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Slave Province in Canada is an Archean granite–supracrustal terrane at the northwestern corner of the Canadian Shield. It is bordered by the Thelon–Taltson orogen (2.0 to 1.9 Ga) to the southeast and the Wopmay orogen (1.9 to 1.8 Ga) to the west. Acasta gneisses, exposed in the westernmost Slave Province, and the Wopmay rocks, located close to the gneisses, were systematically collected for K–Ar and laser step-heating 40Ar/39Ar single-crystal analyses of the biotite and amphibole. The K–Ar biotite ages of the four Wopmay samples range from 1816 ± 18 Ma to 1854 ± 26 Ma. The 40Ar/39Ar biotite analyses of the three Wopmay samples yield plateau ages of 1826 ± 21 Ma, 1886 ± 13 Ma, and 1870 ± 18 Ma. These ages fall within the reported U–Pb zircon age range of the Wopmay orogen. The K–Ar biotite ages of the fifteen Acasta gneisses range from 1779 ± 25 Ma to 1877 ± 26 Ma, except for one younger sample (1711 ± 25 Ma). The 40Ar/39Ar analyses of the biotite crystals from three samples give the plateau ages of 1877 ± 8 Ma, 1935 ± 14 Ma, and 1951 ± 11 Ma. The K–Ar amphibole ages from twelve samples range from 1949 ± 19 Ma to 1685 ± 25 Ma. Two samples of them give ages older than the zircon U-Pb age of Hepburn plutons. The 40Ar/39Ar analyses of the amphibole crystals show varied age relations. The two samples give plateau ages of 1814 ± 22 Ma and 1964 ± 12 Ma. Some samples exhibit apparent old ages of ~2000 Ma in the middle temperature fractions. These old fractions result from the amphibole crystals, originally formed in the Archean, being affected by the thermal events during the Wopmay orogeny but not fully resetting. These observations suggest that the K–Ar system ages of the biotite and amphibole in the Archean Acasta gneiss were rejuvenated during the Paleoproterozoic ages. The Discussion explores the possibility that the heat source rejuvenating the K–Ar system ages may have arisen due to asthenospheric extrusion into the wedge mantle, a process likely triggered by subduction rollback. [ABSTRACT FROM AUTHOR]

• Non-zero I/(Ca + Mg) values were detected in Archean and Paleoproterozoic shallow marine carbonates. • The samples are from several locations and range in age from 2.93 to 2.31 Ga. • These non-zero values indicate the original localized presence of dissolved marine oxygen. Marine oxygenation during the Archean and Paleoproterozoic is poorly constrained. Iodine in carbonate is a possible oxygen indicator. We obtained molar ratios of iodine to calcium-magnesium [I/(Ca + Mg)] for 2.93–2.31 Ga from shallow marine Ca-carbonate (limestone, dolostone) platform sediments at several locations in the southern Superior Province in Canada and the USA. Maximum I/(Ca + Mg) ratios obtained are 0.13, 0.26, 0.05 and 0.22 μmol/mol, for 2.93, 2.86, 2.80 and 2.31 Ga samples, respectively. These non-zero carbonate I/(Ca + Mg) ratios indicate localized oxygen in Archean and Paleoproterozoic shallow marine environments. These data support an early origin for biological oxygen-production and, specifically, the idea that mid-late Archean oxygenation was sufficient to facilitate Ca-carbonate precipitation in shallow marine 'oxygen oases' adjacent to anoxic iron-rich seas [ABSTRACT FROM AUTHOR]

Tonalite-trondhjemite-granodiorite (TTG) suites are the dominant component of Earth's first continents, but their origins are debated. The trace element concentrations of these rocks are conventionally linked to their source depths and inferred geodynamic settings with the implicit assumption that TTG compositions are source-controlled. Alternatively, their variable compositions may be caused by fractional crystallization in TTG plutons after emplacement and less clearly linked to source depth. Most TTGs in Archean mid-crustal exposures are the dominant component of igneous gray gneiss complexes; the processes that influence the evolution of TTG magmas in this setting are poorly understood. We present a petrological-geochemical model that explains the coexistence of TTGs in the middle crust with low-pressure and high-pressure geochemical trends, irrespective of tectonic setting or depth of the TTG source. We propose that mid-crustal TTGs were long-lived crystal mushes with compositions controlled by the separation of early-crystallizing plagioclase and melt. Using phase equilibrium modeling, we demonstrate that a suite of TTGs from the southern Superior Province in Canada represents variably plagioclaserich and melt-rich fractions from a common parent magma. The behavior of plagioclase may have a strong influence on the geochemical trends of TTGs, including the degree of rare earth element fractionation. Our results suggest that trace element compositions of TTGs may not primarily reflect the depth of the source and cannot be used alone to infer Archean geodynamic settings. [ABSTRACT FROM AUTHOR]

The Proterozoic evolution of Laurentia involved intermittent orogens and arc-related crustal growth along a modern-style convergent margin, termed the Great Proterozoic Accretionary Orogen (GPAO). The major lithotectonic provinces of the GPAO in the United States are exposed as telescoped equivalents within the thrust stack of the Grenville Province in Canada. We report zircon U Pb and Lu Hf isotope analyses for two orthogneisses and one quartzite from Archean and Paleoproterozoic domains in the gneiss belt of the SW Grenville Province, Canada. The data constrains Paleoproterozoic crustal growth and sedimentation for this part of the Laurentian margin. The orthogneisses have similar zircon U Pb and Lu Hf isotope systematics that reflect igneous reworking (ca. 1700–1660 Ma) of a Penokean aged (ca. 1.9 Ga) depleted mantle derived source, along with metamorphic reactivation at both ca. 1.45 Ga and during the Grenville Orogeny (1.2–1.0 Ga). The quartzite has a bimodal Paleoproterozoic (2.1–1.8 Ga) and Archean (> 2.5 Ga) detrital zircon age spectrum. The Paleoproterozoic detrital zircon grains have a wide range of Hf(t) compositions (εHf(t) = −12.5 to 10) reflecting co-eval interaction of Archean and depleted Paleoproterozoic sources, contrasted by a more restricted range for the Archean population (εHf(t) = −7 to 4). The new data support the presence of reworked ca. 1.9 Ga depleted mantle sources in the Paleoproterozoic Parautochthon, which extend further east than previously thought. They also identify correlations amongst detrital zircon age spectra and Hf isotope compositions in quartzites from different locations of the Archean Parautochthon. • Juvenile Penokean sources (∼1.9 Ga) extend into the SW Grenville Province. • Penokean (∼1.9 Ga) crust-mantle mixing recorded by detrital zircon Lu Hf isotopes. • Erosion and redeposition of sedimentary sinks can mask orogen detrital systematics. [ABSTRACT FROM AUTHOR]

[Display omitted] • Late Archean granitic plutons in northeastern Superior Province have diverse sources. • Four granitic suites record transition from plume-dominated regime to plate tectonics. • The ∼2730–2700 Ma subduction-related plutonism is the major crustal growth event. • The transition between tectonic regimes occurred over a short time span of 30 My. • The transition was markedly diachronous across the Superior Province. The Superior Province in Canada represents an excellent natural laboratory to test various models of crustal growth and evaluate tectonic regimes during the late Archean. Here, we present new geochemical and geochronological data for ca. 2.8–2.7 Ga plutons intruding different lithotectonic units of the north-eastern part of the Superior Province that demonstrate a complex nature and evolution of magma sources in relation to a changing tectonic setting. Four distinct plutonic suites were newly identified: (1) sodic tonalite–diorite (TD) with a composition resembling low-pressure TTG-like melts, (2) sodic tonalite–granodiorite–diorite (TGD) with medium/high-pressure TTG-like signatures, (3) Mg–K-rich monzogranite to monzodiorite (sanukitoids; MMD), and (4) K-rich granodiorite–granite–monzogranite (GGM). These suites are interpreted as recording a temporal evolution from plume-assisted melting of lower mafic continental crust through melting of a subducted oceanic slab at different depths to large-scale re-melting of the previously formed and amalgamated crustal units. In this evolutionary scheme, the ∼2730–2700 Ma subduction-related plutonism is the most voluminous addition of the juvenile arc material and thus represents the most significant crustal growth event. Altogether, the above inferences and published data suggest that the late Archean plutonism in the Superior Province formed during a transitional regime from plume-dominated to plate-tectonic over a short time span between ∼2730 and ∼2700 Ma and that this transition was markedly diachronous across the Province. [ABSTRACT FROM AUTHOR]