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In this paper, the microstructure and mechanical properties of Al-6.5Si-5.5Cu-0.2Zr-0.01Sr-0.06Ti-0.2Ce cast aluminum alloys were investigated in multistage solid solution systems. The microstructure of the alloy was characterized using an optical microscope (OM), scanning electron microscope (SEM), energy-dispersive spectrometer (EDS), x-ray diffraction (XRD) and transmission electron microscope (TEM), respectively. The hardness and conductivity of the alloy were measured using a Vickers hardness and eddy current conductivity testers, respectively, and the tensile properties were described by a drawing machine. The results showed that the mechanical properties of the alloy are the worst under the four-stage solid solution system (G1). With the increase in multistage solution temperature and holding time, θ phase (Al2Cu) was gradually dissolved into α-Al matrix to enhance the effect of dislocation strengthening. When the solution temperature reached 510 °C, the mechanical properties of the alloy were the best, and the tensile strength and elongation were increased to 354.90 MPa and 9.02%, respectively. With the increase in temperature, eutectic Si agglomeration and large area of insoluble phase between metals were found, resulting in the decrease in mechanical properties. [ABSTRACT FROM AUTHOR]

The paper reports on the atomic investigation about β phase in Mg 96 Gd 2 Y 1 Ni 1 alloy by using the first-principles study and the high-angle annular dark-field scanning transmission electron microscope (HAADF-STEM) corrected by atomic Cs. By using HAADF-STEM, the rectangular β phases were observed in the underage and peak aging stages in Mg 96 Gd 2 Y 1 Ni 1 alloy. The β phase could be precipitated from the previously precipitated β phase, and the β phase grew in steps when it was precipitated. A special transition structure of three atomic layer thicknesses was first observed at the edge of the β phase and the structure of this interface is probably as the β/Mg 1 interface for the analysis of thermodynamic characterization and electronic characterization. The β' phase and the β H structure were precipitated only at the edge of the length directions of the β phase. The β' phase continues to grow into a β phase directly without the formation of β 1 phase, resulting in an increase in the length of the β phase, which is discovered for the first time. [ABSTRACT FROM AUTHOR]

Aluminum–copper-based alloy has a broad liquidus to solidus temperature range, making it susceptible to the formation defects such as pores and shrinkage pores during the process of solidification. Hence, ultrasonic vibration and squeeze casting can help to refine the microstructure and eliminate the formation of pores. In this paper, we used an optical microscope, scanning electron microscope, transmission electron microscope, differential scanning calorimetry, and thermal analysis to study the ultrasonic treatment (UT) and squeeze casting (SC) on the as-cast and heat-treated microstructure of Al–Cu–Mn alloys. The results show that a significant refinement can be obtained by the compound field compared with that of the individual field. The applied UT time is 30 s and 120 s, respectively. The smallest grain size and the finest Al2Cu particles are observed in the alloy with a treated time of 120 s. This is due to the ultrasonic field breaking the dendrites and promoting the flow of molten Al; squeeze casting increases the cooling rate and stimulates the nucleation temperature of α-Al. The size of the θ′ phase after compound field treatment is smaller because more Cu atoms are dissolved in the Al matrix, so the θ' strengthening phase is finely dispersed in the Al alloy matrix. It is concluded that the compound field of UT and SC is a potentially advantageous process to refine the microstructure of Al alloys. [ABSTRACT FROM AUTHOR]

This study was conducted with a high level of thoroughness. X-ray diffraction (XRD), Scanning Electron Microscope (SEM), and Transmission Electron Microscope (TEM) were used to analyze the phase composition and microstructure of the AM-2024Al and the RO-2024Al. The hardness and porosity of the AM-2024Al, as well as the bonding strength between AM-2024Al and RO-2024Al, were also investigated. Furthermore, the corrosion and tribocorrosion properties and failure mechanisms of the AM-2024Al and the RO-2024Al were systematically and thoroughly compared and analyzed. The results of this comprehensive study revealed that the AM-2024Al displayed a similar phase structure and higher hardness in comparison to the RO-2024Al, and the AM-2024Al was compact and tightly bound to the RO-2024Al with a bonding strength of over 55.5 MPa. Furthermore, the AM-2024Al exhibited better corrosion resistance under PDP (potentiodynamic polarization) corrosion and similar wet sliding wear resistance under an approximate pure friction process (OCP corrosion, namely open circuit potential corrosion) and tribocorrosion compared with the RO-2024Al. These findings provide a high level of confidence in the potential of cold spraying additive manufacture 2024Al as a reliable way to repair damaged RO-2024Al. [Display omitted] • The tribocorrosion is first reported for the CS additive manufacturing 2024Al alloy. • The AM-2024Al exhibits superior anti-corrosion compared to the RO-2024Al. • The AM-2024Al has a comparable tribocorrosion resistance to the RO-2024Al. • Splats (AM-2024Al) and grains (RO-2024Al) are partly peeled during the tribocorrosion. • A plastic deformation layer was generated in the wear track surfaces of the two 2024Al. [ABSTRACT FROM AUTHOR]

The microstructure, phase composition, precipitates evaluation, casting, and mechanical properties of the novel cast Al-4Cu-2.1Er-1Mg-0.2Zr-0.2Cr-0.15Fe-0.15Si-0.1Ti alloy were analyzed using by optical microscope, scanning and transmission electron microscopes, differential scanning calorimetry, thermodynamic calculations, hot cracking and mechanical properties measurements. The positive effect of Cr as a substitution of Mn on plasticity and precipitation strengthening was demonstrated. The 0.2Zr, 0.2Cr and 0.1 Ti as a grain refiners provide a fine grain size of 25 μm in the as-cast state due to primary Al 75–80 Cu 10–12 Er 3–4 Cr 7 phase particles formation as a nucleation centers of Al. The hot cracking index (HCI) of the AlCuErMgCr alloy was 12–14 mm which is similar with HCI of the cast Al-Si-Cu-Mg alloys. The good casting properties in the AlCuErMgCr alloy achieved due to a fine grain structure and narrow solidification range. The contribution of the Al 3 (Zr,Er) (40 nm), Al 45 Cr 7 (6 nm), and S'(θ') (100/5 nm) precipitates is 38.5 MPa, 140.4 MPa, and 198.9 MPa and the calculated contribution from dislocation and precipitates is 262.3 MPa. The ultimate tensile strength (UTS) and elongation (El.) of the AlCuErMgCr alloy are 372 MPa and 6% which is higher in 16.6% and 150%, respectively, than in the Mn-containing alloy. Novel alloy has an excellent combination of yield strength (YS) and plasticity at 20–250°C. The YS and El. are 301 MPa and 6% and 225–250 MPa and 4.6–11.5% at 20 and 200–250°C, respectively. The rupture strength at 250°C after 100 h (σ 100 250) is 106 MPa. Mechanical and casting properties of the novel alloy are superior to the properties of commercial 201.0 (Al-Cu-Mn-Mg-Ag-Ti) alloy. • Cr, replacing Mn, had a positive impact on both plasticity and precipitation strengthening. • 0.2Zr, 0.2Cr, and 0.1Ti as grain refiners resulted in the formation of primary Al 75–80 Cu 10–12 Er 3–4 Cr 7 phase particles. • The AlCuErMgCr alloy displayed an ultimate tensile strength (UTS) of 372 MPa and an elongation (El.) of 6%. • The rupture strength at 250°C after 100 hours was determined to be 106 MPa. [ABSTRACT FROM AUTHOR]

The microstructure and properties of the aged Cu-Cr-Zr-Nb alloy were studied by means of hardness tester, universal tensile testing machine, conductivity meter, X-ray diffraction, scanning electron microscope, and transmission electron microscope. The results indicated that the hardness and TS (tensile strength) of the Cu-Cr-Zr-Nb alloy increased first and subsequently decreased with increasing the aging temperature. Nevertheless, the electrical conductivity is gradually increasing. The aged Cu-Cr-Zr-Nb alloy was mostly made up of Cu matrix, Cr particles, Cr 2 Nb, and CuZr compounds. Due to the effects of dislocations accumulated by cold drawing and twins produced during the aging process, the softening temperature of the alloy reached 590 ℃. When the Cu-Cr-Zr-Nb alloy was aged at 490 ℃, < 111 > replaced < 110 > in the optimal orientation of the alloy, and the KAM (kernel average misorientation) value inside the alloy was the largest. The alloy exhibited great comprehensive properties at 490 ℃ for 1 h, with a hardness of 144.4 HBW, a TS of 521 MPa, and an electrical conductivity of 78.3%IACS. The contribution value of YS (yield strength) at different aging temperatures was further calculated. The computational results showed that precipitation strengthening was the main strengthening mechanism of the Cu-Cr-Zr-Nb alloy, and fine-grained strengthening and dislocation strengthening simultaneously played a supplementary role. • Due to the effects of dislocations accumulated by cold drawing, precipitation strengthening of Cr and twins produced during the aging process, the softening temperature of the Cu-Cr-Zr-Nb alloy reaches 590 ℃. • The Cu-Cr-Zr-Nb alloy exhibits great comprehensive properties at 490 ℃ for 1 h, with a hardness of 144.4 HBW, a tensile strength of 521 MPa, and an electrical conductivity of 78.3 %IACS. • The computational results show that precipitation strengthening is the main strengthening mechanism of the Cu-Cr-Zr-Nb alloy. [ABSTRACT FROM AUTHOR]

Zn alloy has attracted much attention as a biodegradable material for biomedical applications. However, due to the significant strain softening of Zn alloys, how to break the bottleneck of synergistic yield strength and uniform elongation is an urgent problem to be solved. In this work, a Zn-2.3Cu-0.8Mn (wt.%) alloy was fabricated via low-temperature extrusion and annealing at 330 °C for 1 h to attain dual heterostructures with bimodal grains and multi-scale second phases, focusing on the effect of heterostructure on the mechanical properties. Uniaxial tensile test and loading-unloading-reloading test were applied to reveal the mechanical properties of the Zn-2.3Cu-0.8Mn alloy, while scanning electron microscope, electron backscatter diffraction, and transmission electron microscope were used to characterize its microstructure. Compared with the as-extruded alloy with uniform and fine grains, 330–1 alloy achieves a better combination of strength and uniform elongation (yield strength: 287.8 ± 8.5 MPa, ultimate tensile strength: 321.4 ± 6.8 MPa, and uniform elongation: 14.2 ± 1.8%). The high strength was primarily attributed to the coordination of grain boundary strengthening, hetero-deformation induced strengthening, Orowan strengthening, and dislocation strengthening. Besides, the coarse grains, twinning, as well as the suppression of grain boundary sliding and phase boundary sliding promoted dislocation proliferation and storage capacity, thereby improving work hardening capacity. The large strain hardening capacity was responsible for excellent plasticity. This study provides a feasible strategy for the design of Zn-based alloys with an excellent combination of high strength and strain hardening capacity. [ABSTRACT FROM AUTHOR]