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Abstract: Over the last 30 years the use of light weight, inexpensive, and durable plastics in automobiles has nearly tripled on a per vehicle basis. Although this has created benefits such as increased fuel efficiency and associated lower CO2 emissions, the growing disposition of plastics from end-of-life vehicles has put increasing pressure on North American landfill capacity. Financial and life cycle assessment models were developed and applied to the current and proposed recycling business operations of AADCO Automotive Incorporated (AADCO), a leading Canadian automotive dismantling company. By applying both kinds of models, two key questions are addressed. First, how much is it expected to cost AADCO to participate in a start-up automotive plastics recycling network? and second, by estimating greenhouse gas emissions and energy requirements, is recycling automotive plastics actually better for the environment compared to manufacturing virgin plastic resin within the boundaries set forth in this case study? The present study concluded that the proposed recycling network would reduce greenhouse gas emissions and energy requirements by nearly 50% when compared to the current operations at AADCO (equating to a reduction of 1063tonnes of CO2(eq) and 18TJ, respectively). However, in spite of the environmental benefits, the magnitude of the added costs for AADCO to participate in the post-consumer automotive plastics recycling network resulted in an unprofitable value proposition for the company. [Copyright &y& Elsevier]

Highlights • The corn stover ethanol models from GREET and GHGenius were compared. • Life cycle greenhouse gas emissions from baseline models differed by 45 gCO 2 e MJ−1. • Key inputs and assumptions in the models were aligned and made identical. • Life cycle greenhouse gas emissions differed by 1.3 gCO 2 e MJ−1 after alignment. • Variations in emissions persisted for key inputs even after model alignment. Abstract This paper evaluates differences in life cycle greenhouse gas emissions of corn stover ethanol produced in the U.S. Midwest, as estimated by the life cycle-based software GHGenius 4.03a, GREET 2013, and GREET 2015. Life cycle assessments are not typically conducted using more than one software package, but comparisons such as the analysis in this paper provide a critical review of a fuel product system. In particular, differences in the data and assumptions become evident for life cycle stages of the same fuel product when compared between life cycle assessment software packages. Using default settings in the three software packages, life cycle greenhouse gas emissions predictions ranged from 2.75 to 47.8 gCO 2 equivalent per MJ of ethanol (gCO 2 e MJ−1), which presents a difference of as much as 45 gCO 2 e MJ−1. Assumptions regarding nitrogen fertilizer, land management, on/off-site enzyme production, and material/energy inputs included/excluded had substantial effects on life cycle greenhouse gas emissions. A consistent corn stover ethanol pathway using equivalent model assumptions and material/energy inputs was developed and implemented in each of the software packages, resulting in life cycle greenhouse gas emissions ranging from 40.7 to 42.0 gCO 2 e MJ−1. The difference in life cycle greenhouse gas emissions was considerably reduced to 1.3 gCO 2 e MJ−1 at most between software packages; however, individual emissions sources such as nitrogen fertilizer production, fertilizer application, corn steep liquor, glucose, sodium hydroxide, and biomass electricity still exhibit variation between software packages (e.g., up to 7.3 gCO 2 e MJ−1 E100 for equivalent glucose input), mainly due to different emissions factors data. Life cycle greenhouse gas emissions appeared consistent because emissions sources that vary between software packages offset each other. Differences in greenhouse gas emissions determined for corn stover ethanol point to the need to improve the life cycle modelling and replicability of life cycle studies on this biofuel pathway. Such inconsistencies are relevant in a carbon economy because the same product will have a different value in different jurisdictions as a result of differences in life cycle assessment software packages. [ABSTRACT FROM AUTHOR]

Steam-treated pellets can help to address technical barriers that limit the uptake of pellets as a fuel for electricity generation, but there is limited understanding of the cost and environmental impacts of their production and use. This study investigates life cycle environmental (greenhouse gas (GHG) and air pollutant emissions) and financial implications of electricity generation from steam-treated pellets, including fuel cycle activities (biomass supply, pellet production, and combustion) and retrofit infrastructure to enable 100% pellet firing at a generating station that previously used coal. Models are informed by operating experience of pellet manufacturers and generating stations utilising coal, steam-treated and conventional pellets. Results are compared with conventional pellets and fossil fuels in a case study of electricity generation in northwestern Ontario, Canada. Steam-treated pellet production has similar GHG impacts to conventional pellets as their higher biomass feedstock requirement is balanced by reduced process electricity consumption. GHG reductions of more than 90% relative to coal and ∼85% relative to natural gas (excluding retrofit infrastructure) could be obtained with both pellet options. Pellets can also reduce fuel cycle air pollutant emissions relative to coal by 30% (NOx), 97% (SOx), and 75% (PM 10 ). Lesser retrofit requirements for steam-treated pellets more than compensate for marginally higher pellet production costs, resulting in lower electricity production cost compared to conventional pellets ($0.14/kW h vs. $0.16/kW h). Impacts of retrofit infrastructure become increasingly significant at lower generating station capacity factors, further favouring steam-treated pellets for both environmental and financial metrics. [ABSTRACT FROM AUTHOR]

Despite international efforts to increase the adoption of alternative fuel vehicles, global gasoline internal combustion engine vehicles (ICEV-Gs) sales are projected to remain strong for the coming decades, with electric vehicles (EV) sales remaining well below 50% under International Energy Agency projections for 2030. The current study analyzes the cumulative reduction of greenhouse gas emissions that can be obtained by 2050 from policies targeting these gasoline powered vehicles. The analysis is applied to the case of the U.S. light-duty vehicles (LDV) fleet, a representative country with a large LDV fleet and slow EV penetration; the work considers technological, decisional and behavioral solutions. Technological pathways include fuel economy improvements, vehicle lightweighting and a greater provision of ethanol blends. Decisional pathways include purchasing decisions related to vehicle size and relative (best-in-class) fuel economy among available models. Behavioral pathways include improvements in driving habits. This study demonstrates the transitional and complementary role to fleet electrification that ICEV-Gs can play to meet climate targets, starting from vehicle models in the market today. A scenario-based analysis confirms that effective and diverse mitigation pathways targeting ICEV-G decarbonisation may lessen the need for aggressive fleet electrification rates – reducing the required cumulative electric vehicle sales through 2050 by at least 10% and by as much as 98% under extreme scenarios in the U.S. The analysis also identifies the limit of the ICEV-G fleet decarbonisation at 40% of cumulative lifecycle emissions from 2021 to 2050 in a very optimistic scenario, suggesting that these measures can complement but not replace the need to develop alternative fuels and powertrains. • Examined GHG mitigation measures targeting gasoline vehicle (ICEV-G) technology • Higher efficiency, hybridization & downsizing help ICEV-Gs meet GHG targets • Such measures can reduce cumulative fleet GHG emissions through 2050 by 5 to 30% • Plausible ICEV-G measures can delay need for full electrification by 5–25 years • Effective policy requires both technological improvements and behavioral changes [ABSTRACT FROM AUTHOR]

Life cycle environmental performance of lignocellulosic ethanol produced through different production pathways and having different co-products has rarely been reported in the literature, with most studies focusing on a single pre-treatment and single co-product (electricity). The aim of this paper is to understand the life cycle energy use and greenhouse gas (GHG) emissions implications of alternative pre-treatment technologies (dilute acid hydrolysis, ammonia fiber expansion and autohydrolysis) and co-products (electricity, pellet, protein and xylitol) through developing a consistent life cycle framework for ethanol production from corn stover. Results show that the choices of pre-treatment technology and co-product(s) can impact ethanol yield, life cycle energy use and GHG emissions. Dilute acid pathways generally exhibit higher ethanol yields (20-25%) and lower net total energy use (15-25%) than the autohydrolysis and ammonia fiber expansion pathways. Similar GHG emissions are found for the pre-treatment technologies when producing the same co-product. Xylitol co-production diverts xylose from ethanol production and results in the lowest ethanol yield (200 L per dry t of stover). Compared to producing only electricity as a co-product, the co-production of pellets and xylitol decreases life cycle GHG emissions associated with the ethanol, while protein production increases emissions. The life cycle GHG emissions of blended ethanol fuel (85% denatured ethanol by volume) range from -38.5-37.2 g CO2 eq/MJ of fuel produced, reducing emissions by 61-141% relative to gasoline. All ethanol pathways result in major reductions of fossil energy use relative to gasoline, at least by 47%. [ABSTRACT FROM AUTHOR]

Existing life cycle assessments of concrete containing supplementary cementitious materials (SCMs) hinge on methodological procedures that might skew the results towards the conclusion that increasing the use of SCMs in concrete always decreases greenhouse gas (GHG) emissions. These procedures relate to the treatment of co-products and selection of functional units. Co-production is typically addressed via cut-off procedures and by-products are always considered to be unconstrained resources, while functional units often do not account for exposure conditions and concrete properties such as strength and workability. To address this limitation, the aim of this study was to investigate the GHG benefits of using SCMs by (1) adopting different approaches to solve multifunctionality (cut-off vs. substitution) and (2) including strength, workability and exposure conditions of concrete in the functional unit. Ontario (Canada) was used as case study, and both SCMs currently used there (i.e., slag, silica fume and metakaolin) and a wide range of alternative cementitious materials used around the world (i.e., fly ash, oil shale ash, calcium carbide residue, volcanic ash, coal bottom ash and rice husk ash) were investigated. The new contribution of this study reveals that different conclusions can be drawn when different methodological procedures are adopted. If the market for SCM is constrained (i.e., by-products are already fully utilized) and the unconstrained alternative on the market is Portland cement, the benefits of using SCM are greatly reduced, or even reversed, if the substitution approach is adopted. In contrast, unconstrained SCMs result in considerable GHG savings unless they significantly reduce the water-to-binder ratio to reach a prescribed strength and require long distance transport. • Market constraints of SCMs should be included in LCA studies of concrete. • Concrete properties and exposure conditions must be included in the functional unit. • If the SCM is constrained, overall GHG benefits of using it are greatly reduced. • Increasing SCMs in concrete does not always decrease its GHG emissions. • The use of alternative unconstrained SCMs should be further explored and promoted. [ABSTRACT FROM AUTHOR]