Non-zero I/(Ca + Mg) recorded in Archean and Paleoproterozoic shallow marine Ca-carbonate sediments.

• Non-zero I/(Ca + Mg) values were detected in Archean and Paleoproterozoic shallow marine carbonates. • The samples are from several locations and range in age from 2.93 to 2.31 Ga. • These non-zero values indicate the original localized presence of dissolved marine oxygen. Marine oxygenation during the Archean and Paleoproterozoic is poorly constrained. Iodine in carbonate is a possible oxygen indicator. We obtained molar ratios of iodine to calcium-magnesium [I/(Ca + Mg)] for 2.93–2.31 Ga from shallow marine Ca-carbonate (limestone, dolostone) platform sediments at several locations in the southern Superior Province in Canada and the USA. Maximum I/(Ca + Mg) ratios obtained are 0.13, 0.26, 0.05 and 0.22 μmol/mol, for 2.93, 2.86, 2.80 and 2.31 Ga samples, respectively. These non-zero carbonate I/(Ca + Mg) ratios indicate localized oxygen in Archean and Paleoproterozoic shallow marine environments. These data support an early origin for biological oxygen-production and, specifically, the idea that mid-late Archean oxygenation was sufficient to facilitate Ca-carbonate precipitation in shallow marine 'oxygen oases' adjacent to anoxic iron-rich seas [ABSTRACT FROM AUTHOR]