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A Specific Nucleophilic Ring-Opening Reaction of Aziridinesas a Unique Platform for the Construction of Hydrogen PolysulfidesSensors.

Authors :
Chen, Wei
Rosser, Ethan W.
Zhang, Di
Shi, Wen
Li, Yilin
Dong, Wen-Ji
Ma, Huimin
Hu, Dehong
Xian, Ming
Source :
Organic Letters. Jun2015, Vol. 17 Issue 11, p2776-2779. 4p.
Publication Year :
2015

Abstract

A hydrogen polysulfide mediated aziridinering-opening reactionwas discovered. Based on this reaction, a novel H2Sn-specific chemosensor (AP) wasdeveloped. APshowed high sensitivity and selectivityfor H2Sn. Notably, the fluorescentturn-on product (1) exhibited excellent two-photon photophysicalproperties, a large Stokes shift, and high solid state luminescentefficiency. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15237060
Volume :
17
Issue :
11
Database :
Academic Search Index
Journal :
Organic Letters
Publication Type :
Academic Journal
Accession number :
103099463
Full Text :
https://doi.org/10.1021/acs.orglett.5b01194