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The study has as its original database the decarbonization process initiated in Mexico by the National Commission for the Efficient Use of Energy (CONUEE) as part of its "Savings Program of Electric Power in Buildings of the Federal Public Administration" (PAEIAPF) of 1999. The primary purpose of PAEIAPF was to reduce the levels of electric power consumption in Federal Government buildings. The program has operated for 20 years; however, its scope only reaches operational carbon. Since 90% of existing buildings will be in use by 2050, the Retrofit Models will be the base to determine solutions for a more resilient living environment that fortifies and extends the grid's capacity and meets climate change mitigation targets. Secondly, significant socioeconomic and profound environmental impacts are not calculated explicitly in existing tools and are often referred to as "secondary" or Non-Energy Benefits (NEB). "The goal is to give them a measurement value to be considered in the decision-making calculus. It is assumed that soon; such factors will enter the general climate change economy, not unlike carbon in the past decade." In this context, the proposed research aims to develop a value-based framework that will support a Building Stock Model and subsequent Retrofit Models, documented in a web-tool platform. The framework has three main steps: A) Building Stock Model: Mapping of selected buildings of the program PAEIAPF in a GIS system. Documentation of the baseline energy consumption and embodied CO2-eq of the existing building. B) Retrofit Models: Involving a Whole Life Cycle Assessment (WLCA) and Non-Energy Benefits (resilience coefficient, health, productivity). C) Web Tool Platform: Application and toolset that allows for consistent documentation, environmental impact evaluation of existing building stock, and solution design in identifying energy reduction concepts. [ABSTRACT FROM AUTHOR]

• Biogas upgrading is environmentally and energetically favourable over combustion. • Storage or utilisation of the captured CO 2 has larger savings than biogas upgrading. • Upgrading, CO 2 storage or utilisation perform well in all impact categories. • The energy system has a substantial impact on the environmental performance. • Methanation provides large climate change savings only in renewable energy systems. Biogas from anaerobic digestion is an important renewable energy source. Combining its utilisation with carbon capture and storage (CCS) or carbon capture and utilisation (CCU) may improve climate change performance. This study uses life cycle assessment to evaluate the environmental impacts of 17 biogas management technology configurations (TCs). The technologies include biogas combustion, upgrading to natural gas quality, CCS, direct utilisation of CO 2 and methanation. The focus is mainly on energy balances and climate change impacts, and the results are subjected to sensitivity-, uncertainty-, and energy system analysis. The TCs with CCS and CCU provide the largest climate change savings (-1400 to - 2100 kg CO 2 -eq/1000 Nm3 biogas). Specifically, the methanation TCs provide the highest savings, but they also depend strongly on the energy sources. When combustion and upgrading TCs are amended with CCS, the resulting climate change savings are robust across the energy systems. The biogas upgrading TCs exhibit substantial climate change savings, mainly due to the natural gas substitution. Combustion TCs without CCS have the lowest climate change savings and the highest quantified uncertainties. The biogas upgrading TCs with storage or direct utilisation of CO 2 provide a good compromise between climate change savings and energy recovery. In the remaining impact categories, the CCU TCs generally perform best, followed by the upgrading TCs and finally, the combustion TCs. The CCS TCs consistently perform worse than their counterparts without CCS, opposite to the climate change results. Overall, amending biogas utilisation with CCS or CCU can contribute to climate change mitigation. [ABSTRACT FROM AUTHOR]

Sustainable fuels and technologies are expected to significantly contribute towards climate change mitigation considering that the transportation sector provides a 23% share out of the total CO 2 emissions. Biodiesel is a green fuel produced by transesterification of triglycerides with an alcohol in the presence of a catalyst. The current study entails modelling and simulation of biodiesel production, through an acid transesterification process, using both classic and intensified methods, coupled with an environmental impact analysis performed following the Life Cycle Assessment methodology. The traditional biodiesel production consists in the synthesis and separation sections, while the intensified method is based on reactive distillation. ChemCAD software was used to simulate and evaluate the processes from a technical point of view. Methanol is generated using CO 2 and H 2 , this method being considered as a new approach for CO 2 utilization. Water electrolysis is employed for H 2 generation, with either biomass or natural gas as power source. A cradle-to-gate environmental analysis is performed within the current research by means of GaBi software, considering the following system boundaries: i) upstream processes: catalyst supply chain, sunflower oil supply chain, natural gas supply chain, limestone extraction and decomposition, ii) main-processes: methanol and biodiesel production, iii) downstream processes: disposal of wastes. ReCiPe method was chosen as the impact assessment method. High purities for the main product and by-product are obtained (i.e., purities higher than 99%). The outcome of the process simulation points to the conclusion that the intensified path gives better performances from technical point of view. The environmental results show that the classic approach performs better when CO 2 and H 2 are used as raw materials, while reactive distillation displays a higher efficiency when natural gas is used as feedstock. [Display omitted] [ABSTRACT FROM AUTHOR]

Bioenergy with carbon capture and storage (BECCS) is regarded as a crucial negative emission technology (NET) in many prospective climate change mitigation scenarios that limit global warming below 2 °C. However, there is still insufficient understanding of the overall life cycle environmental performance of different BECCS configurations. Despite the fact that BECCS entails many technological combinations, the technology is still regarded as a single "black box" technology in most climate scenarios. This study presents a critical review of life cycle assessment (LCA) on a wide range of BECCS options: biomass direct-fired power generation, biomass gasification power generation, bio-hydrogen production, biomass application in industry sectors and other biomass conversion processes, such as pyrolysis and fermentation. It is evident from the review that the biomass direct-fired and gasification power plant with a 100% biomass firing ratio and the gasification-based bio-hydrogen processes have a strong potential to achieve negative emissions. However, the net negative life cycle emissions range widely among studies for each configuration due to variations in technology, LCA methodology and assumptions. Additionally, there is an insufficient assessment of comprehensive environmental impacts for BECCS systems other than GWP, making it still unclear about the trade-offs between the benefit from climate change mitigation and potential negative impacts. Main recommendations for improving LCA on BECCS include developing a generalized guideline and standardization for BECCS LCA, conducting LCAs with comprehensive impact categories, focusing on BECCS configurations being overlooked, considering the impact of land use change and the global warming potential of biomass, and extending LCA in both temporal and spatial dimension. [Display omitted] • Systematically review of life cycle assessment on BECCS systems. • Detailed review on various biomass conversion technologies. • Net negative life cycle emissions range widely among studies. • Insufficient studies of some biomass conversion pathways. • Insufficient studies on multi-environmental environment impact categories. [ABSTRACT FROM AUTHOR]

The ever-increasing anthropogenic greenhouse gas (GHG) emissions worldwide make it quite challenging to meet country-specific Nationally Determined Contributions (NDC) targets. Therefore, it is evident that the existing emissions abatement measures need to be taken a step further. Internationally Transferred Mitigation Outcomes (ITMOs) are allowed in Article 6.2 of the Paris Agreement as a cooperative approach to achieving NDC goals. There is a potential to create ITMOs between Canada and China by replacing coal use in China with British Columbia (BC)'s liquefied natural gas (LNG) supply. Replacing coal with LNG in energy generation applications is a promising approach to mitigate emissions. With global and national pressures to reduce emissions, China has created a market for LNG imports to cater to its rising natural gas (NG) consumption due to the coal-to-gas source switching strategy. However, the terms under Article 6.2 requires generated ITMOs to ensure environmental integrity, support sustainable development goals, and have a robust accounting system. Therefore, the current study aims to quantify the life cycle environmental outcomes of generating ITMOs by exporting LNG from BC to Chinese end-users while integrating uncertainties and to provide policy recommendations in adherence with the requirements of Article 6.2. Different LNG export scenarios were generated in the study and environmental impacts of each scenario were assessed and compared using a life cycle assessment (LCA) framework developed by the authors. Sensitivity and uncertainty analyses were conducted to understand the impacts created by the data uncertainties in the final result. By replacing conventional coal with NG, approximately 40–45% and 26%–32% emissions reductions can be obtainable for Chinese textile and chemical industries, respectively. The highest emissions reduction of approximately 60% was observed when coal is replaced with NG for district heating. The life cycle emissions (LCE) quantification framework provided in the study provides stakeholders with a systematic approach to determine the total GHG emissions and emissions reduction potential of different LNG export scenarios. [ABSTRACT FROM AUTHOR]