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Paper coating plays an important role in the paper properties, printability and application. The nanocoating is a multifunction layer that provides the paper with unique features. In this work, nanocoating formulas were prepared using a green method and component. The nanocoating formulas were based on biopolymers nanostarch NSt and nanochitosan NCh (NCS) decorated with Egyptian kaolinite Ka doped with zinc nanoparticles NCS@xka/ZnONPs (x represents different ratios) support for multifunctional uses. The nanocoating formulas were characterized using a physiochemical analysis as well as a topographical study. FTIR, XRD, SEM and TEM techniques were used. Additionally, the antimicrobial activity of the tested samples was assessed against six microorganisms including Gram-negative and Gram-positive bacteria. The prepared nanocoating formulas affirmed excellent antimicrobial activity as a broad-spectrum antimicrobial active agent with excellent activity against all representative microbial communities. The nanocoating with the highest ratio of Ka/ZnONPs (NCS@40 ka/ZnONPs) showed excellent antimicrobial activity with an inhibition percentage of more than 70% versus all microorganisms presented. The paper was coated with the prepared suspensions and characterized concerning optical, mechanical and physical properties. When Ka/ZnONPs were loaded into NCS in a variety of ratios, the characteristics of coated paper were enhanced compared to blank paper. The sample NCS@40 ka/ZnONPs increased tensile strength by 11%, reduced light scattering by 12%, and improved brightness and whiteness by 1%. Paper coated with NCh suspension had 35.32% less roughness and 188.6% less porosity. When coated with the sample NCS@10 ka/ZnONPs, the coated paper's porosity was reduced by 94% and its roughness was reduced by 10.85%. The greatest reduction in water absorptivity was attained by coating with the same sample, with a reduction percentage of 132%. [ABSTRACT FROM AUTHOR]

This paper gives an overview of various factors that influences the performance of Limestone Calcined Clay Cement (LC3) concrete. Among the various research related to ternary cements, this paper discusses the influential factors, based on the strength and durability aspects. The factors such as the type and purity of kaolinite, limestone, gradation of the limestone, concentration of gypsum, calcined clay, limestone ratio, clinker content, water-to-binder ratio, method and effect of calcination, grinding criteria, optimum temperature of calcination, calcined clay content, method of curing and other factors are interpreted. Even low-grade materials with minimum purity have also been found to achieve the desired properties. Therefore depending upon the knowledge of the importance of every parameter, the best quality concrete could be developed with the available source and facilities. With the available quality and quantity of material, sustainable ternary cement could be obtained. By optimizing the various factors that influence the behavior of LC3 concretes, more economical and durable concrete can be produced. [ABSTRACT FROM AUTHOR]

In the process of long-term water flooding in the Gaoqian Southern Area with an average porosity of 30% and an average permeability of 1333.5 × 10 − 3 μm2, the fluid-solid interaction among oil, water, and rock has a great influence on the pore structure. It has resulted in changes in reservoir parameters with the extension of time. This paper used electron microscopy scanning, mercury injection, X-ray diffraction, physical properties, and oil-water relative permeability curves to study the variation of clay mineral content, pore throat structure, porosity, permeability, and relative permeability curves of high-permeability sandstone after high-pressure water flooding. The results showed that clay minerals such as montmorillonite and kaolinite were dissolved, hydrated, and migrated after long-term water flooding, which resulted in the decrease of clay mineral content in fine sandstone and medium sandstone, the increase of pore throat radius, and the decrease of displacement pressure, median pressure, and separation coefficient. The saturation of the isotonic point of the oil-water relative permeability curve was obviously shifted to the right, the hydrophilicity was significantly enhanced, and the porosity and permeability were effectively improved, but there was a blockage of the throat less than 2 μm in the fine sandstone. In addition, this paper established the equations of water injection, permeability, irreducible water saturation, residual oil saturation, and oil-water relative permeability curve coefficient and establishes the initial permeability model with the well data before water flooding. The logging interpretation results of development wells in the process of water flooding as verification data were used, and the relative error of permeability far lower than the general requirement of permeability error within an order of magnitude was less than 30%, which verified the rationality of the method. [ABSTRACT FROM AUTHOR]

Due to their chemical and physical properties, rare earth elements (REEs) are essential in modern applications such as energy conversion or IT technology. The increasing demand for these elements leads to strong incentives for REE recovery and induces the exploration of new, alternative sources for REEs. Accessing REEs from clay minerals, in our case kaolinite, by an elution process is a promising method. The present study investigates the potential application of REE recovery through elution with different mineral acids (HNO3, H2SO4, and HCl) in a microwave process. The material used in this study—residues from an industrial kaolin production process—contained 2.47 g/kg REEs which is a significant amount for REE recovery. The ability of various mineral acids to solubilize metals was studied to assess the REE content of this residual resource. Around 1.87 g/kg of REEs was eluted from industrial kaolinite residues in hydrochloric acid, 1.71 g/kg in sulfuric acid, and 1.13 g/kg in nitric acid. [ABSTRACT FROM AUTHOR]

This paper conducts triaxial undrained tests on flocculated and dispersed kaolin samples at strain rate range 0.005–1%/min to investigate the effects of structure and strain rate on shear strength. The test results show that the flocculated samples exhibit strain hardening behaviour, while the dispersed samples show strain softening behaviour. The strain rate sensitivity parameter reflects the degree to which shear strength increases with increasing strain rate. The structure affects the strain rate sensitivity parameter, with values of 4.79% and 2.31% for flocculated and dispersed samples, respectively. When the strain rate is 1%/min, due to the low permeability of the dispersed sample, the high strain rate causes a rapid increase in local pore pressure, while the postponed dissipation of excess pore pressure destroys the sample. When studying the influence of clay structure, it is important to use the same strain rate; otherwise, the differences in shear strength may be underestimated. [ABSTRACT FROM AUTHOR]

Copyright of Iraqi Journal of Chemical & Petroleum Engineering is the property of Republic of Iraq Ministry of Higher Education & Scientific Research (MOHESR) and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

This paper presents new data on scour around a vertical pier in cohesive soils. It specifically focuses on the temporal evolution of local scour hole around the pier with increasing the clay/silt ratio content. Series of flume tests were performed using soil mixtures made with 85% fine sand and 15% fines. The fines fraction used in the soil mixtures includes silt, kaolinite clay, and various combinations of both with different proportions. The water velocity during the tests was kept constant and slightly above the erosion critical velocity of the fine sand used in the mixtures. A 3D laser scanner was employed to continuously record the geometry of the scour hole. Results show that increasing the Kaolinite clay in the fine fraction reduces significantly the scour. The mixture with a range around 7.5–10% of kaolinite clay fines content provides the threshold composition for cohesive soil behaviour effect in scouring process, recognized through scour pattern change. As the clay content increases, notable reductions are observed in the dimensions of the scour hole. Furthermore, the temporal evolution of maximum scour depth measured in flume was in agreement with the results from SRICOS-EFA (Scour Rate in COhesive Soil - Erosion Function Apparatus) method. [ABSTRACT FROM AUTHOR]

Purpose: The study aims to assess the efficiency of nanocomposite to improve the properties of gap-filling materials for pottery artifacts. Design/methodology/approach: Five different pastes were used in the laboratory studies. The pastes consist mainly of pottery powder (grog), dental plaster, microballoons and an adhesive of Primal AC33, nano-silica and nano kaolinite in various concentrations. The prepared samples were subjected to accelerated heat and light aging. Besides, some investigations were used to evaluate the efficacy of the additive nanomaterials, such as TEM, digital and scanning electron microscopy microscopes. Contact angle, color change, shrinkage degree, physical properties and compressive strength tests were also conducted. Findings: The results indicated that using Nano-silica considerably improves the mechanical strength and decreases the shrinkage of gap-filling materials. According to the results, a mixture of grog, microballoons and Primal AC33/Nano-silica Nanocomposites is the optimal gap-filling paste for archaeological pottery. Moreover, this paste showed a higher contact angle (120°), lower color change (ΔE = 2.62), lower shrinkage (3.3%), lower water absorption (3.36%), lower porosity (5.05%) and higher compressive strength (5124 N/mm2). Originality/value: This paper attains to develop an economic polymer-nanocomposite that can be used with gap-filling materials for pottery artifacts. [ABSTRACT FROM AUTHOR]

Altered minerals introduced by water-rock reactions during geothermal energy recovery may play a role in the frictional properties of fault gouges, perhaps inducing earthquakes. Based on the geological conditions of potential geothermal reservoirs in northeastern Shenzhen, this paper considers the critical pore pressure (about 50 MPa) and critical effective normal stress (about 20 MPa), which may lead to reactivation of the Henggang-Luohu fault zone due to fluid injection into a potential geothermal reservoir at a buried depth of about 2.5 km with the temperature of 150 °C. Under such hydrothermal conditions (50 MPa fluid pressure and 150 °C), thermodynamic calculations suggest that the reaction of Yanshanian granular granite and water, at equilibrium, can produce silica, kaolinite, and chlorite at a mass ratio of 16:7:2. Here we report 19 direct shear experiments performed on simulated fault gouges consisting of the binary mixture of silica + granite, kaolinite + granite, and chlorite + granite, and the multivariate mixture of silica + kaolinite + chlorite + granite, to investigate the effects of altered minerals on frictional properties of simulated granite fault gouges. Velocity stepping experiments were conducted on the wet samples with 10% water content at an initial normal stress of 20 MPa under drained conditions at room temperature. On this basis and together with acoustic emission observation and microstructural analysis, we discussed the likely mechanism responsible for the observed behavior. The results show that, for the presence of a single altered mineral, silica has little effect on the friction coefficient, though it contributes to velocity weakening and even stick-slip events. Whereas, clay minerals can significantly decrease the friction coefficient, though they have a contribution to velocity strengthening. For the presence of a mixture of silica + kaolinite + chlorite, clay minerals play a dominant role in controlling frictional properties of the simulated fault gouges: altered minerals can also significantly decrease the friction coefficient and contribute to velocity strengthening. Development of R1 shear planes was observed using microstructural analysis for the simulated granite fault gouges consisting of 0% or 33% of the altered minerals, while the R1 shear plane cannot be observed anymore in the sample consisting of 67% of the altered minerals. The number of acoustic emission events decreases significantly when the content of the altered minerals is 33%~67%. This may indicate a transition in the deformation mechanism from brittle to semi-plastic. Our study suggests that if geothermal energy recovery is carried out in northeastern Shenzhen, the fluid injection pressure should be controlled to avoid the slip of the fault. [ABSTRACT FROM AUTHOR]

Copyright of Shedet is the property of Shedet and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Thermal recovery techniques for producing oil sands have substantial environmental impacts. Surfactants can efficiently improve thermal bitumen recovery and reduce the required amount of steam. Such a technique requires solid knowledge about the interaction mechanism between surfactants, bitumen, water, and rock at the nanoscale level. In particular, oil sands ores have extremely complex mineralogy as they contain many clay minerals (montmorillonite, illite, kaolinite). In this study, molecular dynamics simulation is carried out to elucidate the unclear mechanisms of clay minerals contributing to the bitumen recovery under a steameanionic surfactant co-injection process. We found that the clay content significantly influenced an oil detachment process from hydrophobic quartz surfaces. Results reveal that the presence of montmorillonite, illite, and the siloxane surface of kaolinite in nanopores can enhance the oil detachment process from the hydrophobic surfaces because surfactant molecules have a stronger tendency to interact with bitumen and quartz. Conversely, the gibbsite surfaces of kaolinite curb the oil detachment process. Through interaction energy analysis, the siloxane surfaces of kaolinite result in the most straightforward oil detachment process. In addition, we found that the clay type presented in nanopores affected the wettability of the quartz surfaces. The quartz surfaces associated with the gibbsite surfaces of kaolinite show the strongest hydrophilicity. By comparing previous experimental findings with the results of molecular dynamics (MD) simulations, we observed consistent wetting characteristics. This alignment serves to validate the reliability of the simulation outcomes. The outcome of this paper makes up for the lack of knowledge of a surfactant-assisted bitumen recovery process and provides insights for further in-situ bitumen production engineering designs. [ABSTRACT FROM AUTHOR]

In order to estimate the effective storage capacity of carbon dioxide in geological storage, it makes great significance to understand the seepage mechanism of flowing carbon dioxide fluid and its influence on the occurrence state in micropore. In this paper, the molecular simulation method was used to obtain the optimal configuration of kaolinite micropore and carbon dioxide molecules. The molecular dynamics method was used to simulate the flow characteristics of carbon dioxide fluid in kaolinite pores in differential depth of burial under constant pressure drop. The results show that the adsorption capacity of carbon dioxide fluid on the wall of kaolinite decreases with the increase of burial depth, the fluid density in the center of the micropore increases with the increase of burial depth, the diffusion capacity of the fluid changes significantly when the burial depth is greater than 2 km; when a constant differential pressure is applied, the flow of carbon dioxide fluid in the pore conforms to the classical poiseulle flow, the diffusion ability of the fluid increases with the increase of burial depth, nearly doubling, and the slip length also increases with the increase of burial depth; the flow behavior significantly reduces the total amount of carbon dioxide in kaolinite micropore, where the density of the first adsorption layer near the wall decreases by at least 20%, and its effect on fluid is greater than that caused by the increase of burial depth. Therefore, when estimating the effective storage capacity of carbon dioxide in geological storage, the influence of pressure drop and burial depth on the total reduction of geological sequestration should be considered at the same time. The purpose is to provide more detailed theoretical basis for carbon dioxide geological sequestration. [ABSTRACT FROM AUTHOR]

This paper demonstrates the latest developments in particle-scale modelling of a clay. It shows that by creating an initial sample of platelets featuring aggregated stacks, excellent macroscopic behaviour is achieved. This approach is justified by examining SEM images of clay slurries, and is consistent with the behaviour of real clays. The use of aggregated stacks allows a wider range of platelet interactions and micro properties to be simulated and investigated, and significantly, enables interactions to be modelled that are based on a range of real measurements obtained from surface force experiments. [ABSTRACT FROM AUTHOR]

Recently, nanoclays have gained amount of attention as being the potential nanomaterials in the wound healing field. Due to having a high specific area, high adsorption of several therapeutic agents, good chemical inertness, and low cost, these nanomaterials are more interested in using. In this paper, we thoroughly introduced common types of nanoclays such as halloysite, kaolinite, montmorillonite, and bentonite. Interesting physical and chemical characteristics of these nanoclays are described. Further, the methods through which nanoclays are processed to form hydrogels are described. These included methods are not limited to in situ free radical polymerization, supramolecular assembly, freeze-thawing, and grafting. Finally, in this paper clay-based hydrogels and their unique properties such as antimicrobial properties and their application in wound healing are thoroughly discussed. [ABSTRACT FROM AUTHOR]

This paper aims to investigate the tragacanth gum potential as a natural polymer combined with natural clay mineral (montmorillonite, kaolinite, and illite) nanoparticles (NPs) to form NPepolymer suspension for enhanced oil recovery (EOR) in carbonate reservoirs. Thermal gravimetric analysis (TGA) tests were conducted initially in order to evaluate the properties of tragacanth gum. Subsequently, scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX) tests were used to detect the structure of clay particles. In various scenarios, the effects of natural NPs and polymer on the wettability alteration, interfacial tension (IFT) reduction, viscosity improvement, and oil recovery were investigated through contact angle system, ring method, AntonPaar viscometer, and core flooding tests, respectively. The entire experiment was conducted at 25, 50, and 75 °C, respectively. According to the experimental results, the clay minerals alone did not have a significant effect on viscosity, but the addition of minerals to the polymer solution leads to the viscosity enhancement remarkably, resulting mobility ratio improvement. Among clay NPs, the combination of natural polymer and kaolinite results in increased viscosity at all temperatures. Considerable wettability alteration was also observed in the case of natural polymer and illite NPs. Illite in combination with natural polymer showed an ability in reducing IFT. Finally, the results of displacement experiments revealed that the combination of natural polymer and kaolinite could be the best option for EOR due to its substantial ability to improve the recovery factor. [ABSTRACT FROM AUTHOR]

Mineral mapping from satellite images provides valuable insights into subsurface mineral alteration for geothermal exploration. In previous studies, eight fundamental algorithms were used for mineral mapping utilizing USGS spectra, a collection of reflectance spectra containing samples of minerals, rocks, and soils created by the USGS. We used an ASD FieldSpec 4 Hi-RES NG portable spectrometer to collect spectra for analyzing ASTER images of the Coso Geothermal Field. Then, we established the ground-truth information and the spectral library by analyzing 97 samples. Samples collected from the field were analyzed using the CSIRO TSG (The Spectral Geologist of the Commonwealth Scientific and Industrial Research Organization). Based on the mineralogy study, multiple high-purity spectra of geothermal alteration minerals were selected from collected data, including alunite, chalcedony, hematite, kaolinite, and opal. Eight mineral spectral target detection algorithms were applied to the preprocessed satellite data with a proposed local spectral library. We measured the highest overall accuracy of 87% for alunite, 95% for opal, 83% for chalcedony, 60% for hematite, and 96% for kaolinite out of these eight algorithms. Three, four, five, and eight algorithms were fused to extract mineral alteration with the obtained target detection results. The results prove that the fusion of algorithms gives better results than using individual ones. In conclusion, this paper discusses the significance of evaluating different mapping algorithms. It proposes a robust fusion approach to extract mineral maps as an indicator for geothermal exploration. [ABSTRACT FROM AUTHOR]

This paper presents the results of a systematic investigation of the natural radioactivity in rock samples of Davanagere locality, Karnataka, India. The radioactivity in rocks was measured using the NaI(TI) gamma-ray spectrometer. An effort was made to identify the minerals present in rock samples by FTIR spectroscopy. The activity of 232Th, 226Ra and 40K radionuclides in rocks vary from 27.96 ± 1.00 to 103.85 ± 1.90, 50.89 ± 1.98 to 135.28 ± 3.15 and 512.46 ± 4.86 to 974.31 ± 7.05 Bq kg−1with a mean value of 59.79 ± 1.45, 85.79 ± 2.54 and 787.03 ± 6.19 Bq kg−1, respectively. Radiological hazard parameters such as radium equivalent activity, external and internal hazard indices absorbed dose rate, ELCR for indoor exposure and annual effective doses for different body organs were estimated. The activity of natural radionuclides were found to be high compared to the national and world average values. However, the hazard indices were found to be within the recommended limits. The Quartz, Calcite and Kaolinite extinction coefficients in rocks ranged from 87.37 to 121.73, 31.43 to 119.14, and 33.10 to 63.97, respectively. The radionuclide activity concentration was found to depend on the kaolinite and calcite minerals. [ABSTRACT FROM AUTHOR]

Clay is widely applied in landfill projects because of its low permeability. However, it is often ignored that clay exhibits the characteristic of threshold gradient i0, and i0 can exert a certain impact on the service life of landfill barriers. To this end, this paper first conducted permeability tests on seven clays to study the permeation law of these clays and found that the higher the montmorillonite and illite content in compacted clay, the higher i0 was, and the higher the kaolinite and sand content, the lower i0 was. By summarizing previous studies and this paper, a suitable power function relationship between i0 and the intrinsic permeability not only applies to the clays but also to the mixed soils (Kao-H and Clay-J, Kao-H and Bent-H, and Clay-J and Sand-F). Furthermore, based on the experimental conditions, considering that compacted clay is subject to i0, numerical analysis of the liner service life was conducted for single-layer and composite liners using three types of pollutants (Cd, COD and DDT) under leachate heads of 0.3 and 20 m. Under a leachate head of 0.3 m, the single-layer compacted clay barrier was only penetrated by COD at i0 = 0. In the other cases, both the single-layer compacted clay liner and composite liner could satisfy a service life of 100 years. Under a leachate head of 20 m, the service life of the barrier gradually increased with increasing i0. For both forms, i.e., single-layer and composite liners, the barrier breakdown indicator pollutant was COD when considering the non-Darcy seepage effect. [ABSTRACT FROM AUTHOR]

In the present work, the effects of various filler types and content on the characteristics and properties of styrene-butadiene rubber (SBR) were studied. This study prepared SBR filled with different fillers: kaolin, metakaolinite, synthetic zeolite Na-A, alumina (Al2O3) nanoparticles, and hybrid filler (synthetic zeolite Na-A/Al2O3). The silane coupling agent 3-aminopropyltriethoxysilane (APTES) was employed to treat the surface with fillers. Scanning electron microscope (SEM) and X-ray diffraction (XRD) were used to determine the surface morphology. The results demonstrated that fillers improved the physicomechanical properties. Tensile strength and elongation at break (%) in composites containing synthetic zeolite Na-A increased by up to 158.6% at 3 phr and 100% at 2 phr, respectively. The results showed that the surface properties displayed by SEM analysis indicated a good distribution of filler particles. Also, the rubber compound's resistance to organic solvents such as toluene was improved, as evidenced by swelling properties; the swelling ratio decreased by 17.5% while the crosslink density increased by 42.6% at 5 phr Al2O3/synthetic zeolite Na-A. The constants of the various hyperelastic models that explain the behavior of the composite materials under study were determined, and their predictions of the experimentally obtained stress-strain curves were compared. The study's experimental findings will be helpful for several industrial uses, including an extender in water-based paints, rubber fillers, ceramic materials, paper fillers, and coating pigments. [ABSTRACT FROM AUTHOR]

Retention of the pristine hydrogen isotope composition (expressed as δD) formed during mineral formation in equilibrium with water is the basis for any paleoenvironmental reconstructions and for tracing mineral reactions using hydrogen (or H and O) isotope composition in kaolinite. Not only do post-formation reactions cause partial equilibration with ambient water, altering the pristine signature, but also result in the decoupling of H and O diffusion. In this study, kaolinite samples of different structural order (expressed, for example, as the Hinckley Index) were tested for their susceptibility to H isotope exchange under D 2 O vapor in an open system. The H isotope exchange was detected by recording the kaolinite's structural OH and OD stretching mode using infrared spectroscopy. A number of different in-situ and ex-situ testing protocols under diverse temperature ranges (90 °C, 125–275 °C, 300–700 °C), show consistent kinetics and mechanism. In each kaolinite sample, the H isotope exchange rate increases with temperature; however, the major control on the reaction rate is the kaolinite crystallite's structural order, not the particle (agglomerated crystallites) size. The hydrogen isotope composition in kaolinite can be altered independently of oxygen atoms, likely via proton hopping mechanism through structural defects. The H isotope exchange reaction under vapour shows a two-mode kinetics: the time-to-the-quarter (TTTQ; t1/4) dependence dominates in the first part of the reaction or in low-temperature reactions, transitioning to the log 10 t (Elovich) relationship and with lower activation energy, in advanced stages and in higher temperatures. Extrapolating the TTTQ model to temperatures < 90 °C allows estimating the rate of H isotope exchange between water vapor and kaolinite. The paper presents the prediction of preservation of pristine δD signature and thus reliability of using isotope data in kaolinites of different origins and structural order when exposed to pore water / water vapor over geological timescales. [ABSTRACT FROM AUTHOR]

To unravel the permeability variation mechanism of weakly cemented rocks (WCR), the paper conducted triaxial permeability tests on weakly cemented sandstones (WCS) collected from the Jurassic formation in northwest China. The paper identified the correlation of WCS permeability versus porosity, cementation structure, and mineral composition, further developing a model to characterize the WCS stress–damage–permeability relationship. The research indicated that the WCS permeability was initially high due to the naturally high porosity, large pore diameter, and loose particle cementation, thus favoring a significant decline as pore convergence in the compaction stage. In the residual stage, kaolinite and montmorillonite minerals disintegrated into water and narrowed fractures, causing a slight permeability increase from the initial to the maximum and residual stages. The WCS matrix fracturing was phenomenologically accompanied by clay mineral disintegration. By assuming that the matrix can be compressed, jointed, and fractured, the paper defined a damage variable D and accordingly developed a stress–damage–permeability relationship model that incorporated matrix compression, jointing, and fracturing. The model can describe the WCS permeability regime regarding the high initial permeability and slight difference of the maximum and residual permeabilities versus the initial. [ABSTRACT FROM AUTHOR]

Calcined clays are the most promising future supplementary cementitious material which are capable of replacing fly ashes and blast furnace slag on the long run due to their potential to achieve high cement replacement levels and their global availability. In the last decade most research has focused on calcined clays rich in the 1:1 kaolinite. Clay with less than 20 to 25 % kaolinite were seen as worthless. Even the content of 2:1 phyllosilicates in the kaolinitic clays was neglected and not even mentioned although especially these clays are dominant in areas like central and northern Europe. Here, highly kaolinitic clays are rare or used by other industries leading to high prices. This paper is based on published works and highlights whether information obtained for calcined 1:1 dominated clays can be applied for calcined 2:1 dominated clays or not and where further research is needed. [ABSTRACT FROM AUTHOR]

Metakaolin (MK) is one of the most sustainable cementitious construction materials, which is derived through a direct heating procedure known as calcination. Calcination process takes place substantially lower temperatures than that required for Portland cement, making it a more environmentally sustainable alternative to traditional cement. This procedure causes the removal of hydroxyl water from the naturally occurring kaolin clay (Al2Si2O5(OH)4 with MK (Al2O3·2SiO2) as its product. Kaolin naturally exists in large amount within 5°29′N–5°35′N and 7°21′E–7°3′E geographical coordinates surrounding Umuoke, Obowo, Nigeria. Alumina and silica are the predominant compounds in MK, which provide it with the pozzolanic ability, known as the 3-chemical pozzolanic potential (3CPP), with high potential as a cementitious material in concrete production and soil stabilization. Over the years, researchers have suggested the best temperature at which MK is derived to have the highest pozzolanic ability. Prominent among these temperature suggestions were 800 °C (3CPP of 94.45%) and 750 °C (3CPP of 94.76%) for 2 h and 5 h' calcination periods, respectively. In this research paper, 11 different specimens of Kaolin clay obtained from Umuoke, Nigeria, were subjected to a calcination process at oven temperatures from 350 to 850 °C in an increment of 50 °C for 1 h each to derive 11 samples of MK. The MK samples and Kaolin were further subjected to X-ray fluorescence), scanning electron microscopy (SEM) and X-ray diffraction (XRD) Brunauer–Emmett–Teller (BET) tests to determine the microstructural behaviour and the pozzolanic properties via the 3CPP as to exploit the best MK with the highest cementing potential as a construction material. The results show that the MK heated at 550 °C and 800 °C produced the highest pozzolanic potentials of 96.26% and 96.28%, respectively. The enhancement in pozzolanic potential at optimum calcination temperature is attributed to an increase in the specific surface area upon calcination of kaolinite confirmed by BET results. The SEM and XRD results further supported the above result with the strengthened crystal structure of the MK at these preferred temperatures. Generally, 550 °C is more preferred due to the less heat energy needed for its formulation during 1 h of calcination, which outperforms the previous results, that suggested 750 °C and 800 °C in addition to longer hours of heat exposure. [ABSTRACT FROM AUTHOR]

Soil improvement in the most sustainable way is the need of the hour and prime importance for the modern construction industry. Most of the time, it has been observed that the soil below the foundation is not mechanically capable of withstanding the load from the structure, and it might cause the failure/collapse of the structure. To prevent it, various significant soil improvement techniques have been introduced, such as mechanical stabilisation, thermal methods, use of admixtures etc. Ground improvement using admixtures involves the addition of various chemical alternatives to the subsoil to enhance its loadbearing capacity. These procedures also give long-term sustainability regarding the soil's bearing capacity. Various potential scholarly works on ground improvement have been done, i.e., the addition of bentonite, kaolinite, bitumen, rice husk ash, pond ash, lime, and cement into the soil, which has been intensely reviewed. From the combined observed experimental results of several researchers presented in this paper, it can be identified how much improvement of a particular soil property can be made by adding several types of admixtures. A clear idea can be generated as to which type of admixture is most suitable for the improvement of a particular type of soil and which soil properties can be improved by the addition of that admixture. [ABSTRACT FROM AUTHOR]

Talc as a hydrated magnesium silicate is the softest, pearly luster, heat-resistant mineral, which belongs to the clay group of phyllosilicates, with the chemical formula Mg3Si4O10(OH)2. Muslim scholars knew four different kinds of minerals as Talc, whose descriptions might correspond to micas’ phyllosilicates namely Muscovite and Kaolinite, calcium sulfate or Gypsum, and inosilicate Asbestos as well. Some metamorphic Talc-rich schists, such as steatite or soapstone have been also called Talc in Muslim mineralogist alTifashis’ treatise. The goal of this paper is to estimate the above-mentioned minerals from both historical and mineralogical views carefully and to determine how and why these minerals and stones have been confused with talc by some prominent Muslim scholars, looking back to ancient Greek and Latin texts. [ABSTRACT FROM AUTHOR]

The reaction process, mechanism, and kinetics of the decarbonation of coal-series kaolinite (CSK) were investigated using the thermal analysis (TG)–infrared spectrum analysis (IR) coupling method. A pilot test was performed using a suspended calcination system. Further, the carbon content, phase composition, whiteness, oil-absorbed value, and micromorphology of calcined kaolin were characterized. Results showed that the decarburization reaction of CSK was a two-step reaction that mainly occurred in the ranges of 593 °C–836 °C. The mechanism of the decarburization reaction was a phase-boundary reaction (unreacted-core shrinking model) with an activation energy of 214.56 kJ/mol. Calcination at 900 °C or 950 °C for ~3.3 s in a suspension reactor resulted in the decarburization rate of CSK becoming >99.9%. The whiteness of calcined kaolin was mainly positively associated with the decarburization rate, and increasing the calcination temperature aided in increasing the whiteness. The oil-absorbed value of calcined kaolin was positively correlated with the specific surface area. Insufficient or over-calcination decreased the oil-absorbed value of calcined kaolin products. The calcined kaolin product with a whiteness of 89.3% and an oil-absorbed value of 76.1 g/100 g was obtained via suspension calcination process, which meets the requirements of calcined kaolin for paper-making. [ABSTRACT FROM AUTHOR]

This paper presents the results of a selective flocculation/magnetic separation study performed with a sample of iron ore slime from the desliming stage of the industrial flotation circuit of a mine in the southern region in the Quadrilátero Ferrífero-Brazil that was discarded in a tailings dam. Zeta potential measurements of pure minerals previously identified in the sample (goethite = 52.4%, hematite = 26.2%, quartz = 12.3%, kaolinite = 8.2%, and others = 0. 9%) were evaluated to assess the influence of the reagents used (sodium hexametaphosphate – SHMP (dispersant)) and flocculants (corn starch, nonionic polyacrylamide – P2500 and cationic polyacrylamide – P806)) on their surface properties and consequently on the stability of suspensions of the slime and of the pure minerals individually, aiming to establish conditions for selective separation between Fe-bearing minerals (goethite and hematite) and gangue minerals (quartz and kaolinite) in the subsequent magnetic separation step. At pH 10 and a 25 mg/L dosage of SHMP, a higher Fe recovery was verified with starch (2000 g/t) in relation to nonionic and cationic polyacrylamides, and similar Fe contents in all dosages tested of the flocculants. [ABSTRACT FROM AUTHOR]

The paper reports a detailed coal-petrographic and mineralogical–geochemical study of humic coals and coaly rocks in the Upper Devonian Sargaevo deposits in North Timan (Sula River), which are an example of the burial of the oldest coal-forming plants. The following types of organic rocks are identified in the section: "jet-like" coal, liptobiolitic silty–argillaceous coal, and silty–argillaceous–coaly mixtolites. The studied coals and coaly rocks are mainly composed of humic organic components represented by vitrinite and liptinite macerals, with subordinate inertinite group. The vitrinite macerals include gelinite, collotelinite, and telinite (xylenite); the liptinite macerals include sporinite, cutinite, liptodetrinite, bituminite, alginite, and resinite, and the inertinite macerals include inertodetrinite, semifusinite, fusinite, and funginite. The vitrinite reflectance (RV, %) 0.45–0.55% corresponds to the insignificant organic maturity from proto- to meso-catagenesis (rank PC3–MС1). The mineral component of mixtolites and high-ash coals consists of kaolinite, chlorite/smectite (with a predominance of the chlorite component), and quartz. [ABSTRACT FROM AUTHOR]

The WMI (weak muddy intercalation) is a typical weak structural surface in the red-bedded rock mass; ensuring slope stability by increasing the strength of the WMIs helps reduce project costs and carbon emissions. With the advantages of energy saving, high efficiency, and green, microwave technology has attracted scholars' attention to geotechnical material property improvement. However, the mineral composition of the WMIs is complex and variable, and the applicability of microwave technology needs further evaluation. In this paper, the effects of microwave temperature and clay mineral types and content on the physical and mechanical properties of the WMIs were evaluated. The results show that microwave heating can substantially improve the uniaxial compressive strength of the WMIs, regardless of the types and content of clay minerals. Dehydration, dehydroxylation of clay minerals, and local melting of albite occurring in the specimens under microwave heating enhanced the strength of the soil particles and the interparticle joints. The strength increase ratios of the WMI specimens increased with the temperature increase. With the increase in clay mineral content, the strength increase ratio of kaolinite WMIs and illite WMIs decreased, while the strength increase ratios of montmorillonite WMIs increased. The present multiple regression analysis methods are used to establish the strength prediction models of the WMI microwave-reinforced specimens, which can guide the engineering application. [ABSTRACT FROM AUTHOR]

Ground improvement by the construction of stone columns has been widely adopted. This paper presents the results of an experimental study on ordinary and encased stone columns, made of different mix proportions of stone aggregates and shredded tyre chips, subjected to sustained loading, i.e., simulating long-term drained loading conditions. The load was applied in increments and each load increment was applied once the settlement became constant after considerable time under the previous load increment. Results showed a pronounced increase in ultimate load-carrying capacity of such columns as compared to that of pure clay bed, even when the columns were partially made of shredded tyre chips, with remarkable enhancement evident in encased columns. Comparative analysis revealed that these columns under sustained loading performed better than those under quick loading. The surcharge effect with drainage of pore water was evident under sustained loading. 'Efficiency' factor of columns was evaluated to examine the enhancement of load-carrying capacities of such columns with respect to conventional columns and to arrive at optimum/feasible mix proportions composing the columns. A study of the 'efficiency' factor showed replacement of about 50% of stone aggregates with shredded tyre chips is possible in encased columns under sustained loading for all encasing materials tested. However, considering the corrosion of galvanized wire mesh over time, geosynthetics was found to be the efficient encasement material. [ABSTRACT FROM AUTHOR]

In this paper, novel humidity sensors based on montmorillonite, kaolinite, and composite films coated on micro-cantilevers were prepared to measure the relative humidity (RH) values by the deflection of a micro-cantilever (MC) at room temperature. The humidity-sensing properties, such as response and recovery, sensitivity, repeatability, humidity hysteresis, and long-term stability, were investigated in the range of working humidity (10–80% RH). The humidity response in the close humidity range of 10% RH to 80% RH revealed a linear increase in water absorption of montmorillonite, kaolinite, and montmorillonite/kaolinite mixed dispersant (1:1) as a function of RH with linear correlation factors between the humidity change and deflection estimated to be 0.994, 0.991, and 0.946, respectively. Montmorillonite's sensitivity was better than kaolinite's, with the mixed-clay mineral film's response falling somewhere in between. This research provides a feasible and effective approach to constructing high-performance MC humidity sensors that can be operated at room temperature based on clay minerals. [ABSTRACT FROM AUTHOR]

The review presents the results of modeling of the solvation of nanoparticles with deep eutectic solvents that act as stabilizers of metal nanoparticles, which provide a new platform for nanoparticle technology. It is calculated that there is a slower dynamics of solvent molecules, i.e., a slowing down of water near solutes. Such water has limited movement and cannot be organized into tetrahedral forms, in contrast to water in volume. Also, the paper describes systematic studies of the adsorption configuration, distribution density and adsorption energy of molecules H$_{2}$O, CO$_{2}$, CH$_{4}$, N$_{2}$, C$_{8}$H$_{18}$ and fluorocarbons C$_{3}$F$_{8}$ and C$_{5}$F$_{12}$ on the surface of kaolinite (0 0 1). Water adsorption is initiated and occurs due to the growth of clusters around surface groups, which is mainly regulated by the interactions of hydrogen bonds. Further, the paper investigates theoretically physical and mechanical properties of nanoscale systems, in particular, nanotips, amorphous carbon monolayer and nanoparticles. It is shown that the single-layer amorphous carbon is surprisingly stable and is deformed with a high ultimate strength without the propagation of cracks from the point of failure. The sliding on amorphous polyethylene and silicon studied using the method of molecular dynamics is described. The paper also discusses the dependencies of the friction force, acting on nanoparticles, on their velocity and sizes, in particular, the contact area, the structure and the type of the material, as well as on the direction of their shear and temperature. At an angle of rotation $ 45^\circ $, the silicon friction forces reach a minimum value, which can be termed superlubricity. The molecular dynamics modeling of the surface of carbon nanotubes, chitosan, polyvinyl acetate, titanium dioxide, $α$-quartz and zeolite is described to solve application problems ranging from reaction control to targeted delivery and creation of new drugs. The general principles have been identified that artificial water channels made of carbon nanotubes porins must satisfy, which can serve as a basis for further experiments. The organic modification mainly forms a modifier layer by crosslinking the hydrogen bond with the substrate, the flatness of the modified layer is strongly influenced by the type and concentration of the modifier. [ABSTRACT FROM AUTHOR]

Kaolin appears as odorless white to yellowish or grayish powder. Contains mainly the clay mineral kaolinite (Al2O3(SiO2)2(H2O)2), a hydrous aluminosilicate. It is used in the manufacture of china and porcelain and is also widely used in the production of paper, rubber, paint, drying agents, and many other products. It has a role as an excipient and an antidiarrhoeal drug and as an absorbent and filler including in some pesticide formulations. In this study, kaolin was tested under in vitro conditions against Monilia frucidena and Alternaria solani. The conducted tests have shown that it can be а potentially preventive fungicide against these plant pathogens. The substance was able to achieve full blocking of the germination of conidiophores and а growth of mycelium of Monilia frictigena at 0.1 % (m/v) concentration and at 0.3-0.5 % (m/v) towards conidiophores and mycelium of Alternaria solani. [ABSTRACT FROM AUTHOR]

With the great breakthrough in natural gas exploration of Paleozoic Taiyuan formation in Longdong exploratory area in the southwestern part of Ordos Basin, it is urgent to solve the petrological nomenclature of sedimentary bauxite, so as to further study the pore formation mechanism, distribution law, and controlling factors of bauxite reservoirs. In this paper, X-ray diffraction, polarizing microscope, scanning electron microscope, and other methods are used to analyze the mineral composition and structure of bauxite rocks in the study area and give appropriate names. The results show that the sedimentary sequence of bauxite in the study area can be divided into five sections: A, B, C, D, and E. The main mineral components are diaspore (C section content can be more than 90%), illite, kaolinite, and chlorite; accessory mineral include anatase and pyrite; trace components include quartz, feldspar, rutile, hematite, and rock salt; and some of the pores are filled with calcite, siderite, and (iron) dolomite. The rock structure is mainly bedding and massive structure, and some of them have geopetal structure. The texture mainly consists of granular texture, grain (powder crystal) texture, gel texture, and algal bonding texture. Considering the special lithology of section A~C and the lack of existing nomenclature method, based on mineral composition and sedimentary fabric, a triangulation classification nomenclature method is established, which adopts structure+texture as secondary name and the main mineral components diaspore-mud-pyrite of the three end-member mineral components as primary name. It can not only highlight the mineral assemblage characteristics of sedimentary sequence of bauxite but also reflect the lithologic characteristics of reservoir development section and the influencing factors of reservoir formation, effectively reflecting the petrological characteristics of bauxite reservoir. Among them, the diaspore rocks with granular, bean-oolitic, and grain texture are the main lithologies forming the natural gas reservoir space of Taiyuan formation in Longdong area. The naming method is feasible and reliable for sedimentary bauxite rocks, which lays a good foundation for the study of natural gas reservoir, pore formation mechanism, and distribution law in Longdong area, southwest of the basin. [ABSTRACT FROM AUTHOR]

Soil is the main aggregation site of polycyclic aromatic hydrocarbons and an important pathway of migration to other media. In this paper, the adsorption behavior of pyrene and seven different types of surfactants on kaolinite surfaces was studied by molecular dynamics simulation and desorption testing. The molecular dynamics simulation results showed that pyrene was more easily adsorbed on the 001 (-) side of kaolinite. SDBS, SDS, TW80, and TX-100 had strong interactions with pyrene, encapsulating pyrene molecules in aggregates. However, when the concentration of surfactant was too high, the desorption of pyrene molecules on a kaolinite surface will be inhibited. The desorption of pyrene molecules will be inhibited in the presence of BS-12, TW80, and TX-100, while the desorption process can be promoted by using CTAC, DDBAC, SDBS, and SDS as soil remediation agents. The removal rate of pyrene gradually increased with the increase of SDS dosage, while for SDBS, the removal rate showed a trend of first increasing and then decreasing. When the concentration of SDS was 0.014 mol/L, the elution rate of pyrene reached 72.86%. The molecular dynamics simulation results were similar to the desorption test results, verifying the reliability of molecular dynamics simulation. The research results provide theoretical support for the selection of surfactants in the remediation process of pyrene-contaminated soil. [ABSTRACT FROM AUTHOR]

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The paper presents the results of a study of the properties of Poletaevsky kaolin with the aim of using it in the ceramic industry. Based on the results of determining the chemical, mineral and granulometric composition. The mineral composition of Poletaevsky kaolin is kaolinite 80–85 wt %, muscovite and illite 10–15 wt %, quartz up to 10–15 wt %. It has been established that the Hinckley index for Poletaevsky kaolin is 0.68, compared to 1.38 for Glukhovetsky one. The ratio of highly ordered kaolinite to low ordered kaolinite for Poletaevsky kaolin is 22 : 78, for Glukhovetsky kaolin the ratio of highly ordered kaolinite to low-ordered kaolinite is 57 : 43. It was established that Poletaevsky kaolin can be used in the production of ceramic materials by plastic or semi-dry molding. The determined low content of high-ordered kaolinite and the insignificant content of particles less than 2 μm according to the results of laser diffraction analysis can lead to the production of an unstable slip. When firing samples of Poletaevsky kaolin, a minimum water absorption of 5.5 % was achieved at a firing temperature of 1450 °C. In this case, the resulting maximum apparent density was 2.17 g/cm3, the maximum mullite content was 38 %, and the maximum compressive strength was 32 MPa. [Display omitted] [ABSTRACT FROM AUTHOR]

Context: Based on the first-principles calculations, this paper investigates the structural, elastic, electronic, and optical properties of albite and kaolinite, respectively. It is determined that both of them show structural stability, mechanical stability, and brittleness by calculating formation enthalpy, phonon dispersion, elastic, and mechanically relevant properties. Both materials are insulators with an indirect bandgap. By calculating the TDOS and PDOS, the main characteristics of the electronic structure of NaAlSi3O8 come from O-2p and Si-3p states, O-2p, and Al-3p states hybridization, similar to Al4[Si4O10](OH)8. The covalence of Si–O bonds in NaAlSi3O8 is greater than Al–O bonds, and the covalent property sequence of Si–O bands in NaAlSi3O8 is Si2-O3 > Si1-O4 > Si2-O2 > Si1-O8 > Si1-O6 > Si3-O2 > Si3-O4. The optical anisotropy of NaAlSi3O8 and Al4[Si4O10](OH)8 is analyzed. Methods: First-principles density functional theory (DFT) calculation was carried out by the CASTEP computer program. The GGA-PW91 exchange–correlation was used. The energy convergence tolerance, the maximum force, and the maximum displacement were set in the calculation. [ABSTRACT FROM AUTHOR]

The transformation of kaolinite into metakaolinite by thermal activation to obtain highly active aluminosilicate is commonly known. In addition to kaolin, the high content of kaolinite in coal mining waste is another potential source for obtaining an aluminosilicate precursor, thereby protecting the environment and adding value to industrial wastes. In this paper, the kaolinite-based high ash slime (KAS) was calcined at temperatures ranging from 400 °C to 1000 °C under air, N2, and CO2 atmospheres, respectively. The thermal behaviors and structural evolution of each component in KAS were analyzed by thermal analysis (TG-DSC), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). Moreover, the chemical reactivity of Al2O3 and SiO2 in calcined KAS was evaluated by HCl and NaOH leaching methods. The results show that the applied KAS in this study primarily consisted of kaolinite and carbon, while the minor mineral phases included quartz, calcite, and pyrite. Additionally, the structural transformation of kaolinite during calcination included dehydroxylation, sintering, and the formation of mullite. Crystalline kaolinite completely decomposed into semicrystalline metakaolinite at 600–800 °C, accounting for the increase in chemical reactivity. The interlayer sintering of metakaolinite and the recrystallization of amorphous components led to the decrease in chemical reactivity after 800 °C. Furthermore, the thermal behaviors of carbon in KAS are greatly affected by the calcination atmosphere. The presence of carbon reduced the chemical reactivity of calcined KAS. [ABSTRACT FROM AUTHOR]

The molecular structure of cationic surfactants is closely related to their flotation performance. In this paper, three cationic surfactants with different head group structures were selected as collectors of kaolinite, and the substituent effects were studied by the DFT method. The DFT calculation results showed that increasing the number of substituents in the dodecylamine head group can significantly increase its surface and head group charge. Dodecylamine has the lowest LUMO orbital energy, so dodecylamine has the strongest electron attraction ability and the strongest interaction with kaolinite. Electron density differential showed that there was an area of electron aggregation between the collector and the surface of the kaolinite. The interaction energy of DDA on kaolinite surfaces was greater than that of the other two collectors, indicating that the adsorption of DDA on the surface of kaolinite was more stable. Flotation results showed that higher a kaolinite yield was obtained in the presence of dodecyl dihydroxyethyl methyl ammonium chloride. The calculated results of the solvent-accessible surfaces, the head group charge, and the number of bonds between the collector and the kaolinite show good consistency with the actual flotation results of the three collectors, which can be used as a screening index for kaolinite flotation collectors. [ABSTRACT FROM AUTHOR]

The hardfill embankments are composed of cemented sand-gravel (CSG) mixtures. In some cases, however, sand and gravel used in the mixture contain fine-grained fraction. This paper aimed to study the mechanical behavior and microstructure of CSG mixtures in which the base soil contains fine-grained particles with different plasticity specifications. Various contents of kaolinite and bentonite were added to a sand-cement mixture with different cement contents and uniaxial strength and deformation modulus in the mixtures were measured at two curing ages. According to the results, in low cement mixtures, the mixture containing 10% of the additive exhibited the maximum strength and deformation modulus, regardless of the additive type. In a family of bentonite-containing mixtures with higher cement, the strength of mixtures decreased with increasing the bentonite content. However, the mixture with higher cement and 10% of kaolinite presented the best performance from in terms of strength and stiffness. Analyzing the mineralogy and SEM images of mixtures showed that the structure of base soil attained the best packing and a strong matrix was devolved inside the mixture with 10% of fine additive. Furthermore, the kaolinite particles in the mixture containing 10% kaolinite contributed to the hydration process of cement. [ABSTRACT FROM AUTHOR]

This paper describes the fabrication of kaolinite (Al2O3-2SiO2-2H2O) spherical bulbs by slip casting. The bisque-fired parts present a porosity of about 30% with submicron porosity confirmed by scanning electron microscopy. In addition, plate-like grains with channels were observed. After nickel infiltration of the specimens, nanosized Ni particles covered the surfaces of the channels of these grains. Permeation tests in 5% H2 at 400 and 600 °C resulted in fluxes between 0.05 and 0.06 mol·m−2·s−1 at a pressure gradient of 200 MPa·m−1. Potential applications of these specimens include supports for hydrocarbon (namely ethanol) steam reforming. [ABSTRACT FROM AUTHOR]

The thermal safety problem of lithium-ion batteries (LIB) in use requires an excellent thermal management system to preserve it. In the paper, an expansion flame-retardant composed of APP and CFA and kaolinite is used to enhance the flame-retardant property of phase change materials (PCM). The performances of PCM and their property in the thermal management of LIB were studied. The results indicate that the kaolinite can improve the long-term thermostability of PCM. The addition of flame retardant can make the flame-retardant property of PCM reach V0 level. The synergistic action of expansion flame-retardant and kaolinite can increase the residual carbon and enhance the thermal reliability of flame-retardant PCM (RPCM). The RPCM has an obvious cooling effect on the surface temperature of the battery. The RPCM can reduce the maximum temperature of the cell to 37.4 °C at 3 C, which is 12 °C lower than pure PA. The peak temperature of the battery pack at 3 C is also reduced to 50.28 °C by the flame-retardant PCM, and the temperature difference is kept within 5 °C. [ABSTRACT FROM AUTHOR]