1,690 results
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2. Systematic quantitative literature review of the dialogic pedagogy literature
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Paper, Original
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Dialogues -- Usage ,Dialogue -- Usage ,Education -- Methods ,Education ,Languages and linguistics - Abstract
This systematic quantitative literature review was conducted to analyse and synthesise the extant corpus of knowledge on dialogic pedagogy within school settings, and thus identify theoretical and methodological gaps in the literature, which might suggest new avenues for research. A search of eight databases (2014-2020) revealed an initial pool of 2443 papers, which was reduced to 61 after screening for eligibility. An analysis of the 61 papers was framed around the following questions: What is the dominant mode of classroom discourse (monologic or dialogic) reported in the literature? Where is dialogic pedagogy being researched? Who are the dominant voices in the field? and Which year levels and school subjects have been examined using which methodologies? A key finding of the analysis was the absence of substantial research by Australian or New Zealand authors, specifically where mathematics education is concerned. Similarly, there is little investigation focusing on the early years of schooling. While some education areas have been well researched with regard to dialogic pedagogy, further work is required that focuses on areas such as the early years of schooling; non-science contexts; and the use of qualitative research methods. Keywords Systematic quantitative literature review * Dialogic pedagogy * Dialogic practices * Dialogic teaching, 1 Introduction The purpose of this systematic quantitative literature review (SQLR) (Pickering & Byrne, 2014) is to analyse the extant literature available (2015-2020 or 2014-2019 depending on search options available) [...]
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- 2023
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3. Cross-sectional comparisons of dietary indexes underlying nutrition labels: nutri-score, Canadian ‘high in’ labels and Diabetes Canada Clinical Practices (DCCP)
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Paper, Laura, Ahmed, Mavra, Lee, Jennifer J., Kesse-Guyot, Emmanuelle, Touvier, Mathilde, Hercberg, Serge, Galan, Pilar, Salanave, Benoît, Verdot, Charlotte, L’Abbé, Mary R., Deschamps, Valérie, and Julia, Chantal
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- 2023
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4. SGX Switchless Calls Made Configless.
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Peterson Yuhala, Michael Paper, Timothée Zerbib, Pascal Felber, Valerio Schiavoni, and Alain Tchana
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- 2023
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5. Ethical AI and Global Cultural Coherence: Issues and Challenges
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Groumpos, Peter P. and PAPER, PLENARY
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- 2022
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6. Examining the diet quality of Canadian adults and the alignment of Canadian front-of-pack labelling regulations with other front-of-pack labelling systems and dietary guidelines.
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Lee, Jennifer J., Ahmed, Mavra, Julia, Chantal, Ng, Alena Praneet, Paper, Laura, Lou, Wendy Y., and L'Abbé, Mary R.
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- 2024
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7. SARS-CoV-2 seroprevalence among Beninese pregnant women in the third year of the pandemic.
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Figueroa-Romero, Antía, Atchadé, Aurore, Yadouleton, Anges, Fiogbe, Marc, Bonnet, Emmanuel, Yovo, Emmanuel, Accrombessi, Manfred, Hounsa, Sandrine, Paper, Thierry, Dupont, Raphael, Gaudart, Jean, Le Hesran, Jean-Yves, Massougbodji, Achille, Cottrell, Gilles, and González, Raquel
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PREGNANT women ,RAPID diagnostic tests ,SARS-CoV-2 ,THIRD trimester of pregnancy ,COVID-19 pandemic - Abstract
Background: Pregnant women are a vulnerable population to COVID-19 given an increased susceptibility to severe SARS-CoV-2 infection and pregnancy complications. However, few SARS-CoV-2 serological surveys have been performed among this population to assess the extent of the infection in sub-Saharan countries. The objectives of this study were to determine SARS-CoV-2 seroprevalence among Beninese pregnant women, to identify spatial seropositivity clusters and to analyse factors associated with the infection. Methods: A cross-sectional study including women in their third trimester of pregnancy attending the antenatal care (ANC) clinics at Allada (south Benin) and Natitingou (north Benin) was conducted. Rapid diagnostic tests (RDT) for detection of IgG/IgM against the SARS-CoV-2 spike protein were performed using capillary blood. Seroprevalence of SARS-CoV-2 antibodies and associations between SARS-CoV-2 serostatus and maternal characteristics were analyzed by multivariate logistic regression. Spatial analyses were performed using the spatial scan statistics to identify spatial clusters of SARS-CoV-2 infection. Results: A total of 861 pregnant women were enrolled between May 4 and June 29, 2022. 58/861 (6.7%) participants reported having received COVID-19 vaccine. None of the participants had been diagnosed with COVID-19 during their pregnancy. SARS-CoV-2 antibodies were detected in 607/802 (75.7%; 95% CI 72.56%–78.62%) of unvaccinated participants. Several urban and rural spatial clusters of SARS-CoV-2 cases were identified in Allada and one urban spatial cluster was identified in Natitingou. Unvaccinated participants from Allada with at least one previous morbidity were at a three-times higher risk of presenting SARS-CoV-2 antibodies (OR = 2.89; 95%CI 1.19%-7.00%). Conclusion: Three out of four pregnant women had SARS-CoV-2 antibodies, suggesting a high virus circulation among pregnant women in Benin, while COVID-19 vaccination coverage was low. Pregnant women with comorbidities may be at increased risk of SARS-CoV-2 infection. This population should be prioritized for COVID-19 diagnosis and vaccination in order to prevent its deleterious effects. Trial registration: NCT06170320 (retrospectively registered on December 21, 2023). [ABSTRACT FROM AUTHOR]
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- 2024
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8. Performances of two rapid LAMP-based techniques for the intrapartum detection of Group B Streptococcus vaginal colonization.
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Charfi, Rym, Guyonnet, Cécile, Untrau, Meiggie, Giacometti, Gaëlle, Paper, Thierry, Poyart, Claire, Plainvert, Céline, and Tazi, Asmaa
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STREPTOCOCCUS agalactiae ,LOOP-mediated isothermal amplification ,SONICATION ,NEONATAL diseases - Abstract
Purpose: Group B Streptococcus (GBS) is the leading cause of invasive infections in newborns. The prevention of GBS neonatal disease relies on the administration of an intrapartum antibiotic prophylaxis to GBS-colonized women. In recent years, rapid intrapartum detection of GBS vaginal colonization using real-time nucleic acid amplification tests (NAATs) emerged as an alternative to antenatal culture screening methods. Methods: We compared the performances of two loop-mediated isothermal amplification (LAMP) tests, the Ampliflash® GBS and the PlusLife® GBS tests, to standard culture for GBS detection in vaginal specimens from pregnant women. The study was conducted from April to July 2023 in a French hospital of the Paris area. Results: A total of 303 samples were analyzed, including 85 culture-positive samples (28.1%). The Ampliflash® GBS test and the PlusLife® GBS tests gave a result for 100% and 96.3% tests, respectively. The performances of the tests were as follows: sensitivity 87.1% (95% confidence interval (CI) 78.3–92.6) and 98.7% (95% CI 93.0-99.8), specificity 99.1% (95% CI 96.7–99.8), and 91.9% (95% CI 87.3–95.0), respectively. False negative results of the Ampliflash® GBS test correlated with low-density GBS cultures. Time-to-results correlated with GBS culture density only for the PlusLife® GBS test (p < 0.001). Conclusion: Both techniques provide excellent analytical performances with high sensitivity and specificity together with a short turnaround time and results available in 10 to 35 min. Their potential to further reduce the burden of GBS neonatal disease compared with antenatal culture screening needs to be assessed in future clinical studies. [ABSTRACT FROM AUTHOR]
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- 2024
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9. Rare earth element stripping from kaolin sands via mild acid treatment.
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Koch, Max, Paper, Michael, Brück, Thomas B., and Nilges, Tom
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KAOLIN , *CLAY minerals , *SAND , *SULFURIC acid , *HYDROCHLORIC acid , *KAOLINITE - Abstract
Due to their chemical and physical properties, rare earth elements (REEs) are essential in modern applications such as energy conversion or IT technology. The increasing demand for these elements leads to strong incentives for REE recovery and induces the exploration of new, alternative sources for REEs. Accessing REEs from clay minerals, in our case kaolinite, by an elution process is a promising method. The present study investigates the potential application of REE recovery through elution with different mineral acids (HNO3, H2SO4, and HCl) in a microwave process. The material used in this study—residues from an industrial kaolin production process—contained 2.47 g/kg REEs which is a significant amount for REE recovery. The ability of various mineral acids to solubilize metals was studied to assess the REE content of this residual resource. Around 1.87 g/kg of REEs was eluted from industrial kaolinite residues in hydrochloric acid, 1.71 g/kg in sulfuric acid, and 1.13 g/kg in nitric acid. [ABSTRACT FROM AUTHOR]
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- 2024
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10. Effects of elevated CO2 on feeding responses of biological control agents of Pontederia crassipes.
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Paper, M. K., Righetti, T., Raubenheimer, S. L., Coetzee, J. A., Sosa, A. J., and Hill, M. P.
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BIOLOGICAL weed control , *WATER hyacinth , *AQUATIC weeds , *ORTHOPTERA , *BIOLOGICAL pest control agents , *PHOTOSYNTHETIC rates , *PLANT-water relationships - Abstract
Elevated carbon dioxide (eCO2) and rising temperatures will have far‐reaching effects on global plant‐insect interactions, yet their implications for future biological control programs are not fully understood. Studies have shown that elevated CO2 will affect insect feeding guilds differently and these responses can be predicted with some confidence. Water hyacinth, Pontederia crassipes Mart. (Pontederiaceae), is a native and representative species of the Del Plata wetlands (Argentina) that invades outside of its native environment. It is considered one of the world's worst aquatic weeds and a target for biological control. In this study, water hyacinth plants were grown under two CO2 concentrations – current (400 p.p.m.) or elevated (800 p.p.m.) –, with and without two biocontrol agents representing different feeding guilds, the leaf‐chewing Cornops aquaticum Brüner (Orthoptera: Acrididae) and the phloem‐feeding Megamelus scutellaris Berg (Hemiptera: Delphacidae). Under eCO2 concentration, photosynthetic rate, total dry weight, and relative growth rate of P. crassipes acclimated to eCO2 conditions and plants showed very little CO2 fertilization response in eutrophic water. Insect herbivory varied depending on feeding guilds at eCO2; however, P. crassipes growth responses increased when exposed to insect herbivory. Chewing herbivory by C. aquaticum was consistent across CO2 conditions, whereas the feeding by M. scutellaris increased substantially at eCO2. These results indicate that successful biological control of P. crassipes under conditions of elevated CO2 might rely on phloem‐feeding insects, with chewers playing a lesser role. [ABSTRACT FROM AUTHOR]
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- 2023
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11. An Approach to Integrated Digital Requirements Engineering.
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Duprez, Jean, Paper, Pascal, Fraj, Amine, Royer, Laurent, and Petteys, Becky
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REQUIREMENTS engineering ,SYSTEMS engineering ,NATURAL languages ,SIMULATION methods & models - Abstract
Systems engineering activities in the concept and development phases have evolved continuously for decades. The deployment of digital thread, digital engineering, MBSE approaches, and modeling and simulation techniques have driven part of this evolution. Despite this trend, requirements are still largely textual and expressed in natural language, and requirements engineering activities are still often document‐based. However, model‐based requirements‐engineering approaches have emerged in recent years and have demonstrated significant benefits, including improved requirements quality, less ambiguity, and early and efficient verification and validation. The goal of this paper is to present the current outcomes and perspectives of setting up an Integrated Digital Requirements Engineering approach as developed within our company. This approach seeks to optimize usability and maximize benefits to support end‐to‐end V&V activities while fully integrating into MBSE workflows. [ABSTRACT FROM AUTHOR]
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- 2023
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12. Can individual fatty acids be used as functional biomarkers of dairy fat consumption in relation to cardiometabolic health? A narrative review—CORRIGENDUM.
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Sellem, Laury, Jackson, Kim G., Paper, Laura, Givens, Ian D., and Lovegrove, Julie A.
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CARDIOVASCULAR diseases risk factors ,BIOMARKERS ,DAIRY products ,DIETARY fats ,FATTY acids - Abstract
A correction is presented to the article "Can individual fatty acids be used as functional biomarkers of dairy fat consumption in relation to cardiometabolic health?"
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- 2022
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13. Into Africa: Salvinia minima Baker (Salviniaceae) invades South Africa.
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Coetzee, Julie A., Paper, Matthew K., Miller, Benjamin E., Kinsler, David, Cilliers, Carina J., and Hill, Martin P.
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INDIGENOUS peoples of South America ,BODIES of water - Abstract
Salvinia minima Baker (Salviniaceae) has been recorded for the first time in Africa. This South American native macrophyte is highly invasive and damaging, costing millions of dollars to control in the USA, and has the potential to invade many of southern Africa's waterbodies. Field surveys have confirmed the presence of S. minima from four sites in South Africa, with the largest invasion occurring on the highly polluted Hartbeespoort Dam, north east of the country's capital. Salvinia minima has been targeted for biological control in South Africa, using the weevil, Cyrtobagous salviniae, which is undergoing host specificity testing under quarantine conditions. [ABSTRACT FROM AUTHOR]
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- 2022
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14. Examining Nutrient Intakes of Canadian Adults With Diabetes Using the Diabetes Canada Clinical Practice Guidelines Nutrient Profile Model
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Lee, Jennifer, Ahmed, Mavra, Julia, Chantal, Paper, Laura, and L’Abbe, Mary
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- 2022
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15. About Neural Networks and Writing Definitions
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Mickus, Timothee, Constant, Mathieu, and Paperno, Denis
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- 2022
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16. SARS-CoV-2 seroprevalence among Beninese pregnant women in the third year of the pandemic
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Antía Figueroa-Romero, Aurore Atchadé, Anges Yadouleton, Marc Fiogbe, Emmanuel Bonnet, Emmanuel Yovo, Manfred Accrombessi, Sandrine Hounsa, Thierry Paper, Raphael Dupont, Jean Gaudart, Jean-Yves Le Hesran, Achille Massougbodji, Gilles Cottrell, and Raquel González
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Pregnancy ,SARS-CoV-2 ,Sub-saharan Africa ,Public aspects of medicine ,RA1-1270 - Abstract
Abstract Background Pregnant women are a vulnerable population to COVID-19 given an increased susceptibility to severe SARS-CoV-2 infection and pregnancy complications. However, few SARS-CoV-2 serological surveys have been performed among this population to assess the extent of the infection in sub-Saharan countries. The objectives of this study were to determine SARS-CoV-2 seroprevalence among Beninese pregnant women, to identify spatial seropositivity clusters and to analyse factors associated with the infection. Methods A cross-sectional study including women in their third trimester of pregnancy attending the antenatal care (ANC) clinics at Allada (south Benin) and Natitingou (north Benin) was conducted. Rapid diagnostic tests (RDT) for detection of IgG/IgM against the SARS-CoV-2 spike protein were performed using capillary blood. Seroprevalence of SARS-CoV-2 antibodies and associations between SARS-CoV-2 serostatus and maternal characteristics were analyzed by multivariate logistic regression. Spatial analyses were performed using the spatial scan statistics to identify spatial clusters of SARS-CoV-2 infection. Results A total of 861 pregnant women were enrolled between May 4 and June 29, 2022. 58/861 (6.7%) participants reported having received COVID-19 vaccine. None of the participants had been diagnosed with COVID-19 during their pregnancy. SARS-CoV-2 antibodies were detected in 607/802 (75.7%; 95% CI 72.56%–78.62%) of unvaccinated participants. Several urban and rural spatial clusters of SARS-CoV-2 cases were identified in Allada and one urban spatial cluster was identified in Natitingou. Unvaccinated participants from Allada with at least one previous morbidity were at a three-times higher risk of presenting SARS-CoV-2 antibodies (OR = 2.89; 95%CI 1.19%-7.00%). Conclusion Three out of four pregnant women had SARS-CoV-2 antibodies, suggesting a high virus circulation among pregnant women in Benin, while COVID-19 vaccination coverage was low. Pregnant women with comorbidities may be at increased risk of SARS-CoV-2 infection. This population should be prioritized for COVID-19 diagnosis and vaccination in order to prevent its deleterious effects. Trial registration NCT06170320 (retrospectively registered on December 21, 2023).
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- 2024
- Full Text
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17. Performances of two rapid LAMP-based techniques for the intrapartum detection of Group B Streptococcus vaginal colonization
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Rym Charfi, Cécile Guyonnet, Meiggie Untrau, Gaëlle Giacometti, Thierry Paper, Claire Poyart, Céline Plainvert, and Asmaa Tazi
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Group B Streptococcus ,Intrapartum screening ,NAAT ,Neonatal infection ,LAMP ,Therapeutics. Pharmacology ,RM1-950 ,Infectious and parasitic diseases ,RC109-216 ,Microbiology ,QR1-502 - Abstract
Abstract Purpose Group B Streptococcus (GBS) is the leading cause of invasive infections in newborns. The prevention of GBS neonatal disease relies on the administration of an intrapartum antibiotic prophylaxis to GBS-colonized women. In recent years, rapid intrapartum detection of GBS vaginal colonization using real-time nucleic acid amplification tests (NAATs) emerged as an alternative to antenatal culture screening methods. Methods We compared the performances of two loop-mediated isothermal amplification (LAMP) tests, the Ampliflash® GBS and the PlusLife® GBS tests, to standard culture for GBS detection in vaginal specimens from pregnant women. The study was conducted from April to July 2023 in a French hospital of the Paris area. Results A total of 303 samples were analyzed, including 85 culture-positive samples (28.1%). The Ampliflash® GBS test and the PlusLife® GBS tests gave a result for 100% and 96.3% tests, respectively. The performances of the tests were as follows: sensitivity 87.1% (95% confidence interval (CI) 78.3–92.6) and 98.7% (95% CI 93.0-99.8), specificity 99.1% (95% CI 96.7–99.8), and 91.9% (95% CI 87.3–95.0), respectively. False negative results of the Ampliflash® GBS test correlated with low-density GBS cultures. Time-to-results correlated with GBS culture density only for the PlusLife® GBS test (p
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- 2024
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18. Corrigendum: Examining the diet quality of Canadian adults and the alignment of Canadian front-of-pack labelling regulations with other front-of-pack labelling systems and dietary guidelines
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Jennifer J. Lee, Mavra Ahmed, Chantal Julia, Alena Praneet Ng, Laura Paper, Wendy Y. Lou, and Mary R. L'Abbé
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front-of-pack ,FOPL ,dietary patterns ,nutrient profiling ,HEFI ,Nutri-score ,Public aspects of medicine ,RA1-1270 - Published
- 2024
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19. Stripped: contribution of cyanobacterial extracellular polymeric substances to the adsorption of rare earth elements from aqueous solutions
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Michael Paper, Patrick Jung, Max Koch, Michael Lakatos, Tom Nilges, and Thomas B. Brück
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extracellular polymeric substances ,polysaccharides ,Komarekiella ,Nostoc ,Desmonostoc ,biosorption ,Biotechnology ,TP248.13-248.65 - Abstract
The transformation of modern industries towards enhanced sustainability is facilitated by green technologies that rely extensively on rare earth elements (REEs) such as cerium (Ce), neodymium (Nd), terbium (Tb), and lanthanum (La). The occurrence of productive mining sites, e.g., is limited, and production is often costly and environmentally harmful. As a consequence of increased utilization, REEs enter our ecosystem as industrial process water or wastewater and become highly diluted. Once diluted, they can hardly be recovered by conventional techniques, but using cyanobacterial biomass in a biosorption-based process is a promising eco-friendly approach. Cyanobacteria can produce extracellular polymeric substances (EPS) that show high affinity to metal cations. However, the adsorption of REEs by EPS has not been part of extensive research. Thus, we evaluated the role of EPS in the biosorption of Ce, Nd, Tb, and La for three terrestrial, heterocystous cyanobacterial strains. We cultivated them under N-limited and non-limited conditions and extracted their EPS for compositional analyses. Subsequently, we investigated the metal uptake of a) the extracted EPS, b) the biomass extracted from EPS, and c) the intact biomass with EPS by comparing the amount of sorbed REEs. Maximum adsorption capacities for the tested REEs of extracted EPS were 123.9–138.2 mg g−1 for Komarekiella sp. 89.12, 133.1–137.4 mg g−1 for Desmonostoc muscorum 90.03, and 103.5–129.3 mg g−1 for Nostoc sp. 20.02. A comparison of extracted biomass with intact biomass showed that 16% (Komarekiella sp. 89.12), 28% (Desmonostoc muscorum 90.03), and 41% (Nostoc sp. 20.02) of REE adsorption was due to the biosorption of the extracellular EPS. The glucose- rich EPS (15%–43% relative concentration) of all three strains grown under nitrogen-limited conditions showed significantly higher biosorption rates for all REEs. We also found a significantly higher maximum adsorption capacity of all REEs for the extracted EPS compared to cells without EPS and untreated biomass, highlighting the important role of the EPS as a binding site for REEs in the biosorption process. EPS from cyanobacteria could thus be used as efficient biosorbents in future applications for REE recycling, e.g., industrial process water and wastewater streams.
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- 2023
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20. Particularities of wooden carved iconostases in selected post-Byzantine churches of Albania
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This paper presents the data and study results of the post-Byzantine wood carved iconostases of different churches in Albania, which notwithstanding the circumstances of the communistic period have preserved to a considerable extent their typical characteristics. The paper aims to examine the stylistic and morphological aspects of the iconostasis in selected churches in relation to the architecture and tries to identify the relationships, sequences and reasons for such phenomena. The presence of iconostases in the Eastern Orthodox Church is based on the carried rituals and services that are expressed through ecclesiastical sculptures and other works. In these contexts, the iconostasis is the most dominating screen, related to the rood screen of English mediaeval churches, but contrary to them it is a closed and solid structure. In the iconostasis, architecture and wood carving workers collaborate on a large scale in order to create a solid and well-integrated frame. The analysis includes St Mary’s Monastery, also known as the Monastery of Dormition of Theotokos Mary, a medieval Byzantine church on Zvërnec island in the Narta Lagoon, southwest of the city of Vlora, southwestern Albania (SMZ); the Church of Apostles in Hoshtevë, Gjirokastra, with its spectacular interior completely covered with frescoes that became a cultural monument of Albania in 1948 (SA); and the Church of the Dormition of the Theotokos, simply known as Koimissi or St Mary, in the village of Labovë e Kryqit, Gjirokastër County, southern Albania (SM).
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cultural heritage ,post-byzantine ,churches ,albanian ,iconostasis ,Museums. Collectors and collecting ,AM1-501 - Abstract
This paper presents the data and study results of the post-Byzantine wood carved iconostases of different churches in Albania, which notwithstanding the circumstances of the communistic period have preserved to a considerable extent their typical characteristics. The paper aims to examine the stylistic and morphological aspects of the iconostasis in selected churches in relation to the architecture and tries to identify the relationships, sequences and reasons for such phenomena. The presence of iconostases in the Eastern Orthodox Church is based on the carried rituals and services that are expressed through ecclesiastical sculptures and other works. In these contexts, the iconostasis is the most dominating screen, related to the rood screen of English mediaeval churches, but contrary to them it is a closed and solid structure. In the iconostasis, architecture and wood carving workers collaborate on a large scale in order to create a solid and well-integrated frame. The analysis includes St Mary’s Monastery, also known as the Monastery of Dormition of Theotokos Mary, a medieval Byzantine church on Zvërnec island in the Narta Lagoon, southwest of the city of Vlora, southwestern Albania (SMZ); the Church of Apostles in Hoshtevë, Gjirokastra, with its spectacular interior completely covered with frescoes that became a cultural monument of Albania in 1948 (SA); and the Church of the Dormition of the Theotokos, simply known as Koimissi or St Mary, in the village of Labovë e Kryqit, Gjirokastër County, southern Albania (SM)
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- 2022
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21. Examining the diet quality of Canadian adults and the alignment of Canadian front-of-pack labelling regulations with other front-of-pack labelling systems and dietary guidelines
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Jennifer J. Lee, Mavra Ahmed, Chantal Julia, Alena Praneet Ng, Laura Paper, Wendy Y. Lou, and Mary R. L’Abbé
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front-of-pack ,FOPL ,dietary patterns ,nutrient profiling ,HEFI ,Nutri-score ,Public aspects of medicine ,RA1-1270 - Abstract
IntroductionCanada promulgated mandatory front-of-pack labelling (FOPL) regulations in 2022, requiring pre-packaged foods meeting and/or exceeding recommended thresholds for nutrients-of-concern (i.e., saturated fat, sodium, sugars) to display a “high-in” nutrition symbol. However, there is limited evidence on how Canadian FOPL (CAN-FOPL) regulations compare to other FOPL systems and dietary guidelines. Therefore, the objectives of the study were to examine the diet quality of Canadians using the CAN-FOPL dietary index system and its alignment with other FOPL systems and dietary guidelines.MethodsNationally representative dietary data from the 2015 Canadian Community Health Survey-Nutrition survey (n = 13,495) was assigned dietary index scores that underpin CAN-FOPL, Diabetes Canada Clinical Practice (DCCP) Guidelines, Nutri-score, Dietary Approaches to Stop Hypertension (DASH) and Canada’s Food Guide (Healthy Eating Food Index-2019 [HEFI-2019]). Diet quality was examined by assessing linear trends of nutrient intakes across quintile groups of CAN-FOPL dietary index scores. The alignment of CAN-FOPL dietary index system compared with other dietary index systems, with HEFI as the reference standard, was examined using Pearson’s correlations and к statistics.ResultsThe mean [95% CI] dietary index scores (range: 0–100) for CAN-FOPL, DCCP, Nutri-score, DASH, and HEFI-2019 were 73.0 [72.8, 73.2], 64.2 [64.0, 64.3], 54.9 [54.7, 55.1], 51.7 [51.4, 51.9], and 54.3 [54.1, 54.6], respectively. Moving from the “least healthy” to the “most healthy” quintile in the CAN-FOPL dietary index system, intakes of protein, fiber, vitamin A, vitamin C, and potassium increased, while intakes of energy, saturated fat, total and free sugars, and sodium decreased. CAN-FOPL showed moderate association with DCCP (r = 0.545, p
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- 2023
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22. Rare earths stick to rare cyanobacteria: Future potential for bioremediation and recovery of rare earth elements
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Michael Paper, Max Koch, Patrick Jung, Michael Lakatos, Tom Nilges, and Thomas B. Brück
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cyanobacteria ,biosorption ,mechanism ,rare earth elements ,ion exchange ,Biotechnology ,TP248.13-248.65 - Abstract
Biosorption of metal ions by phototrophic microorganisms is regarded as a sustainable and alternative method for bioremediation and metal recovery. In this study, 12 cyanobacterial strains, including 7 terrestrial and 5 aquatic cyanobacteria, covering a broad phylogenetic diversity were investigated for their potential application in the enrichment of rare earth elements through biosorption. A screening for the maximum adsorption capacity of cerium, neodymium, terbium, and lanthanum was conducted in which Nostoc sp. 20.02 showed the highest adsorption capacity with 84.2–91.5 mg g-1. Additionally, Synechococcus elongatus UTEX 2973, Calothrix brevissima SAG 34.79, Desmonostoc muscorum 90.03, and Komarekiella sp. 89.12 were promising candidate strains, with maximum adsorption capacities of 69.5–83.4 mg g-1, 68.6–83.5 mg g-1, 44.7–70.6 mg g-1, and 47.2–67.1 mg g-1 respectively. Experiments with cerium on adsorption properties of the five highest metal adsorbing strains displayed fast adsorption kinetics and a strong influence of the pH value on metal uptake, with an optimum at pH 5 to 6. Studies on binding specificity with mixed-metal solutions strongly indicated an ion-exchange mechanism in which Na+, K+, Mg2+, and Ca2+ ions are replaced by other metal cations during the biosorption process. Depending on the cyanobacterial strain, FT-IR analysis indicated the involvement different functional groups like hydroxyl and carboxyl groups during the adsorption process. Overall, the application of cyanobacteria as biosorbent in bioremediation and recovery of rare earth elements is a promising method for the development of an industrial process and has to be further optimized and adjusted regarding metal-containing wastewater and adsorption efficiency by cyanobacterial biomass.
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- 2023
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23. Efficient Green Light Acclimation of the Green Algae Picochlorum sp. Triggering Geranylgeranylated Chlorophylls
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Michael Paper, Matthias Glemser, Martina Haack, Jan Lorenzen, Norbert Mehlmer, Tobias Fuchs, Gerhard Schenk, Daniel Garbe, Dirk Weuster-Botz, Wolfgang Eisenreich, Michael Lakatos, and Thomas B. Brück
- Subjects
green light ,photosynthesis ,chlorophyll derivatives ,light adaption mechanism ,geranylgeranylated ,eukaryotic microalgae ,Biotechnology ,TP248.13-248.65 - Abstract
In analogy to higher plants, eukaryotic microalgae are thought to be incapable of utilizing green light for growth, due to the “green gap” in the absorbance profiles of their photosynthetic pigments. This study demonstrates, that the marine chlorophyte Picochlorum sp. is able to grow efficiently under green light emitting diode (LED) illumination. Picochlorum sp. growth and pigment profiles under blue, red, green and white LED illumination (light intensity: 50–200 μmol m−2 s−1) in bottom-lightened shake flask cultures were evaluated. Green light-treated cultures showed a prolonged initial growth lag phase of one to 2 days, which was subsequently compensated to obtain comparable biomass yields to red and white light controls (approx. 0.8 gDW L−1). Interestingly, growth and final biomass yields of the green light-treated sample were higher than under blue light with equivalent illumination energies. Further, pigment analysis indicated, that during green light illumination, Picochlorum sp. formed unknown pigments (X1-X4). Pigment concentrations increased with illumination intensity and were most abundant during the exponential growth phase. Mass spectrometry and nuclear magnetic resonance data indicated, that pigments X1-X2 and X3-X4 are derivatives of chlorophyll b and a, which harbor C=C bonds in the phytol side chain similar to geranylgeranylated chlorophylls. Thus, for the first time, the natural accumulation of large pools (approx. 12 mg gDW−1) of chlorophyll intermediates with incomplete hydrogenation of their phytyl chains is demonstrated for algae under monochromatic green light (Peak λ 510 nm, full width at half maximum 91 nm). The ability to utilize green light offers competitive advantages for enhancing biomass production, particularly under conditions of dense cultures, long light pathways and high light intensity. Green light acclimation for an eukaryotic microalgae in conjunction with the formation of new aberrant geranylgeranylated chlorophylls and high efficiency of growth rates are novel for eukaryotic microalgae. Illumination with green light could enhance productivity in industrial processes and trigger the formation of new metabolites–thus, underlying mechanisms require further investigation.
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- 2022
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24. Isolation and Investigation of Natural Rare Earth Metal Chelating Agents From Calothrix brevissima - A Step Towards Unraveling the Mechanisms of Metal Biosorption
- Author
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Wojciech Jurkowski, Michael Paper, and Thomas B. Brück
- Subjects
biosorption ,cyanobacteria ,rare earth elements ,mechanism ,calothrix ,complexation ,Biotechnology ,TP248.13-248.65 - Abstract
In this study water soluble compounds that form complexes with Rare Earth Elements (REE) and other metals were isolated from Calothrix brevissima biomass with chromatographic methods for the first time. Molecular characterization showed that the isolated compounds are most likely polysaccharides comprised of arabinose, xylose, mannose, galactose and glucose. FT-IR analysis revealed functional groups involved in the binding mechanism of Tb are likely sulfate- and to a lesser extend hydroxyl-groups. The binding specificity of the isolated compounds was investigated with different metal solutions. Here, ions of the alkali and alkaline earth metals Na, K, Mg and Ca showed no competition for Tb-binding even at 10-fold excess concentration. Ions of the elements Co and Pb on the other hand replaced Tb at higher concentrations. Addition of the isolated compounds significantly reduced the precipitation of Eu at pH-values between 6.7 and 9.5, indicating that the interaction between the isolated chelators and Rare Earth Metals is stable even at high pH-values.
- Published
- 2022
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25. Nanolignin-containing cellulose nanofibrils (LCNF)-enabled multifunctional ratiometric fluorescent bio-nanocomposite films for food freshness monitoring.
- Author
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Zhao X, Wang W, Cheng J, Xia Y, Duan C, Zhong R, Zhao X, Li X, and Ni Y
- Subjects
- Fluorescence Resonance Energy Transfer, Biogenic Amines analysis, Biogenic Amines chemistry, Fluorescence, Cellulose chemistry, Food Packaging instrumentation, Nanofibers chemistry, Nanocomposites chemistry
- Abstract
Herein, the nanolignin-containing cellulose nanofibrils (LCNF)-enabled ratiometric fluorescent bio-nanocomposite film is developed. Interestingly, the inclusion of LCNF in the cellulose-based film enhances the detecting performance of food freshness, such as high sensitivity to biogenic amines (BAs) (limit of detection (LOD) of up to 1.83 ppm) and ultrahigh discernible fluorescence color difference (ΔE = 113.11). The underlying mechanisms are the fluorescence resonance energy transfer (FRET), π - π interaction, and cation - π interaction between LCNF and fluorescein isothiocyanate (FITC), as well as the increased hydrophobicity due to lignin, which increases the interactions of amines with FITC. Its color stability (up to 28 days) and mechanical property (49.4 Mpa) are simultaneously improved. Furthermore, a smartphone based detecting platform is developed to achieve access to food safety. This work presents a novel technology, which can have a great potential in the field of food packaging and safety., Competing Interests: Declaration of competing interest It is the original work of the authors. All the authors mutually agree that it should be submitted to Food Chemistry The manuscript has not been published or presented elsewhere in part or in entirety and is not under consideration by another journal. The authors declare that they have no conflict of interests. There is no research involving Human Participants and/or Animals., (Copyright © 2024 Elsevier Ltd. All rights reserved.)
- Published
- 2024
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26. Smart Cellulose-Based Janus Fabrics with Switchable Liquid Transportation for Personal Moisture and Thermal Management.
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Xi J, Lou Y, Meng L, Deng C, Chu Y, Xu Z, Xiao H, and Wu W
- Abstract
The Janus fabrics designed for personal moisture/thermal regulation have garnered significant attention for their potential to enhance human comfort. However, the development of smart and dynamic fabrics capable of managing personal moisture/thermal comfort in response to changing external environments remains a challenge. Herein, a smart cellulose-based Janus fabric was designed to dynamically manage personal moisture/heat. The cotton fabric was grafted with N-isopropylacrylamide to construct a temperature-stimulated transport channel. Subsequently, hydrophobic ethyl cellulose and hydrophilic cellulose nanofiber were sprayed on the bottom and top sides of the fabric to obtain wettability gradient. The fabric exhibits anti-gravity directional liquid transportation from hydrophobic side to hydrophilic side, and can dynamically and continuously control the transportation time in a wide range of 3-66 s as the temperature increases from 10 to 40 °C. This smart fabric can quickly dissipate heat at high temperatures, while at low temperatures, it can slow down the heat dissipation rate and prevent the human from becoming too cold. In addition, the fabric has UV shielding and photodynamic antibacterial properties through depositing graphitic carbon nitride nanosheets on the hydrophilic side. This smart fabric offers an innovative approach to maximizing personal comfort in environments with significant temperature variations., (© 2024. The Author(s).)
- Published
- 2024
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27. Viral antibody response predicts morbidity and mortality in alcohol-associated hepatitis.
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Hsu CL, Wang L, Maestri E, Jacob AR, Do WL, Mayo S, Bosques-Padilla F, Verna EC, Abraldes JG, Brown RS Jr, Vargas V, Altamirano J, Caballería J, Shawcross DL, Louvet A, Lucey MR, Mathurin P, Garcia-Tsao G, Stärkel P, Bataller R, Investigators A, Wang XW, and Schnabl B
- Abstract
Background and Aims: Alcohol-associated hepatitis (AH) is associated with very high mortality despite abstinence from alcohol; up to 40% of patients die within 6 months of diagnosis. Patients with AH are especially prone to infections, which can lead to multiorgan dysfunction and poorer prognosis., Approach and Results: We performed comprehensive serological profiling of the viral and bacterial infection history of 36 healthy controls, 48 patients with alcohol use disorder, and 224 patients with AH from 2 multicenter observational studies. We used systematic viral and bacterial epitope scanning by VirScan, a phage-display immunoprecipitation and sequencing technology that detects the peptides recognized by antibodies in patient sera, to comprehensively analyze antiviral and antibacterial antibodies and identify serologic biomarkers to predict patient outcomes. We found significant differences in the serological profiles of the 3 populations. The number of serum antibody epitopes in patients with alcohol use disorder during abstinence was increased compared with during active alcohol use. A decreased number and diversity of viral and bacterial antibody targets were detected in the sera of patients with AH, particularly those with a higher Child-Pugh score. In patients with AH, a decrease in the serum antiviral, but not antibacterial, antibody repertoire was associated with decompensation and mortality. Ninety-day mortality in AH could be predicted using a serum viral epitope signature., Conclusions: Abstinence from alcohol is associated with a significant increase in serum viral and bacterial antibody response. Decreased serum antiviral antibody repertoire is predictive of decompensation of liver disease and mortality in patients with AH., (Copyright © 2024 American Association for the Study of Liver Diseases.)
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- 2024
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28. Performance Enhancement of Self-Powered Electrochromic Device via a PEDOT:PSS Electrode Inherited with Intrinsic Roughness of Substrate.
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Tao M, Liu G, Wang Y, Wang J, Zhang W, and Li Z
- Abstract
The electrode optimization and rational design are of great significance for the performance enhancement of self-powered electrochromic devices (ECDs). It can be effectively enhanced by developing interfacial properties of electrodes, which can promote the internal ion transport within functional components consisting of an electrode, electrochromic layer, and electrolyte layer and thus obtain performance improvement of fabricated devices. This work aims to construct the electrode of poly(3,4-ethylenedioxythiophene): polystyrenesulfonate (PEDOT:PSS) on different substrates and promote interface performance of the prepared electrodes via inheriting the surface topography of substrates. Besides, the prepared PEDOT:PSS electrodes as a dual-function layer including the electrochromic and electrode layer are employed to assemble the ECDs. It is found that the intrinsic roughness of the paper substrate can facilitate the electrochemical performance of the prepared PEDOT:PSS electrode on it effectively, thereby showing a superior electrochemical surface area and diffusion coefficient as well as a lower charge-transfer resistance of 13.56 Ω. Similarly, for the prepared self-powered ECD on the paper substrate, it also indicates a high light absorption property (0.413), well-defined electrochromic contrast (33.09), fast switching (τ
c = 4.0 s, τb = 6.8 s), high coloration efficiency (92.275 cm2 C-1 ), high areal capacity (10.93 mAh m-2 ) at 0.01 mA cm-2 , and lower equivalent series resistance (176.2 Ω) in comparison to parallel ECDs on the PET and glass substrate. Leveraging the intrinsic roughness of the substrate is able to enhance the electrochemical performance of electrodes, which can also provide a new strategy for the construction of high-performance self-powered ECDs.- Published
- 2024
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29. Chitin-Assisted Synthesis of CuS Composite Sponge for Bacterial Capture and Near-Infrared-Promoted Healing of Infected Diabetic Wounds.
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Luo B, Xiong Y, Cai J, Jiang R, Li Y, Xu C, and Wang X
- Subjects
- Animals, Mice, Wound Infection drug therapy, Wound Infection microbiology, Wound Infection pathology, Wound Infection therapy, Reactive Oxygen Species metabolism, Bandages, Staphylococcal Infections drug therapy, Staphylococcal Infections pathology, Wound Healing drug effects, Staphylococcus aureus drug effects, Copper chemistry, Copper pharmacology, Escherichia coli drug effects, Anti-Bacterial Agents pharmacology, Anti-Bacterial Agents chemistry, Chitin chemistry, Chitin pharmacology, Diabetes Mellitus, Experimental pathology, Infrared Rays
- Abstract
Diabetic wounds are prone to recurrent infections, often leading to delayed healing. To address this challenge, we developed a chitin-copper sulfide (CuS@CH) composite sponge, which combines bacterial trapping with near-infrared (NIR) activated phototherapy for treating infected diabetic wounds. CuS nanoparticles were synthesized and incorporated in situ within the sponge using a chitin assisted biomineralization strategy. The positively charged chitin surface effectively adhered bacteria, while NIR irradiation of CuS generated reactive oxygen species (ROS) heat and Cu
2+ to rapidly damage the trapped bacteria. This synergistic effect resulted in an exceptional antibacterial performance against E. coli (∼99.9%) and S. aureus (∼99.3%). The bactericidal mechanism involved NIR-induced glutathione oxidation, membrane lipid peroxidation, and increased membrane permeability. In diabetic mouse models, the CuS@CH sponge accelerated the wound healing of S. aureus infected wounds by facilitating collagen deposition and reducing inflammation. Furthermore, the sponge demonstrated good biocompatibility. This dual-functional platform integrating bacterial capture and NIR-triggered phototherapy shows promise as an antibacterial wound dressing to promote healing of infected diabetic wound.- Published
- 2024
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30. Ultrathin 2D-2D MXene-LDH Interlayer with High Polysulfide Adsorption Ability for Advanced Li-S Batteries.
- Author
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Ge S, Zhao Q, Liu Y, Wang F, Wei G, Liu Y, and Xu B
- Abstract
Lithium-sulfur (Li-S) batteries are considered as promising energy storage systems due to the high energy density of 2600 W h kg
-1 . However, the practical application of Li-S batteries is hindered by the inadequate conductivity of sulfur and Li2 S, as well as the shuttle effect caused by polysulfides during the charge-discharge process. Introducing a conductive interlayer between the cathode and the separator to physically resist polysulfides represents an effective and straightforward approach to mitigate the shuttle effect in Li-S batteries. In this paper, an ultrathin (<1 μm) 2D-2D MXene-LDH interlayer with high polysulfide adsorption ability was introduced to Li-S batteries. The synergistic effect between MXene and layered double hydroxide greatly improved the adsorption effect of the interlayers: the conductive Ti3 C2 Tx MXene chemically adsorbs polysulfides and promotes their fast transfer, and the NiCo-LDH alleviates the restack of MXene and facilitates Li+ diffusion. After inserting the MXene-LDH interlayer, the Li-S batteries exhibit an enhanced specific capacity of 1137.6 mA h g-1 at 0.1 C and retain 622.6 mA h g-1 after 100 cycles. The ultrathin 2D-2D interlayer offers a feasible way for the development of highly efficient and lightweight interlayers in Li-S batteries.- Published
- 2024
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31. Fabrication of Flexible Wearable Mechanosensors Utilizing Piezoelectric Hydrogels Mechanically Enhanced by Dipole-Dipole Interactions.
- Author
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Wang K, Yao Y, Liu H, Wang J, Li X, Wang X, Yang R, Zhou H, and Hu X
- Subjects
- Humans, Tensile Strength, Acrylamide chemistry, Hydrogels chemistry, Wearable Electronic Devices, Acrylic Resins chemistry
- Abstract
Conductive hydrogels have been increasingly employed to construct wearable mechanosensors due to their excellent mechanical flexibility close to that of soft tissues. In this work, piezoelectric hydrogels are prepared through free radical copolymerization of acrylamide (AM) and acrylonitrile (AN) and further utilized in assembling flexible wearable mechanosensors. Introduction of the polyacrylonitrile (PAN) component in the copolymers endows the hydrogels with excellent piezoelectric properties. Meanwhile, significant enhancement of mechanical properties has been accessed by forming dipole-dipole interactions, which results in a tensile strength of 0.51 MPa. Flexible wearable mechanosensors are fabricated by utilizing piezoelectric hydrogels as key signal converting materials. Self-powered piezoelectric pressure sensors are assembled with a sensitivity ( S ) of 0.2 V kPa
-1 . Additionally, resistive strain sensors (gauge factor (GF): 0.84, strain range: 0-250%) and capacitive pressure sensors ( S : 0.23 kPa-1 , pressure range: 0-8 kPa) are fabricated by utilizing such hydrogels. These flexible wearable mechanosensors can monitor diverse body movements such as joint bending, walking, running, and stair climbing. This work is anticipated to offer promising soft materials for efficient mechanical-to-electrical signal conversion and provides new insights into the development of various wearable mechanosensors.- Published
- 2024
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32. Pickering emulsions stabilized by cellulose nanofibers with tunable surface properties for thermal energy storage.
- Author
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He Y, Wang C, Liu Y, Chen J, Wei Y, and Chen G
- Abstract
Cellulose nanofibers (CNFs) have been widely used as a renewable emulsifier to stabilize two immiscible liquids due to their intrinsic amphiphilicity and excellent emulsifying ability. However, it remains challenging to fully understand the effects of carboxylate group content and surface charge density on the emulsifying ability of CNFs and the stability of Pickering emulsion. Herein, carboxymethylated CNFs were extracted from bleached kraft pulp using etherification reaction and high-pressure homogenization, allowing for easy surface charge density and size adjustment by changing sodium chloroacetate content and homogenization cycles. The optimizing CNFs possessed a high Zeta potential (-71.2 mV) and a suitable carboxylate group content (1.81 mmol/g), which enabled CNFs to irreversibly adsorb at the hydrophobic paraffin wax (PW) droplet surface and form interfacial steric barriers, providing large electrostatic repulsion between the PW droplets against coalescence. Thus, the CNF-stabilized PW emulsions could be stored for more than 6 months. Moreover, the phase change enthalpy of the freeze-dried emulsion is as high as 193.7 J/g, which provides the emulsion to reversibly store and release heat. This work provides a comprehensive insight into the interfacial stability mechanism of CNFs as stabilizers and facilitates the potential application in thermal energy storage., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier B.V.)
- Published
- 2024
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33. Preparation of Alkali-Resistant Lignin Nanospheres Loaded with Silver Nanoparticles and Their Applications Toward Antibiosis and Printing.
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Fan Y, Ji H, Ji X, Tian Z, and Chen J
- Abstract
Lignin nanoparticles (LNPs) loaded with silver nanoparticles have exhibited significant application potential in antibacterial and catalytic fields. However, the high solubility of LNPs in silver ammonia solution makes it difficult to achieve the reduction of Ag
+ and the adsorption of silver nanoparticles. In this study, a protecting agent, terephthalic aldehyde (TA) is used to block lignin condensation and introduce aldehyde groups onto the lignin molecular backbone during lignin extraction. Furthermore, the TA stabilized lignin (TASL) is cross-linked with bisphenol A diglycidyl ether (BADGE) to enhance its alkali resistance performance and subsequently prepared into alkali-resistance BADGE- TASL hybrid LNPs (BADGE- TASL hy-LNPs) by anti-solvent precipitation and self-assembly. Because the presence of a large number of aldehyde groups in TASL compensates for the loss of phenolic hydroxyl groups caused by crosslinking reactions, a high loading of silver nanoparticles of 54.00% is obtained after redox reaction and adsorption in silver ammonia solution. When the BADGE-TASL hy-LNPs@Ag is used as an antibacterial agent, its inhibition efficiency reached ≈99%. Besides, the BADGE-TASL hy-LNPs@Ag can serve as a printing material for the preparation of conductive printing ink. Therefore, this study provides a strategy for lignin functionalization and application in printed electronics and antimicrobial fields., (© 2024 Wiley‐VCH GmbH.)- Published
- 2024
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34. Microwave Depolymerization of Lignin via Dynamic Vapor Flow Reaction System: HCOOH as Pretreatment Solvent or Reforming Solvent Vapor.
- Author
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Wang W, Fu Y, Chen Y, Miao H, Zheng H, Pan J, Wang Z, Liu Y, and Jiang W
- Abstract
Different forms of HCOOH in the depolymerization system play an important role in governing the monomeric products from lignin. We reported two strategies for the introduction of HCOOH to enrich the monophenols from kraft lignin by microwave-assisted depolymerization. The reaction of lignin models showed that HCOOH was in favor of the cleavage of C-O bonds (β-O-4 typically) and partial C-C bonds (C
α -Cβ ). Subsequently, Microwave-assisted depolymerization of lignin with two strategies was conducted via a designed dynamic vapor flow reaction system. Strategy A with HCOOH as pretreatment solvent showed excellent monophenols enrichment with total mass yields of 193.71 mg/g (lignin basis). Strategy B using HCOOH as reforming solvent vapor significantly increased the monophenols selectivity. It presented unique reforming and upgrading performance by generating catechol (42.59 mg/g, lignin basis) and homovanillic acid (17.58 mg/g, lignin basis). This study provided potential strategies for the efficient conversion of kraft lignin into high-value platform chemicals., (© 2024 Wiley-VCH GmbH.)- Published
- 2024
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35. Study on the enhancement of paper tensile strength and hydrophobicity by adding PEI-KH560 in pulp suspension.
- Author
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Zhao Y, Ni S, Gao Y, Zhang X, Ji X, and Zhang F
- Abstract
Novel eco-friendly strength agent has inspired much attention of researchers. Herein, the PEI-KH560 prepared by PEI (polyethyleneimine) and KH560 (γ-glycidyl ether propyl trimethoxysilane) was added in the pulp suspension to enhance the paper performance. The results showed that the m(PEI):m(KH560) ratio and PEI's molecular weight were closely related with the paper strength and hydrophobicity. The SEM morphology of paper surface showed that the fiber-fiber crosslinking reached the tightest, at the optimal m(PEI):m(KH560) ratio and PEI's molecular weight. The results showed that when the M
w (molecular weight) of PEI was 10,000 and the m(PEI):m(KH560) ratio was 1:2, the PEI-KH560 presented the best strengthening performance on the paper strength and hydrophobicity. Dry tensile index and wet tensile index could reach 29.9 N·m/g and 1.37 N·m/g after adding the PEI10000 -KH560 in pulp suspension before the paper formation. Further, the effect of process conditions (temperature, time, the addition amount, and pulp concentration) on the strength and hydrophobicity of paper network structure was investigated, after adding PEI-KH560 into the pulp suspension. It was of great significance for studying the mechanism between the chemical structures of PEI-KH560 and paper performance, which provided valuable theoretical practice on the preparation of novel strength agent., Competing Interests: Declaration of competing interest The authors declare that they have no known competing interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier B.V.)- Published
- 2024
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36. Structural engineering in hierarchical nanoarchitectures of metal-organic frameworks and their derivatives.
- Author
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Mao T, Fu H, and Shen K
- Abstract
Metal-organic frameworks (MOFs) have attracted much attention owing to their tuneable structures, high surface areas, and good functionalization. Nanoreactors derived from various MOFs are now widely used in heterogeneous catalysis, electrocatalysis and photocatalysis. The nanoarchitectures of MOFs and their derivatives have a great impact on mass and energy transfer pathways, thus affecting the activity and selectivity of the catalysts. In this review, we intend to provide a universal survey of reported methods to synthesize MOF-based core-satellite, core-shell, yolk-shell and hollow-shell structures or their derivatives in recent years and present a continuous evolution among them. We hope that this review could provide some perspectives for exploring new facile methods to prepare different hierarchical nanoarchitectures of MOFs or their derivatives.
- Published
- 2024
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37. Construction of Vine-Inspired Antimicrobial Filter with Multiscale 3D Nanonetwork for High-Efficiency Air Filtration.
- Author
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Xiong Y, Cai J, Wu Z, Zheng R, Wang L, Wang D, and Wang X
- Abstract
Enhancing the antimicrobial activity of high-efficiency particulate air (HEPA) filters while maintaining filtration efficiency and pressure drop is currently an urgent issue for preventing the spread of pathogenic microorganisms. Herein, inspired by vines which can enwind fences to fix as well as decorate them, a flexible antimicrobial chitin nanofiber (ChNF@CuO
x ) was fabricated and loaded onto the rigid glass fiber (GF) skeleton of a HEPA filter. Through the physical interaction, ChNF@CuOx was spontaneously enwound on GF, and ChNF@CuOx itself interweaved to form a new nanonetwork between the GF skeleton. The obtained antimicrobial air filter (ChNF@CuOx /GF) with a unique nanonetwork increased the filtration efficiency of the HEPA filter. Meanwhile, it possessed excellent inactivation ability against Staphylococcus aureus , Escherichia coli , and Candida albicans due to the urchin-like in situ grown CuOx on the ChNF. In particular, the oxygen vacancies generated unexpectedly in CuOx enabled it to produce reactive oxygen species. After eight cycles of antimicrobial assays, the antimicrobial rates of bacteria were higher than 99.5%, and those of fungi were greater than 98.3%. The successful synthesis of antimicrobial fibers and the construction of multidimensional nanoscale structures through a simple postprocessing method provide a new design mentality for antimicrobial functionalization for HEPA filters.- Published
- 2024
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38. Crosslinking reactions of a model aminated lignin compound as a platform for building thermosetting polymers for lignin-based bio adhesives.
- Author
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Ghahri S, Wibowo ES, and Park BD
- Abstract
As millions of tons of kraft lignin are being wasted, a potential application is to use its crosslinking reactions to build thermosetting bio adhesives. However, the crosslinking reactions between lignin molecules are not fully understood. The present study aims to elucidate the crosslinking reactions of the model lignin compound guaiacylglycerol-β-guaiacyl ether (GGE) via one-step hydroxymethylation/ amination with formaldehyde and diethylenetriamine (DETAM), or one-step glyoxylation/ amination with glyoxal and DETAM via liquid NMR techniques such as
1 H NMR,13 C NMR, 2D1 H-13 C, and1 H-15 N HSQC NMR. Specifically, the 2D1 H-13 C HSQC NMR spectra confirm the presence of -CH2 -NH- with a chemical shift of1 H 2.6-3.6/13 C 40-60 ppm, and the formation of methylene linkages via the crosslinking reaction. Also, the 2D1 H-15 N HSQC NMR spectra clearly detect the formation of amide and imine bonds at1 H 7.8/15 N 110 and1 H 8.07/15 N 121.5 ppm from the crosslinked GGE., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)- Published
- 2024
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39. Total Biosynthesis of Circular Bacteriocins by Merging the Genetic Engineering and Enzymatic Catalysis.
- Author
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Zhao J, Shi F, Huang Y, Hou Y, Jin P, and Hu SQ
- Subjects
- Genetic Engineering, Anti-Bacterial Agents biosynthesis, Anti-Bacterial Agents chemistry, Biocatalysis, Cyclization, Bacteriocins genetics, Bacteriocins chemistry, Bacteriocins biosynthesis, Bacteriocins metabolism, Escherichia coli genetics, Escherichia coli metabolism
- Abstract
Circular bacteriocins are known for their structural stability and effective antimicrobial properties, positioning them as potential natural food preservatives. However, their widespread application is impeded by restricted availability. This research developed a total biosynthesis platform for circular bacteriocins, with a focus on AS-48 by involving recombinant production of the linear precursor in Escherichia coli , followed by enzymatic cyclization of the precursor into cyclic AS-48 using the ligase butelase-1 in vitro . An important discovery is that, aside from fusion tags, the C-terminal motif LE and LEKKK also could affect the expression yield of the precursor. This biosynthesis platform is both versatile and high-yielding, achieving yields of 10-20 mg/L of AS-48. Importantly, the biosynthetic AS-48 exhibited a secondary structure and antimicrobial activities comparable to those of the native molecules. As such, this work proposes an effective synthetic approach for circular bacteriocins, facilitating their advancement and application in the food industry.
- Published
- 2024
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40. Impact of hydrophobically modified cellulose nanofiber on the stability of Pickering emulsion containing insect protein.
- Author
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Fan R, Wang W, Zhang R, Zhu M, Liu W, and Liu P
- Abstract
Background: Cellulose nanofiber (CNF) is an ideal Pickering emulsion stabilizer because of its high aspect ratio and flexibility. CNF was hydrophobically modified by dodecenyl succinic anhydride and used to stabilize the simulated food emulsion system containing insect protein. The prepared dodecenyl succinate nanofiber (D-CNFs) was characterized by contact angle and laser particle size analyzer. The stability of the emulsion system under different conditions was characterized by zeta potential and appearance observation. Lastly, in vitro digestion simulation experiments were carried out to investigate whether the addition of D-CNFs had an effect on the digestion and absorption of oil., Results: The modification process for dodecenyl succinic anhydride to CNFs was that the system temperature was 40 °C, the system pH value was 8.5 and the reaction time was 6 h. The water contact angle of the modified CNFs increased to 83.2 ± 0.9°. D-CNFs were introduced into the simulated food emulsion system containing insect protein. The increase in the concentration of D-CNFs in the aqueous phase promoted the stability of the simulated emulsion system. Increasing the ratio of insect protein was not conducive to the stability of the emulsion. The final fat digestibility of the emulsion with D-CNFs was lower than that of the emulsion without D-CNFs., Conclusion: Overall, the analysis and characterization results show the potential of the modified CNF as a food simulant emulsion stabilizer containing insect protein, which can be used for the development of specific functional foods. © 2024 Society of Chemical Industry., (© 2024 Society of Chemical Industry.)
- Published
- 2024
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41. Ultrastrong Nanopapers with Aramid Nanofibers and Silver Nanowires Reinforced by Cellulose Nanofibril-Assisted Dispersed Graphene Nanoplates for Superior Electromagnetic Interference Shielding.
- Author
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Hu F, Kui M, Zeng J, Li P, Wang T, Li J, Wang B, Wu C, and Chen K
- Abstract
High-strength, lightweight, ultrathin, and flexible electromagnetic interference (EMI) shielding materials with a high shielding effectiveness (SE) are essential for modern integrated electronics. Herein, cellulose nanofibrils (CNFs) are employed to homogeneously disperse graphene nanoplates (GNPs) into an aramid nanofiber (ANF) network and silver nanowire (AgNW) network, respectively, producing high-performance nanopapers. These nanopapers, featuring nacre-mimetic microstructures and layered architectures, exhibited high tensile strength (601.11 MPa) and good toughness (103.56 MJ m
-3 ) with a thickness of only 24.58 μm. Their specific tensile strength reaches 447.59 MPa·g-1 ·cm3 , which is 1.74 times that of titanium alloys (257 MPa·g-1 ·cm3 ). The AgNW/GNP composite conductive layers exhibit an electrical conductivity of 12010.00 S cm-1 , providing the nanopapers with great EMI shielding performance, achieving an EMI SE of 63.87 dB and an EMI SE/t of 25978.80 dB cm-1 . The nanopapers also show reliable durability, retaining a tensile strength of 500.96 MPa and an EMI SE of 57.59 dB after 120,000 folding cycles. Additionally, they have a good electrical heating performance with a fast response time, low driving voltage, effective deicing capability, and reliable heating capacity in water. This work presents a strategy to develop a high-performance nanopaper, showing great potential for applications in electromagnetic compatibility, national defense, smart electronics, and human health.- Published
- 2024
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42. Pre-carbonized nickel-metal organic frameworks to enable lithium-sulfur reactions.
- Author
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Wu Z, Zhang Y, Takyi-Aninakwa P, Hu Y, Lu Z, and Song Y
- Abstract
Metal-organic frameworks, a type of porous architecture, have caught wide attention for their pore-rich and special metal-active centres. However, the non-conductive MOFs show limitations in lithium-sulfur batteries (LSBs). Herein, we first synthesized a lamellar nickel-based MOF and subsequently conducted pre-carbonization to attain a conductive Ni-carbon (Ni@C) catalyst. On account of the retained three-dimensional architecture and elevated conductivity, using Ni@C as the interlayer can realize polysulfide-regulated and kinetically promoted LSBs. This work offers a viable strategy to extend the implementation of MOFs in state-of-the-art LSB systems.
- Published
- 2024
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43. Lysine-mediated surface modification of cellulose nanocrystal films for multi-channel anti-counterfeiting.
- Author
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Hu S, Yue F, Peng F, Zhou X, Chen Y, Song T, and Qi H
- Abstract
Utilizing advanced multiple channels for information encryption offers a powerful strategy to achieve high-capacity and highly secure data protection. Cellulose nanocrystals (CNCs) offer a sustainable resource for developing information protection materials. In this study, we present an approach that is easy to implement and adapt for the covalent attachment of various fluorescence molecules onto the surface of CNCs using the Mannich reaction in aqueous-based medium. Through the use of the Mannich reaction-based surface modification technique, we successfully achieved multi-color fluorescence in the resulting CNCs. The resulting CNC derivatives were thoroughly characterized by two dimensional heteronuclear single quantum coherence nuclear magnetic resonance (2D HSQC NMR) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy and X-ray photoelectron (XPS) spectroscopy. Notably, the optical properties of CNCs were well maintained after modification, resulting in films exhibiting blue and red structural colors. This enables the engineering of highly programmable and securely encoded anti-counterfeit labels. Moreover, subsequent coating of the modified CNCs with MXene yielded a highly secure encrypted matrix, offering advanced security and encryption capabilities under ultraviolet, visible, and near-infrared wavelengths. This CNC surface-modification enables the development of multimodal security labels with potential applications across various practical scenarios., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)
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- 2024
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44. Facile design of structurally robust, highly conductive and well-flexible hybrid film based on MXene, cellulose nanofiber and poly (3,4-ethylenedioxythiphoenes):polystyrene sulfonate for supercapacitors.
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Xu H, Zhu J, Zhao T, Ni S, Yang Y, Hu Q, and Jin X
- Abstract
Robust, conductive and flexible electrode materials have been the focus of attention in portable, wearable electronics. However, it is still a significant challenge to achieve synergistic development of multiple properties simultaneously. Herein, we propose a combination of microscale design and nanostructures strategy to prepare MXene/cellulose nanofiber-poly (3,4-ethylenedioxythiphoenes):polystyrene sulfonate (Ti
3 C2 Tx /CNF-PEDOT:PSS, TC-P) hybrid film by a simple in-situ polymerization and vacuum filtration process. CNF serves as the supporting skeleton of PEDOT:PSS, effectively mitigating its self-aggregation and structural deformation due to the expansion/contraction of the polymer network. And the CNF-PEDOT:PSS composite is capable to open up the interlayer space of Ti3 C2 Tx , which reduces the self-stacking of Ti3 C2 Tx nanosheets. The strong interactions among the three components enable the hybrid film electrode to possess both flexibility and high electrochemical properties. As a result, the film electrode exhibits a remarkable tensile strength of 77.4 MPa and an excellent conductivity of 162.5 S cm-1 , as well as an outstanding areal specific capacitance of 896 mF cm-2 at 4 mA cm-2 . Moreover, the assembled symmetric supercapacitor (SSC) device displays a large areal energy density of 62 µWh cm-2 at a power density of 800 µW cm-2 and demonstrates a long cycle life with 85.1 % capacitance retention after 10,000 GCD cycles. This study provides an effective strategy to balance mechanical flexibility and electrochemical properties, providing an inspiration to prepare flexible electrodes that are widely applied in a new generation of portable, wearable electronics., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)- Published
- 2024
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45. Porous cationic cellulose beads prepared by homogeneous in-situ quaternization and acid induced regeneration for water/moisture absorption.
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Xu F and Cho BU
- Abstract
Chemical modification is a reliable and efficient strategy for designing cellulose-based functional materials. Herein, porous quaternized cellulose beads (QCBs) as cationic superabsorbent were fabricated by homogeneous in-situ chemical grafting cellulose molecular chains with glycidyl trimethylammonium chloride (GTAC) in tetraethylammonium hydroxide (TEAOH)/urea aqueous solution followed by acetic acid induced regeneration. The influence of GTAC dosage on the physicochemical-structural properties of cationic QCBs was deeply investigated. Results revealed that cotton liner could well-dissolved in TEAOH/urea aqueous solution, leading to a homogeneous and efficient quaternization medium for cellulose, thereby giving the high DS and positive charge density for quaternized cellulose. NMR results demonstrated the main substitution of GTAC groups at 2-OH and 6-OH positions of the cellulose chains during quaternization reaction. With increasing GTAC dosage, the network skeleton of QCBs gradually transformed from thick fibrils to thin aggregates, as well as enhanced pore volumes and hydrophilicity. Accordingly, QCBs-1.5 with high pore volume (99.70 cm
3 /g) exhibited excellent absorption capacity and efficiency, absorbing 122.32 g of water and 0.45 g of moisture per gram of the beads in 20 min. This work not only offers a simple strategy for the homogeneous quaternization modification of cellulose, but also provides a porous cellulose-based cationic superabsorbent material., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)- Published
- 2024
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46. Ultra-strong and tough cellulose-based conductive hydrogels via orientation inspired by noodles pre-stretching.
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Jing X, Zhang S, Zhang F, Chi C, Cui S, Ding H, and Li J
- Abstract
Due to the unsatisfactory mechanical properties of natural polymer-based conductive hydrogels, their applications are limited. Shaanxi Biangbiang noodles can be toughened by applying external mechanical forces through stretching and beating movements; this process provides inspiration for the preparation of high-strength hydrogels. In this paper, we propose a strategy for the preparation of ultrastrong and ultratough conductive hydrogels by directional prestretching and solvent exchange. Neatly arranged fiber bundles containing many intermolecular hydrogen bonds and metal ion coordination bonds are successfully constructed inside the prepared hydrogels. The hydrogel has exceptional mechanical properties, with a fracture stress exceeding 50 MPa, fracture strain approaching 105 %, fracture toughness exceeding 30 MJ m
-3 , and high conductivity reaching 11.738 ± 0.06 mS m-1 . Impressively, the hydrogel can maintain its high mechanical properties after being frozen at an ultralow temperature of -80 °C for 7 days. Compared with other tough hydrogels, natural tendons and synthetic rubbers, the hydrogel exhibits excellent mechanical properties. The cellulose-based conductive hydrogel prepared in this study can be applied to robotic soft tissues (such as the Achilles tendon) that require high strength and are operated in extreme environments., Competing Interests: Declaration of competing interest The authors declare no competing financial interest., (Copyright © 2024. Published by Elsevier Ltd.)- Published
- 2024
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47. Aqueous AlCl 3 /ZnCl 2 solution room-induced the self-growing strategy of expanded topological network for cellulose/polyacrylamide-based solid-state electrolytes.
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Li X, Wang Y, Tian Y, Wang Z, Zhang L, and Ma J
- Abstract
The green synthesis strategy for cellulose-containing hydrogel electrolytes is significant for effectively managing resources, energy, and environmental concerns in the contemporary world. Herein, we propose an all-green strategy using AlCl
3 /ZnCl2 /H2 O solvent to create cellulose/polyacrylamide-based hydrogel (AZ-Cel/PAM) with expanded hierarchical topologies. The aqueous AlCl3 /ZnCl2 facilitates the efficient dissolution of cellulose at room temperature, and the dispersed Al3+ -Zn2+ ions autocatalytic system catalyzes in-situ polymerization of acrylamide (AM) monomer. This expands the AM network within the cellulose framework, forming multiple bonding interactions and stable ion channels. The resulting hybrid hydrogel exhibits improved mechanical properties (tensile strength of 56.54 kPa and compressive strength of 359.43 kPa) and enhanced ionic conductivity (1.99 S/m). Furthermore, it also demonstrates excellent adhesion, freeze resistance (-45 °C), and water retention capabilities. Quantum simulations further clarify the mechanical composition and ion transport mechanism of AZ-Cel/PAM hydrogels. The assembled supercapacitor with the hydrogel electrolyte, demonstrates an ideal area-specific capacitance of 203.80 mF/cm2 . This all-green strategy presents a novel approach to developing sustainable energy storage devices., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)- Published
- 2024
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48. Coordinated d-p hybridized hcp@fcc NiRu alloy doped by interstitial atoms for boosting urea-assisted simulated seawater electrolysis at industrial current densities.
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Zhou X, Wei G, Liu C, Zhao Q, Gao H, Wang W, Zhao X, Zhao X, and Chen H
- Abstract
The production of hydrogen through seawater electrolysis has recently garnered increasing concern. However, hydrogen evolution reaction (HER) by alkaline seawater electrocatalysis is severely impeded by the slow H
2 O adsorption and H* binding kinetics at industrial current densities. Herein, a face-centered cubic/hexagonal close packed (fcc/hcp) NiRu alloy heterojunction was fabricated on Ni foam (N doped NiRu-inf/NF) by a low-temperature nitrogen plasma activation. Simultaneously, nitrogen atoms are introduced into the alloy to facilitate d-p hybridization. When N doped NiRu-inf/NF is integrated into a dual-electrode cell for urea-assisted seawater electrolysis, it achieves 100 mA cm-2 with an ultra-low voltage of 1.36 V and excellent stability. Density functional theory (DFT) verifies that the robust d-p hybridization among Ni, Ru and N exhibits more energy level matching for H2 O molecule adsorption at the Ru sites, while simultaneously reducing the interaction between H* and Ni sites in N-doped NiRu-inf., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Inc.)- Published
- 2024
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49. Optimizing paper sludge content and particle size to enhance particleboard properties.
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Mehrvan K, Jonoobi M, Ashori A, and Ahmadi P
- Abstract
The pulp and paper industry generates vast quantities of paper sludge, posing significant environmental challenges due to its disposal in landfills or incineration. This study explores the potential of valorizing paper sludge by incorporating it into particleboard production. It aims to optimize sludge content and particle size to enhance board properties-a novel approach to waste management in the wood composites industry. Through systematic variation of sludge content (0-25%) and particle size (< 0.5 to > 2 mm), we assessed the mechanical and physical properties such as internal bond strength (IB), modulus of rupture (MOR), modulus of elasticity (MOE), water absorption (WA), and thickness swelling (TS). The findings indicate that incorporating paper sludge at moderate levels (5-15%) with optimized particle sizes (< 1 mm) significantly improves the mechanical properties of the particleboard, including increased IB, MOR, and MOE while reducing WA and TS. Principal Component Analysis (PCA) further supported these results, revealing that higher-density boards with enhanced mechanical properties absorb less water, highlighting the interrelationship between structural integrity and moisture resistance. The PCA also identified thickness swelling as an independent factor, suggesting that while mechanical properties can be optimized, additional strategies are needed to control swelling. In conclusion, this study demonstrates that up to 15% paper sludge can be effectively used in particleboard production without compromising quality, provided particle size is carefully controlled. This approach not only offers a sustainable solution for managing paper sludge but also contributes to the development of eco-friendly composite materials, aligning with circular economy principles., (© 2024. The Author(s).)
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- 2024
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50. Lignin-containing cellulose nanocrystals enhanced electrospun polylactic acid-based nanofibrous mats: Strengthen and toughen.
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Ouyang C, Zhang H, Zhu Y, Zhao J, Ren H, and Zhai H
- Abstract
Biodegradable polylactic acid (PLA) nanofibrous mats prepared by electrospinning serve as suitable packaging materials. However, their practical applications are limited by their weak mechanical properties, poor thermal stability, and high cost. In this study, green and low-cost lignin-containing cellulose nanocrystals (LCNCs) with different lignin contents were developed and employed as reinforced materials to synergistically enhance the thermal, mechanical, and hydrophobic properties of PLA electrospun nanofibrous mats. The presence of moderate lignin improved the interfacial compatibility between the LCNCs and PLA, resulting in excellent mechanical properties of the nanofibrous mats. Compared to pure PLA mats, the tensile strength of the composites reached up to 21.0 MPa, representing a 6.6-fold increase. Its toughness was synchronously enhanced by 16 times, reaching a maximum of 3.6 MJ/m
3 . The maximum decomposition temperature of PLA/LCNCs electrospun nanofibrous mats increased from 339 °C to 365 °C. Furthermore, the increase in lignin in the LCNCs positively contributed to improving the hydrophobicity of the PLA/LCNCs electrospun nanofibrous mats. This bio-based strategy of LCNCs employed in the enhancement of fully bio-based PLA nanofibrous mats offers a viable approach for the advancement of packaging films., Competing Interests: Declaration of competing interest We declare that we have no financial and personal relationships with other people or organizations that can inappropriately influence this work, there is no professional or other personal interest of any nature or kind in any product, service and/or company that could be construed as influencing the position presented in, or the review of, the manuscript entitled., (Copyright © 2024 Elsevier B.V. All rights reserved.)- Published
- 2024
- Full Text
- View/download PDF
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