1. Porous organic framework materials for photocatalytic H2O2 production.
- Author
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Yang, Yepeng, Wang, Chengjiao, Li, Yizhou, Liu, Kong, Ju, Haidong, Wang, Jiaqiang, and Tao, Rao
- Subjects
METAL-organic frameworks ,HYDROGEN peroxide ,ENVIRONMENTAL protection ,STRUCTURE-activity relationships ,CHEMICAL synthesis ,ORGANIC semiconductors - Abstract
• Recent advances in POFs for photocatalytic H 2 O 2 production are summarized. • The effective strategies to improve H 2 O 2 production are highlighted. • Elucidates photocatalytic H 2 O 2 production efficiency and possible reaction mechanism. • The current challenges and future perspectives of photocatalytic H 2 O 2 production in POFs is declared. Hydrogen peroxide (H 2 O 2) has been recognized as a rather important chemical with extensive applications in environmental protection, chemical synthesis, military manufacturing, etc. However, the mature industrial strategy (i.e., anthraquinone oxidation) for H 2 O 2 production is featured with heavy pollution and high energy consumption. Photocatalytic technology has been regarded as a sustainable strategy to convert H 2 O and O 2 into H 2 O 2. Recently, porous organic framework materials (POFs) including metal-organic frameworks (MOFs), covalent organic frameworks (COFs), covalent triazine frameworks (CTFs), covalent heptazine frameworks (CHFs), and hydrogen-bonded organic frameworks (HOFs) have exhibited significant potential for green H 2 O 2 photosynthesis by virtue of their diverse synthesis methods, enormous specific surface areas, flexible design, adjustable band structure, and photoelectric property. In this review, the recent advances in H 2 O 2 photosynthesis based on POFs are comprehensively investigated. The modification strategies to improve H 2 O 2 production and their photocatalytic mechanisms are systematically analyzed. The current challenges and future perspectives in this field are highlighted as well. This review aims to give a complete picture of the research effort made to provide a deep understanding of the structure-activity relationship of H 2 O 2 photogeneration over POFs, thus inspiring some new ideas to tackle the challenges in this field, and finally stimulating the efficient development of organic semiconductors for sustainable photogeneration of H 2 O 2. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
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