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In-vitro rhizobial inhibition by fertilizers commonly used in legume production was assessed with commercial inoculant strains, Bradyrhizobium lupini WU425, Mesorhizobium ciceri CC1192 and Rhizobium leguminosarum bv. viciae WSM1455, and a commercial granular inoculant (WSM1455). Standard bacterial inhibition assays were used with four fertilizers: single superphosphate (SSP), granulated DAP (based on diammonium phosphate) and MAP (monoammonium phosphate), and a compound fertilizer (MAP with ZnSO4). WSM1455 was strongly inhibited by DAP and MAP fertilizers, and moderately by SSP, with DAP being non-lethal. However, CC1192 and WU425 were not inhibited by DAP and were less sensitive to MAP fertilizers, with the effects being bacteriostatic rather than bactericidal. Apart from pH effects (particularly SSP), comparisons with analytical grade products indicated that fertilizer impurities might contribute to this inhibition. Granular inoculant mixed with MAP or DAP rapidly lost moisture and viability (75% within 1 h). The fertilizers were found to inhibit rhizobia with strain by fertilizer interactions, with differences in degree and lethality. Consequently, it is suggested that close placement of inoculated seeds near fertilizer at planting or mixing granular inoculants with fertilizers risks poor nodulation outcomes. These in-vitro findings need field validation but may be considered valuable in providing advice to legume growers. [ABSTRACT FROM AUTHOR]

The growing popularity of cold-brewed coffee has resulted in large amounts of localized spent coffee grounds (SCG) generated from production plants. Spent coffee grounds offer many favorable agronomic properties, but also contain caffeine, tannins and phenolic compounds that may be deleterious to plant growth. There is a growing body of research examining the effects of SCG on plants, but little of which pertains to use in turfgrass systems. The objective of this two-year field study was to evaluate the feasibility of using SCG as an agronomic source of nutrients for turfgrass. Field studies were conducted over two years to characterize performance of 'Riley's Super Sport' (Celebration®) bermudagrass (Cynodon dactylon) receiving multiple nutrient source treatments including fresh and composted SCG, as well as synthetic, natural organic, and bridge fertilizers, some which included SCG. Soils were analyzed at the conclusion of the study to determine whether SGC provided long-term effects of on soil pH and/or nutrient concentrations. Our results demonstrated that although SCG possesses between 2.3-2.9% N and a favorable C:N ratio, direct SCG applications over two seasons did not produce responses typical of a fertilizer when applied as a topdressing. However, when combined with poultry litter, the SCG-containing organic fertilizer GeoJava produced improved turf quality relative to other organic and synthetic commercial fertilizers in our study, including Milorganite, ammonium sulfate, and URI-PEL S.R. Further, despite the acidic nature of SCG, their repeated application over multiple years did not result in any long-term changes to soil pH. Although early on, SCG treatments caused mild and transient phytotoxicity, these effects were not observed when it was applied in combination with the manure used in GeoJava. [ABSTRACT FROM AUTHOR]

Background: An importance of tillage, inorganic and organic nutrient sources in the mustard - soybean cropping system lies in their ability to enhance soil fertility, improve nutrient availability, optimize crop growth and yield, and promote sustainable agricultural practices. Any cropping system's sustainability could be increased by implementing better management techniques like zero and reduced tillage with residue retention and better nutrient sources. Results: A field experiment was conducted for four consecutive seasons (Winter 2019 to Rainy 2021) to compare the two enhanced management practices, zero and reduced tillage to conventional tillage across four levels of nutrient sources: 75 and 100% recommended dose of nitrogen through FYM and 75 and 100% recommended dose of fertilizers through urea, single super phosphate and muriate of potash in a two years experiment. Experiment results were evaluated in terms of nutrient status, profitability and productivity of Mustard-Soybean cropping system. The results show a substantial improvement in yield, nutrient status, and overall yield performance of mustard and soybean when using the full recommended dose of fertilizers combined with reduced tillage and mulching, compared to other treatment methods. The implementation of reduced tillage practices recorded significantly higher yield of mustard and soybean over conventional and zero tillage. Conclusion: System productivity and profitability i.e. mustard equivalent yield, productivity, gross returns, net returns, profitability and B: C (benefit: cost) was found to be improved with reduced tillage and 100% recommended dose of fertilizer under reduced tillage practices. To enhance cropping system productivity in various sub-humid regions worldwide, farmers can adopt reduced tillage techniques combined with the full recommended dose of fertilizers (100% RDF). [ABSTRACT FROM AUTHOR]

With the increasing demand for crops, the excessive application of fertilizers has gradually become a significant factor affecting water quality. Therefore, studying the relationship between agricultural fertilizer runoff and water quality is crucial for the sustainable development of agricultural production. The present study sets up a new dynamic model of nitrogen fertilizer loss, introducing variables such as precipitation, fertilization application during dry and rainy seasons, and their lagged and interaction terms. The paper analyzed the issue of fertilizer runoff under the complex interactions of various factors, including spatial and temporal scales and climatic conditions, and explored the relationship between agricultural activities and water quality changes in the context of sustainable development. Due to Hainan Island's independent river system, which is free from transboundary pollution, and its low level of industrial pollution, it provides an excellent sample for assessing the impact of agricultural non-point source pollution on water quality. Based on watershed monitoring data from Hainan Island, this study draws the following conclusions: 1. Precipitation exhibits a pronounced seasonal influence on total nitrogen concentration. 2. Nitrogen fertilizer enters into water bodies through precipitation, resulting in a lag effect on total nitrogen concentration. 3. The influence of grain and tropical crops on nitrogen loss is less significant, while cash crops will trigger the nitrogen overloading of rivers in scenarios where they account for a high proportion of the planting structure of the sown area. [ABSTRACT FROM AUTHOR]

Introduction: Organic fertilizers (OF) are crucial for enhancing soil quality and fostering plant growth, offering a more eco-friendly and enduring solution compared to chemical fertilizers (CF). However, few studies have systematically analyzed the effects of OF/CF on root microbiome of medicinal plants, especially in combination with active ingredients. Methods: In this study, we investigated the composition and function of bacteria and fungi in the rhizosphere or within the root of traditional Chinese medicinal plants, Citri Grandis Exocarpium (Huajuhong), which were treated with OF or CF over 1, 3, and 5 years (starting from 2018). Additionally, we conducted metabolome analysis to evaluate the effects of different fertilizers on the medicinal properties of Huajuhong. Results: The results indicated that extended fertilization could enhance the microbial population and function in plant roots. Notably, OF demonstrated a stronger influence on bacteria, whereas CF enhanced the cohesion of fungal networks and the number of fungal functional enzymes, and even potentially reduced the proliferation of harmful rhizosphere pathogens. By adopting distancebased redundancy analysis, we identified the key physicochemical characteristics that significantly influence the distribution of endophytes, particularly in the case of OF. In contrast, CF was found to exert a more pronounced impact on the composition of the rhizosphere microbiome. Although the application of OF resulted in a broader spectrum of compounds in Huajuhong peel, CF proved to be more efficacious in elevating the concentrations of flavonoids and polysaccharides in the fruit. Discussion: Consequently, the effects of long-term application of OF or CF on medicinal plants is different in many ways. This research provides a guide for OF/CF selection from the perspective of soil microecology and aids us to critically assess and understand the effects of both fertilizers on the soil environment, and promotes sustainable development of organic agriculture. [ABSTRACT FROM AUTHOR]

Green peel of walnut (J. regia L.) is considered as one of the agricultural wastes, while it contains significant amounts of bioactive compounds and minerals. The aim was to evaluate the cytochemistry and the amount of minerals in these peels in order to estimate their possible uses. Mature Persian walnut fruits were collected from a village in the Kerman province of Iran. The green peels were used for manual sectioning and staining. Large amounts of starch and calcium oxalate were seen in peel cells. Carbohydrates were abundant in epidermal cells and superficial areas. Cells in the middle and inner layers had high levels of phenolic compounds. The concentration of tannins in cells of the epidermis, parenchyma, and phloem tissues was notably high. Assessment of mineral elements in peels was performed by the inductively coupled plasma mass spectrometry (ICP-MS) technique. Potassium had the highest amount; calcium was the second most abundant element, followed by phosphorus, magnesium, sulfur, silicon, iron, sodium, aluminum, strontium, titanium, copper, magnesium, selenium, zinc, molybdenum, and nickel, respectively. The great point was that walnut peel can be a complete plant fertilizer, a subject that has not been reported previously. Because fertilizers in the market contain the same elements and almost the same amount of each element similar to walnut peels, as future perspectives, the extraction of minerals and bioactive substances of these peels and investigation of their effects on the growth of model plants are needed. If the results are satisfactory, chemical fertilizer preparation from walnut peels can be economical. [ABSTRACT FROM AUTHOR]

Introduction: Plant seeds from weeds and energy crops have the potential to survive anaerobic digestion (AD). Species able to form physically dormant, i.e., hardseeded (HS) seeds seem particularly resistant. However, it is not yet known to what extent the storage of the digestate after AD affects seed viability. Methods: Seed survival of five HS and six non-HS (NHS) species was investigated in three combinations of digestate storage (DS) and AD. First, untreated seeds were exposed to DS for maximum 12 weeks. To simulate short-circuited AD (ADshort) in biogas reactors, seeds were second subjected to lab-scale AD for 1 day before DS. Third, seeds of six species were exposed to full-scale AD (ADfull) followed by DS. Seed viability was determined using a combination of germination tests and tetrazolium staining. Viability was modeled as a function of exposure time. Results and discussion: Seed viability was affected by DS, AD and AD + DS, but responses varied greatly between species and treatments. With increasing exposure time, viability decreased after a lag-phase, remained stable or even increased. The NHS species Cichorium intybus , Daucus carota , Echium vulgare , and Verbascum thapsus were most susceptible, with seed-killing close to 100% if DS was involved. The HS species Malva sylvestris , Melilotus albus and Melilotus officinalis were most resistant. They survived all treatments and were alive after 35 days of ADfull plus 3 months of DS. The resistance potential of the HS species Abutilon theophrasti and Malva alcea and of the NHS species Chenopodium album and two tomato varieties was intermediate. None of them survived ADfull + DS, but except A. theophrasti they were viable after ADshort + DS. With few exceptions, seed-killing by AD + DS was higher than that by AD alone. In conclusion, DS and AD + DS have the potential to reduce seed viability, but do not completely inactivate all species. Therefore, digestate can be contaminated with viable seeds and may lead to the spread of weeds, especially after a short-circuited AD. In order to ensure the sustainable use of digestates in terms of weeds, we recommend to investigate the factors contributing to seed inactivation and the quantity of seed introduced to AD. [ABSTRACT FROM AUTHOR]

Proper adjustment of fertilizer dosage is necessary to achieve maximum yield. The use of too little or too much fertilizer can negatively affect plant growth. Nitrogen and phosphorus are two important nutrients in plant nutrition. Research on the combined effect of nitrogen and phosphorus on black cumin is very limited. Therefore, a field study was conducted to determine the effects of different nitrogen and phosphorus doses on the growth, yield and yield components of black cumin (Nigella sativa L.) under Mediterranean conditions during two growing seasons. Five doses (0 kg ha−1or control, 30 kg ha−1, 60 kg ha−1, 90 kg ha−1 and 120 kg ha−1) of nitrogen and four phosphorus doses (0 kg ha−1 or control, 20 kg ha−1, 40 kg ha−1 and 60 kg ha−1) were used as experimental factors. All the parameters except for capsule number were significantly affected by the growing season. Nitrogen dose significantly affected all the examined features except for seed number in capsule, seed weight in capsule and harvest index, while phosphorus dose significantly affected only SY and HI. In general, in the 2021–2022 growing season, black cumin had lower growth, yield and related traits. On the other hand, even though nitrogen fertilization, particularly at 90 kg ha−1 and 120 kg ha−1, had a positive effect on the yield and yield components of black cumin, the optimal nitrogen dose was 90 kg ha−1 for fewer input costs according to the results obtained from the present study. A phosphorus dose of 60 kg ha−1 was determined to be the appropriate dose in terms of seed yield, and this dose can be suggested for maximum seed yield of black cumin. [ABSTRACT FROM AUTHOR]

AbstractThroughout much of the world, critical goods and services are provided by parallel public and private distribution systems. However, it is often difficult to causally differentiate the performance of these two channels. In this article, we utilize a policy change in Malawi to estimate the relative efficiency of public and private channels in distributing inputs to smallholder farmers. In the 2015/16 agricultural season, the government allowed a group of private-sector fertilizer dealers to distribute subsidized fertilizer in nine of the country’s 28 districts. We use a panel dataset and a difference-in-differences (DID) strategy to estimate the impact of the pilot reform on a set of variables encompassing the entire process of subsidized fertilizer acquisition and appropriate utilization. We find that households in districts where the private sector distributed subsidized fertilizer were 11 percentage points more likely to acquire it earlier in the planting season (p < 0.01). We also find that households in pilot districts were six percentage points more likely to apply inorganic fertilizer (p < 0.10), but this effect was no longer statistically significant after using household fixed-effects and correcting for multiple hypothesis testing. Additionally, the reform did not affect other outcomes such as timely fertilizer application or maize yields. [ABSTRACT FROM AUTHOR]

Although chemical fertilization has gained a lot of attention due to its ability to increase the yield of fruit trees, it has been known to cause numerous environmental problems such as soil deterioration, alleviating beneficial microorganisms, and reducing fruit quality and safety. Hence, today, we aim to reduce these problems by using eco-friendly and sustainable biostimulants to promote nutritional status, yield, and quality. The effect of wood vinegar (WV) on mango production has yet to be investigated. Therefore, a field trial was conducted during the 2023 and 2024 seasons to evaluate the regulatory effect of individual and combined application of wood vinegar (WV), seaweed extract (SW), and humic acid (HA) on the performance of mango (Mangifera indica L.) cv. Ewais. The results revealed that all treatments had a pronounced effect and significantly improved the total chlorophyll content (107.7 and 106.6%), leaf N (2.02 and 2.23%), P (0.38 and 0.4), and K (1.07 and 1.13%), as well as enhancing the quality of mango fruits by increasing fruit length (11.68 and 12.38 cm), fruit width (7.8 and 8.59 cm), total sugars (40 and 37.3%), and TSS (21.9 and 20.8%) while reducing the total acidity (64.3 and 69.0%) in the 2023 and 2024 seasons, respectively, compared with the control. Based on this study, the treatment of 2 L/ha seaweed + 2 L/ha humic acid + 2 L/ha wood vinegar combined had the greatest effect on enhancing Ewais mango fruit yield by up-regulating leaf mineral acquisition, antioxidant response, and sugar accumulation. This study supports the application of HA and SW in combination with WV to improve mango fruit yield and quality. [ABSTRACT FROM AUTHOR]

A first attempt to assess the potential alternative use of fire extinguisher filler powder after its exhaustion has been investigated in the present research. The chemical composition of fire extinguisher filler powder, specifically type ABC 40%, consists of monoammonium phosphate and ammonium sulfate. As its nitrogen and phosphorus content is particularly high, the thought of its possible use as a fertilizer and/or a soil amendment is a challenge. For this purpose, a pot experiment was carried out and two leafy vegetables (spinach and lettuce) were used as biomarkers. Two soil samples from rural areas, one acidic (pH = 5.8 ± 0.1) and one alkaline (pH = 8.2 ± 0.7), were selected for the experiments. Filler powder from a used fire extinguisher was added to the soil samples in two levels (1 and 2% v/v). It was found that the addition of fire extinguisher filler powder caused no toxicity to either of the two plants studied. On the contrary, an increase in their above-ground biomass was observed, proportional to the amount of powder added. It was established that in the pots where the powder was added, in both plant species observed, the plant height, root length, and chlorophyll content of leaves increased, the total antioxidant capacity was enhanced, and the concentrations of nitrate and phosphate in the leaves and roots of plants also increased, compared to the soil without the addition of fire extinguisher powder. The early signs appear to be encouraging, as an increase was observed in almost all aspects. The mandatory end of the life cycle of the powder as a fire-extinguishing agent and its disposal is also a challenge in the context of the circular economy, as reducing the energy requirements for fertilizer production is one of the objectives of sustainable development. [ABSTRACT FROM AUTHOR]

Background: The significance of stabilized use of fertilizers is more populous between the farmers to get higher quality of produce. In integrative agricultural system, integrated nutrient management (INM) provide best way to solve numerous issues regarding sustainability, improving quality, boosting yield and keeping good soil fertility in efficient and economical way. Cabbage is one of the most valued crop among cole group vegetables and it is rich in vitamins and minerals like vitamin A, vitamin C, vitamin B1, B2 and B3, sulphur, phosphorus, calcium, magnesium, iron, potassium, sodium etc. Methods: Field experiments were conducted to study the effect of vermicompost, inorganic fertilizers and growth retardant (cycocel) with different spacing in cabbage and carried out in factorial randomized block design at Experimental Farm Bundelkhand University, Jhansi (U.P.) during rabi season 2017-18 and 2018-19. Fertilizers with cycocel treatment increases the accumulation of various minerals and vitamins. Result: Result indicated that quality attributes of cabbage were found to be highest and significant in the treatment where 50% RDF (Inorganic Fertilizer) + 50% Organic (vermicompost) were applied at wider crop geometry (45 cm × 45 cm spacing) along with spraying of 300 ppm cycocel (growth retardant). Head yield of cabbage was positively correlated with various quality attributes. Application of vermicompost along with inorganic in head of the cabbage. The experimental findings indicated that reduction in the amount of inorganic fertilizer was not detrimental to quality of cabbage while applying the vermicompost in proper amount that is 50% in combination with inorganic fertilizers. It is evident that integration of vermicompost and inorganic fertilizer at wider spacing under cycocel treatment enhances the quality of cabbage and also sustaining the fertility of soil. [ABSTRACT FROM AUTHOR]

Agricultural crop production practices are being developed for organic, sustainable, and environmentally friendly farming systems. Developing efficient and resourceful crop fertilizers is significantly important for future agriculture. Various biofertilizers, such as animal manures, composts, and vegetable byproducts, have been successfully applied in agriculture. Anaerobic digestate, organic matter obtained from animal or plant waste processing during anaerobic digestion into biomass, has become popular due to its versatility, multiple purposes, and facile application methods. Digestate has recently been widely used in agriculture to enrich the soil with nutrients and thus increase crop yields. Several studies have shown that anaerobic digestate is a valuable fertilizer that can be used as a biofertilizer in field and greenhouse horticulture. Also, research has been carried out on the use of digestate in hydroponic horticulture. This review presents the research results and discusses the possibilities of using anaerobic digestate in greenhouse horticulture. Its objective is to provide a comprehensive understanding of the application of digestate from various sources and its impact on the growth, progress, yield, and quality of greenhouse-grown vegetables. [ABSTRACT FROM AUTHOR]

This study investigates a novel method of utilizing Direct Air Capture (DAC) technology for fertilizer production. Unlike traditional Direct Air Carbon Capture and Utilization (DACCU) technologies, Direct Air Carbon Capture for Fertilizers (FDAC) has the potential to produce fertilizers directly. This study aims to assess the feasibility of FDAC-based fertilizer production by examining the current state of traditional DAC technologies, evaluating the CO2 fixation potential of FDAC, and analyzing the decarbonization effect of producing fertilizers using FDAC. Our evaluation results indicate that CO2 emissions from producing 1 ton of conventional chemical fertilizer, FDAC fertilizer (current status), FDAC fertilizer with ingredient adjustment (sodium hydroxide), and FDAC fertilizer with ingredient adjustment (magnesium hydroxide) are 1.69, 1.12, 1.04, and 1.06 tons of CO2, respectively. The FDAC fertilizer (current status) emits 0.57 tons of CO2 per ton less than commercial fertilizers. FDAC fertilizers also have the potential to reduce CO2 emissions further when the fertilizer composition is adjusted, offering a promising solution for lowering the environmental impact of fertilizer production. Significant CO2 reduction can be expected by replacing conventional low-intensity chemical fertilizers with FDAC-produced fertilizers. [ABSTRACT FROM AUTHOR]

Nitrogen (N) is one of the most important fertilizers in agriculture because it promotes the growth of plants and the uptake of other plant nutrients. This nutrient plays a significant role in determining the yield and nutrient composition of sweet potato root tubers. Therefore, this study aimed to determine the optimum application rate of N in sweet potatoes to maximize yields and increase growth efficiency. Four levels of N (50, 100, 150, and 200 kg/ha) were applied as treatments. A randomized complete block design was used, and each treatment was replicated five times. Vine length, leaf length, stem thickness, and chlorophyll content were measured weekly, and the storage root yield was determined at the end of the experiment. The results showed a significant effect of the N treatments on plant growth, chlorophyll content, vine length, leaf area index and storage root yield. The chlorophyll content and vine length increased with an increase in the N rate. However, an inverse relationship was observed between storage root yield and N rates; the highest yield was recorded for the 50 kg/ha N treatment and the lowest yield was recorded for the 200 kg/ha N applied. Therefore, a rate of 50 to 100 kg/ha N is recommended for the production of orange-fleshed sweet potatoes. [ABSTRACT FROM AUTHOR]

A field study (three years) was carried out to evaluate the outcome of various organic nutrient management technologies including farmyard manure (FYM) and poultry manure (PM) integrated with chemical fertilizers for microbial dynamics and growth and yield of rice at Experimental Farm of Nuclear Institute of Agriculture (NIA), Tandojam, Sindh, Pakistan. The most broadly grown rice variety, NIA-Shandar was selected for this study. The experiment involved integrating organic technologies, specifically Farm Yard Manure (FYM) and Poultry Manure (PM), each applied at 10 tons per hectare. These organic technologies were combined with varying levels of inorganic fertilizers: half (60 kg N ha-1 and 45 kg P2O5 ha-1) and full (120 kg N ha-1 and 90 kg P2O5 ha-1) recommended doses. Additionally, zinc was applied at 10 kg ha-1 . The study employed a randomized complete block design (RCBD) with three replications to assess treatment effects. Both organic technologies perform better for microbial dynamics and rice growth and yield enhancement either alone technology or combined with chemical fertilizers during three rice seasons. The maximum general microbial abundance (9.70 log10 CFU g soil-1), N2 fixing (7.37 log10 CFU g soil-1), P solubilizing (7.97 log10 CFU g soil-1) and Zn solubilizing (6.75 log10 CFU g soil-1) population was recorded in FYM alone or with half N and P2O5 fertilizer application. The highest plant height (106 cm), tiller numbers (17.10), panicle numbers (26.53), panicle length (26.32 cm), one thousand grain weight (26.53 g) and rice grain yield (7.92 t ha-1 ) were perceived in FYM with full rate N and P2O5 fertilizer application. Both technologies along with chemical fertilizer induced soil properties and soil nutrients which reflected to increase soil microbial abundance and growth and yield of rice however, FYM showed higher potential than poultry manure during the three years rice cultivation seasons. Hence, it was indicated that a significant contribution to the development of sustainable agricultural technologies that prioritize soil health, environmental stewardship, and food security. [ABSTRACT FROM AUTHOR]

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Textile waste is becoming among the most polluting waste in the world, discarded mostly in landfills. Valorizing textile waste via anaerobic digestion (AD) helps conserve resources, reduce environmental impact, and foster a circular economy. Although several reviews have discussed textile waste AD, there is a lack of detailed understanding of the challenges encountered during textile waste AD. Therefore, the goal of this review is to focus on challenges encountered and possible solutions for those challenges for biogas and fertilizer conversion via AD. Potential strategies include chemical, biological, and thermal pretreatments that significantly increase the digestion process. Co‐digestion of natural textile waste, cotton, and wool with carbon and nitrogen‐rich substrates improves AD efficiency by twofold. Moreover, separating polyester from polycotton and textile dye removal via solvent and advanced oxidation processes significantly increases methane yield compared with untreated textile waste. This review can aid in analyzing suitable methods to optimize the biogas production of textile waste via AD. [ABSTRACT FROM AUTHOR]

Fertilizer recommendation is the crucial factor to be considered in automation of agricultural predictions. Fertilizer fill the necessary portion of any farming region. There are some micronutrients and macro nutrients which need to be given to crops for proper growth. If fertilization is not done to an optimum level, it may badly harm the soil quality and crop health, so optimum fertilization is important. In this paper we discuss fertilizer and nutrient recommender, where we have used a new feature selection methodology. We have shown the difference between two implementation cases considering presence and absence of feature ranking and selection. Feature ranking and selection has clearly increased the efficiency of the fertilizer & nutrient recommender in our work from 85% to 98%. Feature selection & raking has been introduced with random forest approach. [ABSTRACT FROM AUTHOR]

Introduction: Dracocephalum moldavica L. is a herbaceous, annual plant from the Lamiaceae family that is native to Central Asia and domesticated in Central and Eastern Europe. Essential oil of this plant has antimicrobial and bacterial properties and has many uses in the pharmaceutical, cosmetic, food and perfumery industries. Lead stress in plants causes disturbances in mitosis, leaf chlorosis, decreasing of the vegetative and productive growth stages and reduces photosynthesis and enzyme activities. One of the effects of lead toxicity is due to the similarity of the structure of calcium ions and lead, and for this reason, lead ions disrupt many mechanisms related to calcium ions and prevent the activity of key enzymes.Photosynthesis is one of the most sensitive metabolic processes to lead toxicity, and several studies have reported the inhibition of photosynthesis under lead stress in various plants. Lead prevents the absorption of elements such as magnesium and iron. These elements play a role in the structure of chlorophyll and the oxygen-releasing complex in photosystem II. Heavy metals such as lead inhibit chlorophyll biosynthesis by inhibiting the enzymes gamma-aminolevalonic acid dehydrogenase and protochlorophyll reductase. Also the availability of different nutrients in the soil changes significantly under the influence of environmental stress so that using of vermicompost can be useful in stress condition as well as Jasmonate. Jasmonate is the final oxidation product of unsaturated fatty acids such as linolenic acid, that is effective in increasing the activity of plant defense systems under environmental stress conditions such as lead stress. In order to study the effect of pb (0, 100, 200, 300, 400 mg kg-1 soil) and jasmonate (0, 50, 100, 150 mmol l-1) on Dracocephalum moldavica L. under controlled conditions in soil enriched with vermicompost and without vermicompost an experiment designed and it was done under greenhouse conditions. Materials and methods: This test was done in a random factorial design with 4 repeats and indices including CO2 assimilation rate, transpiration rate, stomatal conductance, water use efficiency(WUE), PSII photochemical efficiency (Fv/Fm), photosynthesis quantum performance, electron transfer rate (ETR), were measured in vegetative and reproductive growth stages. Results and discussion: In the conducted study, it was found that CO2 assimilation rate, water use efficienty, stomatal conductance and Fv/Fm were significantly decreased as lead concentration was increased. Also jasmonate treatment significantly increased CO2 assimilation rate, water use efficienty, stomatal conductance and Fv/Fm in lead stress condition. So that plant treated with 400 mg kg-1 soil pb and 0 mmol l-1 jasmonate showed the lowest CO2 assimilation rate, water use efficienty, stomatal conductance and Fv/Fm while plant treated with 0 mg kg-1 soil pb and 150 mmol l-1 jasmonate showed the highest CO2 assimilation rate, water use efficienty, stomatal conductance and Fv/Fm. transpiration rate was significantly increased as well as increasing pb concentration so that plant treated with 400 mg kg-1 soil pb showed the highest transpiration rate. Also jasmonate treatment significantly decreased transpiration rate in lead stress condition. Vermicompost increased CO2 assimilation rate, water use efficienty, electron transfer rate (ETR) and significantly decreased transpiration rate in lead stress condition. Jasmonate reduces the destructive effects caused by stress on photosynthetic indicators such as the amount of chlorophyll and carotenoids and also increases the performance of photosystem II and consequently increases plant photosynthesis under stress conditions. It has been reported that methyl jasmonate can maintain the concentration of chlorophyll in the reaction center, thereby improving the speed of electron transfer and increasing the efficiency of photosystem II. In addition, jasmonate can prevent the severe reduction of stomatal conductance under stress conditions and increase the quantum efficiency of photosynthesis. In the response of plants to stress, jasmonates act as genes encoding inhibitory proteins such as theonine, hydroxyproline and proline, and in general, by activating defense mechanisms, they help the plant in reducing the absorption and accumulation of heavy metals. Organic fertilizers can also improve plant performance under environmental stress conditions. Vermicompost fertilizer increases porosity, increases absorption and retention of nutrients, improves ventilation, drainage and microbial activity in the soil. Conclusion: Having nutritious mineral elements and plant growth hormones can improve plant growth in the presence of environmental pollutants such as heavy metals by influencing the physiological characteristics. It can be said based on the results obtained lead stress decreased photosynthesis index through effect on electron transport chain and photosynthetic pigments while jasmonate treatment and Soil enriched with vermicompost can reduce the destructive effects of lead stress. So that using of jasmonate and vermicompost in lead stress condition Recommended. [ABSTRACT FROM AUTHOR]

The impact of fertilization and irrigation on heavy metal accumulation in saline–alkali soil and its underlying mechanisms are critical issues given the constraints that soil salinization places on agricultural development and crop quality. This study addressed these issues by investigating the effects of adjusting organic fertilizer types, proportions, and irrigation volumes on the physicochemical properties of lightly to moderately saline–alkali soils and analyzing the interaction mechanisms between microorganisms and heavy metals. The results indicate that the rational application of organic fertilizers combined with supplemental irrigation can mitigate soil salinity accumulation and water deficits, and reduce the soil pH, thereby enhancing soil oxidation, promoting nitrogen transformation and increasing nitrate–nitrogen levels. As the proportion of organic fertilizers increased, heavy metal residues, enrichment, and risk indices in the crop grains also increased. Compared to no irrigation, supplemental irrigation of 22 mm during the grain-filling stage increased soil surface Cd content, Zn content, and the potential ecological risk index (HRI) by 10.2%, 3.1%, and 8%, respectively, while simultaneously reducing the heavy metal content in grains by 12–13.5% and decreasing heavy metal enrichment. Principal component analysis revealed the primary factors influencing Cu and Zn residues and Cd accumulation in the crop grains. Soil salinity was significantly negatively correlated with soil pH, organic matter, total nitrogen, and ammonium nitrogen, whereas soil organic matter, total nitrogen, ammonium nitrogen, soil pH, oxidation–reduction potential, soluble nitrogen, and microbial biomass nitrogen were positively correlated. The accumulation and residues of Zn and Cu in the soil were more closely correlated with the soil properties compared to those of Cd. Specifically, Zn accumulation on the soil surface was primarily related to aliphatic organic functional groups, followed by soil salinity. Residual Zn in the crop grains was primarily associated with soil oxidation–reduction properties, followed by soil moisture content. The accumulation of Cu on the soil surface was mainly correlated with the microbial biomass carbon (MBC), whereas the residual Cu in the crop grains was primarily linked to the soil moisture content. These findings provide theoretical insights for improving saline–alkali soils and managing heavy metal contamination, with implications for sustainable agriculture and environmental protection. [ABSTRACT FROM AUTHOR]

The aim of this work is a synthesis of suitable hydrogel to produce slow‐release fertilizer using recycled cellulose which is obtained from waste paper. For this purpose, initially, we extracted alpha cellulose from waste paper and modified it to obtain carboxymethyl cellulose (CMC). Then, the CMC was converted to a suitable hydrogel through in situ graft copolymerization of acrylic acid and vinyl acetate in the presence of methylene bisacrylamide as a crosslinker. The various factors that affect hydrogel synthesis, such as the amounts of CMC, monomers, initiator, and crosslinker, were evaluated. In the optimized formulation, the weight ratio of monomers to CMC is 7, the molar ratio of monomers to each other is 1, and the crosslinker is used as 3 molar percent of monomers. The products were characterized using Fourier transform infrared, thermal gravimetric analysis, and scanning electron microscope analyses. The swelling behavior of the synthesized hydrogels was evaluated in different environments, such as distilled water, tap water, salt water, and different pH levels. The swelling ratio increases with an increase in pH level. Between the synthesized hydrogels, the best one was selected for slow‐release fertilizer production and loaded with 20‐20‐20 fertilizer (NPK), and the release behavior was evaluated. In an alkaline pH, there was a long time for NPK release within a slow‐release medium and even after 361 h, the release process was continued. Also, the performance of the fertilizer‐loaded hydrogel in soil using water holding capacity and water retention ratio tests were evaluated. [ABSTRACT FROM AUTHOR]

Global warming delays the harvest of kharif crops, which delay the subsequent sowing of Indian mustard, especially in northwestern India and also causes dry winters that exacerbate challenges for the timely sowing of rabi-crops. To check this, a field experiment was conducted during the Rabi-seasons of 2018–19 and 2019–20 to assess the influence of sowing dates, irrigation, and fertilizer levels under late-sown conditions. A split-plot design was used with two sowing dates, two irrigation levels and four fertilizer levels (87.5%, 100%, 112.5% and 125% RDF; Recommended-fertilizers-dose). Crop sown in the 4th week of November significantly reduced seed (46.79 and 38.77%) and stover yield (43.72 and 41.62%) as compared to the 2nd week of November sowing during 2018–19 and 2019–20, respectively. Uptake of NPK by seed and stover was higher with the 2nd week of November sowing. The 2nd week of November sowing resulted in significant increase in water productivity by 63.72% and Benefit cost ratio (B:C) by 75.45% over the 4th week of November sowing. Irrigation at flowering stage increased the seed yield, water productivity and B:C by 11.94%, 1.72% and 9.17%, respectively, as compared to No post-sown irrigation. The biological yield of the Indian mustard increased with every increase in fertilizer doses but the response was significant up to 112.5% RDF (90 kg N, 33.75 kg P2O5 and 22.5 kg K2O ha−1). Application of 112.5% RDF increased the seed, stover yield, water productivity and B:C by 16.17%, 9.29%, 15.66% and 11.27%, respectively, over 87.5% RDF. [ABSTRACT FROM AUTHOR]

This study investigates the wall thickness and specific surface area (SBET) of ammonium nitrate(V) samples of varying provenance. The research focuses on both fertilizer-grade ammonium nitrate(V) and three porous prill samples obtained from different manufacturers. The samples were analyzed using tomography scanning and two distinct porosimetry methods. The wall thickness analysis revealed that fertilizer-grade ammonium nitrate(V) possesses thicker walls, ranging from 0.05 to 0.40 mm, compared to porous prill-type ammonium nitrate(V), which predominantly exhibited wall thicknesses between 0.05 and 0.025 mm, with occasional thicker regions up to 0.040 mm. These variations in wall thickness are likely attributable to differences in manufacturing processes and prilling conditions specific to the ammonium nitrate(V) porous prill-type samples. The specific surface area (SBET), derived from nitrogen adsorption measurements, indicated that the samples exhibited surface areas ranging from 0.011 to 0.466 m2·g, suggesting that these samples do not exhibit particularly high absorption capacities. However, the SBET values obtained from the mercury intrusion method suggested significantly higher absorption capacities, falling within the range of 4.87–18.29 m2·g. These findings suggest that mercury porosimetry may provide a more accurate assessment of the porosity and absorption potential of ammonium nitrate(V) samples. [ABSTRACT FROM AUTHOR]

Soil organic carbon (SOC) plays an important role in maintaining or increasing soil fertility and quality in paddy field, but there is limited information about how SOC mineralization responds to different fertilizer managements under the double-cropping rice system in southern China. Therefore, this study was designed to explore changes in SOC content, soil enzyme activities, SOC mineralization at 0–10 cm and 10–20 cm layers, and its relationship with long-term fertilizer managements in a double-cropping rice system of southern China. The experiment included four fertilizer treatments: chemical fertilizer alone (CF), rice straw and chemical fertilizer (RS+F), 30% organic manure and 70% chemical fertilizer (OM+F), and without fertilizer input as a control (Con). These results showed that SOC and labile organic carbon contents at 0–10 cm and 10–20 cm layers in paddy field with RS+F and OM+F treatments were increased, compared to CF and Con treatments. Compared with Con treatment, SOC mineralization rate and accumulation with CF, RS+F, and OM+F treatments were increased. SOC accumulation and potential mineralization at 0–10 cm and 10–20 cm layers with RS+F and OM+F treatments were increased, compared with CF and Con treatments. SOC mineralization rate and accumulation at 0–10 cm layer with CF, RS+F, OM+F, and Con treatments were higher than that of 10–20 cm layer. These results indicated that soil invertase, cellulose and urease activities in paddy field with RS+F and OM+F treatments were significantly higher than that of CF and Con treatments. There was a significant positive relationship between SOC accumulation and SOC content, soil invertase, cellulose, urease activities but were significant negative correlated with soil pH, bulk density. As a result, these were beneficial practices for improving SOC content and SOC mineralization in a double-cropping rice field of southern China by combined application of rice residue or organic matter with chemical fertilizer managements. [ABSTRACT FROM AUTHOR]

Agronomy biofortification is an important crop management strategy to enhance concentrations of micronutrients in edible portions. The availability of micronutrients for plant uptake is reduced by the high salinity, pH, and lime of soils. Hence, this study aimed to determine the most appropriate time and the best ratio of zinc (Zn) and iron (Fe) consumption during the wheat growth stages in a saline and calcareous soil. The experiment consisted of two factors with four levels; 0, 30, 60, and 120 kg Zn ha−1 as Zn0, Zn1, Zn2, and Zn3 respectively, and 0, 2.5, 5, and 7.5 kg Fe ha−1 as Fe0, Fe1, Fe2, and Fe3 respectively, in a randomized complete block design with four replications. The results showed that the interaction effects of Fe and Zn fertilizers application were significant on the wheat yield indices and concentration of Fe and Zn in wheat shoots and grain. The simultaneous application of 120 kg Zn ha−1 and 5 kg Fe ha−1 caused significant improvement (p < 0.05) in thousand kernel weight (9.1%) and subsequently grain yield (23.4%) compared to the control treatment. The Zn concentration in the wheat shoot during tillering (37.0–58.2 mg Zn kg−1) was higher than the other two growth stages (elongation (29.2–40.8 mg Zn kg−1) and booting (20.0–31.0 mg Zn kg−1)). While the highest Fe concentration in wheat shoots was observed at the stem elongation stage (98.5–268.8 mg Fe kg−1), then the booting stage (91.0–150.8 mg Fe kg−1) and finally the least absorption was at the tillering (80.0–120.0 mg Fe kg−1). Because of the high calcium carbonate, salinity and Zn- deficient soil of the experimental site, the Zn concentration in wheat grain was obtained in a range of 3 to 19 mg kg−1. The results clarified that the fertilizer application of 30 kg Zn ha−1 and 2.5 kg Fe ha−1 can be proportionally and simultaneously increased the concentration of Fe and Zn in wheat grain by 100%. Therefore, the soil application of 30 kg Zn and 2.5 kg Fe per hectare proposed for improvement in quantitative (619 kg ha−1 increase in wheat grain yield) and qualities (100% increase in grain Zn and Fe concentration and 8% increase in thousand kernel weight) indices of wheat yield in calcareous and saline soils. [ABSTRACT FROM AUTHOR]

Among the steelmaking slag, secondary metallurgy slag (SMS) is the most problematic to be recycled. Several attempts to recover such slag as lime replacement, slag flux, pozzolanic materials have been made for long time with pros and cons. However, the amount of recyclable slag is limited and often their employment requires higher energy demand than traditional materials. Nevertheless, the use of SMS in agriculture is poorly or never considered. In this article, the legal and technical evaluation of SMS as raw material for fertilizers production is investigated. Compliance of technical specification, toxic metals concentration, and leaching behavior allows to confirm the technical feasibility of SMS use as a raw material for fertilizers manufacture. Both from the literature data and the experimental results on 16 industrial SMS samples, the requirements for calcium‐magnesium‐sulfur‐based fertilizers, soil correctives and for sanitizing agricultural sewage sludge, appear fully satisfied. The CaO concentration in SMS (35–60 wt%) is abundantly higher than the requirements (≥15 wt%) and CaO is present in most part as water‐soluble complexes such as calcium aluminates (70 wt%), silicates (10 wt%), and sulfide (4 wt%). The pH of the SMS samples leachate is comparable to that of fresh lime (12.35 vs 12.46), highlighting a better behavior for sewage sludge sanitation with respect to limestone (9.98). The measured toxic metals and leachate elements concentration over the corresponding admittable threshold are always lower than 0.5 and 1.0 (mg kg−1/mg kg−1) for liming materials. Finally, these results lead to officially approve the use of SMS as soil corrective according to the Italian Fertilizer Regulation. [ABSTRACT FROM AUTHOR]

Phosphorus is considered one of the essential elements for legumes as it increases nitrogen fixation due to nodulation. Hence, for high productivity in legumes, it should be added as inorganic or organic fertilizer to soils containing insufficient phosphorus. Especially in recent years, using inorganic and organic fertilizers together has gained importance in terms of sustainable agriculture, considering plant growth and soil and environmental health together. The effects of three different doses of phosphorus fertilizer (0, 50, 100 kg P2O5 ha-1), and two different doses of poultry manure (0, 3 t ha-1) applications with two different doses (B0 or B1) of phosphorus solubilizing bacteria (Bacillus megaterium M-3) inoculation on hay yield and yield components of common vetch were examined in this study. In fact, while the highest hay yield and crude protein rate were obtained by bacterial inoculation together with phosphorus fertilizer application, the effect of poultry manure application on yield and yield parameters was variable. Instead, the applications had no significant effect on the number of main branches, ADF and NDF rates. Consequently, the application of 100 kg P2O5 ha-1 together with Bacillus megaterium inoculation can be recommended for high hay yield in common vetch under irrigated conditions in areas with poor or medium soils in terms of phosphorus. [ABSTRACT FROM AUTHOR]

This research was carried out under field conditions to determine the effect of PGPB on the yield and quality of Pulsar F1 eggplant variety under Igdir ecological conditions in 2021. The experiment was conducted with 8 treatments (Brevibacillus reuszeri strain IT 119, Kluyvera cyrocrescens strain IT 160, IT 119 + IT 160, IT 119 + Fertilizer, IT 160 + Fertilizer, IT 119 + IT 160 + Fertilizer, Fertilizer and Negative Control) with 3 replications according to the randomized block design. Bacterial strains were applied by inoculating 100 ml (106 cfu/ml) to the root zone of the plants during seedling stage. PGPB treatments increased total yield, discard yield, marketable yield, plant height, plant stem thickness, number of leaves, plant root wet weight, plant root dry weight, stem wet weight, stem dry weight, number of fruits per plant, fruit wet weight, fruit dry weight and root length compared to negative and positive control groups. The treatments had no effect on fruit diameter. Although both strains were found to be successful, especially Kluyvera cyrocrescens strain IT 160 alone and in combination showed positive effects in terms of the parameters examined in eggplant plants and has the potential to be used as biofertilizer. [ABSTRACT FROM AUTHOR]

Mined rock phosphate is expected to become a scarce resource within the next few decades as global phosphorus (P) deposits are declining. As a result, mineral P fertilizer will be less available and more expensive. Therefore, improved knowledge is needed on other P resources, for example, apatite fertilizers derived from the by‐products of iron mining. Forestry is a potential future consumer of apatite‐rich products with the aim of obtaining more wood per hectare. The actual P availability in apatite to plants has so far been barely quantified. We therefore examined tree P uptake using 33P apatite under chamber‐grown and outdoor conditions. We examined the P uptake for the two main conifer species spruce (Picea abies) and pine (Pinus sylvestris) used in Fenno‐Scandinavian forestry. We synthesized 33P‐enriched apatite and applied it to mesocosms with growing seedlings of spruce and pine. The P uptake from 33P‐labelled hydroxylapatite was subsequently traced by (bio)imaging of radioactivity in the plants and by liquid scintillation counting (LSC) upon destructive harvest in all plant fractions (leaves, stem and roots) and rhizosphere soil. Two climatic conditions were compared, one at natural outdoor conditions and one set as 5°C warmer than the climate record from the previous years. Plant P uptake from 33P‐labelled hydroxylapatite was enhanced in chamber‐grown compared with outdoor seedlings for both tree species. This uptake was manifested in the clear radioactive images obtained over ca. 1 month after soil apatite application. Furthermore, all aboveground plant fractions of both spruce and pine seedlings showed a higher P uptake in warmer than colder daytime environments. The observed quantities and rates of P uptake from 33P‐labelled hydroxylapatite by spruce (18 Bq g−1 hour−1) and pine (83 Bq g−1 hour−1; averages in chamber condition) are as to our knowledge unique observations. Natural forest soils in Sweden are often P‐poor. Our research suggests that apatite‐based P fertilization of spruce and pine forests can increase wood production by overcoming any existing P limitation. [ABSTRACT FROM AUTHOR]

In this study, the effects of chemical fertilizers and fertilizers containing microorganisms on broccoli yield were examined. It is aimed to reduce the amount of chemical fertilizer by using microorganisms. Mundo F1 Broccoli variety was used as plant material. The research was established according to the randomized block trial design with 3 treatments and 3 replications, and 20 plants were used in each replication. Applications: 1. Control: 100% chemical fertilization (U1), 2. Treatment II: 70% chemical fertilization + Microorganisms (U2), 3. Treatment II: 100% chemical fertilization + Microorganisms (U3). The aim of the study is the effects of chemical fertilizers and microorganisms on plant growth and development; To examine the effect of plant height, stem diameter, number of leaves and yield. It was concluded that the number of leaves, plant height and stem diameter generally increased in the plots where microorganisms were applied. When the results were evaluated in terms of yield compared to the control treatment, U2 treatment increased yield by 20% and U1 treatment increased yield by 15%. [ABSTRACT FROM AUTHOR]

Agricultural environmental pollution needs to be reduced in our future. The biggest obstacles to preventing this situation are that agricultural inputs such as synthetic fertilizers increase product yield and scattered agricultural areas. This study involves the optimization of the production process of an easy-to-apply organic fertilizer with high nutritional value by subjecting bat guano, one of the valuable organic fertilizers, to anaerobic digestion together with cattle manure. Response surface method Box-Behnken design, a statistical model, was used for process optimization. The process input parameters were temperature, cattle manure, and bat manure, and the response value was considered as 2% total nitrogen. As a result of the optimization for a total nitrogen value of 2%, the optimum mixture ratio was determined as cattle manure 77.0448%, bat manure 12%, and temperature 40 °C. Analysis results showed that the addition of bat manure increased the N, P, K, and humic and fulvic acid values in the fertilizer. The study revealed that strong organic fertilizers can be used to increase the value of cattle manure organically. It also offers very promising results based on reducing agricultural pollution and ensuring agricultural sustainability. [ABSTRACT FROM AUTHOR]

The increasing occurrence of oil pollution presents a significant environmental challenge, necessitating effective remediation strategies. Hence, the objective of this paper was to evaluate the effect of Nitrogen-15, Phosphorus-15, and Potassium-15 fertilizer on indigenous microorganisms involved in biodegradation of crude oil contaminated soil collected from Shawguwolo Jeddo Metropolis, Okpe L. G. A, Delta State, Nigeria using appropriate standard methods. It was observed that the hydrocarbon reduced from 5315.80 to 2276.57 within four weeks. The highest rate was observed in sample C, which showed a 95.7% reduction in the hydrocarbon contamination. Sample C also showed a 34% increase in the hydrocarbon utilizing bacteria present in the soil. Bioremediation leverages microbial activity to degrade pollutants, offering a cost-effective approach compared to other technologies, as it speeds up the process of degrading hydrocarbon by increasing the growth rate of hydrocarbon utilizing bacteria. [ABSTRACT FROM AUTHOR]

Hemp (Cannabis sativa L.), renowned for its applications in environmental, industrial, and medicinal fields, is critically evaluated in this comprehensive review focusing on the impacts of chemical and organic fertilizers on its cultivation. As hemp re-emerges as a crop of economic significance, the choice between chemical and organic fertilization methods plays a crucial role in determining not only yield but also the quality and sustainability of production. This article examines the botanical characteristics of hemp, optimal growth conditions, and the essential biochemical processes for its cultivation. A detailed comparative analysis is provided, revealing that chemical fertilizers, while increasing yield by up to 20% compared to organic options, may compromise the concentration of key phytochemicals such as cannabidiol by approximately 10%, highlighting a trade-off between yield and product quality. The review presents quantitative assessments of nitrogen (N), phosphorus (P), and potassium (K) from both fertilizer types, noting that K significantly influences the synthesis of terpenes and cannabinoids, making it the most impactful element in the context of medicinal and aromatic hemp varieties. Optimal rates and timing of application for these nutrients are discussed, with a focus on maximizing efficiency during the flowering stage, where nutrient uptake directly correlates with cannabinoid production. Furthermore, the challenges associated with the U.S. industrial hemp market are addressed, noting that reducing production costs and improving processing infrastructure is essential for sustaining industry growth, especially given the slow expansion in fiber and cannabidiol markets due to processing bottlenecks. The review concludes that while chemical fertilizers may offer immediate agronomic benefits, transitioning towards organic practices is essential for long-term environmental sustainability and market viability. The future of the hemp industry, while promising, will depend heavily on advancements in genetic engineering, crop management strategies, and regulatory frameworks that better support sustainable cultivation practices. This nuanced approach is vital for the industry to navigate the complex trade-offs between productivity, environmental health, and economic viability in the global market. [ABSTRACT FROM AUTHOR]

The main objective of the present work was to assess the ecotoxicological safety of the use of thermochemically treated sewage sludge from the wastewater treatment plant (WWTP) of a distillery plant as a soil additive in agricultural soils based on its physicochemical characteristics and the bioaccumulation of selected elements in the plant tissues of maize (Zea mays). We have carried out physicochemical characterization (pH, EC, Corg, Cinorg, CEC, N, H, ash content, PAHs) of sewage sludge feedstock (SS) and sludge-derived biochar (BC) produced by slow pyrolysis at a temperature of 400 °C. The effect of 1% (w/w) amendment of SS and BC on soil physicochemical properties (pH, EC, Cinorg), germination of ryegrass, soil rhizobacteria and microorganisms, as well as on the accumulation and translocation of selected elements in maize (Zea mays) was studied. The results show that pyrolysis treatment of distillery WWTP sludge at 400 °C increases pH (from 7.3 to 7.7), Corg(from 28.86% to 36.83%), N (from 6.19% to 7.53%), ash content (from 23.59% to 50.99%) and decreases EC (from 2.35 mS/cm to 1.06 mS/cm), CEC (from 118.66 cmol/kg to 55.66 cmol/kg), H (from 6.76% to 1.98%) and Σ18 PAHs content (from 4.03 mg/kg to 3.38 mg/kg). RFA analysis of SS and BC showed that pyrolysis treatment multiplies chromium (Cr) (2.2 times), nickel (Ni) (2.96 times), lead (Pb) (2.13 times), zinc (Zn) (2.79 times), iron (Fe) (1.26 times) in the obtained BC, but based on an ecotoxicological test with earthworms Eisenia fetida, we conclude that pyrolysis treatment reduced the amount of available forms of heavy metals in BC compared to SS. We demonstrated by a pot experiment with a maize that a 1% addition of BC increased soil pH, decreased EC and Cinorg and had no significant effect on heavy metal accumulation in plant tissues. According to the results of the three-level germination test, it also does not affect the germination of cress seeds (Lepidium sativum). There was a significant effect of 1% BC addition on soil microbial community, and we observed a decrease in total microbial biomass and an increase in fungal species variability in the soil. Based on these results, we conclude that BC represents a promising material that can serve as a soil additive and source of nutritionally important elements after optimization of the pyrolysis process. [ABSTRACT FROM AUTHOR]

Phosphorus (P) plays an integral part in Iowa's economic and environmental activities through its role as an essential nutrient and waterborne pollutant. However, the amount of phosphorus transported through these activities has not been well quantified. This study estimates the annual mass of P entering and exiting Iowa's landscape from 1998 to 2022 through seven transport pathways. Four input pathways (fertilizer application, manure production, industrial sources, and human sources) and three output pathways (harvesting, livestock grazing, and stream export) were quantified using various agricultural, economic, and water quality datasets. We also estimated the total mass of P present in the top 0.61 m layer of Iowa's landscape using results from a statewide soil sampling survey. The harvest component was the largest, with annual values consistently above 200 million kg. This was followed by the fertilizer and manure components, with annual values near 100 million kg. The other components were much smaller; the mean grazing and stream export values were 15 and 19 million kg, respectively, and human and industrial sources were less than 4 million kg. Stream export was the most dynamic pathway, with the largest coefficient of variation (0.59). The net P budget (inputs–outputs) was negative in 20 of the 25 years assessed, indicating that Iowa typically runs a P deficit. A trend analysis revealed that the manure, human, industry, and harvesting components increased across the 1998–2022 period while the grazing component decreased. The mass of P in Iowa's top layer of soil was 81.5 billion kg—orders of magnitude larger than any individual budget component. This analysis provides a new perspective on P transport pathways in Iowa and may help inform policymakers as they make decisions on the many activities involving P. [ABSTRACT FROM AUTHOR]

Slow-release fertilizer was developed by encapsulating NPK compound pellets with graphene oxide (GO) sheets employing a waterless synthesis technique. As-prepared GO sheets were characterized by XRD, Raman, XPS, FTIR, SEM, and EDS. The XRD patterns of the GO sheets indicate that the peak for the GO is observed at 2θ = 9.3°, and the peak (002) for graphite vanished. Moreover, a higher intensity ratio of the Raman ID/IG of the GO sheets than that of pristine graphite confirms the oxidation of the graphite. The FTIR and XPS analyses provided information on electronic structure, chemical structure, and oxygen-bonding neighbors. The SEM images indicated the GO sheet, whereby its morphology resembles a thin curtain or corrugated shape. The EDS spectrum of coated GO-F pellets revealed the distribution of C, O, N, P, and K elements in the synthesized materials. Afterwards, GO shell formation on fertilizer pellets greatly improved the slow-release characteristics of fertilizer, thus providing plants with their requisite nutrients and reducing environmental pollution. [ABSTRACT FROM AUTHOR]

Research on the observation of nutrient release rates from slow-release and regular fertilizers combined with the percolation rate in the soil is scarce. This work aims to observe potassium and phosphate release behavior from slow-release and regular fertilizer, followed by the percolation of that nutrient in the soil. The characteristics of the soil were analyzed using X-ray Diffraction (XRD), X-ray Fluorescence (XRF), and Scanning Electron Microscope (SEM). The concentration of potassium and phosphate in soil is analyzed using Atomic Absorption Spectroscopy (AAS) and Ultraviolet–Visible Spectroscopy (UV–Vis), respectively. The release rate of nutrients from slow-release fertilizer is 6 to 8 times slower than regular fertilizer. Meanwhile, the rate of nutrients released from slow-release and regular fertilizer followed by soil percolation matches the quadratic equation. Potassium adsorption on the soil surface is significantly higher than that of potassium. The negativity of soil polarity contributed to the high level of potassium adsorption on soil particle surfaces. The low phosphate adsorption capability of magnetite and the negativity of soil polarity contributed to the soil's low phosphate adsorption. [ABSTRACT FROM AUTHOR]

As carbon capture and storage (CCS) technologies mature, the concept of a low-carbon or net-zero-carbon economy becomes more and more feasible. While many chemical and energy products do not contain carbon in their compounds, the upstream production process does. An added CCS module allows the removal of carbon emissions from the production process, which expands the value chain. This paper focuses on one of such commodities—low-carbon-intensity ammonia (LCIA). Even though ammonia is carbon-free in its final product, it is commonly made from natural gas, and the production process could generate significant carbon emissions. The idea of LCIA is to reduce the carbon footprint of the ammonia production process (e.g., blue ammonia) or eliminate carbon from the production process (e.g., green ammonia via electrolysis) so that the entire supply chain is decarbonized. The goal of this paper is two-fold. We first explore the US domestic market and the international market for LCIA. We then discuss relevant federal and local policies that could help grow markets for LCIA. The agricultural sector will be the center of the discussion, which consumes an estimated 70–90% of the global ammonia supply as fertilizers. The paper also examines other potential uses of LCIA, such as alternative fuels for decarbonizing agricultural machinery and transportation sectors. Finally, we argue that developing a comprehensive LCIA value chain, supported by dedicated policy measures and broad stakeholder engagement, is critical for materializing the potential of LCIA in contributing to a climate-resilient and sustainable economy. [ABSTRACT FROM AUTHOR]

Abstract Background An importance of tillage, inorganic and organic nutrient sources in the mustard - soybean cropping system lies in their ability to enhance soil fertility, improve nutrient availability, optimize crop growth and yield, and promote sustainable agricultural practices. Any cropping system’s sustainability could be increased by implementing better management techniques like zero and reduced tillage with residue retention and better nutrient sources. Results A field experiment was conducted for four consecutive seasons (Winter 2019 to Rainy 2021) to compare the two enhanced management practices, zero and reduced tillage to conventional tillage across four levels of nutrient sources: 75 and 100% recommended dose of nitrogen through FYM and 75 and 100% recommended dose of fertilizers through urea, single super phosphate and muriate of potash in a two years experiment. Experiment results were evaluated in terms of nutrient status, profitability and productivity of Mustard-Soybean cropping system. The results show a substantial improvement in yield, nutrient status, and overall yield performance of mustard and soybean when using the full recommended dose of fertilizers combined with reduced tillage and mulching, compared to other treatment methods. The implementation of reduced tillage practices recorded significantly higher yield of mustard and soybean over conventional and zero tillage. Conclusion System productivity and profitability i.e. mustard equivalent yield, productivity, gross returns, net returns, profitability and B: C (benefit: cost) was found to be improved with reduced tillage and 100% recommended dose of fertilizer under reduced tillage practices. To enhance cropping system productivity in various sub-humid regions worldwide, farmers can adopt reduced tillage techniques combined with the full recommended dose of fertilizers (100% RDF).

Indonesia has the potential to develop alternative food sources, one of the cereal crops that has the potential and prospects to be developed is job's tears (Coix lacrima-jobi L.). Efforts that can be made to increase job's tears production are variety selection, proper cultivation techniques, and favorable environmental conditions. Fertilization is one of the most important factors that need to be considered in plant cultivation techniques. This research was conducted in Padang city, West Sumatera. The research was factorial in the form of a complete random design. The job’s tears cultivars used in this riset were Pulut and Batu. The purpose of this study was to determine the effect of NPK fertilizer on growth and yields of two job’s tears cultivars. NPK fertilizer dosage treatment in this study consisted of : 0 kg/hectare, 100 kg/hectare, 200 kg/hectare, and 300 kg/hectare. The results showed that there was no interaction between NPK fertilizer and two job’s tears cultivars. Pulut showed the highest mean values on growth variables (plant height, leaf length, and stem diameter), but Batu showed the highest mean values on yield variables (seed weight / plant). While the best dose of NPK fertilizer to increase growth and yield is 300 kg/hectare.

Many farmers use chemical fertilizers to increase their agricultural productivity, including farmers in Kedungpring Village, Kedungpring Subdistrict, Lamongan Regency. However, it is currently difficult for farmers to meet their fertilizer needs due to the policy of limiting fertilizer subsidies, therefore farmers must have the independence to meet their fertilizer needs. Biofertilizers can be an alternative because they are easy to make by themselves, and are more environmentally friendly than chemical fertilizers. Assistance and training on biofertilizer production for farmers in Kedungpring Village, Lamongan is needed. The purpose of this community service activity is to increase the knowledge of farmers in Kedungpring Village, Lamongan about biological fertilizers, and have the ability to make biological fertilizers, so that they can meet their fertilizer needs. This activity begins with the coordination and planning stages of the activity, providing material on biofertilizers to increase farmers' knowledge of biofertilizers using the lecture method, assistance and training in making biofertilizers using the lecture and practice methods so that farmers have the ability to make biofertilizers, and monitoring and evaluation carried out by the follow-up method. Based on the community service activities carried out, farmers' knowledge about biofertilizers has increased, which is indicated by most farmers having a higher post-test score than the pre-test score, also farmers are able to make their own biofertilizers which are indicated by the color of cloudy brown fertilizer and the distinctive sour smell of fermentation. Through this Community Service activity, farmers in Kedungpring Village also received six bioreactors for making biological fertilizers. Through this whole series of activities, it is an effort to realize sustainable agriculture, and it is hoped that farmers in Kedungpring Village, Lamongan can meet their fertilizer needs independently.

Coffee is one of the plantation commodities that has significant economic value. A factor that needs to be considered in coffee plant cultivation is good planting media composition. This study aims to determine the effect of planting media composition on the growth of robusta coffee seedlings. This study used a Completely Randomized Design with treatments M0= Soil: 100%, M1= Soil: 50% + Coffee Husk Compost: 25% + Rice Husk: 25%, M2= Soil: 25% + Coffee Husk Compost: 50% + Rice Husk: 25%, M3= Soil: 25% + Coffee Husk Compost: 25% + Rice Husk: 50%. The analyses conducted were compost analysis and initial and post-incubation soil analysis. Observation data were analyzed using the F test followed by DNMRT at the 5% level. The research results show that the provision of coffee husk compost and rice husks affects the chemical properties of the soil and the growth of coffee seedlings. The planting media composition of Soil: 25% + Coffee Husk Compost: 50% + Rice Husk: 25% proved to increase the pH of the planting media from 5.5 to 6.6, increase in total N-value from 0.2% to 0.5%, available P from 18.6 ppm to 38.5 ppm and the soil CEC from 7.6 me/100g to 36.6 me/100g. This planting media composition also makes it possible to enhance the growth of robusta coffee seedlings in plant height, stem diameter, number of leaves, leaf width, and root volume. Thus, this planting media composition is a suitable medium for the growth of robusta coffee seedlings.

[Display omitted] • Comparison of different physical and enzymatic OFMSW pre-treatments. • Study of the pre-treatment effects on both the AD products: biogas and digestate. • Evaluation of the most energetically sustainable AD configurations. • Analyses of digestate quality in terms of nutrient content for the application as fertilizer. • UPP2 and cavitation are the best enzymatic and physical pre-treatments, respectively. This study optimized the anaerobic digestion (AD) of separated collected organic fractions of municipal solid waste (OFMSW) to produce energy and digestate as biofertilizer. Due to OFMSW's partial recalcitrance to degradation, enzymatic (UPP2, MCPS, USC4, USE2, A. niger) and physical (mechanical blending, heating, hydrodynamic cavitation) pre-treatments were tested. Experimental and modeling approaches were used to compare AD performance regarding energy sustainability and digestate quality. Digestate was separated into solid and liquid fractions, and then chemically and physically characterized by investigating the nutrient release mechanisms. Principal Component Analysis was applied, equally weighing energy and digestate productions. Unlike previous studies focusing only on biogas, this study evaluated the effects of pre-treatments on both biogas and digestate production, viewing AD as a biorefinery process for urban waste valorization. Results showed that all pre-treatments were energetically sustainable, but enzymatic pre-treatments yielded digestates richer in nutrients (increase of 80% N, 200% P and 150% K as compared to OFMSW) and with greater organic matter degradation compared to physical pre-treatments. The liquid fraction of digestate from enzymatic pre-treatments had higher nutrient concentrations, while those from physical pre-treatments had more balanced nutrient content, making them more suitable for fertigation. [ABSTRACT FROM AUTHOR]

• Increasing periodic aeration rate reduced irreversible fouling of GDM. • Reclaimed wastewater was feasible for hydroponic vegetable cultivations. • Plants grown with treated water were comparable to those with fertilizer. • Shifting nutrient level and operation mode influenced plant growth profile. • Basil grown in reclaimed water had less health risk impact compared to lettuce. In this study, a gravity-driven membrane (GDM) filtration system and hydroponic system (cultivating basil and lettuce) were combined for nutrient recovery from primary municipal wastewater. The GDM system was optimized by increasing the periodic air sparging flow rate from 1 to 2 L/min (∼15 hr per 3–4 days), resulting in a ∼52% reduction of irreversible fouling. However, the total fouling was not alleviated, and the water productivity remained comparable. The GDM-filtrated water was then delivered to hydroponic systems, and the effects of hydroponic operation conditions on plant growth and heavy metal uptake were evaluated, with fertilizer- and tap water-based hydroponic systems and soil cultivation system (with tap water) for comparison. It was found that (i) the hydroponic system under batch mode facilitated to promote vegetable growth with higher nutrient uptake rates compared to that under flow-through feed mode; (ii) a shift in nutrient levels in the hydroponic system could impact plant growth (such as plant height and leaf length), especially in the early stages. Nevertheless, the plants cultivated with the GDM-treated water had comparable growth profiles to those with commercial fertilizer or in soils. Furthermore, the targeted hazard quotient levels of all heavy metals for the plants in the hydroponic system with the treated water were greatly lower than those with the commercial fertilizer. Especially, compared to the lettuce, the basil had a lower heavy metal uptake capability and displayed a negligible impact on long-term human health risk, when the treated water was employed for the hydroponic system. [Display omitted] [ABSTRACT FROM AUTHOR]

As carbon capture and storage (CCS) technologies mature, the concept of a low-carbon or net-zero-carbon economy becomes more and more feasible. While many chemical and energy products do not contain carbon in their compounds, the upstream production process does. An added CCS module allows the removal of carbon emissions from the production process, which expands the value chain. This paper focuses on one of such commodities—low-carbon-intensity ammonia (LCIA). Even though ammonia is carbon-free in its final product, it is commonly made from natural gas, and the production process could generate significant carbon emissions. The idea of LCIA is to reduce the carbon footprint of the ammonia production process (e.g., blue ammonia) or eliminate carbon from the production process (e.g., green ammonia via electrolysis) so that the entire supply chain is decarbonized. The goal of this paper is two-fold. We first explore the US domestic market and the international market for LCIA. We then discuss relevant federal and local policies that could help grow markets for LCIA. The agricultural sector will be the center of the discussion, which consumes an estimated 70–90% of the global ammonia supply as fertilizers. The paper also examines other potential uses of LCIA, such as alternative fuels for decarbonizing agricultural machinery and transportation sectors. Finally, we argue that developing a comprehensive LCIA value chain, supported by dedicated policy measures and broad stakeholder engagement, is critical for materializing the potential of LCIA in contributing to a climate-resilient and sustainable economy.

Background: An essential component of environmental sustainability and sanitation is the management of dry toilets, especially waste disposal. Understanding the composition of the brown water from dry toilets, putting the proper composting technique in place, and guaranteeing safe disposal and reuse procedures are all necessary to handle the waste successfully. It has been discovered that brown water, sometimes known as feces, can be used for brick-making, fuel, fertilizer, and other purposes. Methods: This review focuses on dry toilet technology, management processes, and sanitation systems in Ethiopia and other underdeveloped nations. It utilizes secondary information and searches from Google scholars, Library catalogs, and Researchers to comprehend dry sanitation systems, including their implementation, use, and maintenance. Keywords used in the search include “in-situ treatment,” “fecal sludge treatment,” “fecal slurry management,” and “brown water treatment.” Results: The review used a total of 108 articles and books, agricultural research, and reports on the feces’ physical, chemical, and biological characteristics. It also discussed risks associated with the mismanagement of feces, including parasitic diseases in exposed humans. The main aim of the review was to develop an understanding of brown water uses, composition, and management and select the proper method of composting with dry toilets. Conclusion: Dry toilets in developing countries are utilized for ecological sanitation and agriculture, with feces potentially used as fertilizer. Utilizing feces as fertilizer is a sustainable, eco-friendly, and environmentally responsible practice that can increase productivity while maintaining a clean environment.

The problems of producing and increasing feed volume for livestock industry when growing agricultural feed crops in crop rotation system in the Southern Urals were studied. The possibility of growing forage crops in permanent cultivation under two fertilization regimes was considered. The characteristic features of climate conditions during 32 years of research were described, 10 of them correspond to desert conditions (hydrothermal index 0.4). Based on the study of corn cultivation for silage in monocropping, it was established that this variant of the experiment was the most productive both without fertilizer application (283.62 thousand fodder units from 3 hectares of arable land) and when using mineral fertilizers (303.06 thousand fodder units). Growing barley in crop rotation with soil-protective fallow provides the crop yield of 67.13 thousand fodder units from 1 hectare (total for 19902021).

Abstract The combination of hydrogel and fertilizer as slow release fertilizer hydrogel (SRFH) has become one of the most promising materials to overcome the shortcomings of conventional fertilizer by decreasing fertilizer loss rate, supplying nutrients sustainably, and lowering the frequency of irrigation. The hydrogel based on carboxymethyl cellulose (CMC) and polyacrylic acid (PAA) (CMC/PAA) was synthesized. All materials, Vinasse, hydrogel (CMC/PAA) and (Vinasse/CMC-PAA) were characterized by FTIR, XRD, and SEM. The formed hydrogel was applied to control the salinity of Vinasse to use it as a cheap and economical fertilizer. The results showed that using the prepared hydrogel with Vinasse (V/CMC-PAA) as a slow-release organic fertilizer decreased the EC value through the first six hours from 1.77 to 0.35 mmohs/cm. Also, using V/CMC-PAA can control and keep the potassium as fertilizer for 50 days. The productivity per feddan from the sugar cane crop increased by about 15%, and the number of irrigations decreased from 5 to 4 times.

Hemp (Cannabis sativa L.), renowned for its applications in environmental, industrial, and medicinal fields, is critically evaluated in this comprehensive review focusing on the impacts of chemical and organic fertilizers on its cultivation. As hemp re-emerges as a crop of economic significance, the choice between chemical and organic fertilization methods plays a crucial role in determining not only yield but also the quality and sustainability of production. This article examines the botanical characteristics of hemp, optimal growth conditions, and the essential biochemical processes for its cultivation. A detailed comparative analysis is provided, revealing that chemical fertilizers, while increasing yield by up to 20% compared to organic options, may compromise the concentration of key phytochemicals such as cannabidiol by approximately 10%, highlighting a trade-off between yield and product quality. The review presents quantitative assessments of nitrogen (N), phosphorus (P), and potassium (K) from both fertilizer types, noting that K significantly influences the synthesis of terpenes and cannabinoids, making it the most impactful element in the context of medicinal and aromatic hemp varieties. Optimal rates and timing of application for these nutrients are discussed, with a focus on maximizing efficiency during the flowering stage, where nutrient uptake directly correlates with cannabinoid production. Furthermore, the challenges associated with the U.S. industrial hemp market are addressed, noting that reducing production costs and improving processing infrastructure is essential for sustaining industry growth, especially given the slow expansion in fiber and cannabidiol markets due to processing bottlenecks. The review concludes that while chemical fertilizers may offer immediate agronomic benefits, transitioning towards organic practices is essential for long-term environmental sustainability and market viability. The future of the hemp industry, while promising, will depend heavily on advancements in genetic engineering, crop management strategies, and regulatory frameworks that better support sustainable cultivation practices. This nuanced approach is vital for the industry to navigate the complex trade-offs between productivity, environmental health, and economic viability in the global market.