ethylene oxide treatment, which is toxic to the human and natural environment. In this study was evaluated the influence of EB irradiation used for microbiological decontamination process on paper-based objects. Three different kinds of paper (Whatman CHR 1, office paper and newsprint paper) were treated with 0.4, 1, 2, 5, 10 and 25 kGy electron beam irradiation. Optical and mechanical properties of different sorts of paper treated with e-beam, before and after the radiation process were studied. These results, which correlated with absorbed radiation doses effective for the elimination of Aspergillus niger (A. niger) allowed to determine that EB irradiation with absorbed radiation dose of 5 kGy ensures safe decontamination of different sorts of paper-based objects.

In this pandemic, the requirements of PPE kits are increasing continuously. The doctors and health care workers are using the kits to protect themselves from the virus. After using, these kits become waste. The consumption of these kits becomes a very big challenge for the municipal corporation. Similarly, the papers which are used in offices become waste after use. The consumption of these papers is also a challenge as in the garbage of a city, the maximum percentage is available in the form of waste papers. The waste papers may be recycled after some recycling process and manufacture handmade papers. The quality of handmade papers will be not as good as traditional papers. By the use of waste medical PPE kits and pulp of used office papers, the quality of handmade papers may be increased. Recycling of used papers and medical PPE kits are also useful for the environment and forests. In this manuscript, it is seen that the combined pulp of waste papers and medical PPE kits in the various ratios may increase or decrease the hardness strength, reflection properties, and moisture properties of handmade papers.

In this work, a robust and flexible bilayered MXene/cellulose paper sheet with superhigh electrical conductivity was prepared via vacuum-assisted filtration and a subsequent hot-pressing process for electromagnetic interference (EMI) shielding applications. By tightly assembling few-layered MXene (f-Ti3C2Tx) on the cellulose substrate via hydrogen bonds, an effective and interconnected conductive network was constructed in the paper sheet, resulting in a high electrical conductivity of 774.6–5935.4 S m−1 at various f-Ti3C2Tx loadings. The highly conductive MXene layer can promptly reflect a great amount of incident EM waves, a process which preceded the transmission of EM waves in the cellulose matrix. Owing to the highly efficient reflection-dominated EMI shielding mechanism, the resultant bilayered MXene/cellulose paper sheets exhibit excellent EMI shielding effectiveness of 34.9–60.1 dB and specific EMI shielding efficiency of 290.6–600.7 dB mm−1. Moreover, the MXene/cellulose paper sheets demonstrated improved mechanical strength (up to 25.7 MPa) and flexibility due to the mechanical frame effect acted by the cellulose substrate. Consequently, the robust and flexible bilayered MXene/cellulose paper sheet is a promising candidate for application in next-generation electric devices.

Demands for flexible electronic equipment such as wearable devices and wrap-round displays have motivated the development of flexible energy storage devices. Although cellulose paper is one of the most promising substrates for flexible devices, its intrinsic limitations, such as poor mechanical durability, hamper its practical use. In this study, we adopted the traditional Korean paper, Hanji, with superior mechanical robustness as a substrate for supercapacitor electrodes. The effective infiltration of activated carbons (ACs) as an electrode material into the dense network of Hanji cellulose fibers was performed by a simultaneous one-pot process of network formation and AC embedment. The fabricated symmetric supercapacitors based on the AC-embedded Hanji electrode exhibited a specific capacitance (Csp) of 16.0 F/g measured at a scan rate of 10 mV/s with excellent cycle stability, the Csp retention of 94.5%, over 1000 charge-discharge cycles.

Membrane heat exchangers were used for moisture and heat recovery from a hot and humid natural gas stream in indirect contact with an air stream. A plate membrane module with spiral channels on each side was designed to configure gas and air streams in co-current and counter-current flow. Two types of membranes, a commercial kraft paper, and a laboratory-made thin-film composite membrane, were used as the module core. The thermal efficiency and the water recovery from the humid gas were calculated and compared under different operating conditions. At a unit flow ratio of air/gas, the greatest effectiveness was achieved at a methane flow of 100 cm3/min, but water recovery increased at higher gas flows. For the counterflow configuration, an air/methane flow ratio of 2 was sufficient to achieve the highest total effectiveness and water recovery; however, larger air/gas ratios were beneficial to improve heat and moisture transfer for the co-current configuration. The highest water recovery by the kraft paper and composite membrane was achieved (approximately 15 mgH2O/cm2.h) for the input gas with the highest humidity. The dehumidification performance of kraft paper as a porous and hydrophilic membrane was slightly better than that of the composite membrane containing a dense hydrophilic polymer thin film in most cases. A relatively low heat transfer coefficient was found for the module, which was increased by using higher gas flow rates at higher humidity conditions.

The paper describes the structure and properties of preceramic paper-derived Ti3Al(Si)C2-based composites fabricated by spark plasma sintering. The effect of sintering temperature and pressure on microstructure and mechanical properties of the composites was studied. The microstructure and phase composition were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. It was found that at 1150 °C the sintering of materials with the MAX-phase content above 84 vol% leads to nearly dense composites. The partial decomposition of the Ti3Al(Si)C2 phase becomes stronger with the temperature increase from 1150 to 1350 °C. In this case, composite materials with more than 20 vol% of TiC were obtained. The paper-derived Ti3Al(Si)C2-based composites with the flexural strength > 900 MPa and fracture toughness of >5 MPa m1/2 were sintered at 1150 °C. The high values of flexural strength were attributed to fine microstructure and strengthening effect by secondary TiC and Al2O3 phases. The flexural strength and fracture toughness decrease with increase of the sintering temperature that is caused by phase composition and porosity of the composites. The hardness of composites increases from ~9.7 GPa (at 1150 °C) to ~11.2 GPa (at 1350 °C) due to higher content of TiC and Al2O3 phases.

Burning joss paper is a traditional and long-term historical custom in Oriental countries. However, joss paper contains a lot of toxic components [1] , which can be released into the environment during the burning stage [2] , [3] and caused health risk [4] . The objective of this study is to assess the heavy metals in bottom ash and dust fume by using a burning chamber in the laboratory; thereby, it also assesses the ambient air from the incinerator – a case study at Thien Hau pagoda, District 5, HCM city. The initial result showed that there is a significant amount of heavy metals in the dust fume and bottom ash in order Al [5] ) with 236.21 ppm Cu, 4.93 ppm Cd, and 128 ppm Pb. Moreover, the results of assessing the ambient air quality at a pagoda indicated that the incinerator (S3) was the source with the highest of dust concentration and had a significant impact on air quality to the location around.

Recently, naturally occurring biopolymers have gained interests in its application as adsorbent for the removal of metal ions. The graft copolymerization modification of acrylonitrile monomer in the presence of ceric ammonium nitrate was successfully done on extracted recycled papers. The fabricated grafted adsorbent was analyzed by using scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) mapping, X-ray powder diffraction (XRD), as well as Fourier-transform infrared spectroscopy (FTIR). The parameters of the adsorption process were varied for the pH of the solution, concentration of Ni(II) ions, and time duration. As a result, the most optimum condition was achieved at pH 5 with 160 mg/L in a duration of 1 h, which reached 317.5 mg/g equivalent to 79.3% removal. The adsorption behavior tallied with Freundlich and Pseudo-second-order for adsorption and kinetic models, respectively. Convincingly, acrylonitrile-grafted recycled papers are able to be competitive and act as an efficient adsorbent in metal ions removal.

Friction stir welding is a solid state joining process that welds two or more similar or dissimilar materials having different melting points through a blend of heat created by friction and mechanical mixing of the materials in the locale of the joint. Different alloys having elements like aluminium, magnesium etc and hard materials like steels are generally welded by this method. These materials being light in weight are frequently used in transport and other such industries, where light weight materials having good mechanical properties are preferred. If the joining of these materials is done by any fusion welding techniques, the mechanical properties of the welds are reduced. In friction stir welding the mechanical properties of the materials to be joined are not reduced as welding takes place due to only the forging effect and no melting of materials takes place. This work contains the review of some important research papers on friction stir welding for similar or dissimilar materials. The papers for investigation in this work were considered since the invention of the friction stir welding process in 1991 with filing of a patent to till date and some important of them were selected for our work. The process parameters affecting the properties of welded products, applications and suggestions of the researchers were discussed in this work.

Over the last decade, the Low-Energy Nuclear Physics (LENP) and Nuclear Astrophysics (NAP) communities have increasingly organized themselves in order to take a coherent approach to resolving the challenges they face. As a result, there is a high level of optimism in view of the unprecedented opportunities for substantial progress. In preparation of the 2015 US Nuclear Science Long Range Plan (LRP), the two American Physical Society Division of Nuclear Physics town meetings on LENP and NAP were held jointly on August 21–23, 2014, at Texas A&M, College Station, in Texas. These meetings were co-organized to take advantage of the strong synergy between the two fields. The present White Paper attempts to communicate the sense of great anticipation and enthusiasm that came out of these meetings. A unanimously endorsed set of joint resolutions condensed from the individual recommendations of the two town meetings were agreed upon. The present LENP White Paper discusses the above and summarizes in detail for each of the sub-fields within low-energy nuclear physics, the major accomplishments since the last LRP, the compelling near-term and long-term scientific opportunities plus the resources needed to achieve these goals, along with the scientific impact on, and interdisciplinary connections to, other fields.

This white paper informs the nuclear astrophysics community and funding agencies about the scientific directions and priorities of the field and provides input from this community for the 2015 Nuclear Science Long Range Plan. It summarizes the outcome of the nuclear astrophysics town meeting that was held on August 21–23, 2014 in College Station at the campus of Texas A&M University in preparation of the NSAC Nuclear Science Long Range Plan. It also reflects the outcome of an earlier town meeting of the nuclear astrophysics community organized by the Joint Institute for Nuclear Astrophysics (JINA) on October 9–10, 2012 Detroit, Michigan, with the purpose of developing a vision for nuclear astrophysics in light of the recent NRC decadal surveys in nuclear physics (NP2010) and astronomy (ASTRO2010). The white paper is furthermore informed by the town meeting of the Association of Research at University Nuclear Accelerators (ARUNA) that took place at the University of Notre Dame on June 12–13, 2014. In summary we find that nuclear astrophysics is a modern and vibrant field addressing fundamental science questions at the intersection of nuclear physics and astrophysics. These questions relate to the origin of the elements, the nuclear engines that drive life and death of stars, and the properties of dense matter. A broad range of nuclear accelerator facilities, astronomical observatories, theory efforts, and computational capabilities are needed. With the developments outlined in this white paper, answers to long standing key questions are well within reach in the coming decade.

In the present study, life estimation of accelerated aged insulating papers used in rotating machines is estimated by Arrhenius model. Various types of insulating papers used in rotating machines such as Mylar, Nomex-Mylar-Nomex(NMN), Leatheroid, Dacron-Mylar-Dacron(DMD), Mica Tape, and Kapton are thermally aged at 90°C, 130°C and 170°C with 300hrs duration of each sample. These insulating materials wrapped on copper conductor with single and double layer. Then, breakdown voltage test is performed at each temperature for both single and double layer papers to determine their dielectric strength. Further, correlation analysis between breakdown voltage and different applied temperatures is performed for all paper samples. Popular Arrhenius plot is drawn by short term test data on breakdown voltage for an extrapolation to long term performance of various types of insulating paper used in rotating machines. The results showed that the performance of double layer insulation is almost twice than single layer performance. The aging analysis and testing of insulating papers was performed in TIFAC-Core centre of NIT Hamirpur, H.P., India.

This work investigates the spreading dynamics of three candidate sol-gel solutions, of ranging viscosities, surface tensions and densities, and compares them with water and two commercial blood substitute products. Droplets were created with different sizes (10 to75μL) and impact velocities (1.4 to 6.0m/s) to strike 176gsm cardstock. Over 2200 droplets were created using the six different fluids and their final dried stain diameter was measured. Droplet spread was plotted using the Scheller and Bousfield correlation and uses effective viscosity as a parameter for non-Newtonian fluids. Comparing the results to an expected whole human blood range validated the spread of the candidate FBS sol-gel material in passive drip bloodstain pattern simulation. These findings complement the practical application of the material as a safe substitute for demonstrating droplet spread under controlled conditions on hard paper surfaces.

Waste wig fibers, empty eggshell powder and waste paper were recycled in the development of composite boards as potential sustainable material for wall partitioning. Samples were produced by blending these wastes with cement in the presence of water and cured for 14 and 28 days. The samples produced were examined for density, porosity, thickness swelling, internal bonding strength, modulus of rupture and elasticity in line with standard procedures. From the result obtained, there was reduction in porosity, thickness swelling, while internal bonding strength and modulus of rupture and elasticity were enhanced. An optimum value for modulus of elasticity was attained at 0.96 g/cm3 (3.85 MPa for 14 day curing and 3.5 MPa for 28 day curing), even as internal bonding strength increases with increasing density. It was therefore concluded that recycling of these wastes is effective in the development of sustainable materials for wall partitioning.

Waste paper cups were employed as a source of carbon (P-carbon). Fluorescein molecules were immobilized on this carbon surface. The composite P-carbon/Fluorescein was investigated as an alternative supercapacitor material. The structure and properties of the synthesized materials are confirmed by some characterization techniques like XRD, SEM, EDX, UV and TGA. The functional group present in the material was confirmed by FT-IR and Raman spectral studies. The electrochemical behaviour of the material was analysed by Cyclic Voltametery (CV), Galavanostatic charge discharge (GCD) and Electrochemical Impedance Spectroscopy (EIS) studies. Organic compound DFT calculation was carried out for the immobilized organic compound to evaluate the theoretical band gap energy. The synthesized electro active composite P-carbon/Fluorescein shows an excellent capacitance value of 214 Fg−1 when compared to the individual materials P-carbon and Fluorescein, and it exhibited a good cyclic stability till 1000 cycle of charge discharge study. The study throws light on the fact that waste carbon materials can be modified for energy storage applications.

This review paper mainly focused on microstructural and mechanical properties ofultrafine grained nanocrystalline (Nc) Magnesium alloy fabricated by Severe Plastic Deformation(SPD) process. The influence of SPD over mechanical, microstructural, physical, optical, and corrosion properties of Nanocrystalline magnesium alloy are detailed and discussed. It has been observed that nanocrystalline (Nc) magnesium materials has shown superior properties over the bonding of grains while during the Extrusion, Annealing, quenching, Normalizing, Spark Plasma Sintering (SPS) processes. The outcome based by many researchers showed that nanocrystalline Magnesium alloy processed by Severe Plastic Deformation (SPD) showed an improved properties over the Hardness, Dislocation density, Compressive, Tensile and texture, and it’s found to be increased up to certain limit beyond that decrease of microstructural stability, micro hardness and dislocation density were seen to be observed. The Microstructural and Mechanical properties are well improved by Spark Plasma Sintering (SPS), Extrusion, Annealing, Equal channel angular pressing (ECAP), Accumulative Roll Bonding (ARB) and High-Pressure Torsion (HPT) processes. Grain growth Mechanism, Energies Activation during grain growth, Thermal stability, Relative density and stress corrosion rate were observed by previous Researchers during Fractography analysis over several nanocrystalline (Nc) Magnesium alloy specimens.

Spinel ferrites are very popular due to their large flexible properties and loss eddy current loss. Among spinel ferrites, Ni-Zn nanoferrites plays vital in industry because of its numerous applications in r due to its high permeability and high mechanical strength. Ni – Zn are very good magnetic materials and its magnetic, electrical and structural properties can be varied by changing ions at tetrahedral and octahedral sites. Ni-Zn nano ferrites papers were studied and summarized the conclusions of different studied by varying synthesis methods, varying shape of nanomaterials, changing dopant, changing sintering temperature and changing annealing temperature.

LM14 alloy reinforced with paper sludge ash is fabricated using stir casting technique and also the effect of paper sludge ash on the composites with various weight percentages (2.5, 3.5, 5) was investigated. From SEM imaging the presence of the reinforcements were observed. EDS analysis confirms the particulates of the reinforcement in the elemental composition. The hardness is increased by 32.3 % from 3.5 wt. % PSA composite and the tensile strength are increased by 42.9% and for 3.5 what% PSA composite when compared to base. Further, addition of reinforcement beyond 3.5 wt. % of PSA with matrix causes reductions in hardness and strength. This effect was due to the non solubility of PSA with matrix. The hot tensile behavior of the composites was observed. The Impact energy of the composites decreased as the content of reinforcement increases. It is observed from the current study, the composites with 3.5 wt% PSA shows better properties.

This paper reports the development and fabrication of a low-cost handheld point of care device that can quantify the concentration of biomarkers using a paper microfluidic assay. The commercially available light-to-digital converting sensor was used to achieve this objective. This RGB sensor was efficient in the digital values of the red, green, and blue components of the sample or object. It has an inbuilt white LED source, an array of photodiodes with color filters, an analog-to-digital converter module, and also an IR blocking filter. The sensor was interfaced with the Arduino UNO board, and the corresponding results were displayed on the serial monitor. This device was tested for manually prepared primary color samples and also for total protein. The colorimetric detection of protein was performed for 1 g dL-1 to 14 g dL-1 concentrations on a paper microfluidic device. The change in color intensity of the paper device with an increase in total protein concentration was monitored and calibrated the device for real sample analysis.

Joining of materials with the help of submerged arc welding machine is widely used in the concerned industries. The quality of the weld is identified by several welding output parameters like weld width, re-inforcement height, depth of penetration, hardness, impact strength and tensile strength etc. The input welding parameters on which outputs depend are welding current, voltage, feed rate, speed of welding, electrode extension, diameter of electrode and electrode angle etc. All the researchers try to optimize these parameters according to the concerned requirement. In this review paper it was tried to consider different research papers containing the research and analysis made on input output parameters of submerged arc welding process. This paper also focused on analysis of some research papers containing heat input rate, cooling rate of weld, micro structure of weld and heat affected zone and their effect on the performance of the joint. Total 28 research papers were selected for our consideration after a thorough investigation of several such papers. After the analysis of the research papers the future scope of research was also suggested.

Agriculture is the important aspect of country economy. Farmers employ laborers for various purposes of works to be carried out on their farm. One of the important works is to make a ridge and furrow in their agricultural fields. In general, farmers use tractors, plowing machines, and other manual methods for making ridges and furrows in the agricultural field which increases the cost of operation to produce ridges and furrows. Further, the manual method of producing ridges and furrows needs more labor and takes more number of days to complete the work. Work. It also needs a lot of physical work. [1] . Plowing machines are costly and use power. This machine is highly economical and efficient which would replace the existing manual method of removal of furrows. Further, the machine is operated by freely available solar energy. The new machine is capable of reducing the physical work and also speed up the removal of wastages along the furrow. This furrow formation machine is mainly designed and fabricated to dug the tunnel and to form the furrows along the boundary of the land and along both the sides of the crops.

The aim of this study is to design a fully automatic Sundry board machine for reduction of congestion in the cardboard making process and increase the quality and quantity of production. For this purpose, the manual cutting and transfer of sheet is replaced by automated mechanism. The mechanisms include the incorporation of the cutting arrangement in the cutting drum itself, deployment of air pressure to separate the sheet edge from the cutting drum, a cross cutting mechanism and a mechatronic system to control these all mechanism. The initial review is done on the semi-automatic machine followed by the requirement definition. The required components are brainstormed and individually developed. A time based relation is designed such that a microcontroller can be programmed later on for the synchronism of all the components. Thisrelation is visually represented and the entire system is now ready for assembling.

Traditional slurry-based electrodes consist of heavy current collectors and electroactive materials with a low weight percentage, which inevitably increase the total weight and cost of lithium-ion batteries (LIBs). Consequently, the development of low-cost, lightweight, flexible and binder-free electrodes for LIBs is highly desirable but also greatly challenging. In this work, we report the synthesis of small ZnO nanoparticles uniformly embedded in N-doped carbon (NC) nanoplate arrays (NPAs) tightly grown on a N-doped carbon paper (NCP) substrate (ZnO/NC NPAs@NCP) through a facile metal-organic framework-engaged strategy. This electrode design not only avoids the utilisation of insulating polymer binders but also offers other advantages, including large electrode/electrolyte contact areas, abundant electroactive sites, good wettability of the electrolyte, fast electron/ion transport and efficient volume accommodation. Notably, the freestanding ZnO/NC NPAs@NCP electrode displays a high reversible capacity of 610 mA h g−1 (based on the mass of entire electrode) at a current density of 100 mA g−1 for 50 cycles and excellent long-term cycling stability (363 mA h g−1 at 500 mA g−1 for 200 cycles). Furthermore, a full cell employing ZnO/NC NPAs@NCP as the anode and commercial LiFePO4 as the cathode is constructed, indicating the feasibility for practical application. Moreover, an analysis of the electrode kinetics confirms the favourable lithium-ion storage kinetics within the ZnO/NC NPAs@NCP electrode. The present work could provide a new approach to develop low-cost, lightweight and flexible electrodes for advanced energy storage.

Carbon materials with layered structure and high conductivity are promising electrode candidates for dual-ion batteries (DIBs). However, the size mismatch of electrolyte ions and interlayer spacing of carbon materials limits the overall performance of DIBs. Thus, finding an effective strategy to adjust the interlayer spacing of carbon materials is of great importance. Here, we describe an efficient electrochemical strategy combining ion pre-intercalation and gas evolution reaction treatment to expand the interlayer spacing and modify graphene layers of carbon fiber papers. Furthermore, through the theoretical calculation we have demonstrated that the anion adsorption energy is reduced and kinetics is accelerated by the introduction of functional groups on the graphene layer. After the electrochemical modification, the discharge capacity of CFP increases more than 50%, the transfer resistance reduces even more than 40% and the capacity retains 94% after 1000 cycles in an ionic liquid electrolyte. These promising results demonstrate an effective and convenient method to solve the size mismatch issue, and therefore, arouse the potentials of carbon materials and other materials with layered structure for high performance DIBs.