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The increased production and expanding demand for cellulosic products have required companies to provide solutions for the proper disposal of generated residues without compromising soil quality. In this context, the current research aimed at evaluating the ecotoxicological impacts of dregs application in subtropical soils. The experiments were carried out with the earthworm Eisenia andrei , the springtail Folsomia candida , and the potworm Enchytraeus crypticus in two subtropical soils (Neosol and Cambisol) collected in the southern region of Brazil. The considerable differences in texture and organic matter content motivated the choosing of these soils. The reproductive rate of all organisms was influenced, with varying EC 50 values depending on the soil type. However, more pronounced effects were observed for Neosol. The springtail F. candida proved to be the most sensitive to contamination (EC 50 = 5.8 g kg−1 for Neosol and 48.5 g kg−1 for Cambisol), followed by the earthworm E. andrei (EC 50 = 62.4 g kg−1 for Neosol and 129.5 g kg−1 for Cambisol) and the potworm E. crypticus (EC 50 = 67.2 g kg−1 for Neosol and 230.4 g kg−1 for Cambisol). As a result, while dregs can be used to correct soil acidity, they have been shown to have negative effects on important organisms responsible for functions critical to maintaining ecosystem quality. [Display omitted] • Dregs are a by-product from the pulp and paper industry that is suggest to be a soil pH corrective. • Soil organisms are vital to the maintenance of the soil health. • Dregs are capable of affect the reproduction rates of soils organisms. • The toxicity of dregs varies according to the soil chemical characteristics. • Metal levels in the dregs matrix are less of concern than the increases in Na content. [ABSTRACT FROM AUTHOR]

Cadmium-contaminated soil significantly threatens global food security and human health. This scenario gives rise to significant worries regarding widespread environmental pollution. Biochar and arbuscular mycorrhizal fungi (AMF) can effectively immobilize cadmium in the soil in an environmentally friendly way. Existing studies have separately focused on the feasibility of each in remediating polluted soil. However, their association during the remediation of cadmium-polluted soils remains unclear. This review paper aims to elucidate the potential of biochar, in conjunction with AMF, as a strategy to remediate soil contaminated with cadmium. This paper comprehensively analyzes the current understanding of the processes in cadmium immobilization in the soil environment by examining the synergistic interactions between biochar and AMF. Key factors influencing the efficacy of this approach, such as biochar properties, AMF species, and soil conditions, are discussed. The influences of biochar–AMF interactions on plant growth, nutrient uptake, and overall ecosystem health in cadmium-contaminated environments are highlighted. This review indicates that combining biochar and AMF can improve cadmium immobilization. The presence of AMF in the soil can create numerous binding sites on biochar for cadmium ions, effectively immobilizing them in the soil. Insights from this review contribute to a deeper understanding of sustainable and eco-friendly approaches to remediate cadmium-contaminated soils, offering potential applications in agriculture and environmental management. [ABSTRACT FROM AUTHOR]

Polycyclic aromatic hydrocarbons (PAHs) represent a category of persistent organic pollutants that pose a global concern in the realm of food safety due to their recognized carcinogenic properties in humans. Food can be contaminated with PAHs that are present in water, air, or soil, or during food processing and cooking. The wide and varied sources of PAHs contribute to their persistent contamination of food, leading to their accumulation within these products. As a result, monitoring of the levels of PAHs in food is necessary to guarantee the safety of food products as well as the public health. This review paper attempts to give its readers an overview of the impact of PAHs on crops, their occurrence and sources, and the methodologies employed for the sample preparation and detection of PAHs in food. In addition, possible directions for future research are proposed. The objective is to provide references for the monitoring, prevention, and in-depth exploration of PAHs in food. [ABSTRACT FROM AUTHOR]

Biosensors (biological sensors) are a promising alternative to standard analytical techniques for testing and monitoring in the environment, among others, heavy metals. Biological materials that detect heavy metals include enzymes, bacteria, fungi, and plant and animal cells. The paper aimed to evaluate the possibilities of biosensor usage in environmental analysis, considering an easy and environmentally friendly analysis of individual compounds (e.g., heavy metals) or their mixtures in various samples directly in the environment, as well as continuous monitoring of these compounds. The work considers biosensors' characteristics, classification, and operation principles. Attention is paid to the possibility of using bioluminescent bacteria as biological material in a biosensor. Examples of the study of heavy metals using various biological sensors were given. It also indicates the possibility of using biosensors to determine microplastics by applying specific hormones (estrogens) receptor use and peptides as a solution or incorporating them into living microbial cells. Additionally, support was given to the use of biosensors to monitor plastics' degradation in the water environment using recombinant whole-cell microbial biosensors as detectors for plastic monomers such as acrylic acid monomers. The application of the biosensors highlighted in the paper is to shorten the time of toxicity studies by using new indicators or acceptors. However, several challenges must be overcome, such as cell viability and activity. A continuous water-monitoring system that can handle a severely toxic sample has yet to be developed in toxicity monitoring [ABSTRACT FROM AUTHOR]

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The assessment of soil contamination in the vicinity of integrated siderurgical plants is of outmost importance for agroecosystems and human health, and sensitive techniques should be employed for accurate assessment of chemical elements (metals, potential toxic elements, rare earths, radioelements) in soil and further evaluation of potential ecological and safety risk. In this paper a total of 45 major, minor and trace elements (Al, As, Au, Ba, Br, Ca, Cd, Ce, Co, Cr, Cs, Cu, Dy, Eu, Fe, Hf, Hg, I, K, La, Mg, Mn, Mo, Na, Nd, Ni, Pb, Rb, Sb, Sc, Sm, Sn, Sr, Ta, Tb, Th, Ti, Tm, U, V, W, Y, Yb, Zn and Zr) were quantified in soils located around a large siderurgical works (Galati, SE Romania) using instrumental neutron activation analysis (INAA) in combination with X-ray fluorescence (XRF) and inductively coupled plasma mass spectrometry (ICP–MS). The statistical analysis results and vertical distribution patterns for three depths (0–5 cm, 5–20 cm, 20–30 cm) indicate inputs of toxic elements in the sites close to the ironmaking and steelmaking facilities and industrial wastes dumping site. For selected elements, a comparison with historical, legislated and world reported concentration values in soil was performed and depth migration, contamination and toxic risk indices were assessed. The distribution of major, rock forming elements was closer to the Upper Continental Crust (UCC), and to the Dobrogea loess, a finding confirmed by the ternary diagram of the incompatible trace elements Sc, La and Th, as well as by the La to Th rate. At the same time, the La/Th vs. Sc and Th/Sc vs. Zr/Sc bi-plots suggested a felsic origin and a weak recycling of soils' mineral components. [ABSTRACT FROM AUTHOR]

When soils available for the construction of liners do not display the characteristics necessary for a good performance, mixtures with other materials can be employed for achieving the desired quality. Several researchers have addressed those mixtures from either a geotechnical or a gas diffusion perspective, emphasizing low hydraulic conductivity. However, in recent years, growing attention has been drawn to the ability of liners to mitigate contamination. The literature lacks studies on the use of amendments for soil liners or cover systems to retain potentially toxic metals, which are important inorganic contaminants. This paper provides a systematic review of the literature considering publications available on Web of Science and SpringerLink databases between January 1st, 2012, and December 5th, 2022. The aim of the review was to identify the types of soils and amendments studied as liners or cover systems for such retention of potentially toxic metals, the methodologies of application of the alternative materials in the soils, and the research gaps and perspectives in the field. Seventeen papers that addressed 31 materials as amendments were retrieved. The most studied amendment was coal fly ash, and 17 amendments were residues or by-products, which indicates concerns over waste destination and sustainability. Among the potentially toxic metals analyzed are Pb, Cu, and Cd. Gaps such as lack of pilot, field-scale, and long-term studies, as well as perspectives for future research (e.g., different liner configurations, concomitant mixtures of two or more materials in the soil, and focus on the sustainability of amendments), were identified. [ABSTRACT FROM AUTHOR]

Nickel (Ni) is a silver-white metal with high antioxidative properties, often existing in a bivalent form in the environment. Despite being the fifth most abundant metal on Earth, anthropogenic activities, including industrial processes, have elevated Ni levels in environmental media. This study investigated Ni contamination in various food groups in Zhejiang Province, China, mainly focusing on Ni levels in beans, vegetables, aquatic foods, meat products, cereal products, and fruits. A total of 2628 samples were collected and analyzed. Beans exhibited the highest Ni content in all samples. The overall detection rate of Ni was 86.5%, with variation among food categories. For plant-origin foods, legumes had the highest Ni concentration while for animal-origin foods, shellfish showed the highest median Ni concentration. The results indicate generally acceptable Ni exposure levels among Zhejiang residents, except for children aged 0–6. Beans were identified as the primary contributor to high Ni exposure risk. The paper suggests monitoring Ni contamination in food, especially for vulnerable populations, and provides insights into exposure risks in different age groups. [ABSTRACT FROM AUTHOR]

Predominantly, the inhabitants of Demsa and environs use shallow hand-dug wells as a primary source of drinking water but this water source is vulnerable to contamination from various external sources due to lack of protection, thus, the geological conditions and anthropogenic activities of the people living in the area. Therefore, the objective of this paper is to assess the levels of some heavy metals and physicochemical parameters in water from Hand-Dug Wells in Demsa and Environs in Adamawa State, Nigeria using appropriate standard methods. The results obtained reveals that the mean concentrations (mg/L) of metals and physicochemical parameters were calcium (4.236), magnesium (3.702), cadmium (0.104), sodium (9.400), copper (0.003), iron (0.132), potassium (14.200), manganese (0.148), zinc (0.004), lead (0.000), chromium (0.000), arsenic (0.000), nickel (0.008), sulphide (0.473), chloride (0.450), phosphate (4.040), fluoride (0.286) and nitrate (46.19). The results further showed that the concentration (mg/L) values for magnesium (3.702), cadmium (0.104), phosphate (4.040) and nitrate (46.19) were all above the acceptable limits of WHO, FEPA and NSDWQ. As a precaution, a systematic approach to removing heavy metals from groundwater sources in the study area is proposed, using techniques like chemical precipitation, ion exchange, or reverse osmosis. [ABSTRACT FROM AUTHOR]

This paper examined a total of two hundred and fifty (250) samples of slender amaranth vegetable (Amaranthus viridis) and bush-okra (Corchorus olitorius) from farms and markets in the communities around Edu Local Government Area of Kwara State of Nigeria between January and July 2023 for evaluation of parasites that infect humans using the sedimentation method. Parasites isolated from vegetable samples from the farm showed that Ascaris lumbricoides (17.6%) was the most encountered followed by Entamoeba histolytica (11.2%) and the least was Enterobius vermicularis (3.2%). In the market samples, Ascaris (11.2%) was the most prevalent parasites encountered while Trichuris trichiura, Strongyloides stercoralis and E. vermicularis (1.6%) were the least prevalent. One hundred and fourteen (45.6%) samples were contaminated with various parasites. Of the total contaminated vegetable, 74/125 (59.2%) were found in the farm vegetables while 40/125 (32.0%) were encountered in the market vegetables. Corchorus olitorius were found to be more contaminated in both the farms 39/110 (35.5%) and market 23/110 (20.9%). From the study, it was seen that the rate of contamination was highest in the month of July, while the month of January had the least rate of contamination for both farm and market vegetable samples. The difference in the contamination rate in both farm and market samples were seen to be significant (P < 0.05). This study recommends proper washing of vegetables prior to consumption and proper sewage treatment before usage as fertilizer. [ABSTRACT FROM AUTHOR]

Petroleum products consist of hazardous chemicals such as benzene, toluene, ethylbenzene, xylene, and naphthalene, which can be detrimental to all parts of the ecosystem, especially the land. Hence, the objective of this paper was to evaluate the potential of castor seed (Ricinus communis) for remediation of petroleum products contaminated soil in Billiri, Gombe State, Nigeria using appropriate standard techniques. Tests results showed that the petroleum products significantly altered the physicochemical properties, heavy metals and THC of the soil. The soil porosity decreased from 76.20% to 36.5%; the soil pH decreased from 7.10 to 6.0; the THC increased from 0.268 mg/kg to 878.4 mg/kg while heavy metals content such as copper level increased from 17.20 mg/kg to 53.9 mg/kg; the lead content increased from 10.39 mg/kg to 16.0 mg/kg; while the iron content increased from 31.72 mg/kg to 63.4 mg/kg after the contamination. After the 14 weeks phytoremediation period, Ricinus communis was able to degrade the THC in the soil from 878.4 mg/kg to 254 mg/kg while also showing potential for the degradation of other heavy metals in the soil. [ABSTRACT FROM AUTHOR]

The groundwater consists of about 20% of the earth's fresh water is the most widely used for drinking. Hence, the objective of this paper was to assess the seasonal variations of heavy metals and microbial parameters on well water quality in Urban Centre (UC), Effluent Locations (EL) and Non-Effluent Location (NEL) of Kano metropolis, Nigeria using appropriate standard techniques. The research collected 768 water samples from 48 wells at three different locations: Urban Centre (UC), Effluent Locations (EL) and Non-Effluent Location (NEL) in the city during dry and wet seasons in one year and subjected samples to laboratory analysis for determination of the concentrations of elements and bacteria in line with American Public Health Association (APHA, 2005). Higher mean values of Cadmium, Chromium, Mercury, Arsenic, Iron, Lead, Zinc, Manganese, Total Coliform and Escherichia Coli of 0.14mg/L, 5.11mg/L, 0.095mg/L, 0.15mg/L, 0.53mg/L, 3.1mg/L, 8.62mg/L and 4.1mg/L respectively at EL except Cadmium (UC). Analysis of Variance (ANOVA) and T-test 0.05% confidential level showed that Chromium F(2, 3) = 17.225, p =0.019, Arsenic F(2, 3) = 16.11, p = 0.031 and Iron F(2, 3) = 17.135, p = 0.021 while microbial parameters showed that E. coli F(2,3) =11.88 p = 0.038 parameters wells located at the UC, EL NEL areas of Kano. The results showed that heavy metal concentrations and microbial contamination in the metropolis are significantly different from each other where the mean level is significant at P<.05 across different locations, with higher levels found in industrial and urban areas during the rainy season. These findings highlight the need for improved management and monitoring of well water quality in Kano metropolis to protect public health. [ABSTRACT FROM AUTHOR]

Household food waste is increasingly recognised as a global wicked problem for its greenhouse gas emissions, economic damage, and resource loss. Although targeted in the UN's Sustainable Development Goals, countries can only respond according to their capacity. For Australia, national policy has put the pressure on states and territories to divert food waste away from landfill into a nascent circular economy. For councils, this increasingly means implementing a FOGO (Food Organics/Garden Organics) kerbside collection. Despite funding and infrastructure development, many are resisting. Framed by the tenets of policy diffusion, this paper presents the results of a nationwide exploratory survey aimed at identifying how and why council-based waste services staff resist, emulate or lead FOGO implementation. By assessing participants current kerbside systems and their attitudes towards household food waste management, the survey found costs, contamination, and capacity and were key concerns. However, responses to these varied considerably despite similarities of situation, often relating more to collaborative attitudes across waste services, council, and councillors. This paper recognises that a conducive environment for change is urgently needed for Australia to achieve organics diversion targets and shift household food towards a circular economy. It provides a starting point for further research into the complex and nuanced dynamics between council waste services and FOGO implementations, from external drivers and council paradigms to individual attitudes and perceptions. • Policy push alone is not enough to achieve Australia's food waste diversion targets. • Achieving uncontaminated household food waste requires strong national legislation and policy. • Regional collaborations between councils are beneficial yet under-used. • Inter-council emulation enhances infectious inaction where policy and support is lacking. • National food waste awareness-raising reduces community confusion. [ABSTRACT FROM AUTHOR]

Purpose: To investigate the influence of contamination and different cleaning methods on resin bonding to cobalt-chromium (CoCr) alloy disks. Materials and Methods: A total of 160 CoCr disks were divided into 3 groups. The first group (N = 64) was air abraded with alumina particles; the second group (N=64) was air abraded and contaminated with silicone disclosing agent and saliva; the third group (N=32) was neither air abraded nor contaminated. The first two groups were divided into 4 subgroups (N = 16) according to the cleaning method: ultrasonic bath in 99% isopropanol, use of a cleaning suspension of zirconium oxide particles, use of a cleaning suspension based on 10-MDP salt, and treatment with atmospheric plasma. The third group was divided into 2 subgroups (N = 16): treatment with atmospheric plasma and no treatment. All CoCr specimens were bonded to plexiglas tubes filled with a bonding resin that contained phosphate monomer. Tensile bond strength (TBS) was examined by tensile testing after 3 and 150days of water storage plus 37,500 thermal cycles (N = 8). Results: After contamination, TBS was significantly reduced after 150days of water storage. Groups without air abrasion showed initially low TBS and debonded spontaneously after 150days of water storage. Conclusion: None of the cleaning methods was able to remove saliva and silicone disclosing agent on CoCr-alloy surfaces. Surface activation by plasma treatment has no long-term effect on the bond strength. [ABSTRACT FROM AUTHOR]

Cadmium-contaminated soil significantly threatens global food security and human health. This scenario gives rise to significant worries regarding widespread environmental pollution. Biochar and arbuscular mycorrhizal fungi (AMF) can effectively immobilize cadmium in the soil in an environmentally friendly way. Existing studies have separately focused on the feasibility of each in remediating polluted soil. However, their association during the remediation of cadmium-polluted soils remains unclear. This review paper aims to elucidate the potential of biochar, in conjunction with AMF, as a strategy to remediate soil contaminated with cadmium. This paper comprehensively analyzes the current understanding of the processes in cadmium immobilization in the soil environment by examining the synergistic interactions between biochar and AMF. Key factors influencing the efficacy of this approach, such as biochar properties, AMF species, and soil conditions, are discussed. The influences of biochar–AMF interactions on plant growth, nutrient uptake, and overall ecosystem health in cadmium-contaminated environments are highlighted. This review indicates that combining biochar and AMF can improve cadmium immobilization. The presence of AMF in the soil can create numerous binding sites on biochar for cadmium ions, effectively immobilizing them in the soil. Insights from this review contribute to a deeper understanding of sustainable and eco-friendly approaches to remediate cadmium-contaminated soils, offering potential applications in agriculture and environmental management.

Water pollution is a significant threat to aquatic ecosystems. Various methods of monitoring, such as in situ approaches, are currently available to assess its impact. In this paper we examine the use of fish in active biomonitoring to study contamination and toxicity of surface waters. We analysed 148 previous studies conducted between 2005 and 2022, including both marine and freshwater environments, focusing on the characteristics of the organisms used as well as the principal goals of these studies. The main conclusions we drew are that a wide range of protocols and organisms have been used but there is no standardised method for assessing the quality of aquatic ecosystems on a more global scale. Additionally, the most commonly used developmental stages have been juveniles and adults. At these stages, the most frequently used species were the fathead minnow (Pimephales promelas) and two salmonids: rainbow trout (Oncorhynchus mykiss) and brown trout (Salmo trutta). Few studies used earlier stages of development (embryos or larvae), mostly due to the difficulty of obtaining fish embryos and caging them in the field. Finally, we identified research gaps in active biomonitoring for water quality assessment which could indicate useful directions for future research and development. [Display omitted] • Environmental risk assessment methods using fish are not standardised. • Environmental parameters strongly influence organism response. • Early life stages of fish offer several advantages for active biomonitoring. • Early life stages of fish are seldom used for risk assessment in the field. [ABSTRACT FROM AUTHOR]

Military actions bring many negative consequences both in the short and long term. In particular, not only people suffer during armed aggression, but also the ecosystem and agrocenoses. This article examined the impact of bombardment of agricultural land with aerial bombs and established whether it was really contaminated with heavy metals. Samples were collected in two regions of Ukraine - Sumy and Chernihiv - from craters formed by bombing. The soil was taken directly from the bottom of the crater, at three points on its slope and 20 meters from the crater, in a conditionally undamaged area. The soil was analyzed in the laboratory using X-ray fluorescence analysis. The study analyzed the content of barium, zirconium, rubidium, zinc, and vanadium soil samples from a crater. The impact of aerial bombings on the concentration of heavy metals in the soils of the farms under investigation is unclear, it may be inferred. The concentration of barium, zirconium, and manganese on the crater slopes is higher in certain farms than in others, but overall trends do not show an obvious increase in these elements when compared to the control sites. However, several farms did not report significant shifts in the heavy metal composition, indicating how challenging it is to monitor whether explosions affect the concentrations of these elements. With a few exceptions, other heavy elements including strontium, rubidium, and zinc did not consistently exhibit excesses in the craters. Therefore, further, more thorough assessment of soil contamination should be carried out and methods for remediation should be developed. [ABSTRACT FROM AUTHOR]

Environmental contamination found in urban areas generally has a chemical composition that favors the generation of a variety of physical, chemical and biological processes that differ from natural soil parameters. Thus, understanding natural attenuation processes in tropical environments is still a challenge, as is understanding how biogeochemical processes can influence and modify natural soil characteristics. The study aimed to apply methods that are not commonly used in investigations of contaminated areas, in order to assess the applicability of non-invasive methodology for detailed stratigraphic characterization and biogeochemical changes resulting from contamination by hydrocarbons in a complex hydrogeological environment site. To date, few studies have presented results obtained using non-invasive techniques to understand biochemical processes. The research was based on the interpretation of results obtained by high-resolution physical environment characterization techniques (such as gamma geophysical profiling and electrical conductivity surveys) and chemical analysis of groundwater. The data was interpreted to obtain a detailed characterization of the study area and evidence of the occurrence of natural attenuation of creosote contamination. The results indicated that the combination of geoenvironmental and geophysical methods is an interesting alternative for obtaining data and understanding the mineralogical and stratigraphic variation of the contaminated area. The physical parameters variations obtained by the methods suggested the presence of local geochemical alterations resulting from natural processes of attenuation of contamination by aliphatic and aromatic hydrocarbons in a tropical environment. The natural attenuation processes were confirmed through groundwater samples, biological analysis and metagenomic classification. [ABSTRACT FROM AUTHOR]

Elevated concentrations of metals in rivers can pose significant risks to human health. Consequently, it is essential to monitor metal levels in river water to minimize human exposure, particularly through consumption of harvested fish and other uses. This study examined the water quality of the Ona River in Ibadan, Nigeria. Seven potentially toxic elements (PTEs), namely Fe, Cu, Mn, Zn, Pb, Cd, Cr and four macronutrients: Mg, Na, K, Ca were investigated. Surface and pore water samples were collected from six sampling points during the peak of the dry and the rainy seasons. These were analyzed according to standard procedures and processed using the Simple Fuzzy Classification (SFC) model with four classes. The results revealed that the PTEs: Fe, Pb, Cd, Cr, and Mn were detected above guideline limits in several sampling points, indicating possible contamination from anthropogenic sources. Simple fuzzy classification puts the quality of water in the investigated portion of the river in the range of 67.4–88.5% in the C1 (pristine) category during the dry season and 61.9–88.6% in C1 (pristine) during rainy season. However, there were membership functions of up to 58.7 and 63.2; 61.2 and 75.4 as well as 44.3 and 43.5% in C2, C3, and C4 categories (contaminated, polluted and extremely polluted, respectively) during the first and second sampling, respectively. Due to the high concentrations of toxic and bioaccumulative metals in the river, efforts should be made to control the discharge of pollutants into the river. These will prevent human health exposure risks tendencies for various uses, including fish production. [ABSTRACT FROM AUTHOR]

Introduction: This study aimed to evaluate the prevalence of Klebsiella pneumoniae contamination in raw lettuce from Risalpur, Pakistan, and to analyze the antibiotic susceptibility profiles of the isolated strains. The presence of foodborne pathogens such as K. pneumoniae poses significant public health risks, particularly in regions with suboptimal hygiene practices and improper food handling. Methods: Lettuce samples were collected from various sources in Risalpur and screened for K. pneumoniae. Antimicrobial susceptibility testing was performed to evaluate the effectiveness of various antibiotics against the isolated strains. Statistical analyses, including ANOVA and linear regression, were conducted to assess differences in inhibition zones and to predict antibiotic effectiveness based on concentration. Results: The results revealed a significant prevalence of K. pneumoniae in the lettuce samples, highlighting the risks associated with poor hygiene, transportation, storage, and contaminated irrigation water. The isolated strains exhibited high susceptibility to gentamicin but demonstrated notable resistance to doxycycline, vancomycin, and ticarcillin. Multidrug-resistant (MDR) strains were identified. ANOVA showed significant differences in inhibition zones, and the linear regression model predicted a Zone of Inhibition based on antibiotic concentration (β0 = 10.6667, β1 = 0.4556). Discussion: The identification of MDR strains of K. pneumoniae underscores the urgent need for enhanced antibiotic stewardship and food safety protocols to manage foodborne pathogens. Improved hygiene practices throughout the food production and supply chain are critical to mitigate health risks and address the challenge of growing antibiotic resistance. [ABSTRACT FROM AUTHOR]

This study was conducted to investigate the presence of benzene in the ground and drinking water in the eastern Niger Delta, where multiple oil and gas production facilities are present. Samples from drinking water wells were collected for measurements of benzene, toluene, ethylbenzene, and xylenes (BTEX). Additionally, the dissolved organic carbon (DOC) concentration was determined for the first time to establish the groundwater's total hydrocarbon and non-hydrocarbon load. The groundwater BTEX and benzene levels were up to 3904 µg/L and 3500 µg/L, respectively. DOC concentrations were up to 49 mg/L. The highest benzene concentrations were detected in wells near an underground petroleum pipeline. However, the concentrations decreased with distance from the pipeline to levels less than 0.1 µg/L. Despite benzene contamination, the aquifer has shown promising aerobic attenuation potential, having up to a 7.5 (95%) mg/L DO level and 2.11 mg/L BTEX biodegradation capacity for DO. However, the high groundwater temperature of up to 32.5 °C may weaken attenuation. The benzene and BTEX point attenuation rates ranged from 0.128 to 0.693 day−1 and 0.086 to 0.556 day−1, respectively. Hence, by natural attenuation alone, up to 66.5 and 85 years would be required to reach Nigeria's groundwater benzene and BTEX remediation goals, respectively. [ABSTRACT FROM AUTHOR]

Terminal lakes (without outflow) retain elements and compounds that reach them through fluvial, point source or atmospheric deposition. If the lake sediment is exposed, some of these chemicals could become toxic dust particulates. The Great Salt Lake (GSL) in Utah is a terminal lake that experienced record-low lake elevation in 2021-22, exposing vast areas of playa. Here, we used inductively coupled plasma mass spectrometry to analyze the environmental chemistry of GSL shallow sediment during historic lows in spring, summer, and fall of 2021. Contaminants at the subsurface interface are most able to influence diffusion into the water column and uptake by benthic biota. We focused our analysis on copper, thallium, arsenic, mercury, lead, and zinc, which have been historically deposited in this region and are toxic when at high concentrations. We compared records of regional mining activity to understand the current contamination and assess relevant spatial and temporal gradients. We also used two different extraction methods (EPA 3050b and NH4AcO at pH=7) that can distinguish "environmentally available" vs. tightly associated and less available fractions. We observed consistent concentration of copper across sites indicating a larger relative impact of atmospheric deposition, with some evidence indicating further impacts of point sources. Arsenic, on the other hand, is maintained at high levels in submerged sediments and is likely geologically-and fluvially- derived. Thallium and mercury fluctuate seasonally and correlate with lake elevation. Lead and zinc levels are relatively low in GSL sites compared with freshwater input sites, indicating the deep brine layer may sequester these heavy metals, preventing their release into the water column. Overall, the concentrations of most metals in GSL sediments have declined from historic highs. However, each contaminant has distinct sources, seasonality, mobility and transmission. Complete recovery (if possible) may require many more decades and individual remediation strategies. [ABSTRACT FROM AUTHOR]

Food contamination has emerged as a significant global health concern, posing substantial challenges to the food industry. Bacteria are the primary cause of foodborne diseases. Consequently, it is crucial to develop accurate and efficient sensing platforms to detect foodborne bacteria in food products. Among various detection methods, biosensors have emerged as a promising solution due to their portability, affordability, simplicity, selectivity, sensitivity, and rapidity. Electrospun nanofibers have gained increasing popularity in enhancing biosensor performance. These nanofibers possess a distinctive three-dimensional structure, providing a large surface area and ease of preparation. This review provides an overview of the electrospinning technique, nanofibers and nanofiber-based biosensors. It also explores their mechanisms and applications in the detection of foodborne bacteria such as Salmonella, Listeria monocytogenes (L. monocytogenes), Escherichia coli (E. coli), Staphylococcus aureus (S. aureus) and Pseudomonas putida (P. putida). [ABSTRACT FROM AUTHOR]

Fish farming is increasingly important globally and nationally, playing a crucial role in fish production for human consumption. Monitoring microbiological and chemical contaminants from water discharge is essential to mitigate the risk of contaminating water and fish for human consumption. This study analyzes the physicochemical and E. coli parameters of water and tambacu fish muscles (Colossoma macropomum × Piaractus mesopotamicus) in Western Maranhão, Brazil. It also includes a qualitative characterization of zooplankton in the ponds. Samples were collected from tambacu ponds in a dam system fed by natural watercourses from the Tocantins River tributaries, located at the connection of the Brazilian savanna and Amazon biomes. The physicochemical and E. coli parameters of water did not meet national standards. The zooplankton community included Rotifera, Cladocera, Copepoda, and Protozoa representatives, with no prior studies on zooplankton in the region, making these findings unprecedented. The biological quality of freshwater is crucial in fish farming, as poor quality can lead to decreased productivity and fish mortality, raising significant food safety concerns. The water quality studied is related to the potential influence of untreated wastewater as a source of contamination, leaving the studied region still far from safe water reuse practices. The findings on chemical and E. coli contamination of fish farming waters concern human health and emphasize the need for appropriate regulations. [ABSTRACT FROM AUTHOR]

Plastic pollution has become a growing concern for environmental and human health in recent years. Currently, research suggests that soil compartments might be highly contaminated, with compost being one of the major sources for plastic contamination, especially at reduced sizes. In Geneva, microplastic contamination has already been evaluated in industrial compost but not yet in field-side compost. Therefore, this work focuses on the evaluation of concentrations and the characterization of microplastic particles (MPs) in field-side compost in Geneva. Four different field-side composts were sampled in Geneva and sieved with sizes ranging from >5 mm to 0.5 mm. The MPs were visually sorted when possible, and the smaller ones were treated by digestion and density separation processes. All of the MPs were analyzed with infrared spectroscopy. The results (sizes > 5 mm to 1.25 mm) reveal concentrations between 195 ± 64 and 1315 ± 375 plastic particles/kg of compost and the presence of conventional plastics in every compost. MPs were present in almost every size fraction for the four composts, and the origin of waste seemed to influence their concentrations. Indeed, composts free from organic household waste had lower concentrations than the ones accepting that kind of waste. Littering and waste still wrapped in plastic were also noticed for the composts with higher concentrations of MPs. The characterization results highlight the variety of plastic types among the composts, mostly represented by PE (polyethylene), PVA (polyvinyl alcohol), PP (polypropylene), and DAIP (polydiallyl iso-phthalate) in general but also specific contamination by PEMA (poly ethyl methacrylate) for only one of the composts. Further work is needed to evaluate the distribution of MPs according to their size or the types of waste used in composting, especially the potential degrading conditions of plastics, to mitigate their presence in composts. [ABSTRACT FROM AUTHOR]

This study was conducted in the territory of the industrial site of the Udachny Mining and Processing Division (Yakutia, Russia). The objects of study were permafrost soils and two species of shrubs (Betula middendorffii T. and Duschekia fruticose R.). Soil and plant samples were analyzed by atomic absorption spectrometry for the presence of potentially toxic elements (Pb, Ni, Mn, Cd, Co, Co, Cr, Zn, Cu, and As). The bioaccumulation factor for each element was also calculated. In the studied plants, the investigated elements were arranged in the following descending row in terms of their content: Mn > Zn > Cr > Ni > Cu > Pb > As > Co > Cd, but in terms of bioaccumulation degree, they decrease in the following row: Cr > Zn > Ni > Mn > Pb > Cu > Cd > Co—for Betula middendorffii, Cr > Zn > Ni > Pb > Cu > Mn > Mn > Cd > Co—for Duschekia fruticose. The bioaccumulation factor results confirmed that Betula middendorffiii and Duschekia fruticosa are resistant to high concentrations of Cr, Ni, Co, Cu, Mn, and Zn elements coherent to kimberlites. [ABSTRACT FROM AUTHOR]

Simple Summary: This study compared the bacterial contamination between two common peripheral intravenous catheter placement sites, in the front leg versus the hind leg, in dogs undergoing dental scaling under general anaesthesia. Regardless of the dog's size, a significantly higher bacterial contamination load was found at the front leg compared to the hind leg placement site. The bacteria isolated from the injection port of the cannula were mainly Staphylococcus, Neisseria, and Bacillus species. These findings suggest that to reduce the risk of contamination of the peripheral intravenous catheter during dental scaling procedures in dogs, placing the catheter in the hind leg may be beneficial. During dental scaling in dogs under general anaesthesia, contamination of the peripheral intravenous catheter (PIVC) is unavoidable due to splatter and the generated aerosol. Bacterial contamination was compared between two commonly used PIVC placement sites. Thirty-nine client-owned dogs with a minimum length from their nose to their tail base of 50 cm were randomly assigned to receive a PIVC in either their cephalic or saphenous vein. Irrespective of the PIVC placement site, brain heart infusion agar dishes were placed in the cephalic and saphenous vein areas. Their lids were closed 0, 5, and 10 min into the procedure. Contamination was measured by counting the colony-forming units after incubation on different substrates. The data were analysed with descriptive statistics, ANOVA, and ANCOVA (p < 0.05). The cephalic vein area showed a significantly higher bacterial load than the saphenous vein area (p ≈ 0.0) regardless of the length of the dog. Furthermore, the dorsal PIVC injection ports were sampled before and after scaling, and the colonies isolated were counted and subjected to MALDI-TOF-MS for identification. The bacteria mainly belonged to the genera Staphylococcus, Neisseria, and Bacillus. Our results suggest that for dental scaling in dogs, the PIVC should be placed in the pelvic limb whenever possible to reduce the potential risk of contamination. [ABSTRACT FROM AUTHOR]

In this work, TiO2 spherical nanoparticles with a mean diameter of 10.08 nm (SD = 4.54 nm) were synthesized using Aloe vera extract. Rutile, brookite, and anatase crystalline phases were identified. The surface morphology of a carbon paste electrode does not change in the presence of nanoparticles; however, the surface chemical composition does. The voltammetric response to dicresyl dithiophosphate was higher when the electrode was modified with TiO2 nanoparticles. After an electrochemical response study from pH 1.0 to 12.0, pH 7.0 was selected for the electroanalysis. The electroactive area of the modified sensor was 0.036 cm2, while it was 0.026 cm2 for the bare electrode. The oxidation process showed mixed adsorption-diffusion control. The charge transfer resistance of the modified sensor (530.1 Ω, SD = 4.08 Ω) was much lower than that of the bare electrode (4298 Ω, SD = 8.53 Ω). The linear quantitative range by square wave voltammetry was from 5 to 150 μmol/L, with a limit of detection of 1.89 μmol/L and a limit of quantification of 6.26 μmol/L under optimal pulse parameters of 50 Hz frequency, 1 mV step potential, and 25 mV pulse amplitude. The sensor response was repeatable and reproducible over 30 days. The results on real flotation and synthetically contaminated soil samples were statistically equivalent to those obtained by UV-vis spectrophotometry. A dithiocarbamate showed an interfering effect on the sensor response to dithiophosphate. [ABSTRACT FROM AUTHOR]

The present study addresses advanced monitoring techniques for particles and airborne molecular contaminants (AMCs) in cleanroom environments, which are crucial for ensuring the integrity of semiconductor manufacturing processes. We focus on quantifying particle levels and a representative AMC, hydrogen chloride (HCl), having known detrimental effects on equipment longevity, product yield, and human health. We have developed a compact laser sensor based on open-path cavity ring-down spectroscopy (CRDS) using a 1742 nm near-infrared diode laser source. The sensor enables the high-sensitivity detection of HCl through absorption by the 2-0 vibrational band with an Allan deviation of 0.15 parts per billion (ppb) over 15 min. For quantifying particle number concentrations, we examine various detection methods based on statistical analyses of Mie scattering-induced ring-down time fluctuations. We find that the ring-down distributions' 3rd and 4th standard moments allow particle detection at densities as low as ~105 m−3 (diameter > 1 μm). These findings provide a basis for the future development of compact cleanroom monitoring instrumentation for wafer-level monitoring for both AMC and particles, including mobile platforms. [ABSTRACT FROM AUTHOR]

Anthropogenic environmental pollution is a major development challenge in Ugandan rivers and lakes, the key drivers being industrialization, agriculture, and urbanization. The aim of the study was to assess the potential of heavy metal and microplastic contamination in River Mpanga, Fort Portal, Uganda. Triplicate water and sediment samples were collected from three sampling sites, preserved, and analyzed at the Chemistry Department, Makerere University for heavy metals, while microplastics analysis was conducted at NaFIRRI, Jinja. Sediment heavy metal contamination was assessed from the geoaccumulation index, while microplastic characterization and quantification were determined from stereomicroscopy and morphological features. Arsenic was the most prevalent metal with a mean concentration of 13.2 ppm thus higher than permissible maximum limits of WHO. The mean concentrations (ppm) of copper, lead, and cadmium were 0.01, 0.01, and 0.001 respectively, and below the permissible maximum. Sediment samples revealed very strong arsenic contamination, strong contamination for copper, moderate to strong contamination for lead, and a potential lack of contamination for cadmium. The higher concentrations of the heavy metals in the sediments compared to water could be attributed to bioaccumulation, as evidenced by the high geoaccumulation values. Microplastics occurred throughout the river and included fragments, filaments, film, pellets, form, and fibers. The presence of heavy metals and microplastics was attributed to anthropogenic activities within the river vicinity, which discharged heavy metal-laden waste into River Mpanga. High arsenic concentrations and sediment accumulation of contaminants pose serious potential public health threats to the local communities. [ABSTRACT FROM AUTHOR]

Abstract The paper presents examples of the consequences of the lack of negative pressure in the work zone during asbestos removal. The asbestos fibre concentrations generated in those work zones were relatively low. This was due to the leakage in barriers restricting the work zone. Therefore the asbestos content in the outside air, near the renovated rooms was increasing. In the cases discussed, these works resulted in short-term pollution of the building's outdoor air to a depth of up to 15 m. Such contamination can cover the entire interior of the building. This may lead to long-term retention of asbestos fibre in the facility, despite the completion of asbestos removal. For example, non-friable asbestos-cement sheets removal in those work conditions increased indoor air by contamination up to 3000 f/m3 (outside the work zone). In the case of removing friable asbestos inside the building type “LIPSK”, indoor air contamination locally was up 21,000–51,000 f/m3, and outside the work zone to 18,000–28,900 f/m3. These values are above the average concentration of asbestos fibres in the same type of buildings (

The beer industry is one of the most rapidly developing industries in Chinese beverage alcohol industry, in which the production of raw materials and processing of beer are closely related to the quality of products and industrial development. The control of Deoxynivalenol (DON) from contamination of raw materials or processing of beer is one of the most critical and interesting research areas. This paper analyzes the contamination of DON, which is an important mycotoxin that affects the quality and safety of beer. Combined with the migration and transformation of DON during the key stages of beer processing, the measures for controlling DON in beer processing are elaborated from three major methods of physics, chemistry and biology, which provides the theoretical basis for controlling DON contamination and improving the quality of beer.

The inception of forensic DNA elimination database represents a pivotal advancement in forensic science, aiming to streamline the process of distinguishing between DNA found at crime scenes and that of individuals involved in the investigation process, such as law enforcement personnel and forensic lab staff. In subsequent phases, once familiarity with the database is achieved by its administrators and other stakeholders, and they have accrued sufficient experience, the possibility of expanding the database to encompass first responders—including firefighters, paramedics, emergency medical technicians, and other emergency services personnel—can be contemplated. Key challenges in managing these databases encompass the grounds for collecting samples, ensuring the integrity of both samples and profiles, along with the duration of retention, access to the database, and the protocols to follow when a match is found in the database. This paper outlines the conceptual and detailed legislative framework in Hungary, where the forensic DNA elimination database was introduced in 2022. • Elimination DNA databases help exclude individuals with legitimate reasons for being at a crime scene by compiling their DNA profiles. • The utilization of the elimination database was introduced in Hungary on January 1, 2022; however, a systematic analysis of the regulation suggests improvements to the regulation. [ABSTRACT FROM AUTHOR]

Melamine is a recognized food contaminant that can arise incidentally or intentionally in specific categories of food. This study aimed to validate the melamine detection and quantification in infant formula and milk powders and also analyzed 40 samples consist of infant formula and milk powders from commercially available food products, from different geographic regions of Iran. The approximate content of melamine in samples was measured by High-performance liquid chromatography-ultra violet (HPLC–UV) system. A calibration curve (R2 = 0.9925) was established for detection of melamine in the range of 0.1–1.2 μg mL−1. Limit of quantification and limit of detection were 1 μg mL−1 and 3 μg mL−1, respectively. The presence of melamine in infant formula and milk powdered was investigated and it was observed that the amount of melamine in samples of infant formulas and milk powders was 0.001–0.095 mg kg−1 and 0.001–0.004 mg kg−1, respectively. These values were found to be within the prescribed limits by the European Union and Codex Alimentarius Commission legislation. It is important to note that the consumption of these dairy products, which contain low content of melamine, does not pose any significant threat to consumer health. Furthermore, the results of the risk assessment confirmed this issue. [ABSTRACT FROM AUTHOR]

This study aims to find a more realistic management approach to Municipal solid waste (MSW), focusing on Ndokwa West LGA, Delta State, Nigeria. It employs a combination of geospatial analyses and laboratory examination of water samples from three borehole locations congruent to landfills in the study area. GPS-measured positions of the five landfill sites were plotted on the topographic plan of the study area and analysed. This landfills' location, which is the southeastern part of the area, is a lowland. By hydraulic gradient and flow pattern of the area deducted from DEM, these landfills are within the pathway of major groundwater resources. Proximity analyses with 5 to 10 km buffer zones show that most of the topographic features are at risk of considerable pollution due to landfill's leachate into the surrounding area. Groundwater vulnerability map shows 21.5% of the studied area at a high risk of contamination, 7.5% at medium, and ~71% at low risk. The Dissolved Oxygen (DO) levels from the three boreholes were significant, suggesting severe pollution, and pointing to the landfill as the main cause. Colour showed an unobjectionable state and signified pollution of the wells. Temperature (0°C) ranged from 20 to 26°C, much higher than the 5°C limit, set by the WHO and NSDWQ. The water pH ranges from 6.05 to 7.02, suggesting traces of heavy metals in water samples. Nitrate and nitrite have values ranging from 5.0 to 6.162 and 0.251 to 0.455 mg/l, suggesting the water samples contain some contaminants. Lead (Pb) (from 0.25 to 0.65 mg/l) is practically beyond the WHO and NSDWQ permissible limits for heavy metals. The accumulation of lead in landfills has substantial effects on groundwater pollution. The Heavy Metal Index Calculation scale rated the result of heavy metals analyses as 'VI,' representing a 'Seriously Affected' water supply system. [ABSTRACT FROM AUTHOR]

Groundwater, a vital freshwater resource catering to agricultural, domestic, and industrial needs, faces a pressing challenge of contamination due to escalating human activities. This study focuses on the Ayad River Basin in the Udaipur district of Rajasthan, employing the FEFLOW simulation code for the first time. A steady-state numerical model and a groundwater contaminant prediction model for total dissolved solids (TDS), nitrate, and fluoride were developed, simulating trends over the next five years with an accuracy exceeding 95%. The results reveal an eastward increase in TDS, nitrate, and fluoride concentrations, attributed to contamination from two waste disposal sites-Titadi and Baleecha. Titadi, operational for four decades until closure in 2010, retains residual waste over 32 thousand m2. The initiation of a new dumping ground at Baleecha by the Udaipur Municipal Corporation post-2010 exacerbates regional contamination. Nitrate contamination is particularly high in agricultural zones with excessive chemical fertilizer usage. Of the 27 scenarios tested, 23 support using the water for irrigation but would require treatment before using it for drinking. Recommendations include deploying a chemical sensor network for real-time data input into the web enabled FEFLOW model, real-time monitoring and alerts, and a mobile application providing personalized guidance on water usage and health risks in case of contamination. This study can be beneficial to decision-makers, who work on the policy and groundwater management strategies. [ABSTRACT FROM AUTHOR]

Soil contamination by trace elements is a worldwide concern that can result from several sources, such as mining, smelting, car traffic exhaust, agriculture plant protection products such as fungicides, and fertilizers. Among the metals involved, copper can cause alterations in the photosynthetic, respiratory, and enzymatic processes of plants, leading to reduced growth of roots and shoots. An alternative to dealing with metals present in the soil is phytoremediation, which consists of using plants to extract or stabilize these elements. The leguminous Crotalaria juncea is widely used as a green manure and may be advantageous due to its capacity for biological nitrogen fixation and biomass accumulation. This research aimed to evaluate the growth and physiological behaviour of C. juncea in copper-contaminated soil and its potential use as a phytoremediation plant. For the fresh and dry mass of shoots and roots, compared with 30 mg.dm−3 of Cu, there was a decrease in values with the increase in concentrations up to a dose of 480 mg.dm−3. The roots were less sensitive to increased Cu concentrations than the shoots. The tolerance index decreased as copper concentrations in the soil increased. From 60 mg.dm−3, its vegetative growth decreased, but C. Juncea was able to tolerate and accumulate copper in the root system, presenting high potential as a phytostabilizing species. [ABSTRACT FROM AUTHOR]

This study presents an extensive evaluation of the contamination levels in fish, mollusks, water, and sediments in the Black Sea over eight years, from 2016 to 2023. The primary aim was to determine the concentrations and distribution patterns of heavy metals (HMs), polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), and other persistent organic pollutants (POPs) in fish, water, and sediments of the Black Sea, and their implications for marine ecosystem health and human safety. Data were collected through scientific cruises and the methodology involved systematic sampling across different regions of the Romanian Black Sea, followed by rigorous laboratory analyses to identify and quantify the presence of contaminants. The study also examined the temporal trends of these pollutants, providing insights into their sources, pathways, and persistence in the marine environment. Additionally, the research assessed the bioaccumulation of contaminants in various biota, offering a critical perspective on food safety and potential risks to human consumers. The findings revealed significant spatial insights, highlighting areas of concern that require immediate attention and action. Notably, industrial discharge, agricultural runoff, and historical pollution hotspots were identified as major sources of contamination. This research underscores the need for enhanced monitoring and regulatory frameworks to mitigate pollution sources and safeguard the Black Sea ecosystem, advocating for sustainable practices and effective management strategies to preserve marine resources in the Black Sea. [ABSTRACT FROM AUTHOR]

Access to safe drinking water remains a fundamental issue in rural areas of Ethiopia. This study aimed to evaluate the physicochemical and bacteriological quality of drinking water at protected sources in the Farta district, South Gondar Zone, Ethiopia. The study covered 16 rural Kebeles and was conducted on 75 protected dug wells with hand pumps (HDWs) and 17 protected springs (PSs). Data were collected during the wet and dry season, and field measurement were conducted on water samples pH, turbidity, electrical conductivity, and temperature, while laboratory analysis focused on E. coli prevalence. Additionally, sanitary risk assessment was also performed. The result showed that, the pH values ranged from 5.4 to 8.1, turbidity levels varied between 0 to 100 nephelometric turbidity unit (NTU), electric conductivity ranged from 62 to 584 µS/cm, and temperature ranged from 12.1 to 27 °C. Among all the samples, 39.1% had a pH below the minimum standard value of 6.5, close to 50.5% did not meet the turbidity requirement (5NTU), and all samples were safe against electric conductivity levels. The E. coli contamination was widespread, and only a small percentage of water sources, such as 21.7% HDWs, 6.7% PSs during dry season, and 13% HDWs during wet season were negative to E. coli detection. A significant proportion of water sources, such as 18% HDWs and 13% PSs during dry season, as well as 44.9% HDWs and 46.7% PSs during wet season, fell into the high microbial health risk category. Sanitary inspections revealed that only 16.7% of water sources were classified as low sanitary risk. This study revealed that majority of water sources were unfit to drinking and may endanger the public health. To ensure safe water availability frequent cleaning and disinfection of water sources, implementation of household water treatment, and improvement of WASH (water, sanitation and hygiene) infrastructure is needed. [ABSTRACT FROM AUTHOR]

Despite the numerous sensory, organoleptic and nutritional qualities, fish meat may also contain some toxic compounds with negative effects on human health. Polycyclic aromatic hydrocarbons (PAHs) are a class of chemicals resulting from incomplete combustion, found at high levels in thermally processed foods, especially in smoked fish. This research studied the influence of wood type (beech, plum and oak) and fish species (rainbow trout, carp and Siberian sturgeon) on PAH contamination in hot smoked fish. Benzo(a)Piren, Σ4PAHs and Σ15PAHs were considered as main indicators of PAH contamination. All-PAHs was quantified in all samples, indicating a specific dynamic of values due to the influence of variables. Generally, BaP (benzo(a)pyrene) content in the samples ranged from 0.11 µg/kg to 8.63 µg/kg, Σ4PAHs from 0.70 µg/kg to 45.24 µg/kg and Σ15PAHs from 17.54 µg/kg to 450.47 µg/kg. Thus, plum wood promoted the highest levels of PAHs, followed by oak and beech. Carp and Siberian sturgeon presented the highest concentrations of PAHs. Some of these parameters had levels that exceeded the limits allowed by legislation via Commission Regulation (EU) No 835/2011. Results revealed BaP levels > 2 µg/kg when plum wood was used in rainbow trout (4.04 µg/kg), carp (4.47 µg/kg) and Siberian sturgeon (8.63 µg/kg). Moreover, the same trend was found for Σ4PAHs, which exceeded 12 µg/kg in rainbow trout (17.57 µg/kg), carp (45.24 µg/kg) and Siberian sturgeon (44.97 µg/kg). [ABSTRACT FROM AUTHOR]

In present study, wastewater quality was evaluated applying multivariate analysis (PCA) and water quality index with respect to the Indian standards in the selected urban areas of Jaipur region, Rajasthan, India. Maximum average values of BOD5, TDS, chloride and fluoride were recorded as 21 mg/L, 1501 mg/L, 285.0 mg/L and 1.8 mg/L, respectively, along with metal concentration in order of Zn (6.31 mg/L )> Fe (0.52 mg/L )> Mn (0.25 mg/L), Cu (0.16 mg/L)> Pb (0.11 mg/L)> Ni (0.02 mg/L). PCA indicates four components extracted with a total variance of 78.48% from the water quality parameters. Wastewater Quality Index (WWQI) analysis emphasis level of pollution load at different sites which revealed 40% of the selected sites were inappropriate for reuse without treatment, however, 60% of the sites with moderate pollution load could be suitably reuse in agricultural and aquaculture. Findings of the present study conclude that multivariate analysis and wastewater quality index could be used as an effective tool for environmental monitoring, assessing, and categorizing wastewater to opt appropriate treatment, reuse and recycling options for sustainable wastewater management. [ABSTRACT FROM AUTHOR]

In this study, the degradation system of Shewanella oneidensis MR-1 and goethite was constructed with chlorpyrifos as the target contaminant. The effects of initial pH, contaminant concentration, and temperature on the removal rate of chlorpyrifos during the degradation process were investigated. The experimental conditions were optimized by response surface methodology with a Box–Behnken design (BBD). The results show that the removal rate of chlorpyrifos is 75.71% at pH = 6.86, an initial concentration of 19.18 mg·L−1, and a temperature of 30.71 °C. LC-MS/MS analyses showed that the degradation products were C4H11O3PS, C7H7Cl3NO4P, C9H11Cl2NO3PS, C7H7Cl3NO3PS, C9H11Cl3NO4P, C4H11O2PS, and C5H2Cl3NO. Presumably, the degradation pathways involved are: enzymatic degradation, hydrolysis, dealkylation, desulfur hydrolysis, and dechlorination. The findings of this study demonstrate the efficacy of the goethite/S. oneidensis MR-1 complex system in the removal of chlorpyrifos from water. Consequently, this research contributes to the establishment of a theoretical framework for the microbial remediation of organophosphorus pesticides in aqueous environments. [ABSTRACT FROM AUTHOR]

The exponential increase in the production and transportation of petroleum-derived products observed in recent years has been driven by the escalating demand for energy, textiles, plastic-based materials, and other goods derived from petroleum. Consequently, there has been a corresponding rise in spills of these petroleum derivatives, particularly in water sources utilized for transportation or, occasionally, illegally utilized for tank cleaning or industrial equipment maintenance. Numerous researchers have proposed highly effective techniques for detecting these products, aiming to facilitate their cleanup or containment and thereby minimize environmental pollution. However, many of these techniques rely on the identification of individual compounds, which presents significant drawbacks, including complexity of handling, subjectivity, lengthy analysis times, infeasibility for in situ analysis, and high costs. In response, there has been a notable surge in the utilization of sensors or generalized profiling techniques serving as sensors to generate characteristic fingerprints of these products, thereby circumventing the aforementioned disadvantages. This review comprehensively examines the evolution of techniques employed for detecting petroleum-derived products in water samples, along with their associated advantages and disadvantages. Furthermore, the review examines current perspectives on methods for the removal and/or containment of these products from water sources, to minimize their environmental impact and the associated health repercussions on living organisms and ecosystems. [ABSTRACT FROM AUTHOR]