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Currently, bioaccessibility testing at contaminated sites is dominated by techniques designed to assess oral bioaccessibility to humans. Determining the plant bioaccessibility of toxic trace elements is also important. In mining landscapes, sulphides are an important source of potentially toxic elements. Simple tests to evaluate readily leachable metals and metalloids exist but do not extract elements temporarily constrained within the sulphide fraction. Sequential extractions describe the association of trace elements with different geochemical fractions but are time consuming, costly and provide excessive detail. This paper proposes a new test for plant bioaccessibility in sulphidic mine wastes and soils that uses hydrogen peroxide to simulate environmental oxidation. The bioaccessible fraction determined is operationally defined and does not predict actual plant uptake. The test targets a) the portion of an element that is currently available in the pore water for uptake by plant roots and also b) the fraction that is temporarily constrained in sulphide minerals but may become available upon oxidation of the substrate. A case study was conducted at a historic mine waste repository site in Cornwall, U.K. where near total As concentrations were extremely elevated and Cd, Cu, Pb, Sb and Zn were also high. Our test determined that bioaccessible concentrations of As, Cd, Cu and Zn and to a lesser extent Sb and Pb were highest in samples of pyritic grey tailings. This is attributed to sulphide mineral oxidation and, particularly for Cd and Zn, the dissolution of soluble secondary minerals. High As concentrations in the marbled tailings were not bioaccessible. Results from the case study show that this new test provides useful information on the future bioaccessibility of contaminants, allowing for classification of mineralised sulphidic waste materials which otherwise cannot be obtained using established geochemical and mineralogical techniques. Furthermore, the test is rapid, repeatable and cost effective. [ABSTRACT FROM AUTHOR]

Abstract: Inshore fishing communities in England, as elsewhere, are facing challenges as they struggle to deal with policy measures aimed at reducing fishing effort. Drawing on findings from a study aimed at exploring the role of fishing for place-making and identity creation in Cornwall, we argue that there may be potential opportunities for developing inshore fisheries under the rural development paradigm. By considering lessons from the agri-food sector, this paper considers models of multifunctionality and the scope for translating these approaches into the fisheries sector. By re-embedding fish in place, through marketing, branding and enabling small-scale supply chains that recognise fisheries' wider role in communities, fishing can be understood as a ‘multifunctional’ activity in coastal areas by re-connecting fishers with markets, consumers and the environment. To facilitate this, the importance of inshore fisheries to the socio-cultural and economic life of coastal communities needs to be recognised. Through valuing the often intangible benefits, such as identity, social cohesion and heritage, that fisheries bring to communities, fishing can be a useful development mechanism to enhance the economic and social sustainability of coastal communities. This creates new agendas for policy makers to understand the wider range of benefits afforded by marine fishing than productivist approaches alone. While initiatives are emerging to move the industry in this direction, coordinated and integrated policy development is needed to enhance these efforts and contribute to the creation of sustainable coastal communities with marine fishing as the focus. [Copyright &y& Elsevier]

Abstract: Relationships between landscape-scale geomorphology and aspects of the human environment (including heritage and material cultures) are best examined in landscapes with a strong geomorphological imprint of past climatic and environmental changes, and where human activity has been present for a long period of time. In Cornwall, southwest England, a strong geomorphological signature is imparted by weathering of granite bedrock under cold Quaternary climates, and a strong cultural and heritage imprint is manifested in material and nonmaterial ways through archaeology, art, literature and folklore, and is illustrated in this paper through examples of Bodmin Moor (north Cornwall) and West Penwith (west Cornwall). Landscapes of Bodmin Moor include wide valleys with underfit rivers and upland summits with prominent tors, resulting from granite weathering and slope processes during the Tertiary and Quaternary. Pollen records show how human activity has changed on the moor over time, with a peak of settlement during the Bronze Age, and expansion of grazing into the Iron Age. Daphne du Maurier's novels, set on or adjacent to Bodmin Moor, emphasize the moor's relationship to unstable and intense human emotions and crises. In West Penwith, which is geomorphological similar to Bodmin Moor, geomorphology–culture relations are demonstrated in different ways but through a similar sense of place and regional identity. The St Ives School of early 20th Century art, including the local artist Peter Lanyon and the sculptor Barbara Hepworth, draws inspiration from the local land and seascapes. The oral traditions and folklore of Zennor emphasize the importance of witchcraft and superstition that are in part founded on the wildness of upland summits and stormy coastline. Across West Penwith, tin mining and the mining trade exerted a strong impact on regional socioeconomic and cultural development from the Bronze Age until the end of the 19th Century, seen through settlement patterns, scientific innovation and Nonconformism. Today these geomorphology–culture relations are memorialized in the Cornwall and West Devon Mining Landscape World Heritage Site. [Copyright &y& Elsevier]

Abstract: Concerns about the sustainability of an ageing farming population have brought interest in so called entry-exit issues in policy circles. Policy interventions to date have offered limited scope in stimulating farm transfer in UK, however, the increase in unconventional tenures which include partnerships, share farming and contract farming (collectively called joint ventures) would appear to offer new opportunities for those wishing to enter or leave farming. In recognition of this the Fresh Start initiative in Cornwall set up a matchmaking element with the aim of identifying and facilitating potential joint ventures agreements between new entrants and older farmers. The emphasis was on setting up long-term arrangements that would enable the new entrant to ‘buy into’ an existing farm business, gradually taking over managerial control. This paper examines the processes of matching partners for the possible formation of farm joint ventures, using qualitative data derived from interviews with the participants, deliverers and stakeholders involved in the matchmaking element of this initiative. The results reveal that there is a deep rooted reluctance amongst participants in the initiative to enter formal long term joint ventures due to differing motivations, expectations, and concerns about their respective responsibilities in the working relationship and about the validity of the legal framework. Only where a relationship had already been informally established was there a commitment to formalise a joint venture agreement. Future emphasis in policy should therefore be on helping to facilitate and formalise existing partnerships, rather than trying to artificially orchestrate matches where the parties do not know each other. [Copyright &y& Elsevier]

Abstract: In this paper a generic methodology is presented that allows the impacts of climate change on wave energy generation from a wave energy converter (WEC) to be quantified. The methodology is illustrated by application to the Wave Hub site off the coast of Cornwall, UK. Control and future wave climates were derived using wind fields output from a set of climate change experiments. Control wave conditions were generated from wind data between 1961 and 2000. Future wave conditions were generated using two IPCC wind scenarios from 2061 to 2100, corresponding to intermediate and low greenhouse gas emissions (IPCC scenarios A1B and B1 respectively). The quantitative comparison between future scenarios and the control condition shows that the available wave power will increase by 2–3% in the A1B scenario. In contrast, the available wave power in the B1 scenario will decrease by 1–3%, suggesting, somewhat paradoxically, that efforts to reduce greenhouse gas emissions may reduce the wave energy resource. Meanwhile, the WEC energy will yield decrease by 2–3% in both A1B and B1 scenarios, which is mainly due to the relatively low efficiency of energy extraction from steeper waves by the specific WEC considered. Although those changes are relatively small compared to the natural variability, they may have significance when considered over the lifetime of a wave energy farm. Analysis of downtime under low and high thresholds suggests that the distribution of wave heights at the Wave Hub will have a wider spread due to the impacts of climate change, resulting in longer periods of generation loss. Conversely, the estimation of future changes in joint wave height-period distribution provides indications on how the response and power matrices of WECs could be modified in order to maintain or improve energy extraction in the future. [Copyright &y& Elsevier]

Abstract: A number of studies have shown the importance of accurate base line data as a basis for the development of more sustainable environmental policies. The role of this paper is to propose a standardised per capita unit that could be utilised to measure healthcare waste generation patterns across a range of both patient and non-patient departments. Based on a case study of waste generation in selected departments in the Cornwall NHS, the results demonstrate that general and acute care wards are amongst some of the highest per capita generators of healthcare waste. The potential benefits of utilising the unit, including the departments that should be targeted are also discussed. [Copyright &y& Elsevier]