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Objective: Although HTLV-1 is associated with severe diseases, there is ongoing vertical transmission since prenatal HTLV screening is not implemented in countries where the virus is present. We performed a cross-sectional analysis to verify the impact of counseling pregnant HTLV-1 seropositive women, who participate in the GIPH cohort study in Brazil, on this vertical transmission. Methods: GIPH study started in 1997 as an open prevalent cohort of HTLV-positive individuals. Children born from HTLV-1 seropositive women were divided into: (1) born before and (2) after the participation of mothers in the GIPH cohort (“GIPH babies”). The pregnant women participating in the study were counseled in order to prevent viral transmission, with recommendations of avoiding breastfeeding, giving infant formula, and preferably having the delivery by cesarean section. Results: We identified 54 children born of HTLV seropositive mothers. 3/21 (14.3%) of the children born from mothers who received no counseling were found positive for HTLV-1, in contrast to 1/18 (5.6%) of the “GIPH babies”, whose mothers received counseling. 15 children were not tested, either due to the family’s refusal or impossibility to locate them. Discussion: We found that it was worthwhile to counsel the mothers, since, as previously reported in the literature, we could observe a decline in the vertical transmission, which demonstrates the importance of prenatal screening of the virus. These actions should be widespread in countries where HTLV is present, in order to avoid the silent transmission of HTLV and future diseases in children born from positive mothers.

In this paper, we present a new design for a 1 atm gas-mixing furnace using the gas mixture CO–CO2–SO2. This furnace can simulate disequilibrium processes such as magmatic and volcanic degassing. Here, we present the technical aspects of the design. The furnace can sustain temperatures of up to 1650 ∘C and has a hot zone that spans 200 mm vertically, where the hotspot is determined to be ∼ 32 mm below the midpoint of the furnace enclosure. The four mass flow controllers are individually calibrated and accurate to within 0.8 % of the specified value. The fO2 is accurately reproduced in the furnace within ±0.002 log units, as calibrated by the Fe–FeO reaction across the iron–wüstite (IW) buffer at 1300 ∘C. The furnace can reliably simulate dynamic conditions, where the fO2 can be modulated at a maximum rate of 2.0 log units min−1 by varying the gas mixture. A delay of 40 s is observed to attain the fO2 calculated from the gas mixture, at the hotspot. A series of safety measures to protect the user from exposure to the toxic gases are detailed. In our experiments, the furnace is used to determine sulfur isotope fractionation factors among melt, sulfide, and the gas phase, within a magmatic context, using either crystals of olivine or silica glass tubes. The furnace has the potential to investigate various other dynamic high-temperature reactions occurring on Earth.

International audience; The paper reports a system combining Solar Thermal Collectors (STC), Borehole Thermal Energy Storage (BTES), a Heap Pump (HP) and a backup boiler for space heating and Domestic Hot Water (DHW) production. The integration of the components and the overall control strategy are described. The system is flexible, being able to select the best thermal source and to use it directly or through a HP, while only the excess solar heat is stored into the BTES. The contribution of every subsystem to the energy mix is discussed. For a "reference configuration" combining the three subsystems ("Design D") and characterized by heating and DHW needs of 510.5 MWh.y − 1 and 226.7 MWh.y − 1 respectively, a BTES volume of 15000 m 3 , a distance between boreholes of 3 m, a STC area of 2500 m 2 , and a solar tank volume of 100 m 3 , the system uses 274 units of gas and electricity to provide 1000 units of heating and DHW. This reference configuration outperforms any alternative design: Design A (STC only), Design B (STC and HP) and design C (STC and BTES) would respectively require 612, 480 and 591 units of gas and electricity to do so. A one-at-a-time analysis reveals that the STC area, azimuth and inclination, the solar tank volume, the BTES volume, the borehole density and the HP power are key parameters to the overall system performance.

International audience; The metamodel-based approach (also referred to as the surrogate approach) is commonly applied to overcome the computational burden of numerical models that are used to simulate the evolution of reservoir fluids and pressures in response to any production scheme. In this study, we propose an adaptation of this approach for aquifer thermal energy storage (ATES) systems. ATES systems are characterized by cyclic loading/unloading production schemes, which result in a strong similarity in the dynamics of the intercyclic evolution of variables such as the temperature at the producer well. Instead of training several metamodels, i.e., one per cycle (“independent” metamodelling approach), we take advantage of the intercyclic similarity to train a single metamodel within the setting of multifidelity cokriging (“multicyclic” metamodelling approach). To explore the predictive performance of this approach, we applied a random subsampling validation approach multiple times to 300 simulation results of a realistic ATES system in the Paris basin by considering three characteristics, i.e., the minimum and maximum temperature, and the rate of temperature decrease at each cycle. Numerical experiments with varying training dataset sizes (from 33 to 66% of the total number of results) and using 100 test samples show that (1) the predictive error of the multicyclic metamodelling reaches lower levels (by 20–50%) than that of the independent approach; (2) this higher predictive performance is achieved while saving computational time cost because the training phase only needs a few tens of “complete” simulations (run over all cycles) together with a few hundreds of “partial” simulations (stopped at the first cycle); the latter simulations are less expensive to evaluate because of shorter simulated time.

International audience; The development of an integrated theory of subsurface drainage based on hydrology and hydrogeology concepts is presented. The historical context, the main hypothesis derived from the Boussinesq equation and the validation of the model predictions are discussed. Theoretical developments of this equation demonstrate that a single parameter (σ)-a combination of soil and drainage system properties-is sufficient for predicting the dynamics of subsurface drain flow rates. We also demonstrate that these drain flow rates are a function of the level of water replenishment in the system (classically the water table elevation), of the recharge intensity of the aquifer and of a buffer function related to the swelling or deflation of the water table shape during recharge events. For values of σ > 1, the buffer role of the water table is negligible. In that case approx. 13% of the water table recharge contributes to the flow rate, which is shown to explain the observed disconnection between water table elevations and peak flow rates at the outlet of classic agricultural drainage systems and to predict these peak flow rates accurately. A modelling approach based on this theory and validated experimentally (SIDRA model) allowed us to test the quality of the peak flow prediction. The SIDRA model also includes a surface runoff module and has been coupled to different modelling tools and used to analyse the impacts of subsurface drainage on water quality. The approach contributed towards the development of tools that helped to connect better the drainage systems to the hydrological functioning of watersheds.

International audience; Wetlands are the largest natural source of methane (CH4) to the atmosphere. The eddy covariance method provides robust measurements of net ecosystem exchange of CH4, but interpreting its spatiotemporal variations is challenging due to the co-occurrence of CH4 production, oxidation, and transport dynamics. Here, we estimate these three processes using a data-model fusion approach across 25 wetlands in temperate, boreal, and Arctic regions. Our data-constrained model—iPEACE—reasonably reproduced CH4 emissions at 19 of the 25 sites with normalized root mean square error of 0.59, correlation coefficient of 0.82, and normalized standard deviation of 0.87. Among the three processes, CH4 production appeared to be the most important process, followed by oxidation in explaining inter-site variations in CH4 emissions. Based on a sensitivity analysis, CH4 emissions were generally more sensitive to decreased water table than to increased gross primary productivity or soil temperature. For periods with leaf area index (LAI) of ≥20% of its annual peak, plant-mediated transport appeared to be the major pathway for CH4 transport. Contributions from ebullition and diffusion were relatively high during low LAI (

A multichannel seismic reflection profile acquired during the SISMAORE cruise (2021) provides the first in-depth image of the submarine volcanic edifice, named Fani Maore, that formed 50 km east of Mayotte Island (Comoros Archipelago) in 2018–2019. This new edifice sits on a ∼140 m thick sedimentary layer, which is above a major, volcanic layer up to ∼1 km thick and extends over 120 km along the profile. This volcanic unit is made of several distinct seismic facies that indicate successive volcanic phases. We interpret this volcanic layer as witnessing the main phase of construction of the Mayotte Island volcanic edifice. A ∼2.2–2.5 km thick sedimentary unit is present between this volcanic layer and the top of the crust. A complex magmatic feeder system is observed within this unit, composed of saucer-shape sills and seal bypass systems. The deepest tip of this volcanic layer lies below the top-Oligocene seismic horizon, indicating that the volcanism ofMayotte Island likely began around 26.5Ma, earlier than previously assumed., Un profil de sismique réflexion multitrace acquis lors de la campagne océanographique SISMAORE (2021) apporte la première image en profondeur du volcan sous-marin Fani Maore, qui s’est formé à 50 km à l’est de l’île de Mayotte (archipel des Comores) en 2018–2019. Ce nouvel édifice repose sur une première couche sédimentaire d’environ 140 m d’épaisseur au-dessus d’une couche volcanique majeure épaisse de 1 km et qui s’étend sur 120 km le long du profil. Cette dernière unité volcanique est constituée de plusieurs faciès sismiques distincts qui indiquent des phases volcaniques successives. Nous interprétons cette couche volcanique comme le témoin de la phase principale de construction de l’édifice volcanique de l’île de Mayotte. Une couverture sédimentaire de 2.2–2.5 km d’épaisseur est présente entre cette couche volcanique et le toit de la croûte. On y observe de nombreux sills en forme de soucoupe ainsi que des zones à faciès de remontées de fluides, dessinant un système d’alimentation magmatique complexe sous la principale couche volcanique. L’extrémité la plus profonde de cette couche volcanique se place en dessous de l’horizon sismique de l’Oligocène supérieur et indique que le volcanisme de l’île de Mayotte a probablement commencé vers 26.5 Ma, plus tôt que ce qui était supposé auparavant.

Conceptual models of orogenic accretionary prisms assume that peak temperatures (Tmax⁡) increase towards the internal domains as crustal rocks are accreted from the lower to the upper plate. However, the recognition of pre-orogenic heating events in mountain belts questions the magnitude of thermal overprint during nappe stacking. Using Raman spectroscopy on carbonaceous material (RSCM) to calculate Tmax⁡, we have investigated the thermal record of Lower Jurassic to Eocene strata exposed along six stratigraphic sections at the front of the Digne Nappe (SW Alps), from the Devoluy Massif to the Castellane Arc. Our results highlight two groups of depth-dependent temperatures: (1) a regionally extensive and constant Tmax⁡ up to 300–330 ∘C measured in the Jurassic succession and (2) regionally variable lower temperatures (<150 ∘C) recorded either in the Upper Mesozoic or the syn-orogenic sequence. Modelling shows that the highest palaeotemperatures were achieved during the Early Cretaceous (∼ 130 Ma), associated with the Valaisan–Vocontian rifting, while the lowest Tmax⁡ reflect post-rift thermal relaxation in the Alpine foreland basin. This study provides a striking new example where mid-crustal palaeotemperatures measured in sediments accreted from the downgoing plate are inherited. An estimated peak thermal gradient of 80–90 ∘C km−1 requires a crustal thickness of 8–10 km during the Early Cretaceous, hence placing constraints for tectonic reconstruction of rift domains and geophysical interpretation of current crustal thickness in the SW Alps. These results call for the careful interpretation of palaeothermal data when they are used to identify past collisional thermal events. Where details of basin evolution are lacking, high-temperature records may be misinterpreted as syn-orogenic, which can in turn lead to an overestimation of both orogenic thickening and horizontal displacement in mountain belts.

International audience; As decisions on climate change adaptation involve stakeholders with different values, beliefs and attitudes (VBA), decision outcomes depend on how stakeholders interact and how power is distributed. In this paper, we explore the VBA of stakeholders involved in three water management projects focusing on dams, micro-reservoirs, or wetlands in a Peruvian watershed facing droughts. We apply a framework with the core ideas of the hydrosocial cycle, the decision context perspective, and the VBA hierarchy to show how stakeholders’ perspectives and power influence practices on the ground. The analysis of VBA reveals three different perspectives on water management held by different stakeholder groups. First, a community-based perspective, frequent among local communities, favors micro-reservoirs managed by communities. Second, an infrastructure-based perspective, frequent among public sector stakeholders, shows a preference for dams managed by the private sector. Third, a nature-based perspective, with a preference for wetlands managed by the public sector, is found across stakeholder groups. In the three water management projects, different power distributions determine which VBA dominate and influence practices on the ground. Dams on the ground represent power from the public and private sectors, while micro-reservoirs represent local grassroot control. In the wetland project, the outcomes of the evolving hydrosocial cycle are still unclear and will depend on how multiple perspectives are considered. Examining and questioning the decision context in which adaptation occurs can help excluded stakeholders achieve more power and agency and tackle the fundamental question of ‘adaptation of what and for whom’.

Flood damage assessment is crucial for evaluating flood management policies. In particular, properly assessing damage to agricultural assets is important because they are complex economic systems particularly exposed to floods. The modelling approaches used to assess flood damage are of several types and can be fed by damage data collected post-flood, from experiments or based on expert knowledge. The process-based models fed by expert knowledge are the subject of research and also widely used in an operational way. Although identified as potentially transferable, they are in reality often case-specific and difficult to reuse in time (updatability) and space (transferability). In this paper, we argue that process-based models, based on a rigorous modelling process, can be suitable for application in different contexts. We propose a methodological framework aimed at verifying the conditions necessary to develop these models in a spirit of capitalisation by relying on four axes which are (i) the explicitation of assumptions, (ii) the validation, (iii) the updatability, (iv) the transferability. The methodological framework is then applied to the model we have developed in France to produce national damage functions for the agricultural sector. We show in this paper that the proposed methodological framework facilitates an explicit description of the modelling assumptions and data used, which is necessary to consider for a reuse in time or for transfer to another geographical area. In this sense, this methodological framework constitutes a solid basis for considering the validation, transfer, comparison and capitalisation of data collected around models based on processes relying on expert knowledge. In conclusion, we identify research tracks to be implemented so as to pursue this improvement in a spirit of capitalisation and international cooperation.

International audience; The world’s population is constantly growing, the global standard of living is increasing, urbanisation is developing on all continents and both the digital transformation and the necessary energy transition are underway. These different “societal phenomena” have in common that they exponentially increase the need for raw materials (metals and other minerals). For example, the demand for certain strategic metals for manufacturing batteries required for electric mobility and the energy transition is expected to explode. According to the recent raw material score board (2021) from the European commission, the lithium demand will increase by a factor of 20 in 2030; an increase by 5 is expected for cobalt. Projections for copper use show that consumption in the next 25 years will be higher than the total cumulative consumption since the Copper Age (during the Neolithic). To meet these supply challenges whilst respecting the major sustainable development goals adopted by the United Nations, it is necessary to improve the resource efficiency, meaning using the Earth’s limited resources in a sustainable manner whilst minimising impacts on the environment: delivering greater value with less input. In other words, R&D action must help to improve the environmental and societal efficiency of extractive activities, to optimise the use of metals and materials throughout their life cycle by reducing losses, and finally to set up recycling processes as part of a circular economy. The shift from a linear to a circular economy is imperative to ensure that the economic growth is not only based on the use of natural resources. [...] The objective of this paper is not only to show the common challenges faced by ore and waste treatment technologies but also to highlight some specific innovation needs associated with each resources depending of their origin (primary secondary end of life).

International audience; In Europe, payment for environmental services is increasingly perceived as an alternative to government-led incentives for promoting pro-environmental land use and attaining policy objectives of groundwater quality and quantity. The processes linking land-use decisions and ecosystem services related to aquifers (EcSA) are complex, involving different time and space scales. This raises specific challenges for the effectiveness of payment for environmental services related to aquifers (PEvSA). After defining the concepts of PEvSA, we highlight these challenges—uncertain links between land use and EcSA, spatial and temporal dimensions, monitoring and compliance issues, the invisibility of aquifers and the social equity/efficiency dilemma—and identify good practice and innovative designs for addressing them. We then review how existing PEvSA schemes throughout the world have succeeded, or not, in addressing these challenges and identify evidence of their effectiveness. We conclude that future implementation of PEvSA should pursue (i) the use of science-based approaches for determining land-use prescription; (ii) the adoption of result-oriented payments adapted to PEvSA; (iii) the use of longer term contracts adapted to water transfer time in aquifers; (iv) a finer spatial targeting of PEvSA; (v) the use of contracts with collective conditionality; and (vi) the labelling of products that generate EcSA as ways for stimulating demand. We finally call for establishing formal evidence of the impact of PEvSA on EcSA.

In the current context of raising concerns related to nuclear accidents and warfare, the lessons learnt from the Fukushima accident in 2011 are of particular interest. Indeed, the Japanese authorities implemented an ambitious decontamination program, which strongly differs from the strategy adopted in Chernobyl where the most contaminated area remains closed to the population nowadays. However, the impact of this strategy on the dispersion of radioactive contaminant fluxes across mountainous landscapes exposed to typhoons remains to be quantified. Based on the unique combination of river monitoring and modelling in a catchment representative of the most impacted area in Japan, we could demonstrate for the first time that decontamination only led to a decrease of 17% of the radionuclide fluxes in the river system. Furthermore, we calculated that 67% of the initial radiocesium remains stored in forests and may contribute to radiocesium dispersion in river systems in response to future erosive events. As the current research was conducted in an area representative of the 1,117 km²-area where remediation was completed early in 2017, it raises questions about the overall sustainability and cost-benefit effectiveness of such a remediation program that generated 9,100,000 m3 of waste for a cost of ~12 billion USD. Only a limited proportion of the initial population returned to their hometown (~30% by 2019), which remains a major challenge for the future of this region, although the primary goal of authorities to decrease the radiation dose rates in the inhabited areas was achieved.

From the end of the Carboniferous onwards, the over-thickened and hot Variscan crust collapsed (late-orogenic collapse), accompanied by the rise of high-grade metamorphic domes along low-angle detachment faults and the development of mainly half-graben or pull-apart type asymmetric intramountain coal basins.These Carboniferous-Permian late orogenic basins widely developed around 300 Ma and were filled with siliciclastic continental material, accompanied by a widespread intrusive and extrusive magmatic activity. These basins crop out in the internal parts of the belt south of the Variscan Front in several limited locations in and around the Variscan basement of Western Europe (Massif Central, Vosges-Black Forest, Alps, Harz). They occur as small isolated and disconnected “basins” with incomplete sedimentary series. Their present-day area does not reflect their initial extent and thickness, which can be explored by studying their subsurface prolongation beneath their Meso-Cenozoic sedimentary covers.We propose a geological overview of the late Variscan Carboniferous-Permian Brécy basin (SW Paris basin, France), based on the reprocessing and interpretation of vintage seismic lines and related deep boreholes. We aim (i) to discuss its sedimentary filling, which is hidden beneath the Meso-Cenozoic cover of the Paris basin, (ii) to present thickness maps of its 3.9 km-thick sedimentary filling, and (iii) to describe its structural extensional features related to a syn- to post-rift tectonic scenario. We finally compared our new results to other Carboniferous-Permian deposits in France (to discuss its lateral correlation with neighboring basins) and northwest Europe, suggesting that the Brécy Basin may represent - due to its thickness and location - a missing link between late Variscan basins in southern and northern Europe.

International audience; Natural peatlands represent 1/3 of the world C soils and contribute significantly to sequestration of atmospheric CO2 by assimilation and storage of non-well decomposed organic C, due to their specific predominant vegetation such as Sphagnum species. However, they are encountering anthropogenic-induced pressures that disturb their structure (implying shift of vegetation), with potential consequences on their carbon sink function. In an attempt to mitigate this effect, restoration experiments were undertaken at La Guette peatland, a hydrologically disturbed temperate Sphagnum-peatland invaded by vascular plants, which is now a carbon source. Hydrological restoration was performed by blocking drains with dams and vegetation restoration was undertaken by either i) removing first 5 cm of peat (bare plots) or ii) removing first 5 cm of peat and transferring Sphagnum mosses (Sphagnum plots). To study the effect of these experiments, CO2 and CH4 fluxes together with environmental variables and vegetation indices were monitored from 2014 to 2017 in 24 2mx2m plots. The annual carbon budget for each plot was estimated using empirical models. Preliminary results show that the hydrological restored site presented lower annual mean CO2 emissions than the undisturbed site. In addition, Sphagnum plots had the lowest annual mean CO2 emissions followed by bare peat plots then by intact plots. Hence, the results of these models provide evidence that hydrological and vegetation restorations favour the return to the C sink function of the peatland. However, there is still a need for larger-scale studies to better estimate the effect of restoration activities on peatland greenhouse carbon budgets.

The SUDOE AQUIFER project (http://www.igme.es/aquifer/) aims at capitalizing, testing, diffusing and transferring innovative practices for groundwater monitoring and integrated management.BRGM has developped the « MétéEAU Nappes » web platform (https://meteeaunappes.brgm.fr/fr) for several years. It enables to visualize the current and future behavior of groundwater bodies in France and to forecast groundwater availability in many monitoring wells which have been modeled using a lumped hydrological model [1].Although more than 500 wells are monitoring groundwater level in real time in unconfined aquifers in the Adour-Garonne basin (France) (https://ades.eaufrance.fr/), none of these monitoring points have been modeled to enable 6 months groundwater levels forecast. The SUDOE AQUIFER project enables to model ten monitoring points in 2022 and 2023 to forecast groundwater levels using different climatic scenarios. These forecasts are updated on a monthly basis and can be compared to groundwater levels thresholds (piezometric drought thresholds from local authority use-restriction orders [2]).These groundwater level forecasts are further used to predict groundwater withdrawable volume using a three-dimensional groundwater flow model in the Garonne, Tarn and Aveyron alluvial plain [3]. The main activity of this region is agriculture and the main groundwater use is crop’s irrigation. Groundwater withdrawal is especially important in the summer, and can impact the volume of groundwater reaching the rivers and sustaining their baseflow. This competition in use creates the need to accurately define potential withdrawable volumes.Combining the lumped hydrological models with a three-dimensional groundwater flow model enables to define the potential withdrawable volume based on (1) the summer climatic scenario chosen by the decision maker, (2) the forecasted groundwater level at the end of the low-water season and (3) the status of the groundwater body (critical, balanced, conservative) to achieve at the end of the low-water season. This decision support tool is developed as a web platform and will be accessible to groundwater managers and decision makers. After choosing the groundwater level forecasted at the start of the irrigation period within 6 scenarios based on different climatic conditions, three potential withdrawable volumes will be defined depending on the status of the groundwater body considered acceptable to obtain at the end of the low-water season. This information can then be communicated to groundwater users.These innovative practices will be extended to other regions where increase groundwater pressure forces local authority to develop methods and tools to sustainably manage groundwater bodies.Références bibliographiques : [1] Mougin B., Nicolas J., Vigier Y., Bessière H., Loigerot S. (2020). « MétéEAU Nappes » : un site Internet contenant des services utiles à la gestion des étiages. La Houille Blanche, numéro 5, p. 28-36. https://doi.org/10.1051/lhb/2020045[2] Surdyk N., Thiéry D., Nicolas J., Gutierrez A., Vigier Y., Mougin B. (2022). MétéEAU Nappes: a real-time water-resource-management tool and its application to a sandy aquifer in a high-demand irrigation context. Hydrogeology Journal. https://doi.org/10.1007/s10040-022-02509-1[3] Le Cointe, P., Nuttinck, V., Rinaudo, JD. (2020). A Tool to Determine Annual Ground-Water Allocations in the Tarn-et-Garonne Alluvial Aquifer (France). In: Rinaudo, JD., Holley, C., Barnett, S., Montginoul, M. (eds) Sustainable Groundwater Management. Global Issues in Water Policy, vol 24. Springer, Cham. https://doi.org/10.1007/978-3-030-32766-8_13

International audience; The knowledge acquired on the exhumation of the Pyrenean chain and the evolution of the adjacent foreland basins makes this Alpine-type domain a good laboratory to better constrain a full sediment routing system in a compressive context and to apprehend the driving processes controlling the sediment routing in space and time. This integrated approach aims at enhancing our basin mastering approach as well as improving our predictions of reservoir properties. This Source-to-Sink study seeks to understand the evolution of sedimentary routing from the Source (orogenic relief, craton, basin recycling) through the transfer zone (peripheral or internal to the basin) to the final sink (flexural basin, deep turbiditic margin). Within this new cartography, we propose to compile the data over the entire peri-Pyrenean domain. We produced large scale quantitative and qualitative maps to better observe and interpret the tectonic, climatic and surface processes impacts of the SRS behavior. These maps include kinematic reconstructions of the Iberian-European-Mediterranean system, restored sequential cross-sections, history/magnitude of exhumation by thermochronology, source tracking, characterization of weathering and erosion surfaces, synthesis of the major structures activity, paleogeographic reconstructions, analysis of sedimentary geometries and transport directions as well as the quantification of volumes preserved in the basins. Their interpretation is combined with a time representation along the routing system, linking classical basin wheeler diagram representation to source erosion and lithologies to obtain a continuous view on the sediment journey. The time steps chosen for these 5 maps account for the different stages of tectono-sedimentary evolution of the peri-Pyrenean system at the early-, syn- and post-orogenic stages. The compilations carried out compare exhumed domains and sedimentation zones in terms of fluxes and volumes and make it possible to map the routing systems and point out the main drivers for the surface evolution during the construction/destruction cycle of an orogen. Research work financed and carried out as part of the BRGM-TOTAL Source-to-Sink program

Past metallurgical sites and deposits account for a significant proportion of potentially contaminated sites in the European Union (EU): about 100,000 have been identified only in the North West regions of the EU. While recent wastes from sites still in operation are commonly recovered, this is not the case for old aggregated materials with a high content of ferrous (and other) metals, white and black slag, etc., which are considered to be sources of pollution and are costly to manage or dispose of. These sites could be considered as opportunities to recover large volumes of resources (metals, materials and land) using urban mining techniques if they were better characterized.The induced polarization (IP) method is a geophysical method known to be sensitive to the presence of various metallic particles disseminated in the soil layers. If qualitative interpretation of the measured IP parameters in the field (i.e. resistivity and chargeability) are widespread, quantitative interpretation in terms of concentrations of different metallic particles is yet to be developed.The example of the Pompey field site (FR), investigated as part of the NWE-REGENERATIS project (https://www.nweurope.eu/projects/project-search/nwe-regeneratis-regeneration-of-past-metallurgical-sites-and-deposits-through-innovative-circularity-for-raw-materials/), is used in this study to present the interest in using time domain IP (TDIP) field measurements to characterize metallurgical past deposits. Several paths are explored to convert resistivity and chargeability TDIP tomographies into quantitative interpretation of metallic element concentrations: (1) extraction of frequency data from TDIP field measurements; and (2) upscaling of lab results through numerical simulations.Regarding (1), TDIP measurement were made with different time windows (different frequencies), giving us access to spectral IP (SIP) processing and interpretation at 5 frequencies. These new frequency interpretations of the TDIP can be compared to lab measurements and facilitate the upscaling of the found petrophysical relationships.Regarding (2), in order to interpret the TDIP results in terms of concentration of metallic particles, known petrophysical relationships and geochemical measurements obtained at the lab scale need to be interpreted at the field scale. We propose to use a Bayesian framework for inferring field-scale metallic particles concentrations, taking into account heterogeneity and anisotropy within the inversion schemes. This work is ongoing.For both (1) and (2), it is crucial to find the best petrophysical relationships linking the IP parameters to concentration and size of metallic particles. Wong (1979) developed a physics-based electrochemical model that is still used today. We further investigate the Wong model to explore the role of the background porous medium itself in determining the IP signature of disseminated metallic particles and discuss the sensitivity of the model to estimate metallic grains concentration.All these different research paths lead to a better understanding of metallic particles IP signature at a small scale, as well as discussions on how to use these findings to better characterize and reevaluate past metallurgical sites and deposits.This study was funded by the North West Europe (NWE) Interreg project called NWE-REGENERATIS that aims at the regeneration of past metallurgic sites and deposits through innovative circularity for raw materials, and by Schlumberger-Doll Research Center (USA, MA).

International audience; In this contribution, we investigate the spatial and temporal evolution of mid-crustal flow in the Agly massif (North Pyrenean Zone) that represents the southern foreland of the Variscan orogenic plateau. In the Agly massif, the middle crust is represented by an Ediacarian-Devonian series of metasedimentary rocks that recorded high-grade metamorphism synchronously with crustal thinning (D2) and dextral wrenching (D3) during Carboniferous. D2 crustal thinning formed a penetrative S2 flat-lying foliation and localized C2 extensional shear zones with a top-to-the-North kinematics. D2 planar fabrics are deformed by a D3 dextral transpression localized into a two-kilometers wide highstrain zone. We performed LA-ICPMS U-Th-Pb dating on zircon and monazite from small magmatic bodies and from metamorphic rocks showing strain features relative to D2 and/or D3. Our results, compiled with published data, argue that the middle crust of the Agly massif reached high-temperature and suprasolidus conditions at ca. 325-320 Ma and was partially molten until ca. 300 Ma. They also indicate that the D2 thinning and top-to-the north shearing was active from ca. 325 to 290 Ma. D2 extension and D3 transpression were synchronous from ca. 308 to 290 Ma. Making a comparison with the Pyrenean Axial Zone, the Montagne Noire and the French Central massif, we propose a two-step tectonic model for the mid-crustal flow with a horizontal flow towards South in both the orogenic plateau and the southern forelands between ca. 325 and 310 Ma and locally reoriented into an E-W longitudinal flow between 310 and 300 Ma in high-strain dextral strike-slip shearing domains.

International audience

International audience; Clay minerals retain or adsorb metal ions in the Earth’s critical zone. Rocks, sediments and soils rich in clay minerals can concentrate rare earth elements (REEs) in ion adsorption-type deposits (IADs) and are similarly effective at metallic contaminant remediation. However, the molecular-scale chemical and physical mechanisms of metal ion retention remain only partly understood. In this Review, we describe the nature, location and energy requirements of metal retention at clay mineral surfaces. Retention originates mainly from electrostatic interactions during cation exchange at low pH and chemical bonding in surface complexation and precipitation at neutral and high pH. Surface complexation can induce surface redox reactions and precipitation mechanisms including neoformation of clay mineral layered structures. In IADs, outer-sphere adsorption is the major retention mechanism of REE ions. By contrast, the use of clay minerals in pollution control relies on various mechanisms that can coexist, including cation exchange, surface complexation and nucleation growth. To more effectively leverage clay mineral–metal interactions in resource recovery and contaminant remediation, complex mechanisms such as surface precipitation and redox reactions must be better understood; for instance, by utilizing advances in quantum mechanical calculations, close combination between synchrotron and simulation techniques, and upscaling of molecular-level information in macroscopic thermokinetic predictive models.

International audience; The late Carboniferous–early Permian represents a key period in the Phanerozoic history, given the major global geodynamic and climate modifications. The aim of this work is to better understand the context and characteristics of the sedimentation recorded in the continental environments of eastern equatorial Pangea at this time, through the example of the Autun Basin (northeastern Massif Central, France). The Autun Basin contains the historical stratotype of the Autunian continental stage, and its stratigraphy was recently improved by accurate numerical ages. This basin formed in an extensional tectonic context during the latest stages of the Variscan orogeny, and it is essential to study its paleoenvironmental evolution to provide new insights into the sedimentary evolution of contemporaneous surrounding basins. Using field and subsurface data, we propose a refined sedimentological model for the Autun Basin, relying on updated facies interpretations, organic matter content fluctuations, and sequence stratigraphy concepts and correlations. The continental environments of the lower sedimentary succession of the Autun Basin, previously considered to be fluvial and lacustrine, are herein re-interpreted as mainly lacustrine, comprising fine-grained organic matter-rich deposits, and supplied by coarser-grained deltaic siliciclastic sediments, without preservation of strict fluvial sedimentation. The determination of the sequence stratigraphy cycles, strengthened by the quantification of the organic matter content, and reflected by the temporal succession of progradational and retrogradational trends, is used to determine new correlations between several sections, as well as to reconstruct the paleoenvironment evolution at the Carboniferous–Permian transition. This study provides evidence that the sedimentation area of the Autun Basin at the time of its filling was much larger than the preserved basin area, and suggests connections with contemporaneous neighboring French basins, pointing to a large sedimentary system in the northeastern Massif Central area rather than narrow and isolated basins.

International audience; Serpentinization and carbonation of ultramafic formations is a ubiquitous phenomenon, which deeply influences the biogeochemical cycles of water, hydrogen, carbon…while supporting the particular biosphere around the oceanic hydrothermal vents. Carbonation of peridotites and other mafic and ultramafic rocks is also a hot topic in the current energy landscape as the engineered sequestration of mineral CO2 in these formations could help reduce the atmospheric emissions and cope with climate change. In this study, we present two reactive percolation experiments performed on a natural serpentinite dredged from the ultraslow South-West Indian Oceanic Ridge. The serpentinite cores (length 3-4 cm and dia. 5.6 mm) were subjected for about 10 days to the continuous injection of a NaHCO3-saturated brine at respectively 160°C and 280°C. Petrographic and petrophysical results as well as outlet fluid compositions were compared to numerical batch simulations performed with the PHREEQC open software allowing to reconstruct the mineralogical evolution of both cores. The most striking observation is the fast and dramatic decrease of the permeability for both experiments principally due to the precipitation of carbonates. On the contrary, serpentine was found to be less impacting as it precipitates in low-flow zones, out of the main percolation paths. In total, about 5.6% of the total injected CO2 was retained in the core, at 280°C. In the same time, hydrogen was consistently produced with a total recovered H2 corresponding to 0.8% of the maximum H2 possible. The global behavior of the cores is interpreted as the result from an interplay between interacting spatio-temporal lengthscales controlled by the Damköhler number.

International audience; Global climate change-induced stresses on coastal water resources include water use restrictions, saline intrusions, and permanently modifying or damaging regional resources. Groundwater in coastal regions is often the only freshwater resource available, so an in-depth understanding of the aquifer, and the aquifer's response to climate change, is essential for decisionmakers. In this study, we focus on the coastal aquifer of Roussillon (southern France) by developing and investigating a steady-state groundwater flow model (MODFLOW 6) and calibrated with PEST++ on a Python interface (FloPy and PyEmu). Model input and boundary conditions are constrained by various scenarios of climate projections by 2080, with model results predicting the aquifer's response (and associated uncertainty) to these external forcings. Using simple assumptions of intrusion estimates, model results highlight both strong climatic and anthropogenic impacts on the water table. These include aquifer drawdowns reaching several meters locally, and the seawater interface advancing locally several hundred meters inland and rising by several meters. Intrusions of this magnitude risk endangering exploited water wells and their sustainability. Our results demonstrate the critical importance of properly characterizing the geology and its heterogeneity for understanding aquifers at risk because poor predictions may lead to inappropriate decisions, putting critical resources at risk, particularly in coastal environments. Keywords Coastal aquifer • Climate change • Seawater intrusions • MODFLOW • Inverse modeling • PEST++

Metamodelling techniques (also referred to as surrogate modelling) have shown high performance to overcome the computational burden of numerical hydrodynamic models for fast prediction of key indicators of marine flooding (e.g. total flooded area). To predict flood maps (e.g. spatial distribution of maximum value of water depth during a flood event), a commonly-used approach is to rely on principal component analysis to reduce the high dimensionality of the flood map (related to the number of pixels typically of several 1000 s) by transforming the spatial output into a low number of latent variables (typically

International audience; A major challenge in runoff and soil erosion modelling is the adequate representation of the most relevant processes in models while avoiding over parameterization. In the European loess belt, progressive soil crusting during rainfall events, resulting in infiltration-excess runoff, is usually considered the dominant process generating runoff on catchments covered with silty soils. Saturation-excess may also occur and affect their runoff and erosion behavior. However, saturation-excess runoff occurrence and quantification have rarely been performed and is usually not taken into account when modelling runoff and erosion in these environments. Accordingly, a continuous simulation of the Austreberthe catchment (214 km2), located in the European loess belt (Normandy, France), was conducted with the new Water and Sediment (WaterSed) model over 12 years, corresponding to more than 780 individual rainfall events, at a 25 m spatial resolution.The inter-annual variability of runoff and erosion was closely linked to the number of intense events per year and their distribution through the year. The model was properly calibrated over a representative set of 35 rainfall events, considering either infiltration-excess and/or saturation-excess runoff. It was also able to reproduce the measured runoff volume for most of the monitoring period. However, the three years with most rainfall were adequately modelled only including saturation-excess runoff. An analysis performed at the seasonal scale revealed that saturation was modelled in the catchment during almost all of the modelling period, suggesting the importance of this often overlooked process in current modelling attempts.

International audience; Solubility experiments were performed on a trachyte and a pantellerite from Pantelleria. The trachyte has SiO 2 = 65.2 wt%, Al 2 O 3 = 15.2 wt% and a peralkaline index (P.I. = molar[(Na 2 O + K 2 O)/Al 2 O 3 ]) ∼ 1 while the pantellerite has SiO 2 = 72.2 wt%, Al 2 O 3 = 11 wt% and a P.I. = 1.3. Solubility experiments were performed in the pressure range of 50-300 MPa at T = 950°C for the trachyte and 50-200 MPa at T = 850°C for the pantellerite. The water content of experimental glasses was determined by Karl Fischer titration, elemental analyser and FT-IR spectroscopy. Water content appears similar in both compositions for analogous pressure conditions, varying from ∼2.5 wt% at 50 MPa to ∼5.8 at 200 MPa. Comparison of the experimental data with the thermodynamic models shows that the empirical model of Moore et al. [1998] better matches the experimental data for both compositions, while the thermodynamic models of Papale et al. [2006] and Ghiorso and Gualda [2015] tend to overestimate melt water content, probably due to the paucity of peralkaline melt compositions used for calibration. One inference of these new solubility data is on MI-derived depth of felsic reservoirs at Pantelleria which deepens from 2.4 to 3.5 km.

Owing to their roles in the arsenic (As) biogeochemical cycle, microorganisms and plants offer significant potential for developing innovative biotechnological applications able to remediate As pollutions. This possible use in bioremediation processes and phytomanagement is based on their ability to catalyse various biotransformation reactions leading to, e.g. the precipitation, dissolution, and sequestration of As, stabilisation in the root zone and shoot As removal. On the one hand, genomic studies of microorganisms and their communities are useful in understanding their metabolic activities and their interaction with As. On the other hand, our knowledge of molecular mechanisms and fate of As in plants has been improved by laboratory and field experiments. Such studies pave new avenues for developing environmentally friendly bioprocessing options targeting As, which worldwide represents a major risk to many ecosystems and human health.

International audience; The current study tries a new approach to simulating interactions between waves and seagrass through Smoothed Particle Hydrodynamics (SPH). In this model, the plants are defined as a solid that respects Hooke's law, and are assumed to have direct interaction with the fluid. Given the characteristics of the SPH method, especially in terms of computational time, the dimensions of the simulations were limited. The first goal of the current study was to optimize the approach to avoid reaching certain limits such as the rupture of the simulated plant. Plant movements under waves and/or currents have been studied by several authors in various in-situ, physical, and numerical experiments concerning various vegetation species, thus proving that plant movements can be successfully reproduced by SPH 2D/3D. Manning's roughness coefficient, n, was calculated to confirm that the results were in accordance with what had been measured in flume studies. Even though there is still room for improvement, it is shown that this method can be used to estimate Manning's coefficient for coastal vegetation (seagrass and saltmarsh vegetation) and to greatly improve the modeling and forecasting of coastal erosion and storm surge risks by including the effects of vegetation in integrated models.

As part of the Springer Nature Content Sharing Initiative, you can publicly share full-text access to a view-only version of your paper by using thefollowing SharedIt link: https://rdcu.be/cCd8u; International audience; The study of groundwater resources using pumping test data is usually carried out with the Theis solution, which enables the hydraulic parameters of porous aquifers such as the transmissivity and storage coefficient, to be estimated from the water-level drawdown. However, the data fitting can fail and provide only an indication that the pumped aquifer has a complex structure. Here, a diagnostic plot on log-derivative drawdown is used to identify flow regimes and thus aquifer heterogeneities, leading to plausible conceptual models. Nevertheless, the diagnostic plot is insufficient and must be accompanied by further modelling because of the nonuniqueness of the drawdown log-derivative signal. The proposed approach is applied to an alluvial plain in France, known to be complex because the deposition processes change over time, resulting in channel belts limited by low-permeability deposits in the floodplain or three-dimensional (3D) interconnected structures. Six analytical models were used to simulate drawdown and its derivatives during a three-day transient pumping test. The diagnostic performed on the pumping well showed that four conceptual models, with highly contrasted hydrodynamic behaviours, may correspond to the diagnostic. The joint use of pumping-well and observation-well data allowed the only appropriate model to be identified—a dual-permeability model characterizing a multilayer aquifer. The conceptual model matched the geological observations in boreholes and corroborates the fluvial sequence stratigraphy of the alluvial plain. The pumping test used here is a tool to explore the 3D architecture of the fluvial reservoir at the scale of the depositional sequence in the floodplain.; El estudio de los recursos hídricos subterráneos a partir de los datos de los ensayos de bombeo suele realizarse con la solución de Theis, que permite estimar los parámetros hidráulicos de los acuíferos porosos, como la transmisividad y el coeficiente de almacenamiento, a partir del descenso del nivel del agua. Sin embargo, el ajuste de los datos puede no funcionar y proporcionar sólo una indicación de que el acuífero bombeado tiene una estructura compleja. En este caso, se utiliza un diagrama de diagnóstico de la depresión logarítmica derivada para identificar los regímenes de flujo y, por tanto, las heterogeneidades del acuífero, lo que conduce a modelos conceptuales plausibles. Sin embargo, el diagrama de diagnóstico es insuficiente y debe ir acompañado de una modelización adicional debido a la no unicidad de la señal log-derivada de la depresión. El enfoque propuesto se aplica a una llanura aluvial en Francia, conocida por su complejidad debido a que los procesos de deposición cambian con el tiempo, dando lugar a franjas de canales limitadas por depósitos de baja permeabilidad en la llanura de inundación o a estructuras tridimensionales (3D) interconectadas. Se utilizaron seis modelos analíticos para simular la depresión y sus derivados durante un ensayo de bombeo transitorio de tres días. El diagnóstico realizado en el pozo de bombeo mostró que pueden corresponder cuatro modelos conceptuales, con comportamientos hidrodinámicos muy contrastados. La utilización conjunta de los datos del pozo de bombeo y del pozo de observación permitió identificar el único modelo apropiado: un modelo de doble permeabilidad que caracteriza un acuífero multicapa. El modelo conceptual coincidió con las observaciones geológicas en pozos de sondeo y corrobora la estratigrafía de la secuencia fluvial de la llanura aluvial. El ensayo de bombeo utilizado aquí es una herramienta para explorar la arquitectura 3D del depósito fluvial a escala de la secuencia deposicional en la llanura aluvial.; L’étude des ressources en eau souterraine à partir de données d’essais de pompage est généralement réalisée avec la solution de Theis, qui permet d’estimer les paramètres hydrauliques des aquifères poreux, tels que la transmissivité et le coefficient d’emmagasinement, à partir du rabattement du niveau d’eau. Cependant, l’ajustement des données peut échouer et fournir seulement une indication relative à la complexité de la structure de l’aquifère sollicité par pompage. Ici, un tracé de diagnostic de la dérivé du rabattement selon une échelle logarithmique est utilisé pour identifier les régimes d’écoulement et donc les hétérogénéités de l’aquifère, conduisant à des modèles conceptuels plausibles. Néanmoins, le diagnostic de puits est insuffisant et doit être accompagné d’une modélisation plus poussée en raison de la non-unicité du signal de la dérivée du rabattement selon une échelle logarithmique. L’approche proposée est appliquée à une plaine alluviale en France, connue pour être complexe car les processus de dépôt ont évolué au cours du temps, donnant lieu à des zones de chenaux limitées par des dépôts peu perméables dans la plaine d’inondation ou à des structures tridimensionnelles (3D) interconnectées. Six modèles analytiques ont été utilisés pour simuler le rabattement et ses dérivés pendant un essai de pompage transitoire de trois jours. Le diagnostic réalisé sur le puits de pompage a montré que quatre modèles conceptuels, aux comportements hydrodynamiques très contrastés, peuvent correspondre au diagnostic. L’utilisation conjointe des données des puits de pompage et des puits d’observation a permis d’identifier le seul modèle approprié - un modèle à double perméabilité caractérisant un aquifère multicouche. Le modèle conceptuel correspond aux observations géologiques dans les forages et corrobore la stratigraphie séquentielle fluviale de la plaine alluviale. L’essai de pompage utilisé ici est un outil permettant d’explorer l’architecture 3D du réservoir fluvial à l’échelle de la séquence de dépôt dans la plaine d’inondation.; O estudo dos recursos hídricos subterrâneos utilizando dados de teste de vazão é comumente resolvido por meio da equação de Theis, o que permite que os parâmetros hidráulicos dos aquíferos porosos, como a transmissividade e o coeficiente de armazenamento, possam ser estimados a partir do rebaixamento do nível d’água. Porém, o ajuste dos dados pode falhar, indicando apenas que o aquífero bombeado apresenta uma estrutura complexa. Aqui, um gráfico de diagnóstico da derivada logarítmica do rebaixamento é usado para identificar o regime de fluxo e, portanto, a heterogeneidade do aquífero, levando a modelos conceituais plausíveis. Ainda assim, o gráfico de diagnóstico é insuficiente e deve ser acompanhado de mais modelos, devido ao sinal não único da derivada logarítmica do rebaixamento. A abordagem proposta foi utilizada em uma planície aluvial na França, conhecida por ser complexa, pois os processos de deposição mudam com o tempo, o que resulta em um cinturão de canais limitados por depósitos de baixa permeabilidade na planície de inundação ou por estruturas tridimensionais (3D) interconectadas. Seis modelos analíticos foram utilizados para simular o rebaixamento, e suas funções derivadas, durante um teste de bombeamento transiente de 3 dias. O diagnóstico simulado para o poço de bombeamento mostrou que quatro modelos conceituais, cada um com comportamento hidrodinâmico contrastante, podem corresponder ao diagnóstico. A junção dos dados do poço de bombeamento e dos dados de poço de observação permitiu a identificação do único modelo apropriado – um modelo de permeabilidade dual caracterizando um aquífero multicamadas. O modelo conceitual coincide com as observações da geologia dos poços e corrobora com a sequência estratigráfica fluvial da planície aluvial. O teste de bombeamento utilizado é uma ferramenta para explorar a arquitetura 3D do reservatório fluvial na escala da sequência deposicional da planície de inundação.; 利用抽水试验数据研究地下水资源通常采用 Theis 解, 它可以根据水位降深估算多孔介质含水层的水力参数, 如传导系数和蓄水系数。然而, 数据拟合可能会失败, 并且只能表明抽水含水层具有复杂的结构。在这里, 对数导数降深的诊断图用于识别流态, 从而识别含水层的异质性, 由此可形成合理的概念模型。然而, 由于降深对数导数信号的非唯一性, 仅用诊断图是不够的, 必须再建模分析。所提出的方法应用于法国众所周知复杂的冲积平原, 由于沉积过程随时间变化, 导致河岸带受到漫滩中低渗透性沉积物或三维 (3D) 互连结构的影响。在为期三天的非稳定抽水测试期间, 六个解析解模型用于模拟降深及其导数。抽水井上进行的诊断表明, 具有高度异质的水动力行为的四个概念模型可能与诊断相符。抽水井和观测井数据的联合使用可确定唯一合适的模型, 即表征多层含水层的双渗透模型。概念模型与钻孔中的地质观察相匹配, 并证实了冲积平原的河流相地层。此处使用的抽水试验是在漫滩沉积相尺度上探索冲积相储层 3D 结构的工具。

Human urine concentrates 85% of the nitrogen and 65% of the phosphorus excreted by humans, making it a potential alternative crop fertilizer. However, knowledge gaps remain on the fate of nitrogen in situations favouring NH3 volatilisation and on the availability of P from urine. This study aimed at identifying the fate of nitrogen and phosphorus supplied by human urine from source separation toilets in a calcareous soil. To this end, a spinach crop was fertilized with 2 different doses of human urine (170 kgN.ha-1 + 8.5kgP.ha-1 and 510 kgN.ha-1 + 25.5 kgP.ha-1) and compared with a chemical fertiliser treatment (170 kgN.ha-1 + 8.5kgP.ha-1) and a water treatment. The experiment was conducted in 4 soil tanks (50 cm depth) in greenhouse conditions, according to a randomized block scheme. We monitored soil mineral nitrogen over time and simulated nitrogen volatilisation using Hydrus-1D and Visual Minteq softwares. We also monitored soil phosphorus pools, microbial biomass CNP, soil pH and electrical conductivity. Only an excessive input of urine affected soil pH (decreasing it by 0.2 units) and soil conductivity (increasing it by 183%). The phosphorus supplied was either taken up by the crop or remained in the available P pool. Ammonium seemed to be nitrified within about 10 days after application. However, both Visual Minteq and Hydrus models estimated that more than 50% of the nitrogen supplied was lost by ammonia volatilisation. Overall, our results indicate that direct application of urine to a calcareous soil is possible without harming soil properties, but that heavy losses of volatilised nitrogen are to be expected.

International audience; Groundwater level prediction is an applied time series forecasting task with important social impacts to optimize water management as well as preventing some natural disasters: for instance, floods or severe droughts. Machine learning methods have been reported in the literature to achieve this task, but they are only focused on the forecast of the groundwater level at a single location. A global forecasting method aims at exploiting the groundwater level time series from a wide range of locations to produce predictions at a single place or at several places at a time. Given the recent success of global forecasting methods in prestigious competitions, it is meaningful to assess them on groundwater level prediction and see how they are compared to local methods. In this work, we created a dataset of 1026 groundwater level time series. Each time series is made of daily measurements of groundwater levels and two exogenous variables, rainfall and evapotranspiration. This dataset is made available to the communities for reproducibility and further evaluation. To identify the best configuration to effectively predict groundwater level for the complete set of time series, we compared different predictors including local and global time series forecasting methods. We assessed the impact of exogenous variables. Our result analysis shows that the best predictions are obtained by training a global method on past groundwater levels and rainfall data

A number of challenges must be faced when using soil moisture sensors, such as accounting for soil heterogeneity in measurements or dealing with sensor faults. As a consequence, it is difficult to obtain reliable estimations of the water status in the root zone and using sensor data for irrigation planning is not straightforward. In this work, a method is proposed to interpret soil water content measurements that is based on the use of a model to correct and complement sensor data, in particular in the case of a non uniform water distribution. This approach relies on the assumption that porosity is the main driver of heterogeneity in hydraulic properties at small scales, which allows to factor out the spatial variations of the sensor's signal. With practical applications in mind, a simple model and an efficient calibration procedure are developed, in particular considering the online application of the method to complement sensor data in real time. The capabilities of the model are illustrated with data from experiments on the growth of lettuces in greenhouses with reclaimed wastewater irrigation. Requiring only a short calibration period, the model is successfully validated and is proven to be a valuable tool to correct for sensor malfunctions. Moreover, the proposed method is shown to allow the meaningful estimation of the water status of the soil crop system, in particular when measurements of sensors positioned close to each other showed important differences.

The lake level of the Dead Sea, Southern Levant, has fluctuated with an amplitude of ∼250 m in response to the last glacial-interglacial cycle. This exceptional sensitivity to climate change, and the availability of long sedimentary archives, make the Dead Sea a benchmark for long quantitative paleohydrological reconstructions. However, discontinuities and chronological uncertainties in the marginal sedimentary record have hampered the reconstruction of Dead Sea lake levels beyond the Last Glacial (70–14 ka before present, BP). Here, we apply a two-pronged methodology. First, we measure the lake water density along ICDP deep core 5017-1-A using a new method, Brillouin spectroscopy on two-phase halite fluid inclusions; we combine it with the composition of pore water and the thickness of halite layers in the core to reconstruct lake level, volume, mass balance and subsidence rate. Second, we tune the chronology of lake levels from outcrops by matching it to the chronology of the deep core. The resulting lake level reconstruction, spanning 237–70 ka BP, is validated by the excellent agreement between outcrop- and mass balance-based methodologies. It shows a long-term recession of the lake, its level decreasing from one interglacial to the other, down to a Holocene record low. There are two reasons for this lake level fall. First, with an average rate of 2.65 ± 0.15 m/ka, subsidence has outpaced sedimentation at least over the last ∼130 ka. Second, by reducing the solute inventory of the lake, massive halite precipitation events such as that of 131–116 ka BP have durably increased surface water activity and evaporation, and thus lowered the lake level, up to today. Conversely, our analysis suggests that, during 191–11 ka BP, the dissolution of Mount Sedom salt diapir and freshwater inflows provided to the lake about three times the mass of solute NaCl contained in the modern Dead Sea (in 1985). This massive solute influx, occurring mainly during glacial highstands, strongly contributed to lowering surface water activity and evaporation and, therefore, to increasing the lake volume. Our results suggest that Dead Sea lake levels are more accurately interpreted in terms of climatic change if surface water activity is taken into account.

Evidence are dearly needed to understand under which conditions it is relevant for decisions makers to invest in NBS for water-related risk. This chapter presents the methodological framework developed for the economic assessment of NBS for water-related risks and its application to seven case studies. We particularly develop methods for the evaluation of implementation and opportunity costs, the assessment of the reduction of damage costs, and the monetary value of co-benefits. The study confirms that the cost of implementation and maintenance of NBS strategies is lower than the cost of grey solutions for the same level of water risk management, emphasizing the better cost-effectiveness of these solutions. Benefits in terms of avoided damages are however generally not sufficient to cover investment and maintenance costs. Co-benefits represent the largest share of the value generated by NBS strategies. The overall cost-benefit analysis implemented in four cases, is positive in three case studies and negative in one. This confirms the importance to carry out thorough economic assessments for the elaboration of Natural Assurance Schemes.

The Lez catchment is characterized by a rapid urbanization, due to the attractiveness of the city of Montpellier, and is exposed to a typical Mediterranean weather with high risk of flash flood and other emerging issues, such as air pollution, heat island effects and biodiversity losses. We present the evaluation of two types of NBS to address these challenges, (i) urbanization strategies that have an impact on the conservation of agricultural and natural land and (ii) a network of green infrastructure (GI), with a focus on the economic analysis. Our results reveal that our most ambitious GI strategy can reduce up to a 20% of the mean annual damages due to annual flood damages. The largest share of the economic value of our NBS however lies in the co-benefits they generate. Overall, the two GI strategies present a positive cost-benefit analysis. We finally identify a pathway towards implementation in terms of financing and organizational challenges.

This chapter summarizes the main findings from the book in relation to the conceptual framework centered on the linked but separate concepts of assurance and insurance value of nature, to then highlight the key methods developed namely physical assessments, co-design, and a full integrated economic assessment model that incorporates the value of avoided costs and other co-benefits. This can help to generate and implement natural assurance scheme projects aligned with adaptive planning, innovative financing and new business models centered around prevention by investing in nature.

This chapter discusses the methodological approach for natural assurance schemes (NAS). We developed and applied methodologies and strategies to increase the readiness in technology (TRL), institutions (IRL) and investment/financing (IVRL) and illustrated them in contrasting case studies. To assess how readiness is crafted to effectively green water risk reduction and water security plans, we propose an integrated analytical framework that builds on participatory adaptive planning approaches. Through an ex-post expert assessment of NAS implementation in 9 case studies, we demonstrate how methodologies and strategies to increase TRL, IRL and IVRL can contribute to operationalization of NAS under a wide range of contexts and boundary conditions. Case studies have (1) varying biophysical conditions, spatial scale and vulnerability to water related natural hazards that require diverse NAS approaches, but also (2) varying readiness levels for implementation of nature based solutions in NAS. Institutional readiness is generated throughout the entire planning process, through a combination of joint assessment of risk perceptions and the institutional set-up as well as facilitation of awareness and agreement on responsibilities. Investment readiness is generated through the generation of the NAS business canvas and can be translated into investment plans built around the 5 business cases proposed in the Financing Framework for water security. We illustrate that for nature-based solutions (NBS) to be integrated in water security and climate adaptation strategies effectively, the NAS approach needs to craft readiness at all levels, tailoring an integrated set of methods and tools available through a collaborative process with stakeholders.

International audience

International audience; In semi-arid regions as in India, where agriculture relies on groundwater abstraction, increase of water resources availability through managed aquifer recharge (MAR) or rainwater harvesting (RWH) is often perceived as a major solution. Studies on these structures efficiency exists but despite the interest, limited information is available on the temporal variation of their replenishment. In a monsoon driven climate, the inter-annual variations are crucial to assess the potential of water storage and multi-year management especially for these structures. Here, we aim at developing a methodology to reconstruct water storage of RWH tanks to further improve our understanding on long term efficiency and multi-years drought management. To tackle this issue, long-term monitoring of a RWH tank located in Telangana in southern India is achieved by a combination of field monitoring over 2 years (tanks surface and water levels) and a daily water balance compared to LANDSAT measurements of the tank area. The procedure allows reconstructing the tank filling dynamic over a 14-years period at a daily time step and show the extreme variability of the tank filling level. During this period, the yearly maximum tank volume ranges from 8 650 to ~ 200 000 m 3. On the 14-years period, the tank reach its maximum capacity only once and, for 1/3 of the time, yearly maximum replenishment is below 15 % of its capacity. The surface water availability remains limited in time since the tank dries-up annually, except for 2 years. However, water percolation to the aquifer is slightly enhanced for some years. During this monitoring period, very few extreme raining events (6) contribute for more than 50 % of the collected volume. This observation highlights (1) the dependency of the structure to extreme storm events, (2) the limited capacity for a multiyear's management and (3) the farmers vulnerability to successive droughts.

International audience

International audience; Fluids in magmas play a key role in magma differentiation and transportation of economic metals for ore deposits. As a chalcophile and incompatible element, zinc and its isotopes have been increasingly applied to study the magmatic-hydrothermal processes. However, zinc isotopic fractionation between aqueous fluids and magmas has not been well constrained. Here we experimentally determined equilibrium fractionation factors of Zn isotopes between aqueous fluids and silicate magmas (Δ66Znfluid-magma= δ66Znfluid - δ66Znmagma). The results reveal that aqueous fluids are isotopically heavier than the coexisting silicate magmas. No correlation between Δ66Znfluid-magma and temperature or chlorine contents in fluids is observed under our experimental conditions. Instead, Δ66Znfluid-magma is negatively corresponded with NBO/T of the melt (the ratio of non-bridge oxygen and tetrahedron ions), and positively correlated with the molar ratio of Al/(0.5K+Ca+Fe) in the bulk magmas, suggesting the controlling of silicate composition on Zn isotope fractionation. Our data therefore indicate that the isotopically heavier Zn in the fluids exsolved from magmas may account for the higher δ66Zn of pegmatites and high-silica granitic rocks. Moreover, involvement of magmatic fluids can explain the highly variable and remarkably heavier Zn isotopic signatures of fumaroles, thermal spring waters, and seafloor hydrothermal fluids compared to the igneous rocks. This study provides information that can be used to guide research using Zn isotopes to trace fluid activity and magmatism.

SUMMARYThe brutal onset of seismicity offshore Mayotte island North of the Mozambique Channel, Indian Ocean, that occurred in May 2018 caught the population, authorities and scientific community off guard. Around 20 potentially felt earthquakes were recorded in the first 5 d, up to magnitude Mw 5.9. The scientific community had little pre-existing knowledge of the seismic activity in the region due to poor seismic network coverage. During 2018 and 2019, the MAYOBS/REVOSIMA seismology group was progressively built between four French research institutions to improve instrumentation and data sets to monitor what we know now as an on-going exceptional submarine basaltic eruption. After the addition of 3 medium-band stations on Mayotte island and 1 on Grande Glorieuse island in early 2019, the data recovered from the Ocean Bottom Seismometers were regularly processed by the group to improve the location of the earthquakes detected daily by the land network. We first built a new local 1-D velocity model and established specific data processing procedures. The local 1.66 low VP/VS ratio we estimated is compatible with a volcanic island context. We manually picked about 125 000 P and S phases on land and sea bottom stations to locate more than 5000 events between February 2019 and May 2020. The earthquakes outline two separate seismic clusters offshore that we named Proximal and Distal. The Proximal cluster, located 10 km offshore Mayotte eastern coastlines, is 20–50 km deep and has a cylindrical shape. The Distal cluster start 5 km to the east of the Proximal cluster and extends below Mayotte's new volcanic edifice, from 50 to 25 km depth. The two clusters appear seismically separated, however our data set is insufficient to firmly demonstrate this.

Des 1990, l’OMS (1999) a percu l’importance des determinants environnementaux de la sante, ce qui l’a amenee a elargir sa definition de la sante de 1946 : « la sante environnementale comprend les aspects de la sante humaine, y compris la qualite de la vie, qui sont determines par les facteurs physiques, chimiques, biologiques, sociaux, psychosociaux et esthetiques de notre environnement. Elle concerne egalement la politique et les pratiques de gestion, de resorption, de controle et de prevention des facteurs environnementaux susceptibles d’affecter la sante des generations actuelles et futures. »Partant du constat de l’impact de la qualite des ecosystemes sur la sante humaine, le concept d’exposome a emerge. Celui-ci est defini comme la totalite des expositions a des facteurs environnementaux que subit un organisme humain, depuis sa conception jusqu’a sa fin de vie en passant par le stade du developpement in utero (Wild, 2005). La notion de « One health » elaboree par Zindsstag et collaborateurs (2011) insiste en outre sur la bidirectionnalite des relations et appelle a developper des approches integrees pour garantir une sante environnementale globale (humaine, vegetale, animale et ecosystemique). A partir de differents exemples, nous questionnons ici le niveau d’integration disciplinaire et spatio-temporelle necessaire a la prise en compte et a l’operationnalisation du concept de sante environnementale globale. Nous montrons ainsi que la sante environnementale offre un cadre d’actions pour repondre au besoin urgent du developpement d’une gouvernance des risques multidimensionnelle et integree.

Understanding diagenetic reactions in accreted sediments is critical for establishing the balance of fluid sources and sinks in accretionary prisms, which is in turn important for assessing the fluid pressure field and the ability for faults to host seismic slip. For this reason, we studied diagenetic reactions in deformation bands (shear zones and veins) within deep mud sediments from the Nankai accretionary prism (SW Japan) drilled at site C0001 during IODP Expedition 315, by means of microscopic observation, X-ray diffraction, and major- and trace-element analyses. Deformation bands are not only more compacted than the host sediment but are also enriched in framboidal pyrite, as observed under microscopy and confirmed by chalcophile-element enrichments (Fe, S, Cu, As, Sb, Pb). In tandem, one shear zone sample displays a destabilization of smectite or illite–smectite mixed layers and a slight crystallization of illite relative to its sediment matrix, and another sample shows correlated increases in B and Li in shear zones and veins compared to the host sediment, both effects suggesting a transformation of smectite into illite in deformation bands. The two diagenetic reactions of sulfide precipitation and smectite-to-illite transformation are explained by a combined action of sulfate-reducing and methanogen bacteria, which strongly suggests an increased activity of anaerobic microbial communities localized in deformation bands. This local bacterial proliferation was possibly enhanced by the liberation of hydrogen from strained phyllosilicates. We suggest that the proliferation of anoxic bacteria, boosted by deformation, may contribute to the pore water freshening observed at depth in accretionary prisms. Deformation-enhanced metabolic reactions may also explain the illitization observed in major faults of accretionary prisms. Care is therefore needed before interpreting illitization, and other diagenetic reactions as well, as evidence of shear heating, as these might be biogenic instead of thermogenic.

The Couriège prospect (French Guiana) provides key examples of the diversity of gold distribution related to supergene processes. The nature of gold in two contrasted weathering profiles is examined as a function of the weathering lithofacies. The autochthonous profile hosts weathered Au-bearing quartz veins whereas the pediment profile is enriched in free gold issued from dismantled gold-bearing quartz veins. The gold distribution is controlled by: (1) the preservation of primary gold as free gold in both transported and autochthonous horizons and as electrum inclusions in detrital pyrite; and (2) the formation of secondary gold through dissolution/precipitation processes, expressed as gold spherulites on the free gold grain surface, an Ag-depleted rim around transported free gold grains and Ag-depleted gold micro-inclusions hosted by oxidized autochthonous pyrite. Gold enrichment through supergene chemical processes remains limited within the truncated autochthonous profile. A new conceptual model is proposed for the area, defining the role of chemical and physical processes in gold endowment and accounting for the geomorphological context. The overall evolution includes (1) deep weathering and peneplenation, (2) dismantlement and transport of lateritic material and (3) the development of a latosol cover. This study highlights that gold exploration in tropical environments must consider the residual v. transported nature and the inheritance of targeted pedogenic horizons.

SUMMARYWhich physical parameters are the most influential when predicting earthquake ground motions in a 3-D sedimentary basin? We answer quantitatively by doing a global sensitivity analysis of two quantities of interest: the peak ground motions (PGMs) and a time–frequency representation (the S transform) of ground motions resulting from the synthetic anelastic responses of the EUROSEISTEST. This domain of interest is modeled by two layers with uncertain depth-dependent mechanical properties and is illuminated by a plane S-wave propagating vertically upward in an uncertain homogeneous elastic bedrock. The global sensitivity analysis is conducted on 800+ physics-based simulations of the EUROSEISTEST requiring 8+ million core-hours (i.e. ≈ 900 yr of mono-core computation). The analysis of the PGMs at the free surface displays the spatial influence of the uncertain input parameters over the entire basin scale, while the analysis of the time–frequency representation shows their influence at a specific location inside the basin. The global sensitivity analysis done on the PGMs points out that their most influential parameter in the middle of the basin is the quality factor QS (it controls up to 80 per cent of the PGMs in certain locations where the sediments thickness is larger than 200 m). On the other hand, the geological layering configuration (here represented by the depth of a geological interface controlling the geological layering) strongly influences the PGMs close to the basin edges, up to 90 per cent. We also found that the shear wave velocity at the free surface of the basin and the one of the bedrock underlying the basin are to be considered on an equal footing, both influencing the PGMs in the middle of the basin and close to its edges. We highlight that the bedrock to basin amplification of the PGMs shows a clear increase with respect to the thickness of the sediments, but this amplification saturates from 200 m of sediments around the value of three and is frequency dependent. This PGMs amplification starts from about one tenth of the mean S-wavelength propagating in the basin. The global sensitivity analysis done on the S transform of the ground motions shows that (i) the own effect of the parameters fully controls the first S-wave train and mostly controls the direct arrival of the basin-induced surfaces waves, (ii) the quality factor QS controls 40–60 per cent of the decay of amplitude of coda waves, the remaining part being mainly controlled by interaction effects due to the coupling effect of several parameters and (iii) the interaction effects between the parameters increases with time, suggesting under the hypotheses of our study that the own effects control the ballistic wave propagation while the interaction effects control the diffusive wave propagation.

International audience; Displaces the storyline that overexploitation occurs when groundwater abstraction exceeds aquifer recharge.