1. Magnetic properties, structural investigation and optical studies of Er3+doping Cd-Mg spinel ferrite.
- Author
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Venu, S., Prasad, N. V. Krishna, Kumar, N. Hari, ChandrababuNaidu, K., Vinod, G., and Ravinder, D.
- Abstract
The effect of using citrate-gel auto combustion method to substitute erbium rare-earth ion on magnetism cadmium composition of chemicals formula Cd0.2Mg0.8ErxFe2-xO4 (CMEF) (x = 0.000, 0.005, 0.010, 0.015, 0.020, and 0.025). Synthesized powder were sintered for 4 h at 600 °C after the crushed powders were calcined. These CMEF nanoferrites' structural and magnetic properties were investigated using P-XRD, E-DAX, FE-SEM, HR-TEM, FT-IR, and VSM investigations. Analysis has been done on the benefits of the crystallite size, phase, and various structural features of CMEF using P-XRD data. The assessed crystalline size is within the range of 20.43 nm and 24.30 nm, while the lattice constant ranges from 8.34 to 8.37 Å. photos obtained with the HR-TEM showed that the Er3+ doped Mg-Cd nanoferrites had particle sizes between 10.5 and 20.7 nm, while the FE-SEM photos showed grain sizes between 19.3 nm and 40.3 nm. With the help of elemental analysis (%) from EDAX, and the CMEF of elements that comprise the given chemical composition were thoroughly analysed without interfering substances. The spinel structure was confirmed by the presence of two stretching bonds between metal nitrates and function groups, as shown by the FT-IR spectra that were obeyed. VSM generates the characteristic hysteresis loops of the synthesised sample at 300 K temperature in the magnetic experiments. The findings showed that at 300 K, all of the MCEF nanoferrites exhibited ferromagnetic behaviour. Substantial magnetization was reached at 300 K for 20–18.48 emu/g). The Hc values were determined to lie between 107.46 and 129.53 Oe, while the squareness or remanent ratio values at 300 K varied. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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