1. Construction of ZnO/Ni@C hollow microspheres as efficient electromagnetic wave absorbers with thin thickness and broad bandwidth.
- Author
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Jiang, Yuchen, Zhang, Hao, Zuo, Xueqing, Sun, Chen, Zhang, Yifeng, Huang, Hui, Fan, Zeng, Li, Chengwei, and Pan, Lujun
- Subjects
ELECTROMAGNETIC waves ,RADAR cross sections ,ZINC oxide ,CHEMICAL vapor deposition ,MICROSPHERES ,BANDWIDTHS - Abstract
• A unique dielectric-magnetic compound of ZnO/Ni@C hollow microsphere is designed and constructed. • Synergistic effects are realized by the hollow structure and multiple loss mechanisms. • Efficient electromagnetic wave absorbers with broad bandwidth and thin thickness. • Computer simulation technology is performed to simulate the radar cross section and the electromagnetic field. Ingenious microstructure design and rational composition collocation have been proved to be an effective strategy for developing efficient electromagnetic wave (EMW) absorbers. It would be promising to fabricate a hollow structured composite integrating multiple loss mechanisms (conduction, magnetic, and polarization losses) for excellent EMW absorption. Herein, a novel dielectric-magnetic compound of ZnO/Ni@C hollow microsphere was prepared through hydrothermal reactions followed by an in-situ chemical vapor deposition (CVD). In this ternary composite, abundant ZnO/Ni heterostructures formed the hollow microsphere skeletons and provided unique Schottky junctions, which endowed the composite with improved impedance matching and strong polarization loss. Meanwhile, the amorphous-polycrystalline carbon layer deposited on the surface of each microsphere enhanced the conduction and interfacial polarization losses. In addition, the magnetic Ni nanoparticles induced magnetic loss. Benefiting from the synergistic effect of the hollow structure and multiple loss mechanisms, the ternary composite exhibits an effective absorption bandwidth as wide as 6.55 GHz at a thickness of only 1.85 mm, accompanied by a minimum reflection loss of –39.8 dB. Besides, the radar cross-section and the electromagnetic field simulation further verify the superior EMW absorption performance of the composites. Our work provides a new reference for the fabrication of dielectric-magnetic ternary hollow microspheres as EMW absorbers with thin thickness and broad bandwidth. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
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