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This paper describes the fabrication and characterization of porous SiC ceramics derived from highly-filled preceramic papers. The SiC ceramics were obtained by spark plasma sintering of stacked preceramic papers at temperatures of 2100 and 2200 °C under pressures of 5–60 MPa for 10 min. The microstructure and phase composition were analyzed by scanning electron microscopy and X-ray diffraction, respectively. Gas permeation tests were performed using hydrogen permeation cell at room temperature. It is revealed that the porosity of sintered SiC can be varied from 9 to 45 % depending on the sintering parameters. The shrinkage of the materials during spark plasma sintering occurs in four stages. The linear shrinkage value of the material increases from 7 to 47 % at 2100 °C and from 20 to 50 % for the samples sintered at 2100 and 2200 °C, respectively. Correlation dependencies between porosity and mechanical properties of the fabricated SiC were established. The obtained porous SiC ceramics exhibit high bending strength of 165 MPa and gas permeation flux of 78 molH 2 /m2/s at the porosity of 36 % that make it suitable for ceramic-based membranes. [ABSTRACT FROM AUTHOR]

This study evaluates the potential use of discarded plasterboard paper as fibers from buildings to reinforce concrete. Various concentrations of wastepaper fibers (0.5%, 1%, 1.5%, 2%, and 2.5% by weight of the binder) were investigated in this research. To mitigate the water absorption effect of the paper fibers, metakaolin was employed as a partial cement replacement. The results demonstrate that the inclusion of the wastepaper fiber enhances the mechanical and durability performance of the concrete. The optimal fiber proportion was identified as 1%, leading to a 29% increase in the compressive strength, a 38% increase in the splitting tensile strength, a 12% decrease in the water absorption, and a 23% decrease in the drying shrinkage with respect to the concrete containing 20% metakaolin. However, exceeding this optimal fiber content results in decreased mechanical and durability properties due to the fiber agglomeration and non-uniform fiber distribution within the concrete matrix. Based on the microstructural analysis, the improved performance of the concrete is ascribed to decreased porosity, more refined pore structure, and reduced propagation of microcracks within the concrete matrix in the presence of wastepaper fiber. According to the results, concrete containing 20% metakaolin and 1% wastepaper fiber exhibits durability and mechanical properties comparable to those of the traditional concrete. This finding highlights the significant promise of reducing dependency on conventional cement and incorporating suitable recycled materials, such as discarded plasterboard, and secondary by-products like metakaolin. Such a strategy encourages the preservation of resources, reduction in carbon dioxide emissions, and a decrease in the ecological footprint resulting from concrete production. [ABSTRACT FROM AUTHOR]

Background: The potential effect of image noise artefacts on Digital Volume Correlation (DVC) analysis has not been thoroughly studied and, more particularly quantified, even though DVC is an emerging technique widely used in life and material science over the last decade. Objective: This paper presents the results of a sensitivity study to shed light on the effect of various noise artefacts on the full-field kinematic fields generated by DVC, both in zero and rigid body motion. Methods: Various noise artefacts were studied, including the Gaussian, Salt & Pepper, Speckle noise and embedded Ring Artefacts. A noise-free synthetic microstructure was generated using Discrete Element Modelling (DEM), representing an idealistic case, and acting as the reference dataset for the DVC analysis. Noise artefacts of various intensities (including selected extreme cases) were added to the reference image datasets using MATLAB (R2022) to form the outline of the parametric study. DVC analyses were subsequently conducted employing AVIZO (Thermo Fisher). A subset-based local approach was adopted. A three-dimensional version of the Structural Similarity Index Measure (SSIM) was used to define the similarity between the compared image datasets on each occasion. Sub-pixel rigid body motion was applied on the DEM-generated microstructure and subsequently "poisoned" with noise artefacts to evaluate mean bias and random error of the DVC analysis. Results: When the local approach is implemented, the sensitivity study on zero motion data revealed the insignificant effect of the Gaussian, Salt & Pepper, and Speckle noise on the DVC-computed kinematic field. Therefore, the presence of such noise artefacts can be neglected when DVC is executed. On the contrary, Ring Artefacts can pose a considerable challenge and therefore, DVC results need to be evaluated cautiously. A linear relationship between SSIM and the correlation index is observed for the same noise artefacts. Gaussian noise has a pronounced effect on the mean bias error for sub-pixel rigid body motion. Conclusions: Generating synthetic image datasets using DEM enabled the investigation of a variety of noise artefacts that potentially affect a DVC analysis. Given that, any microstructure – resembling the material studied – can be simulated and used for a DVC sensitivity analysis, supporting the user in appropriately evaluating the computed kinematic field. Even though the study is conducted for a two-phase material, the method elaborated in this paper also applies to heterogeneous multi-phase materials also. The conclusions drawn are valid within the environment of the AVIZO DVC extension module. Alternative DVC algorithms, utilising different approaches for the cross-correlation and the sub-pixel interpolation methods, need to be investigated. [ABSTRACT FROM AUTHOR]

This paper presents the influence of adding rinsed ilmenite mud waste (R-MUD) on the microstructure of Portland cement composites, compared to similar composites containing fly ash (FA). The aim of the study is the assessment of the pozzolanic activity of ilmenite mud waste by its impact on the microstructure of the cement matrix in comparison to the undoubted pozzolanic activity of fly ash. The presented test results include pore size distribution, phase composition, pozzolanic activity using thermal analysis, R3 bound water test, and microstructural analysis using scanning electron microscopy (SEM). Tests were performed on mortars cured for up to 360 days. The results presented in this paper have shown that R-MUD has a pozzolanic activity level similar to FA or better, which influences pore size distribution in the composite and its microstructure. During the curing process, the microstructure of composites containing R-MUD became more compact and sealed than those with FA, which might also increase their durability. The results of the R3 tests have proven the pozzolanic activity of R-MUD but its level was lower than FA. R-MUD might be a useful substitute for fly ash, especially given the lack of good-quality fly ash on the market. [ABSTRACT FROM AUTHOR]

Both copper and lithium act as strong fluxes and lower the temperature of the clinker melt formation. Sulphur promotes the stabilisation of more hydraulically active modification of alite M1. It is expected that this combination could produce an alite clinker at significantly lower temperatures with high quality technological parameters. In this paper, the effect of combined oxides of copper, lithium and sulphur addition on the phase composition and clinker structure of Portland cement was investigated. The reference raw meal was prepared from common cement raw materials. Each of the mentioned oxides was added to the reference raw meal in two different concentrations, and 8 combinations were prepared. Chemically pure compounds (NH4)2SO4, CuO and Li2CO3 were used as a source of these oxides. The raw meals were burned to equilibrium at 1450°C. Their phase composition was determined by X‐ray diffraction analysis, the microstructure was monitored by optical microscopy, and the microchemistry of the clinker phases was observed by electron microscopy with EDS analysis. It was found that in samples with high lithium or copper content, there is an increase in belite and free lime at the expense of alite. The combination of Cu + Li has the most negative effect, followed by Li alone and Cu alone. The higher SO3 content slightly offsets this negative effect. LAY DESCRIPTION: Clinker is the main intermediate in the production of Portland cement. It is formed at high temperatures in a rotary kiln and its main component is the mineral alite – tricalcium silicate. Alite crystallises in several polymorphic modifications, and sulphur stabilises the modification that increases cement strength. Both copper and lithium act as strong fluxes and lower the temperature of the clinker melt formation. The addition of a combination of these 3 elements to the raw meal for clinker burning is expected to lower the melt formation temperature, and clinker with a high alite content will be formed at lower temperatures than normal. This would both save energy consumption for burning and reduce CO2 emissions in cement production. In this paper, the effect of combined of copper, lithium, and sulphur addition on the phase composition and clinker structure of Portland cement was investigated. The reference raw meal was prepared from common cement raw materials, two limestones, clay shale and Fe correction. Each of the mentioned elements was added to the reference raw meal in two different concentrations, and 8 combinations were prepared. Chemically pure compounds (NH4)2SO4, CuO, and Li2CO3 were used as a source of these elements. The raw meals were burned at 1450°C. Their phase composition was determined by X‐ray diffraction analysis, the microstructure was monitored by optical microscopy, and the microchemistry of the clinker phases was observed by electron microscopy with energy dispersive spectroscopy. It was found that in samples with high lithium or copper content, there is an decrease in alite. The combination of Cu + Li has the most negative effect, followed by Li alone and Cu alone. The higher sulphur content slightly offsets this negative effect. Finally, a clinker was prepared with the addition of these 3 dopants at a temperature of 1325°C, 125°C lower than in conventional industrial production, which had a high quality phase composition with a high alite content. [ABSTRACT FROM AUTHOR]

C4AF is considered the least reactive main clinker phase, but its reactivity may be affected by adding supplementary cementitious materials (SCMs). Pure C4AF was synthesised in a laboratory furnace, and the role of silica fume without gypsum on its early hydration properties was monitored. Burning was carried out in four stages to achieve 99% purity of C4AF. Heat flow development was monitored by isothermal calorimetry over 7 days of hydration at 20°C and 40°C. The role of silica fume on hydrogarnet phase katoite (Ca3Al2(SiO4)3 –x(OH)4x x = 1.5–3) formation during early hydration was studied. Rapid dissolution of C4AF, formation of metastable C‐(A,F)‐H and its conversion to C3(A, F)H6 was evidenced by isothermal calorimetry as a large exotherm. Changes in microstructure during early hydration were documented by SE micrographs, EDS point analyses, X‐ray mapping and line scans by SEM‐EDS. The phase composition was characterised by DTA‐TGA and QXRD after 7 days of hydration. The katoite diffraction pattern is similar for the reference sample and sample with silica fume, but substitution in its structure can be revealed by X‐ray microanalyses. The composition of katoite is variable due to the various extent of substitution of 4OH− by SiO44− due to silica fume. LAY DESCRIPTION: The paper discusses the role of silica fume on katoite formation during early hydration of C4AF. Rapid dissolution of C4AF, formation of metastable C‐(A,F)‐H and its conversion to C3(A, F)H6 was evidenced by isothermal calorimetry. Changes in microstructure during early hydration were documented by SE micrographs and X‐ray mapping and line scans by SEM‐EDS. The phase composition after 7 days of hydration was characterised by DTA‐TGA and QXRD. The high mobility of Al and Ca and the low mobility of Fe in the relic microstructure is discussed in the paper. Although katoite has the similar diffraction pattern for reference sample and sample with silica fume, different degrees of substitution in its structure can be seen in the silica fume system using SEM X‐ray microanalyses. [ABSTRACT FROM AUTHOR]

P92 steel is a modern martensitic heat-resistant steel currently used for seamless products for pressure equipment operating in supercritical operating parameters. The paper presents the results of a study on the strength properties and structure of a P92 steel welded joint used for pressure components of power units. The paper presents an assessment of the suitability for further operation of both the parent material and a circumferential similar welded joint of finished products in the form of P92 steel pipes after annealing for 3000 hours at 600 and 650°C. Annealing at 650°C results in faster increase in the size of the precipitates and their coagulation along grain boundaries of former austenite and martensite laths. The changes in mechanical properties were compared in relation to the state of the structure of the parent material and the material of the welded joint. Quantitative analysis of M23C6 precipitates was also carried out. [ABSTRACT FROM AUTHOR]

The cellular automata (CA) method has played an important role in the research and development of metallic materials. CA can interpret the microstructure changes of materials and obtain more abundant, accurate and intuitive information of microstructure evolution than conventional methods. CA can visually represent the process of grain formation, growth, development and change to us in a graphical way, which can assist us in analysis, thinking and solving problems. In the last five years, the application of CA in materials research has been rapidly developed, and CA has begun to occupy an increasingly important position in the simulation research of metallic materials. After introducing the advantages and limitations of CA compared to other widely used simulation methods, the purpose of this paper is to review the recent application progress on the microstructure simulation of metallic materials using CA, such as solidification, recrystallization, phase transformation and carbide precipitation occurring during forming and heat treatment. Specifically, recent research advances on microstructure simulation by CA in the fields of additive manufacturing, welding, asymmetrical rolling, corrosion prevention, etc., are also elaborated in this paper. Furthermore, this paper points out the future work direction of CA simulation in the research of metallic materials, especially in the simulation of the crystal structure, the prediction of mechanical properties, CA simulation software and rule systems, etc. These are expected to attract wide attention of researchers in the field of metallic materials and promote the development of CA in materials research. [ABSTRACT FROM AUTHOR]

Purpose: This paper aims to identify the optimal forming angle for the selective laser melting (SLM) process and evaluate the mechanical properties of the SLM-formed GH3536 alloy in the aero-engine field. Design/methodology/approach: Forming the samples with optimized parameters and analyzing the microstructure and properties of the block samples in different forming angles with scanning electron microscope, XRD, etc. so as to analyze and reveal the laws and mechanism of the block samples in different forming angles by SLM. Findings: There are few cracks on the construction surface of SLM formed samples, and the microstructure shows columnar subgrains and cellular subgrains. The segregation of metal elements was not observed in the microstructure. The pattern shows strong texture strength on the (111) crystal plane. In the sample, the tensile strength of 60° sample is the highest, the plasticity of 90° forming sample is the best, the comprehensive property of 45° sample is the best and the fracture mode is plastic fracture. The comprehensive performance of the part is the best under the forming angle of 45°. To ensure the part size, performance and support structure processing, additional dimensions are added to the part structure. Originality/value: In this paper, how to make samples with different forming angles is described. Combined with the standard of forged GH3536 alloy, the microstructure and properties of the samples are analyzed, and the optimal forming angle is obtained. [ABSTRACT FROM AUTHOR]

The present paper investigates the effect of carbon nanofibers (CNFs) on the microstructure and mechanical properties of Carbon fiber reinforced carbon and silicon carbide binary matrix (C/C–SiC) composite prepared by using the reactive melt infiltration technique. The CNFs used in this paper were generated through in-situ reaction in the pores of C/C preforms using the chemical vapor deposition. Results indicate introducing additional carbon sources in the form of CNFs in the C/C preform can remarkably improve the permeability of molten Si, resulting in higher density and more uniform microstructure of the RMI-deriver C/C–SiC composites. Consequently, the in-situ formation of CNFs reduces the residual Si content by 64.71% and increases the mechanical strength and modulus at room temperature by [22.31% and 17.89%] and after heat treatment at 1500 °C by [35.6% and 47.48%] with respect to no-CNF containing composites due to a lower amount of residual Si content and additional reinforcement effect of the unreacted CNFs. [ABSTRACT FROM AUTHOR]

Solar thermal power generation is an important direction of energy utilization, and thermal storage materials are the key to ensure the continuous use of energy. In this paper, forsterite - zirconia composite ceramics were prepared by adding different contents of 3Y–ZrO 2 and their physical properties, phase composition, microstructure thermal shock resistance and thermal physical properties were studied. The results showed that the water absorption, bulk density and bending strength of sample A3 sintered at 1600 °C (59.10 wt% fused magnesia, 40.90 wt% quartz and 30 wt% 3Y–ZrO 2) were 0.35 %, 3.27 g/cm3 and 83.66 MPa, respectively. The crystal phase of sample A3 was forsterite and c-ZrO 2. Mg2+ and Y3+ replace Zr4+, formed oxygen vacancy in the anion position, distort the coordination layer and release some interlayer stress to promote the stability of c-ZrO 2. In the sintering process, the zirconia solid solution existed in the form of second phase, which reduced the growth rate of periclase, facilitated the pore discharge in the sample and promotes sintering. The thermal conductivity of forsterite - zirconia composite ceramics at room temperature was 5.52 W/(m·K). At 1000 °C, the specific heat capacity and heat storage density were 1.09 J/(g·K) and 1062.36 kJ/kg, respectively. The forsterite - zirconia composite ceramic prepared in this study was suitable for high temperature environment, its heat storage capacity was excellent, and it was suitable for high temperature heat storage system. [ABSTRACT FROM AUTHOR]

Metal additive manufacturing technologies provide new opportunities for manufacturing complex components. However, the limited data on fracture behavior are delaying adoption in safe‐critical applications. This paper aims to evaluate the effect of orientation and the intra‐build design parameters on EBM Ti6Al4V fracture toughness using a design of experiments. Three builds comprised of over 150 compact tension samples were printed representative of the EBM build chamber, followed by microstructural characterization, X‐ray microcomputed tomography, and fracture toughness testing per ASTM E399. The average fracture toughness was 65 MPa√m, with anisotropy as the largest source of variation due to crack growth behavior with respect to the build direction. Microstructure coarsening was observed with increase in height, resulting in an increase in fracture toughness, irrespective of sample geometry or orientation. Build orientation and sample location influenced the microstructure and fracture toughness and should be considered when adopting EBM components in load‐bearing applications. [ABSTRACT FROM AUTHOR]

3D printing is an excellent choice for manufacture of ceramic cores; however, the inter-layer structures in 3D printed sample leads to anisotropy in microstructure and properties. In this paper, silica-based ceramic cores were prepared by digital light processing, and metallic Si powder was employed as mineralizer to relieve the anisotropy. The metallic Si powder converts into SiO 2 in oxidation reaction with significant volume expansion, which inhibits the shrinkage rate and partly fills the interlayer gaps of the ceramic core. Meanwhile, the metal Si powder leads to lower curing thickness in 3D printing, and thicken the interlayer gaps. Due to the cooperation of the oxidation reaction and decreased curing thickness by the metallic Si powder, the 0.4 wt% of metallic Si powder reduced the anisotropy in structure and mechanical property due to the alleviated inter-layer structure and the interlayer and intralayer strengths show optimal values of 11.4 MPa and 17.2 MPa at room temperature, respectively. This work inspires new guidance to 3D printing of ceramic cores with uniform microstructure and excellent mechanical properties. [ABSTRACT FROM AUTHOR]

Insulators are vital components used in electrical transmission lines. It's crucial to keep their production cost low since they are widely used in electricity transmission. Instead of expensive alumina-based insulators, we can make cheaper ones using clay and bauxite found in nature. Adding more alumina makes them stronger, which is important for high voltage transmission. This paper aims to study the production process of bauxite-based insulators. We examined the insulators' structure using SEM images and EDAX spectrum analysis to see their formations, porosity ratio, and density. This research helps us learn more about these insulators and how they can be used effectively for high voltage transmission lines. [ABSTRACT FROM AUTHOR]

This paper was attempted to investigate the microstructure degradation and low cycle fatigue (LCF) performance of a serviced K465 Ni‐based superalloy turbine blade. LCF tests were carried out with small‐scale plate specimens sampled from the blades. Relationship between residual LCF life and microstructure state was estimated. The results indicate that the coarsening of γ/γ′ phases was the most significant microstructure degradation mode for the serviced blades. Both the γ matrix width and the γ′ precipitate diameter increased with the increase of service duration, while the γ′ precipitate volume fraction slightly decreased. The most severe microstructure degradation occurred at the leading edge along the chord direction, particularly at 50–70 % airfoil spans. The residual LCF life exhibited an accelerated decrease characteristic as increases of microstructure degradation degree. The coarsened microstructure diminished shear resistance of the superalloy, which resulted in additional accumulated inelastic deformation and a corresponding reduction in LCF life. Highlights: Service induced microstructure evolution and LCF life decay of a blade were investigated.Coarsening was identified as the main degradation form of γ/γ' phases in serviced blade.Accelerated decrease of residual LCF life was identified as increases of coarsening.Reduced plastic deformation resistance owing to coarsening is crucial to decay LCF life. [ABSTRACT FROM AUTHOR]

The paper concerns the influence of heat treatment (annealing, quenching and aging) on the microstructure and hardness of flat bars samples from the CuAl10Ni5Fe4 alloy. The microstructures were observed in light and scanning electron microscopes. The appearance and area fractions of the martensite beta phase and their influence on the mechanical properties were examined. The annealing study at a temperature of 950 °C for 1 hour, followed by rapid quenching in water and subsequent tempering at a temperature of 350-500 °C for 15-120 minutes, demonstrated the potential for a significant increase in the hardness of aluminum bronze from approximately 200 HV3 up to 600 HV3. This suggests new possibilities for the material's applications. [ABSTRACT FROM AUTHOR]

In this paper, the effects of frequency on the flash sintering behavior and microstructure of Li 6.4 Ga 0.2 La 3 Zr 2 O 12 (0.2Ga-LLZO) were investigated. The results showed that an increase in frequency had little effect on the onset temperature, but this increase reduced the duration of the weak current stage the incubation stage. Moreover, this phenomenon led to a decrease in the power loss during the constant current stage. Scanning Electron Microscope images showed that the microstructure was symmetrically distributed, and the uniformity increased with increasing frequency. Finite element simulations and an IR thermocamera were used to analyze the temperatures of the specimens. The symmetric distribution of temperature during the flash sintering process was the root cause. The results of AC impedance spectroscopy showed that when the frequency of flash sintering was ≥ 400 Hz, the ionic conductivity of Ga-LLZO was greater than that of conventional sintering. The results of this work demonstrated the important role of frequency in controlling the microstructures of ceramic materials in flash sintering. [ABSTRACT FROM AUTHOR]

This paper utilizes the plasma arc as the heat source to successfully fabricate well-formed thin-walled parts using combined cable wire duplex stainless steel 2209. Microstructure of parts exhibited the favorable two-phase ratio and the absence of σ-phase. It was found that appropriate heat input (1.68 kJ/cm) and cooling rate (5 °C/s) can effectively avoid the precipitation of σ-phase. Furthermore, the properties of the as-deposited samples were comparable to those of the samples heat-treated at 1300 °C, proving that no subsequent heat treatment was required for 2209 stainless steel fabricated by plasma arc additive manufacture. The samples showed excellent properties, in which the ultimate tensile strength and yield strength were improved by about 7% and 24% compared with GB/T4237-2015. The impact toughness meets the requirements of EN10028-7-2016, which is about 35% higher than that of the cold metal transfer samples, and the corrosion resistance is comparable to that of hot rolled 2205. [ABSTRACT FROM AUTHOR]

Automobile structural components are subject to high stress, friction and corrosive environmental conditions. Though aluminum alloys exhibit lightweight and high corrosion resistance, there is a need to improve the high strength-to-weight ratio and resistance to friction. This paper presents microstructural analysis, hardness, dry sliding wear behavior, and corrosion behavior of AA7075 reinforced with silicon carbide (SiC) particles. The composite specimens were prepared at the concentration of 2.5 and 5wt.% SiC. The microstructure of AA7075 showed dendritic morphology while composite specimens showed nondendritic morphology grains. Reinforcement of SiC resulted in increased nucleation site and refinement of grain during solidification. XRD analysis of base alloy showed α matrix with η (MgZn2), T(Al–Zn–Mg–Cu) and Al7Cu2Fe phases, while the composite sample showed the presence of additional S(Al2CuMg) and θ (Al2Cu) phases. Composite samples showed higher hardness values than base alloy due to grain boundary strengthening and Orowan strengthening. The enhancement of hardness of AA7075 by 20% and 37.5% were obtained with the addition of 2.5 and 5wt.% SiC particles respectively and also predicted with less coefficient of friction and less wear rate at all the tested load conditions. At the same time, the respective reduction in wear rates of AA7075 was found to be 50 and 65%. The worn-out surface of the base alloy was found to have undergone extensive plastic deformation and resulted in delamination with extensive patches and no clear groove marks. The composite sample of 2.5wt.% SiC showed mild patches with clear groove marks, while the Composite of 5wt.% SiC showed groove marks with fine width parallel to sliding directions. The wear mechanism was found to be transferred from adhesive mode to abrasive mode through a mixed mechanical layer with an added concentration of SiC particles from 0wt.% to 5wt.%. Weight loss during immersion corrosion increases with an increase in the amount of SiC due to an increased amount of metallic phase which increases microgalvanic corrosion and pitting. Hence, composite samples showed decreased corrosion resistance than base alloy. [ABSTRACT FROM AUTHOR]

This paper presents a thorough manufacturability study of 2507 super duplex stainless steel (SDSS) produced by the Laser Powder-Directed Energy Deposition (LP-DED) process. First, experimental observations on single-track surface morphology and geometrical characteristics are described. Then, dimensional and porosity analyses of thin walls and bulk samples are presented and discussed in order to identify the optimal process parameter combinations, from a process point of view, for further characterizations to determine the general properties of LP-DED-printed samples. Finally, the results obtained on wrought steel of the same grade are compared to those of the printed material in terms of microstructure, texture, and ferrite/austenite ratio. A set of meticulously chosen process parameters with regard to the process and the machine (nozzle size, maximum power deliverable) gives the optimal results for the as-built LP-DED material in terms of porosity and microstructure quality but with smaller grains (irrespective of the phase studied) and a higher proportion of ferrite (about 75%). [ABSTRACT FROM AUTHOR]

MCrAlY (M = Ni and/or Co) metallic coatings are essential for the protection of hot-end components against thermal and corrosion damage. Increasing the Al content is considered a feasible solution to improve the high-temperature performance of MCrAlY coatings. In this paper, the effects of high Al contents (12–20 wt.%) on the phase constituents and cast microstructures in MCrAlY alloys were studied by high-energy X-ray diffraction and electron microscopy techniques combined with phase equilibria calculations. High Al content improved the stability of β, σ, and α phases. Meanwhile, an evolution of the cast microstructure morphology from a dendrite structure to an equiaxed grain structure was observed. The thermal properties were analyzed, which were closely related to the phase constituents and solid-to-solid phase transitions at evaluated temperatures. This work is instructive for developing high-Al-content MCrAlY coatings for next-generation thermal barrier applications. [ABSTRACT FROM AUTHOR]

The application of advanced high-strength steel grades (AHSS) in different kinds of industry is connected to more than their attractive mechanical properties. The present paper focuses on improving the welding Docol 1300M steel to reach an acceptable microstructure and mechanical parameters. It was decided to manufacture joints with different welding parameters using different filler materials. The electrode wires were varied to increase the carbon content in the weld, and nitrogen was added to the argon shielding mixture to obtain non-metallic inclusions that strengthen the fusion zone. Specimens of joints welded with the gas metal arc welding (GMAW) process for non-destructive and destructive tests were examined. Tensile and bending tests as well as microscopic inspections using a light (LM) and scanning electron microscope (SEM) were also conducted. The results from the fatigue test confirmed the validity of the proposed welding process for the Docol 1300M joint. The collected data enabled the following conclusion: The article's novelty is represented by the use of shielding gas mixtures containing argon and nitrogen in the GMAW welding process of AHSS steel to create titanium non-metallic inclusions, which will translate into better performance properties of the entire joint. [ABSTRACT FROM AUTHOR]

In this paper, we study the influence of densified microsilica and colloidal nanosilica admixtures on the mechanical strength and the microstructural characteristics of special mortars used for immobilizing radioactive concrete waste. The experimental program focused on the replacement of cement with micro- and/or nanosilica, in different proportions, in the basic composition of a mortar made with recycled aggregates. The technical criteria imposed for such cementitious systems, used for the encapsulation of low-level radioactive waste, imply high fluidity, increased mechanical strength and lack of segregation and of bleeding. We aimed to increase the structural compactness of the mortars by adding micro- and nanosilica, all the while maintaining the technical criteria imposed, to obtain a cement matrix with high durability and increased capacity for immobilizing radionuclides. The samples from all the compositions obtained were analyzed from the point of view of mechanical strength. Also, micro- and nanosilica as well as samples of the optimal mortar compositions were analyzed physically and microstructurally. Experimental data showed that the mortar samples present maximum compressive strength for a content between 6 and 7.5% wt. of microsilica, respectively, for a content of 2.25% wt. nanosilica. The obtained results suggest a synergistic effect of micro- and nanosilica when they are used simultaneously in cementitious compositions. Thus, among the analyzed compositional variants, the mortar composition with 3% wt. microsilica and 2.25% wt. nanosilica showed the best performance, with an increase in compressive strength of 23.5% compared to the control sample (without micro- and nanosilica). Brunauer–Emmett–Teller (BET) analysis and scanning electron microscopy (SEM) images highlighted the decrease in pore diameter and the increase in structural compactness, especially for mortar samples with nanosilica content or a mixture of micro- and nanosilica. This study is useful in the field of recycling radioactive concrete resulting from the decommissioning of nuclear research or nuclear power reactors. [ABSTRACT FROM AUTHOR]

With the rapid development of electronic technology and large-scale integrated circuit devices, it is very important to develop thermal management materials with high thermal conductivity. Silicon carbide whisker-reinforced copper matrix (Cu/SiCw) composites are considered to be one of the best candidates for future electronic device radiators. However, at present, most of these materials are produced by high-temperature and high-pressure processes, which are expensive and prone to interfacial reactions. To explore the plating solution system suitable for SiCw and Cu composite electroplating, we tried two different Cu-based plating solutions, namely a Systek UVF 100 plating solution of the copper sulfate (CuSO4) system and a Through Silicon Via (TSV) plating solution of the copper methanesulfonate (Cu(CH3SO3)2) system. In this paper, Cu/SiCw composites were prepared by composite electrodeposition. The morphology of the coating under two different plating liquid systems was compared, and the mechanism of formation of the different morphologies was analyzed. The results show that when the concentration of SiCw in the bath is 1.2 g/L, the surface of the Cu/SiCw composite coating prepared by the CuSO4 bath has more whiskers with irregular distribution and the coating is very smooth, but there are pores at the junction of the whiskers and Cu. There are a large number of irregularly distributed whiskers on the surface of the Cu/SiCw composite coating prepared with the copper methanesulfonate (Cu(CH3SO3)2) system. The surface of the composite is flat, and Cu grows along the whisker structure. The whisker and Cu form a good combination, and there is no pore in the cross-section of the coating. The observation at the cross-section also reveals some characteristics of the toughening mechanism of SiCw, including crack deflection, bridging and whisker pull-out. The existence of these mechanisms indicates that SiCw plays a toughening role in the composites. A suitable plating solution system was selected for the preparation of high-performance Cu/SiCw thermal management materials with the composite electrodeposition process. [ABSTRACT FROM AUTHOR]

With development of present energy-saving society, lightweight and green development in the automotive and aerospace industries have put forward urgent demands for heat-resistant cast aluminum alloys. Present cast aluminum alloys are of lightweight and have excellent mechanical properties when serving in ambient environment. However, when serving at temperatures of 200–300 ℃ or even higher, the alloys inevitably soften and the high-temperature mechanical properties decline rapidly, hardly meeting the requirements for high-performance equipments. This paper summarizes the development process of classic heat-resistant aluminum alloys, especially the microstructural characteristics of heat-resistant cast aluminum alloys in the past decade, and reviews the current microstructure tuning strategies of heat-resistant aluminum alloys from the aspects of intrinsic heat resistance of the second phases, phase interface modification, diffusion-controlled phase transition, grain boundary stabilization and composite material design. Finally, we propose the prospects for the future development of heat-resistant aluminum alloys. [ABSTRACT FROM AUTHOR]

Lightweight strategy is essential for the development of transportation vehicles and aerospace industries. As a type of lightweight material, high-strength aluminum alloys are limited to service temperatures below 200 °C due to the rapid coarsening of strengthening nano-precipitates, which cannot satisfy the increasing demands of practical applications. High-temperature applications beyond 250 °C become the bottle-neck problem of Al alloys. In this paper, we review existing literature on the improvement of high-temperature performance of aluminum alloys by stabilizing nano-precipitates. On the basis of atomic-scale microstructure regulation, several design strategies, such as interface segregation, co-precipitation, core/shell structure, and interstitial ordering, have been proposed, resulting in the development of a number of heat-resistant Al alloys for use at 300–400 °C. Moreover, the fundamental theories of solid-state phase transformation, especially precipitation aging and coarsening, are correspondingly advanced on the frontiers of science. [ABSTRACT FROM AUTHOR]

The positive relationship between knowledge transfer and knowledge innovation is recognized by most scholars, while knowledge heterogeneity, as a knowledge situation of the enterprise organization, affects knowledge transfer within enterprise organizations. Therefore, as a state, knowledge transfer can be regarded as a result of knowledge heterogeneity, and it becomes the intermediary state between knowledge heterogeneity and knowledge innovation. The organizational structure of individuals within an enterprise organization may affect these three elements and their interrelationships. In this paper, data are collected by means of on-the-spot investigation and a network questionnaire for analysis. The results show that the microstructure state of the individual in the enterprise organization plays a moderating role for the first three elements. The lower that the micro-restriction of the individual is, the more favorable the knowledge heterogeneity is for the inverted U-shaped impact of knowledge transfer and knowledge innovation and the more favorable the occurrence of knowledge innovation. [ABSTRACT FROM AUTHOR]

We attempt to formalise the relationship between the poroelasticity theory and the effective medium theory of micromechanics. The assumptions of these two approaches vary, but both can be linked by considering the undrained response of a material; and that is the main focus of the paper. To analyse the linkage between poroelasticity and micromechanics, we do not limit ourselves to the original theory of Biot. Instead, we consider a multi‐porous extension of anisotropic poroelasticity, where pore fluid pressure may vary within the bulk medium of interest. As a consequence, any inhomogeneities in the material are not necessarily interconnected; instead, they may form isolated pore sets that are described by different poroelastic parameters and fluid pressures. We attempt to incorporate the effective methods inside Biot‐like theory and investigate the poroelastic response of various microstructures. We show the cases where such implementation is valid and the others that appear to be questionable. During micromechanical analysis, we derive a particular case of cylindrical transverse isotropy—commonly assumed in conventional laboratory triaxial tests—where the symmetry is induced by sets of aligned cracks. [ABSTRACT FROM AUTHOR]

The difference in microstructure leads to the diversity of shale mechanical properties and bedding fractures distribution patterns. In this paper, the microstructure and mechanical properties of Longmaxi marine shale and Qingshankou continental shale were studied by X-ray diffractometer (XRD), field emission scanning electron microscope (FE-SEM) with mineral analysis system, and nanoindentation. Additionally, the typical bedding layers area was properly stratified using Focused Ion Beam (FIB), and the effects of microstructure and mechanical properties on the distribution patterns of bedding fractures were analyzed. The results show that the Longmaxi marine shale sample contains more clay mineral grains, while the Qingshankou continental shale sample contains more hard brittle mineral grains such as feldspar. For Longmaxi marine shale sample, hard brittle minerals with grain sizes larger than 20 mm is 18.24% and those with grain sizes smaller than 20 mm is 16.22%. For Qingshankou continental shale sample, hard brittle minerals with grain sizes larger than 20 mm is 40.7% and those with grain sizes smaller than 20 mm is 11.82%. In comparison to the Qingshankou continental shale sample, the Longmaxi marine shale sample has a lower modulus, hardness, and heterogeneity. Laminated shales are formed by alternating coarse-grained and fine-grained layers during deposition. The average single-layer thickness of Longmaxi marine shale sample is greater than Qingshankou continental shale sample. The two types of shale have similar bedding fractures distribution patterns and fractures tend to occur in the transition zone from coarse-grained to fine-grained deposition. The orientation of the fracture is usually parallel to the bedding plane and detour occurs in the presence of hard brittle grains. The fracture distribution density of the Longmaxi marine shale sample is lower than that of the Qingshankou continental shale sample due to the strong heterogeneity of the Qingshankou continental shale. The current research provides guidelines for the effective development of shale reservoirs in various sedimentary environments. [ABSTRACT FROM AUTHOR]

Soil-improvement techniques with binders are used in several geotechnical engineering applications as a sustainable solution for the reuse of waste soils. Due to their inherent complexity and their mechanical behaviour, pyroclastic soils are generally considered waste geomaterials in their natural state. Lime treatment of pyroclastic soils can be considered a viable solution for their reuse in geotechnical applications. In this paper, some peculiar features of the chemo-physical evolution and mechanical behaviour of lime-treated pyroclastic soils are evidenced through a multi-scale experimental investigation. While, for clayey soils, the fine fraction is mainly responsible for ion exchange and pozzolanic reactions induced by lime, for pyroclastic soils, pozzolanic reactions are dominant processes due to the low quantity of clay minerals along with the abundance of aluminates and silicates as the main constituents of their amorphous phase. The link between the phenomena detected at the microscale level, the mineralogical composition, and the macroscopic behaviour of two lime treated pyroclastic soils of different origin is explored through a multiscale approach. [ABSTRACT FROM AUTHOR]

In this paper, the possibility of retreated lithium slag (RTLS) with a high content of alkali, sulfate and fluoride as a partial replacement for fly ash (FA) to produce autoclaved aerated concrete (AAC) was investigated. The influence of the RTLS dosage on the AAC performance were examined. The composition and microstructure of hydrates as well as the microstructure of the RTLS-FA-based AAC compositions were determined by XRD, FTIR, TG-DSC and SEM. The results illustrated that the incorporation of RTLS changed the crystal structure and the microstructure of the tobermorite. With increased RTLS contents, the morphology of tobermorite was changed, and the grass-like tobermorite gradually transformed into network-like tobermorite. The newly formed tobermorite improved the mechanical performance of the AAC. Compared with the RTLS10, the content of tobermorite in the RTLS30 increased by 8.6%. [ABSTRACT FROM AUTHOR]

Due to its lightweight, high strength, good machinability, and low cost, aluminum alloy has been widely used in fields such as aerospace, automotive, electronics, and construction. Traditional manufacturing processes for aluminum alloys often suffer from low material utilization, complex procedures, and long manufacturing cycles. Therefore, more and more scholars are turning their attention to the laser powder bed fusion (LPBF) process for aluminum alloys, which has the advantages of high material utilization, good formability for complex structures, and short manufacturing cycles. However, the widespread promotion and application of LPBF aluminum alloys still face challenges. The excellent printable ability, favorable mechanical performance, and low manufacturing cost are the main factors affecting the applicability of the LPBF process for aluminum alloys. This paper reviews the research status of traditional aluminum alloy processing and LPBF aluminum alloy and makes a comparison from various aspects such as microstructures, mechanical properties, application scenarios, and manufacturing costs. At present, the LPBF manufacturing cost for aluminum alloys is 2–120 times higher than that of traditional manufacturing methods, with the discrepancy depending on the complexity of the part. Therefore, it is necessary to promote the further development and application of aluminum alloy 3D printing technology from three aspects: the development of aluminum matrix composite materials reinforced with nanoceramic particles, the development of micro-alloyed aluminum alloy powders specially designed for LPBF, and the development of new technologies and equipment to reduce the manufacturing cost of LPBF aluminum alloy. [ABSTRACT FROM AUTHOR]

The concentration of heavy metals in soil layers has increased due to the rapid development of the industry. Lead and zinc are two frequent heavy metal contaminants in soil. This paper aims to study the effect of these types of contaminants on different fines, including kaolinite, bentonite, and zeolite mixed with sand. First, mixtures of sand and kaolinite, bentonite, and zeolite were prepared, then they were contaminated by two contaminants of lead and zinc nitrates, separately. Consolidated undrained triaxial tests, Soil Conservation Service (SCS) double hydrometer tests, scanning electron microscope (SEM), Atterberg limits, and pH determination tests were conducted on the soil samples to investigate the changes in the strength and microstructure in the presence of heavy metals. In general, triaxial test results showed that various parameters influence the strength results of these heavy metal-contaminated sandy soil samples such as type, percentage, and structure of the fine portion, type, and concentration of contaminants, bonding mechanism of fine grains, and ion exchange capacity. For instance, in the presence of kaolinite (and kaolinite-zeolite mixtures), contamination with lead decreased the strength of soil samples, but in the soil mixtures containing bentonite (and bentonite-kaolinite mixtures), an opposite trend was seen. The plasticity index of mixtures containing kaolinite and zeolite increased in the presence of heavy metal contaminants, but it decreased when the fine portion of the soil was bentonite. Heavy metal contaminants decreased the pH of all soil mixtures and made them to be acidic. The results of the SCS double hydrometer test and SEM indicated that contaminated kaolinite and zeolite soil mixtures have a dispersed structure, while bentonite soil mixtures are not dispersive. [ABSTRACT FROM AUTHOR]

:In paper, recycled Al-1.15Mg-1.02Si-0.7Cu alloy was optical prepared by meiting and casting, the microstructural evolution of the alloy were analyzed by using optical nicroscopy(OM), scanning e!ectron microscopy (SEM), e!ectron back scattered diffraciion(EBSD) and transmission e!ectron nicroscope(TEM),the effects of heal treatment on the mechanical and corrosionlresistant properties of the extruded proUes were invesiigated. The results show that the recrystaliization of the alloy was competed by soiid solution at 550C and fine equaaxaal crystass were obtanned. The iime required for the alloys to reach peak hardness under artificia1 aging cond!tions at 155,175 and 195 C was 18,8 and 4 h, respectively, and the peak hardnesses were 132.96 HV,132. 94 HV and 132.22 HV, respectively, wtth the extruded profiles obtanning the highest tensle strength of 410. 42 MPa and higher elongation of 14. 75% under aging cond!tions at 175 C/8 h. The optimizedsoid solution process ss 550 C/1 hand the artifidal aging process ss 175 C/8 h. The tendency of the alloy to intergranular corrosion ss more pronounced,and the alloy corrodes most severely under peakaged cond!tions, followed by over-aged and weakest underaged. [ABSTRACT FROM AUTHOR]

Atmtng at the problem that brittle Ti-Fe intermetalHc compounds are easily formed tn the additive manufacturing process of titanium/steel composites, which deteriorates the interface properties. In this paper, n^kel (ERN-1)was se!ected as the Interlayer,and the integrated preparation of TC4/309L composites was reaiized by laser fuse additive manufacturing technology. The effect of Ni interlayer addition on the rmcrostructure and properties of the interface was analyzed. The resuits show that "The interface of TC4/309L composites with Ni interlayer Is mainly composed of Fe/Ni interface and Ti/Ni interface. For the Fe/Ni interface,Fe and Ni form an infinite soiid solution, and no obvious defects such as cracks and pores are found, achieving a good metallurgical bonding. The Ti/Ni interface contains TiFe,TiNi3,TiNi,Ti2Ni and other brittle intermetalic compounds,and the maximum hardness of the interface reaches 670. 1 HV. The micro-area tensie test of the interface bondng strength shows that the bonding strength is 30. 5 MPa,and it breaks at the Ti/Ni Interface,showing brittie fracture characteristics. [ABSTRACT FROM AUTHOR]

For evaluating the resistance performance of cement-stabilized soils in cold regions, the variation of the strength of the cemented sand–gravel (CSG) mixture concerning the hydration process should be explored. This paper aims to study the effect of freeze–thaw (F–T) cycles on the strength and microstructure of a CSG mixture with 10% cement that is subjected to 12 cycles of freezing at a temperature of −23°C for 24 h and then melted at room temperature of 24°C for the next 24 h. The uniaxial compressive strength (UCS), California bearing ratio (CBR), and weight volume loss of the samples were measured after individual F–T cycles. Furthermore, the change in the microstructure of the CSG mixture in various F–T cycles was explored. The results showed a considerable reduction in the UCS up to Cycle 3, then a slight increase for Cycles 3–6, and finally a gradual decrease for further cycles. However, the CBR and weight loss slightly fluctuated up to Cycle 6, and then gradually decreased for subsequent cycles. The majority of compounds of hydrated cement were damaged in the first three cycles. In the following cycles, between Cycles 3 and 6, the portlandite compound was dissolved and recrystallized within the microvoids. Depending on the environmental conditions, carbonation may be generated from the hydrated cement fraction, which fills the microvoids and improves the strength and structure of the mixture. During further cycles after the sixth cycle, the mechanical action of the ice lenses coupled with the disintegration of the hydrate compounds imposed many new microvoids and cracks with considerable length and width, which intensified the strength reduction of the moisture and weakened the adhesion between grains. Since cement is widely used in pavement and dam engineering for stabilizing soils, the durability of cemented soils is of prime concern. This study may help improve the durability and resistance of cemented soils in cold climates. The F–T action not only influences the macrostructure of cement-stabilized soils by imposing a wide crack and ice lens but also induces a considerable change in the complexes existing in the hydrated cement paste of the mixture. Three patterns govern the change of the mixture microstructure in various F–T cycles that correspond to the observed trend in strength. The mentioned trend for the microstructure change and, consequently, the strength variation of the CSG mixture are associated with many factors such as pH, cement content, CO2 content, moisture content within the mixture, and relative humidity within the environment. Accordingly, the pattern of microstructural changes in the CSG mixture after the middle F–T cycles may vary depending on environmental conditions. [ABSTRACT FROM AUTHOR]

Three quarters of the world's significant urban centers are located in coastal regions where clay minerals are prevalent. The microstructures and physico-mechanical properties of clay sediments are highly susceptible to alterations in pore water chemistry. The pore water chemistry in soil changes easily due to groundwater pollution, seawater erosion, degradation, etc. However, there are several inconsistencies in the literature on the change of physical and mechanical properties of clay soils caused by the change of pore water chemical properties, i.e., disparate experimental results were reported for the same soil property, or varying explanations were proposed for the identical experimental results. Currently, the research in this field mainly focuses on the macroscopic behavioral modifications while lacking the explanations of microscopic mechanism. Therefore, this paper presents a comprehensive review of researches conducted over the past four decades on the impact of pore water chemistry (including salt type, salinity, ion valence, pH) on soil properties such as the microstructure, settlement, Atterberg limits, shear strength, conductivity, unsaturated soil mechanics properties and thermal properties. The fundamental mechanisms underlying the varied experimental observations on clay sediments affected by salt and pH are systematically explored, and deficiencies in this field are identified. The observed dispersion in the literatures is attributed to the spatial variation and heterogeneity of soil compositions, different test methods, and insufficiency of the fundamental microscopic mechanisms of the observed soil behaviors, etc. Therefore, it is necessary to further explore the essential mechanisms of the test results in the future to establish a unified conclusion. [ABSTRACT FROM AUTHOR]

The mechanisms of microstructure transformation and mechanical anisotropy of laser-MIG hybrid additive manufacturing TC11 titanium alloy after solution aging treatment are investigated. In this paper, different solution temperatures and cooling modes are applied to tailor the microstructure and improve high-temperature properties and anisotropy. The result shows the microstructure of the samples in the as-deposited state is dominated by a widmanstatten structure composed of lamellar α clusters. Following solution aging treatment, a large area of basket-weave structure is obtained in the samples. A major influence of spheroidization of lamellar α clusters and dynamic recrystallization on mechanical anisotropy is revealed. The heat-treated samples exhibit more superior combined strength, elongation, impact toughness. The hardness difference between the layers and mechanical anisotropy decreases. During high-temperature tensile tests, the tensile strength increases with rising solution temperature; while, the elongation shows the opposite trend. The tensile fracture exhibits abundant uniform equiaxed dimples, and the fracture mode changes from intergranular fracture to transgranular fracture. Solution treatment at 990 °C for 2 h followed by air cooling is considered to be the optimal heat treatment process. Consequently, it results in a high tensile strength of 811 MPa and an excellent impact toughness of 50 J, representing improvements of 16.08% and 71.08%. [ABSTRACT FROM AUTHOR]

Fine-grained soils containing diatom microfossils of biological origin are found worldwide. However, although these soils are acknowledged to have unique physical and mechanical properties, the exact role of diatoms in determining their compression and hydraulic behaviours remains unclear, especially when high effective stress is involved, and the underlying micromechanism is yet to be revealed. This study investigated the compression and permeability of diatomaceous soils prepared by mixing pure diatom and kaolin powders through one-dimensional constant rate of strain compression tests with a maximum vertical stress of 10 MPa. The microstructure of the soils studied was observed by atomic force microscopy, scanning electron microscopy and mercury intrusion porosimetry, and the microstructural evolution during compression was traced. The results indicate that the special hollow structure of diatom particles with internal pores contributes significantly to the high void ratio, compressibility and permeability of diatomaceous soils, and increasing the diatom content improves the pore distribution non-uniformity of the diatom–kaolin mixtures. In addition, the diatom particles have high brittleness and breakage potential, leading to microstructural rearrangement during compression, especially pore-structure adjustment. Lower compressive stress deforms the inter- and intra-aggregate pores, but higher vertical stress damages the diatoms' hollow structure, which changes the compression and hydraulic parameters in a different manner from the case of conventional clay. This paper enriches the knowledge concerning the multilevel behaviour of fine-grained soils containing diatom microfossils and provides a fundamental dataset. [ABSTRACT FROM AUTHOR]

Plumology is being used in a variety of avian research fields such as from ecology and evolution to prey-predator relationship. However, very few systematic studies have been conducted in India using plumology. The paper compares macro- and micro-structural feathers' features from four species of family Columbidae viz. the Spotted dove (Spilopelia chinensis), Grey-fronted green pigeon (Treron affinis), Eurasian collared dove (Streptopelia decaocto) and Common pigeon (Columba livia) from different Indian localities. A morphometric analysis of the downy and contour feathers' structures of the listed species was carried out. Since the feathers were taken from significantly damaged carcasses, it was necessary to determine the pterylae of the flying feathers to which the latter belong. Morphometric features of feathers viz. calamus, rachis, vane and mounted barb length were measured. An atypical for Columbidae feature presence of villi has been observed but only for T. affinis species. The presence of typical pigmented quadrilobed nodes was noted in all Columbidae species. Pigmented and non-pigmented plain pronged nodes and plain swollen nodes were observed. The presence of three different nodes on barbules and nodes' pigmentation may be considered as key taxonomic characteristics for studied Columbidae species. The feather comparison method made it possible to identify pterylae of studied feathers. [ABSTRACT FROM AUTHOR]

Background: Osteoporosis is a bone disease related to increased bone loss and fracture‐risk. The variability in bone strength is partially explained by bone mineral density (BMD), and the remainder is contributed by bone microstructure. Recently, clinical CT has emerged as a viable option for in vivo bone microstructural imaging. Wide variations in spatial‐resolution and other imaging features among different CT scanners add inconsistency to derived bone microstructural metrics, urging the need for harmonization of image data from different scanners. Purpose: This paper presents a new deep learning (DL) method for the harmonization of bone microstructural images derived from low‐ and high‐resolution CT scanners and evaluates the method's performance at the levels of image data as well as derived microstructural metrics. Methods: We generalized a three‐dimensional (3D) version of GAN‐CIRCLE that applies two generative adversarial networks (GANs) constrained by the identical, residual, and cycle learning ensemble (CIRCLE). Two GAN modules simultaneously learn to map low‐resolution CT (LRCT) to high‐resolution CT (HRCT) and vice versa. Twenty volunteers were recruited. LRCT and HRCT scans of the distal tibia of their left legs were acquired. Five‐hundred pairs of LRCT and HRCT image blocks of 64×64×64$64 \times 64 \times 64 $ voxels were sampled for each of the twelve volunteers and used for training in supervised as well as unsupervised setups. LRCT and HRCT images of the remaining eight volunteers were used for evaluation. LRCT blocks were sampled at 32 voxel intervals in each coordinate direction and predicted HRCT blocks were stitched to generate a predicted HRCT image. Results: Mean ± standard deviation of structural similarity (SSIM) values between predicted and true HRCT using both 3DGAN‐CIRCLE‐based supervised (0.84 ± 0.03) and unsupervised (0.83 ± 0.04) methods were significantly (p < 0.001) higher than the mean SSIM value between LRCT and true HRCT (0.75 ± 0.03). All Tb measures derived from predicted HRCT by the supervised 3DGAN‐CIRCLE showed higher agreement (CCC ∈$ \in $ [0.956 0.991]) with the reference values from true HRCT as compared to LRCT‐derived values (CCC ∈$ \in $ [0.732 0.989]). For all Tb measures, except Tb plate‐width (CCC = 0.866), the unsupervised 3DGAN‐CIRCLE showed high agreement (CCC ∈$ \in $ [0.920 0.964]) with the true HRCT‐derived reference measures. Moreover, Bland‐Altman plots showed that supervised 3DGAN‐CIRCLE predicted HRCT reduces bias and variability in residual values of different Tb measures as compared to LRCT and unsupervised 3DGAN‐CIRCLE predicted HRCT. The supervised 3DGAN‐CIRCLE method produced significantly improved performance (p < 0.001) for all Tb measures as compared to the two DL‐based supervised methods available in the literature. Conclusions: 3DGAN‐CIRCLE, trained in either unsupervised or supervised fashion, generates HRCT images with high structural similarity to the reference true HRCT images. The supervised 3DGAN‐CIRCLE improves agreements of computed Tb microstructural measures with their reference values and outperforms the unsupervised 3DGAN‐CIRCLE. 3DGAN‐CIRCLE offers a viable DL solution to retrospectively improve image resolution, which may aid in data harmonization in multi‐site longitudinal studies where scanner mismatch is unavoidable. [ABSTRACT FROM AUTHOR]

The study of alkali-activated materials as a replacement for portland cement has been growing in recent years due to the sustainable nature of these materials. Nevertheless, ternary alkali-activated pastes using waste glass as a precursor have been insufficiently studied concerning their rheological, mechanical, and microstructural properties. In addition, there is a lack of research studying alkali-activated mixtures using basic oxygen furnace (BOF) slag and glass waste as precursors. Therefore, this paper aims to study the effect of glass powder (GP) content as a precursor, the effect of the activator ratio in alkali-activated ternary pastes of BOF slag, metakaolin (MK), and GP, and the influence of the Na2SiO3/NaOH ratio on its mixtures. The activator solutions of NaOH and Na2SiO3/NaOH were used in the production of the pastes. The liquid/solid ratio was kept fixed at 0.6 and the molarity of the NaOH solution was fixed at 12 M, seeking to analyze the impact of the Na2SiO3/NaOH ratio, with adopted values of 0.75, 1.5, and 2.5. We also aimed to study the impact of the glass content in the mixture for the values of 10%, 20%, and 25%, replacing the BOF slag. The workability by the minislump test, rheology, compressive strength for 1 and 28 days, and microstructural parameters were analyzed. ANOVA was performed to determine the significance of variables in the workability and compressive strength parameters. Pastes with the highest activator ratio (Na2SiO3/NaOH=2.5) produced better compressive strength (34.74 to 36.11 MPa) and lower minislump spreads (90 to 98 mm) compared with the mixtures with Na2SiO3/NaOH=1.5 and 0.75, besides indicating a denser microstructure, linked to higher production of aluminosilicate gels. Higher GP contents generated pastes with lower mechanical performance (16.7 MPa for Na2SiO3/NaOH=0.75) and microstructural qualities, albeit with better workability (124-mm minislump spread). [ABSTRACT FROM AUTHOR]

Compared with traditional portland cementitious material, alkali-activated material (AAM) had the advantages of low carbon emission, energy saving, excellent durability, strength, and high temperature resistance. It has been proved that the addition of a fiber or nano-particle could improve the mechanical properties of AAM. The fresh and hardened properties of nano-CaCO3 (NCC) and polypropylene fiber (PPF) reinforced AAM were studied in this paper. The hybrid effects of PPF with various volume fractions (0%, 4%, and 8%), aspect ratios (0–464.52), and NCC with various content (0%, 1%, and 2%) on the slump spread, flow rate, flexural strength, compressive strength, and ultrasonic velocity of AAM were investigated. For flowability, the mixture with 0.4% 6 mm and 0.4% 12 mm PPF was the optimal, showing a positive hybrid effect. The hybrid use of PPF and NCC significantly improved the flexural strength, but the compressive strength was not significantly improved. The hybrid effect factors for compressive strength were lower than those for flexural strength. The positive hybrid effect of strength was most obvious when the nano-CaCO3 was 1%. The threshold for fiber factors was 200. Microstructure studies showed that the bridging effect of PPFs can limit the crack development and enhance the strength of AAM. Nano-CaCO3 promoted the denseness of AAM and bond between fiber and matrix. The hybrid of PPF in different lengths and NCC could decrease fiber consumption, reducing the cost and promoting the engineering application of fiber-reinforced AAMs. The effect of hybridization of calcium carbonate nano-particles with polypropylene fibers on the fresh and hardening properties of alkali-activated materials has practical applications in the construction industry. One of its main advantages is its excellent flowability, which allows the material to be self-consolidating. This property allows it to be used effectively in areas such as post-tensioned grouting, pipe concrete, and other grouting processes, where the material flows effortlessly and fills voids efficiently. In addition, the mixing effect of the CaCO3 -nano-particles and the polypropylene fibers enhances the stability and strength of the material, which further enhances the durability and structural stability of the concrete elements. Overall, this blend has excellent flow and self-consolidation properties, making it an important choice for applications such as postgrouting and reinforced concrete construction. [ABSTRACT FROM AUTHOR]

Developing hollow components that integrate a large number of complex coolant channels for thermonuclear reactors remains a challenging task, owing to potential technical problems such as dissimilar metal connections, over-aging, and large welding areas (meter-scale). In this paper, CuCrZr/316L hollow components were manufactured using an improved explosive welding technique, where theoretical calculations and composite filling mold were used to achieve ideal welding conditions. Microstructure analysis showed that irregular waves of continuous and complete metallurgical bonding were detected at the bonding interface, and the defects at the corner of the flow channel were controlled at the hundred-micron level. The joint exhibited high shear strength (~ 292 MPa) under the given high-temperature conditions (200 ℃), whose peak strength, stress–distance curve, and failure mode were almost consistent with the experimental results at room temperature (25 ℃). Finally, under all conditions of the helium-leak test, the leak tightness of the CuCrZr/316L hollow component met the standard requirement. [ABSTRACT FROM AUTHOR]

This paper is a study of the mechanical properties and microstructures of the similar friction weld joints (TiAl6V4 and AA2024) using a servo-controlled Rotary Friction Welding (RFW) system. The friction welding operations were performed with seven different values of the friction pressure in the range of 2–14 MPa. The temperature is recorded during friction welding tests using k-type thermocouples. Tensile tests and microhardness measurements were carried out to obtain the mechanical properties of the friction weld joints. Microstructural changes of individual zone of the friction welds were investigated using an optical microscope (OM), and the fracture surfaces were observed using a scanning electron microscope (SEM). For AA2024, the fracture occurs most frequently in the central zone, resulting in lower tensile strength values, while for TiAl6V4, the fracture is occurs outside the friction weld interface, indicating that the friction weld joint is more resistant than the base metal. Microscopic analysis of the fracture surfaces of the AA2024 samples revealed diverse morphologies, with rough cupular surfaces predominating, indicating a dominant ductile fracture mode. Similarly, TiAl6V4's friction welded specimen also exhibited cupules of various sizes across its surface, primarily associated with a ductile fracture mode. Overall, the optimal friction pressure values (respectively 8 and 10 MPa for TiAl6V4 and AA2024) correspond to the highest values of the mechanical properties. [ABSTRACT FROM AUTHOR]

Tribaloy™ T800, a Co-based alloy, exhibits remarkable tribological properties by virtue of its high-volume fraction of intermetallic Laves phase making it an attractive hard-facing material. Hard-facing by laser deposition results in dilution from the substrate, and thereby, the properties of the clad are altered. This paper reports the influence of processing parameters on the dilution, microstructure, and wear behaviour of Tribaloy™ T800 on AISI 316 stainless steel. A systematic set of 20 clads was deposited by varying laser power and cladding speed, keeping powder flow and spot diameter constant. While dilution decreased at lower laser powers (800 and 1000 W) with increasing cladding speed (5–20 mm s−1), at higher laser powers (1200 and 1400 W), the opposite trend was observed. The Fe intermixing from the substrate along with the cooling rate governs the volume fraction and size of the Laves phases which controls the properties of T800 clads. The clad with the least geometric dilution (5.7%) exhibits the lowest wear rate of 0.54 × 10−5 mm3 N−1 m−1, increasing to 2.88 × 10−5 mm3 N−1 m−1 as the dilution increased to 60%. [ABSTRACT FROM AUTHOR]

In this paper, high-density (60−x)Fe−Cr−Co−xCu (x: 0–6 wt.%) permanent magnet alloys were fabricated by laser powder bed fusion (LPBF) in-situ alloying technique, and the effects of Cu content on the microstructure, magnetic, and mechanical properties of the alloy were systematically investigated. The addition of 2 wt.% Cu enhanced the coercivity H c and the energy product (B H) max of the alloy in the isotropic state by 19.4 and 27.9%, respectively, compared to the alloy without Cu. The impacts of Cu content on the magnetic properties were investigated by combining experimental results and first-principles calculations. Furthermore, the addition of Cu improved the yield strength of the alloy, and the strengthening mechanism was analyzed in detail. The yield strength of the alloy with 2 wt.% Cu reached 908 MPa, representing a notable 7% increase relative to the Cu-free alloy. [ABSTRACT FROM AUTHOR]

Damage and fracture of archaeological potteries not only jeopardize the long-term preservation but also hinder their exhibition. To repair these pottery sherds effectively, this study introduces a novel inorganic phosphate-based adhesive and evaluates its effectiveness through a series of experiments. To determine the optimal base adhesive, the paper investigates the influence of varying weight ratios of the H2O–H3PO4 system and the Al(OH)3–H3PO4 system on properties including tensile lap-shear strength, microstructure, high-temperature resistance and phase composition. However, the original black color of the traditional CuO–phosphate adhesive limits its application. The innovation of this study lies in the addition of nano-TiO2 to the adhesive, which not only improves the bonding strength but also adjusts the color of the adhesive. This study has defined the optimal formulation (i.e., base adhesive = m[Al(OH)3]:m[H3PO4] = 7:100, filler = 10wt% nano-TiO2), and the final product shows no residual acid in adhesives. Additionally, the fracture surfaces are successfully bonded with a high strength of 3.56 MPa. Various ageing tests including dry-thermal ageing, hygrothermal ageing and UV irradiation ageing are conducted to assess the ageing resistance of the inorganic phosphate-based adhesive. The results indicate strong tolerance of adhesive to high temperature and high humidity environment. Preliminary applications in archaeological pottery restoration suggest that the inorganic phosphate-based adhesive offers considerable promise for repairing shattered pottery. [ABSTRACT FROM AUTHOR]

Gear shafts are commonly manufactured by machining of gear teeth and shaft separately. This kind of approach entails quite some problems, such as long processing time, large die, and low production efficiency. To tackle these problems, this paper innovatively proposes a new process of cross wedge rolling (CWR) that is specifically tailored to the manufacturing of gear shafts, with which the shaft and teeth are formed at one go. The finite element model of CWR forming of gear shaft is established to simulate and analyze the CWR forming process. A three-factor and three-level response surface test is designed to optimize the processing parameters, where the friction coefficient, rolling temperature, and die movement speed are chosen as three factors, and inhomogeneous deformation is set as the response. The optimal parameters are obtained as follows: the rolling temperature is 1240 ℃, the speed of the die movement is 336 mm/s, and the friction coefficient is 0.8. This result is subsequently verified by experiments. Further on, the microstructure evolution of the characteristic points of the CWR forming process of gear shaft is analyzed. It is found that the grains at the gear teeth section are continuously refined and grown from the boundary at the early section of deformation, and the final grains grown are much smaller than the original ones. In addition, the grains appear to grow in a short range of time in the process of deformation, but the overall trend is towards refinement. In the shaft section, the evolutions of the grains in the two stepped shaft segments are almost the same; the grain deformation shows cyclic changes; the degree of grain refinement in the shaft is higher than that in the teeth; and the degree of grain refinement in the shaft center is higher than that in the shaft edge. The results of the study provide a theoretical basis for short-process forming of high-performance gear shafts by cross wedge rolling. [ABSTRACT FROM AUTHOR]