1. Optimizing the yield and physico-chemical properties of pine cone cellulose nanocrystals by different hydrolysis time
- Author
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Rafael Balart, Daniel Garcia-Garcia, Monica Ek, Rosana Moriana, and Juan López-Martínez
- Subjects
Solid-state chemistry ,genetic structures ,Polymers and Plastics ,Materialkemi ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,Physico-chemical properties ,chemistry.chemical_compound ,Hydrolysis ,CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA ,Materials Chemistry ,Polymer Technologies ,Sulfuric hydrolysis conditions ,Cellulose nanocrystals ,Pappers-, massa- och fiberteknik ,Sulfuric acid ,Paper, Pulp and Fiber Technology ,021001 nanoscience & nanotechnology ,Alkali metal ,Yield-recovery ,Polymerteknologi ,0104 chemical sciences ,Pine cones ,chemistry ,Chemical engineering ,Yield (chemistry) ,sense organs ,0210 nano-technology ,Conifer cone - Abstract
[EN] Cellulose nanocrystals (CNCs) were isolated for the first time from pine cones (PC) by alkali and bleaching treatments and subsequent sulfuric acid hydrolysis (64 %) at 45 ºC. The influence of the hydrolytic reaction time (30, 45 and 90 min) on the yield, chemical composition and structure, and thermal stability of CNCs was evaluated. The removal of non-cellulosic constituents during the alkaline and bleaching treatment resulted in high pure cellulosic fibres. The isolation of CNCs from these cellulosic fibres at different reaction times was verified by the nano-dimensions of the individual crystals (< 3 and, This work was supported by the Ministry of Economy and Competitiveness (MINECO) [MAT2014-59242-C2-1-R]. D. García-García wants to thanks the Spanish Ministry of Education, Culture and Sports for their financial support through an FPU Grant [FPU13/06011].
- Published
- 2018