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Start Over Author "Rosser, Ethan W." Publisher american chemical society
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1. A Specific Nucleophilic Ring-Opening Reaction of Aziridinesas a Unique Platform for the Construction of Hydrogen PolysulfidesSensors.

Author

Chen, Wei, Rosser, Ethan W., Zhang, Di, Shi, Wen, Li, Yilin, Dong, Wen-Ji, Ma, Huimin, Hu, Dehong, and Xian, Ming

Subjects
*NUCLEOPHILIC reactions, *RING-opening reactions, *AZIRIDINES, *HYDROGEN sulfide, *POLYSULFIDES, *CHEMICAL detectors
Abstract

A hydrogen polysulfide mediated aziridinering-opening reactionwas discovered. Based on this reaction, a novel H2Sn-specific chemosensor (AP) wasdeveloped. APshowed high sensitivity and selectivityfor H2Sn. Notably, the fluorescentturn-on product (1) exhibited excellent two-photon photophysicalproperties, a large Stokes shift, and high solid state luminescentefficiency. [ABSTRACT FROM AUTHOR]

Published
2015
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