1. Excited-State Lifetime Modulation by Twisted and Tilted Molecular Design in Carbene-Metal-Amide Photoemitters
- Author
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Qinying Gu, Florian Chotard, Julien Eng, Antti-Pekka M. Reponen, Inigo J. Vitorica-Yrezabal, Adam W. Woodward, Thomas J. Penfold, Dan Credgington, Manfred Bochmann, Alexander S. Romanov, Eng, Julien [0000-0002-7118-7242], Reponen, Antti-Pekka M [0000-0002-2076-410X], Penfold, Thomas J [0000-0003-4490-5672], Credgington, Dan [0000-0003-4246-2118], Bochmann, Manfred [0000-0001-7736-5428], Romanov, Alexander S [0000-0003-2617-6402], and Apollo - University of Cambridge Repository
- Subjects
34 Chemical Sciences ,General Chemical Engineering ,Materials Chemistry ,General Chemistry - Abstract
Funder: Samsung Display Corp., Carbene-metal-amides (CMAs) are an emerging class of photoemitters based on a linear donor-linker-acceptor arrangement. They exhibit high flexibility about the carbene-metal and metal-amide bonds, leading to a conformational freedom which has a strong influence on their photophysical properties. Herein we report CMA complexes with (1) nearly coplanar, (2) twisted, (3) tilted, and (4) tilt-twisted orientations between donor and acceptor ligands and illustrate the influence of preferred ground-state conformations on both the luminescence quantum yields and excited-state lifetimes. The performance is found to be optimum for structures with partially twisted and/or tilted conformations, resulting in radiative rates exceeding 1 × 106 s-1. Although the metal atoms make only small contributions to HOMOs and LUMOs, they provide sufficient spin-orbit coupling between the low-lying excited states to reduce the excited-state lifetimes down to 500 ns. At the same time, high photoluminescence quantum yields are maintained for a strongly tilted emitter in a host matrix. Proof-of-concept organic light-emitting diodes (OLEDs) based on these new emitter designs were fabricated, with a maximum external quantum efficiency (EQE) of 19.1% with low device roll-off efficiency. Transient electroluminescence studies indicate that molecular design concepts for new CMA emitters can be successfully translated into the OLED device.
- Published
- 2022