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[Display omitted] • Facile and scalable self-assembly of perylene diimide polymer with carbon paper. • Effective facilitation of carrier separation by π-π built-in electric field. • Narrowed band gap and low VB due to the VB tail states induced by π-π interactions. • Enhanced photocatalytic water oxidation activity of the PDIP/CP photocatalyst sheet. • Suitability of the PDIP/CP photocatalyst sheet for large-scale applications. Photocatalytic water splitting is a highly promising future energy technology. In contrast to the extensive work on particulate photocatalysts, there is still a lack of sufficient investigation for regularized photocatalysts. Here, from perylene diimide polymer (PDIP) and commercial carbon paper (CP), we develop a self-assembled PDIP/CP photocatalyst sheet that is easily scalable and can be used for photocatalytic water oxidation. Driven by strong interfacial π-π interactions, the PDIP spontaneously adsorbs onto the CP, which leads to a narrowed band gap, down-shifted VB edge, and enhanced separation of the photogenerated charge carriers of the PDIP. Under visible light, the PDIP/CP photocatalyst sheet shows significantly enhanced photocatalytic water oxidation activity (4 h cumulative oxygen evolution is 1.7 times higher than that of the powder-suspended system) and considerable cycling stability. The PDIP/CP photocatalyst sheet has the potential for large-scale device applications. [ABSTRACT FROM AUTHOR]

Room-temperature phosphorescence carbon dots (CDs) show the highlighted advantages in chemical sensing and bioimaging owing to its long lifetime, however, acquiring the efficient phosphorescence of carbon dots is still encountering difficulty due to the spin prohibition. Here, we synthesized one type of CDs through one-step hydrothermal method. To be specific, the CDs displayed the blue fluorescence in aqueous, and emitted the bright green phosphorescence when being coated on the filter paper. Importantly, introducing coumarin to the CDs resulted in the distinct quenching of both its fluorescence and phosphorescence. Based on this phenomenon, we successfully established a dual-channel detection of coumarin. The fluorescence detection channel exhibited a linear range of 5–350 μM with a detection limit of 0.196 μM, while the phosphorescence detection channel achieved a linear range of 50–1000 μM with a detection limit of 0.268 μM. The further investigation revealed that IFE and SQE were mainly responsible for the fluorescence quenching of CDs, while the phosphorescence quenching was originated from the increased energy gap between the singlet and triplet states (ΔE ST) of CDs, thus obstructing the ISC process. Moreover, we employed the CDs as the phosphorescent ink for anti-counterfeiting. [Display omitted] [ABSTRACT FROM AUTHOR]

For coordinated regional growth and the development of high-quality manufacturing, China must narrow its regional energy efficiency gap and catch up inter-regionally. This paper focuses on whether China's inter-provincial manufacturing energy efficiency has technological diffusion and a catch-up effect and explores its possible influencing factors, which are important for narrowing the differences in China's manufacturing energy efficiency and promoting the improvement of the overall level of efficiency. Between 2011 and 2020, 30 Chinese manufacturing industries will be evaluated using a non-radial distance function model under environmental conditions. By employing the Dagum Gini coefficient method, regional disparities were analyzed, with hyper-variable density and efficiency discrepancies between regions making a noteworthy contribution. This paper evaluated a catch-up effect by constructing a frontier productivity model that considered the influence of China's manufacturing energy efficiency. Results show a general rise in energy efficiency, particularly in coastal regions, higher than inland ones. The Gini coefficient of energy efficiency in manufacturing experienced a slight increase; however, when comparing it to the regional efficiency frontier, the catch-up effect and technology diffusion effect of China's provincial manufacturing energy efficiency become more pronounced when taking into account the national efficiency frontier; the sub-regional manufacturing energy efficiency catch-up effect has different performances; the catch-up and technology diffusion effect is more evident after controlling for Economic development, innovation levels, the environmental regulation, and the proportion of high-energy-consumption output value and other influencing factors. [ABSTRACT FROM AUTHOR]

For example: "peak intensity along the (1 0 0) plane" instead of correct "from the plane", "crystal orientation have changed with (...) concentration" - should be: crystallite orientation. Some remarks on the paper "Influence of zinc concentration on band gap and sub-band gap absorption on ZnO nanocrystalline thin films sol-gel grown" by Munirah, Ziaul Raza Khan, Anver Aziz, Mohd. (http://creativecommo ns.org/licenses/by- nc- nd/4.0/) MaterialsScience-Poland,38(3),2020,pp. 407-408 http://www.materialsscience.pwr.wroc.pl/ DOI:10.2478/msp-2018-0102 Some remarks on the paper "Influence of zinc concentration on band gap and sub-band gap absorption on ZnO nanocrystalline thin films sol-gel grown" by Munirah, Ziaul Raza Khan, Anver Aziz, Mohd. [Extracted from the article]

In the wake of increasing global emphasis on sustainable environmental practices, South African organisations strive to integrate green business principles into their strategies. The paper's objective was to evaluate the importance and implementation of an energy policy within the financial services sector in line with ISO50001. The paper presents findings from a quantitative non-experimental study within the South African financial services sector through a structured questionnaire. The findings showed that although the implementation of an energy policy is important, there is still a gap in the adoption of an energy policy within the financial services sector. The study further found that a notable percentage (29.5%) of respondents indicated that the energy policy did not provide sufficient guidance on energy targets and objectives. Setting an energy policy is the starting point and driving force for implementing energy management. It should be the priority of managers who have not yet done so. Further research on how energy policies are structured through content analysis could add value to organisations that have not yet implemented such policies. [ABSTRACT FROM AUTHOR]

Recalcitrant compounds resulting from anthropogenic activity are a significant environmental challenge, necessitating the development of advanced oxidation processes (AOPs) for effective remediation. This study explores the synthesis of cuprous oxide nanoparticles on cellulose-based paper (Cu2O@CBP) using Eucalyptus globulus leaf extracts, leveraging green synthesis techniques. The scanning electron microscopy (SEM) analysis found the average particle size 64.90 ± 16.76 nm, X-ray diffraction (XRD) and Raman spectroscopy confirm the Cu2O structure in nanoparticles; Fourier-transform infrared spectroscopy (FTIR) suggests the reducing role of phenolic compounds; and ultraviolet–visible diffuse reflectance spectroscopy (UV-Vis DRS) allowed us to determine the band gap (2.73 eV), the energies of the valence band (2.19 eV), and the conduction band (−0.54 eV) of Cu2O@CBP. The synthesized Cu2O catalysts demonstrated efficient degradation of methylene blue (MB) used as a model as recalcitrant compounds under LED-driven visible light photocatalysis and heterogeneous Fenton-like reactions with hydrogen peroxide (H2O2) using the degradation percentage and the first-order apparent degradation rate constant (kapp). The degradation efficiency of MB was pH-dependent, with neutral pH favoring photocatalysis (kapp = 0.00718 min−1) due to enhanced hydroxyl (·OH) and superoxide radical (O2·−) production, while acidic pH conditions improved Fenton-like reaction efficiency (kapp = 0.00812 min−1) via ·OH. The reusability of the photocatalysts was also evaluated, showing a decline in performance for Fenton-like reactions at acidic pH about 22.76% after five cycles, while for photocatalysis at neutral pH decline about 11.44% after five cycles. This research provides valuable insights into the catalytic mechanisms and supports the potential of eco-friendly Cu2O nanoparticles for sustainable wastewater treatment applications. [ABSTRACT FROM AUTHOR]

This Special Issue of the IEEE Transactions on Electron Devices will feature the most recent developments and the state of the art in the field of ultra wide band gap semiconductors and devices for power control and conversion, including both experimental results and theoretical developments. Papers must be new and present original material that has not been copyrighted, published or accepted for publications in any other archival publications, that is not currently being considered for publications elsewhere, and that will not be submitted elsewhere while under considerations by the Transactions on Electron Devices. Topics of interest include, but are not limited to: IDtra Wide Band Gap Materials: Advances in material synthesis, defect characterization, transport and high-field properties, and material-level integration; evaluation of fundamental materials-limited figures of merit; Power Devices: Vertical and lateral MOSFETs, HEMTs and MIS-HEMTs, IGBTs, Schottky and pn junction rectifiers, and other device concepts; fabrication and device characterization; designs and device structures for controlling field profiles, edge termination; Thermal Management: Approaches to mitigate thermal effects in power devices using ultra wide band gap materials; Integration: Monolithic and heterogenous integration for system-level applications using ultra wide band gap materials. Integration with Si or other semiconductors for system-on-chip and system-in-package implementations, including heterogenous and package-level integration for high-performance power conversion applications. [ABSTRACT FROM AUTHOR]

In the present work, visible light active bismuth oxyiodide (BiOI) was immobilized on a commercial, non-conductive support (an Al2O3 based ceramic paper) using a novel two-step spray coating technique and investigated with different characterization methods (e.g., SEM, Raman, XPS). Our main goal was to eliminate the separation costs after the photocatalytic measurement and investigate the chemical relevance and opportunity to use this technique in the industry. Our as-prepared uniform BiOI layer had similar properties to the well-known reference BiOI powder. The Raman and XPS measurements confirmed that the enriched amount of the surface iodine defined the color and as well the band gap of the BiOI layer. The durable BiOI layers have prominent photocatalytic activity under UV and visible light irradiation as well. The scale-up procedure proved that the designed BiOI coated paper was reusable and potentially applicable in the industry by straightforward scale-up, which is due to the elaborated non-conventional BiOI coverage estimation method. This immobilization technique could open several opportunities for immobilizing many other visible light active photocatalysts with simple materials and low cost. [ABSTRACT FROM AUTHOR]

Co-doping of phosphorus and boron elements into crystalline silicon quantum dot (c-Si QD) is an effective approach for enhancing the photoluminescence (PL) performance. In this paper, we report on the preparation of hydrogenated silicon nitride (SiNx:H) thin films embedded with phosphorus-boron co-doped c-Si QDs via plasma enhanced chemical vapor deposition route. Mixed dilution including hydrogen (H2) and argon (Ar) is applied in the in-situ deposition process for optimizing the deposition process. The P-B co-doped c-Si QD/SiNx:H thin films exhibit a wide range of PL spectra. The emission is greatly improved especially for the short-wavelength light when compared to the SiOx:H thin film containing P-B co-doped c-Si QDs. The effects of H2/Ar flow ratio on the structural and optical characteristics of thin films are systematically investigated through a series of characterizations. Experimental results show that various properties, such as crystallinity, QD size, optical band gap and doping concentrations, are effectively controlled by tuning H2/Ar flow ratio. Based on the red-shift of QCE-related PL peak, the successful P-B co-doping into Si QDs are verified. Finally, a comprehensive discussion has been made to analyze the influence of H2-Ar mixed dilution on the film growth and impurity doping in detail in this paper. [ABSTRACT FROM AUTHOR]

Functionalized graphene oxide papers are assembled materials with a wide range of potential applications; however, scientific studies about how the physical properties of functionalized graphene oxide papers are affected by the presence of new functional groups have not been addressed. Here, electrical resistance, optical band gap, and mechanical properties of flexible and free-standing functionalized graphene oxide papers with nitroxide moieties (NGOP's) have been studied, and two of them (mechanicals and electricals) were correlated with the interlayer d spacing for the first time; herein, a new insight about the key role that an optimum amount of functionalization agent plays over the physical properties of NGOP's is presented. In all cases, (functionalized or pristine) graphene oxide papers were prepared using anhydrous DMF instead water in order to study and highlight the pure effect of the functionalized groups over their physical properties. The functionalized nanomaterials exhibited significantly improved physical properties, which can be tuned by varying the interlayer d spacing, and this interlayer distance was systematically modified controlling the amount of functionalizing agent used. Thus, controlling the amount of functionalizing agent in the functionalization process is possible to obtain new assembled materials with modulated properties. [ABSTRACT FROM AUTHOR]

This paper reviews sintered silver (s-Ag) die-attach materials for wide band gap (WBG) semiconductor packaging. WBG devices that die-attach with s-Ag have attracted a lot of attention owing to their low energy loss and high temperature operation capabilities. For their practical operation, a reliability design should be established based on the failure of physics of the s-Ag die layer. This paper first focuses on the material characteristics of the s-Ag and tensile mechanical properties. Then, the s-Ag die-attach reliability is assessed with high-temperature storage, power cycling, and thermal shock tests. Each fracture mode was discussed by considering both the fracture surface analysis results and its mechanical properties. Finally, the effective reliability design parameters of the s-Ag die layer are introduced. [ABSTRACT FROM AUTHOR]

This paper proposes a full-duplex (FD) antenna design with passive self-interference (SI) suppression for the 28 GHz mmWave band. The reduction in SI is achieved through the design of a novel configuration of stacked Electromagnetic Band Gap structures (EBGs), which create a high impedance path to travelling electromagnetic waves between the transmit and receive antenna elements. The EBG is composed of stacked patches on layers 1 and 2 of a four-layer stack-up configuration. We present the design, optimization, and prototyping of unit antenna elements, stacked EBGs, and integration of stacked EBGs with antenna elements. We also evaluate the design through both HFSS (High Frequency Structure Simulator) and over-the-air measurements in an anechoic chamber. Through extensive evaluations, we show that (i) compared to an architecture that does not use EBGs, the proposed novel stacked EBG design provides an average of 25 dB of additional reduction in SI over 1 GHz of bandwidth, (ii) unit antenna element has over 1 GHz of bandwidth at −10 dB return loss, and (iii) HFSS simulations show close correlation with actual measurement results; however, measured results could still be several dB lower or higher than predicted simulation results. For example, the gap between simulated and measured antenna gains is less than 1 dB for 26–28 GHz and 28.5–30 GHz frequencies, but almost 3 dB for 28–28.5 GHz frequency band. [ABSTRACT FROM AUTHOR]

The research addresses the pressing need to understand wind conditions for optimal wind energy utilization, a crucial aspect of achieving global energy sustainability. While previous studies have focused on assessing wind energy potential and terrain roughness, gaps persist in understanding how wind and spatial conditions affect blade geometry. Therefore, this study aims to investigate the impact of local wind conditions on wind turbine blade geometry, integrating nonuniform wind inflow due to wind shear into the theoretical model. Through the paper, it explores blade design for varying inflow conditions and analyses the relationship between terrain type and blade designs. A novel approach to wind turbine blade design, utilizing a theoretical model that combines the local momentum theorem with insights from propeller vortex theory was adopted. Through the analysis, the authors demonstrate that variations in terrain significantly influence blade geometry, underscoring the necessity for tailored turbine designs based on local conditions. The findings reveal discrepancies in blade geometry across different turbine capacities and terrain types, offering novel insights into wind turbine performance optimization. By tailoring blade geometry to specific locations enhances resource utilization, offering insights for energy policymakers. The research provides validated methods for optimizing turbine geometric parameters, opening avenues for increased local investment in wind energy and promoting distributed energy development. Illustrated with wind plants examples, the paper concludes by outlining future research directions in this field. [ABSTRACT FROM AUTHOR]

Periodic structures are a type of metamaterial in which the physical properties depend not only on the details of the unit cell but also on how unit cells are arranged and interact with each other. In conventional engineering structures, each unit cell interacts with adjacent cells. Methods developed for vibrational and wave propagation analysis in periodic engineering structures consider only nearest-neighbor interactions. The dispersion curves of such systems, in which only adjacent cells interact, have been extensively studied. Metamaterial properties depend on the interactions of a unit cell with other cells. Further interactions, and specifically, interactions beyond the closest neighbors, imply a more complex band structure and wave behavior. In this paper, an example class of such structures, in which electrostatic forces are the driving force, has been investigated. In this paper, properties affecting these periodic structures, such as elastic forces, have been investigated. An attractive property of such structures is that the band structures of such metamaterials can be tuned by changing electric voltages. [ABSTRACT FROM AUTHOR]

Vibration and noise pollution is one of the main pollution in modern society. In order to obtain good vibration damping effect, more effective phononic crystals should be designed. Based on the theory of elastic wave propagation in solids, three types of phononic crystals are designed in this paper using tungsten blocks embedded in a rubber matrix, which are cup-shaped phononic crystal, solid cylindrical phononic crystal, and hollow cylindrical phononic crystal. Firstly, the band gap characteristics and vibration losses of the three phononic crystals are analyzed by using the finite element method. Secondly, the physical mechanism of band gap formation is explored by vibration modes. Finally, the cup-shaped phononic crystal was introduced into the core layer of the sandwich plate to form the cup-shaped phononic crystal sandwich plate, and its vibration damping performance was analyzed. The results show that the three phononic crystals can form three band gaps in the range of 0–800 Hz, and the first low-frequency band gap starts at about 140 Hz and is all wider than 200 Hz. It is noteworthy that the average loss of vibration transmission of the three types of phononic crystals is more than 69 dB, which possesses stronger damping capability and wider low- and middle-frequency band gaps than the flat plate type phononic crystals. The vibration direction of the phononic crystal is at an angle of 90° to the wave vector, which prevents the propagation of elastic waves. The phononic crystal embedded in the sandwich panel plate is more in line with the actual demand of vibration damping and obtains good vibration damping effect. The research in this paper can provide more feasibility for phononic crystal damping. [ABSTRACT FROM AUTHOR]

[Display omitted] • GABA-derived CDs: Synthesis & purification by column chromatography. • CDs with green emission in solution & yellow solid-state emission under UV light. • Theoretical studies to support structural, vibrational, & electronic features of CDs. • Flexo-prints with good lightfastness, stability & rub resistance using water-based ink. • Forger sees yellow fluorescence & user authentication by Cu2+ ion induced quenching. Forgery of valuable products causes a negative impact on the society as well as the economy of the country. There is a growing demand to not only differentiate or authenticate genuine documents/products but also to protect their integrity. Carbon dots (CDs) are a class of fluorescent nanomaterials that are well-known for their facile synthesis, good photostability and less toxicity profile. The current research work focuses on the preparation of CDs via hydrothermal method using γ-aminobutyric acid (GABA) that contains amino and carboxylic groups. Column chromatography technique is adopted to purify the GABA-derived CDs from the reactants and by-products. The fourth fraction obtained after column purification containing CDs with fluorescence emission in the visible region is chosen for further studies. The presence of spherical CDs confirmed through TEM imaging are chemically characterised using SAED, EDS, DLS, FTIR, XPS, Raman and XRD spectroscopy. The blue (λ em = 490 nm) and green (λ em = 538 nm) emitting CDs present in the fourth fraction displayed a fluorescence lifetime of 1.90 ns and 2.02 ns. Theoretical studies are performed using B3LYP/6-31G(d,p) theory level on different plausible structures. The HOMO-LUMO band gap of 2.3 eV deduced using DFT calculation is in close agreement with the optical band gap of 2.6 eV derived from Tauc plot. A complex forming mechanism is proposed for the fluorescence quenching of CDs upon examining the EDS data of the precipitate obtained upon addition of cupric ions. Further, the CDs are used as pigments to formulate a water-based ink for flexographic printing on UV-dull paper substrate. The printed samples exhibited good colorimetric values, lightfastness, and rub resistance. The security features of the ink film include an UV-induced yellow fluorescence, which will be known to the forger and a secondary quenching of fluorescence when exposed to cupric ions, which can be used by the user to validate document/product authenticity. This stimulus responsive optical property is also explored in the design of ionochromic security paper based on cupric ion induced fluorescence quenching of CDs for data storage and decryption. Moreover, the lesser surface roughness and electrical parameter values obtained for the print proofs could be further explored for the potential application of CD-derived ink in electronic anticounterfeiting. [ABSTRACT FROM AUTHOR]

Based on the local resonance theory, the vibration isolation performance of four-component periodic pile barriers consisting of a matrix, an outer pipe, an inner pipe, and a pile core was investigated using the finite element method (FEM). This configuration is contrasted with traditional three-component periodic pile barriers, which are composed of a matrix, a pipe, and a pile core. The four-component systems demonstrate significantly broader bandgaps compared to three-component systems. To validate the efficiency of the FEM, model test on pile barriers were conducted, facilitating a comparison between the FEM and experimental observations of bandgap characteristics. Additionally, the effects of the outer pipe's density, elastic modulus, and thickness on the complete bandgap characteristics were comprehensively studied within the four-component structure. It is found that the broadest vibration isolation band gaps occur under hexagonal arrangement pattern. In square and hexagonal lattice configurations, the density, elastic modulus, and thickness of the outer pipe pile's pile have predominantly influenced the upper bound frequency (UBF). There has been a positive correlation between the elastic modulus and the UBF, while the density and thickness have shown inverse relationships. Moreover, there exists a elastic modulus threshold, marking a transition in the displacement mode of the UBF, from the outer irreducible Brillouin zone (M or X) to the inner zone (Γ). Once the threshold is exceeded, both the vibration displacement mode and the width of bandgap remain substantially unchanged. The results obtained in the present paper are very useful for the design and application of periodic pile barriers in ambient vibration reduction. [ABSTRACT FROM AUTHOR]

Materials datasets usually contain many redundant (highly similar) materials due to the tinkering approach historically used in material design. This redundancy skews the performance evaluation of machine learning (ML) models when using random splitting, leading to overestimated predictive performance and poor performance on out-of-distribution samples. This issue is well-known in bioinformatics for protein function prediction, where tools like CD-HIT are used to reduce redundancy by ensuring sequence similarity among samples greater than a given threshold. In this paper, we survey the overestimated ML performance in materials science for material property prediction and propose MD-HIT, a redundancy reduction algorithm for material datasets. Applying MD-HIT to composition- and structure-based formation energy and band gap prediction problems, we demonstrate that with redundancy control, the prediction performances of the ML models on test sets tend to have relatively lower performance compared to the model with high redundancy, but better reflect models' true prediction capability. [ABSTRACT FROM AUTHOR]

In this paper, the design of a dual-band filter based on the band gap waveguide (BGW) is presented. In the low-frequency band, the TE201 mode rectangular waveguide cavity resonator was used to design the bandpass filter, which significantly reduces the impact of the high-frequency transmission line (TL). In the high-frequency band, a TE101 mode cavity resonator based on the gap waveguide (GW) structure was used to design the high-frequency band filter. A lower insertion loss can be achieved with the use of all-metal structure. A dual-band filter prototype was fabricated to verify its performance. According to the measurement results, the insertion loss is less than 1.3 dB and the return loss is better than 14 dB in the frequency range of 5.92–6.06 GHz; and the insertion loss is less than 1.77 dB and the return loss is better than 15 dB in the frequency range of 80.6–86.2 GHz. The frequency ratio is as large as 13.9, and because the high-frequency band filter is embedded in the cavity resonator of the low-frequency band filter, it saves space to a certain extent and realizes the integrated design of the dual-band filter, which is of great significance for the improvement of the performance of the dual-band communication system in higher-frequency bands. [ABSTRACT FROM AUTHOR]

CsGeI2Br-based perovskites, with their favorable band gap and high absorption coefficient, are promising candidates for the development of efficient lead-free perovskite solar cells (PSCs). However, bulk and interfacial carrier non-radiative recombination losses hinder the further improvement of power conversion efficiency and stability in PSCs. To overcome this challenge, the photovoltaic potential of the device is unlocked by optimizing the optical and electronic parameters through rigorous numerical simulation, which include tuning perovskite thickness, bulk defect density, and series and shunt resistance. Additionally, to make the simulation data as realistic as possible, recombination processes, such as Auger recombination, must be considered. In this simulation, when the Auger capture coefficient is increased to 10−29 cm6 s−1, the efficiency drops from 31.62% (without taking Auger recombination into account) to 29.10%. Since Auger recombination is unavoidable in experiments, carrier losses due to Auger recombination should be included in the analysis of the efficiency limit to avoid significantly overestimating the simulated device performance. Therefore, this paper provides valuable insights for designing realistic and efficient lead-free PSCs. [ABSTRACT FROM AUTHOR]

The utilization of lithium-ion batteries (LIBs) is increasing sharply with the increasing use of mobile phones, laptops, tablets, and electric vehicles worldwide. Technologies are required for the recycling and recovery of spent LIBs. In the context of the circular economy, it is urgent to search for new methods to recycle waste graphite that comes from the retired electrode of LIBs. The conversion of waste graphite into other products, such as new electrodes, in the field of energy devices is attractive because it reduces resource waste and processing costs, as well as preventing environmental pollution. In this paper, new electrode materials were prepared using waste anode graphite originating from a spent mobile phone battery with an xBT·0.1C12H22O11·(0.9-x)(NH4)2HPO4 composition, where x = 0–50 weight% BT from the anodic active mass of the spent phone battery (labeled as BT), using the melt quenching method. Analysis of the diffractograms shows the graphite crystalline phase with a hexagonal structure in all prepared samples. The particle sizes decrease by adding a higher BT amount in the composites. The average band gap is 1.32 eV (±0.3 eV). A higher disorder degree in the host network is the main factor responsible for lower band gap values. The prepared composites were tested as electrodes in an LIB or a fuel cell, achieving an excellent electrochemical performance. The voltammetric studies indicate that doping with 50% BT is the most suitable for applications as electrodes in LIBs and fuel cells. [ABSTRACT FROM AUTHOR]

In this paper, a multi-layered mushroom-type electromagnetic band gap (EBG) structure is proposed. A double layer two via EBG (DLTV EBG) structure is designed at 1.65 GHz. The proposed DLTV-EBG structure consists of a two-layer dielectric substrate, which reduces the lateral sizes due to a multilayer topology. By adjusting the patch dimensions and positions of the vias, the center frequency, and equivalent L and C parameters meet design requirements. In a DLTV-EBG, layer-1 has a square ring patch; layer-2 has a circular ring; outer square ring patch with 2 edged located vias gives the additional capacitance and inductance to achieve compactness. The simulation of the DLTV-EBG structure is carried out using the Ansys high-frequency structure simulator (HFSS) and experimentally validated. The band gap of the DLTV-EBG structure is measured using suspended microstrip line (SML) method. The Experimental results agree well with simulation one. The periodic size of the proposed DLTV-EBG structure is 0.05λ1.65 GHz, which is a good candidate where compact size is highly desired. [ABSTRACT FROM AUTHOR]

The single-layer MoS2 is a highly sought-after semiconductor material in the field of photoelectric performance due to its exceptional electron mobility and narrow bandgap. However, its photocatalytic efficiency is hindered by the rapid recombination rate of internal photogenerated electron–hole pairs. Currently, the construction of heterojunctions has been demonstrated to effectively mitigate the recombination rate of photogenerated electron–hole pairs. Therefore, this paper employs the first principles method to calculate and analyze the four heterojunctions formed by MoS2/WSe2, MoS2/MoSe2, MoS2/AlN, and MoS2/ZnO. The study demonstrates that the four heterojunctions exhibit structural stability. The construction of heterojunctions, as compared to a monolayer MoS2, leads to a reduction in the band gap, thereby lowering the electron transition barrier and enhancing the light absorption capacity of the materials. The four systems exhibit II-type heterojunction. Therefore, the construction of heterojunctions can effectively enhance the optical properties of these systems. By forming heterojunctions MoS2/WSe2 and MoS2/MoSe2, the absorption coefficient in the visible light region is significantly increased, resulting in a greater ability to respond to light compared to that of MoS2/ZnO and MoS2/AlN. Consequently, MoS2-based heterojunctions incorporating chalcogenide components WSe2 and MoSe2, respectively, exhibit superior catalytic activity compared to MoS2 heterojunctions incorporating non-chalcogenide components ZnO and AlN, respectively. The absorption spectrum analysis reveals that MoS2/MoSe2 exhibits the highest light responsivity among all investigated systems, indicating its superior photoelectric performance. [ABSTRACT FROM AUTHOR]

This paper examines the influence of building characteristics, occupant demographics and behaviour on gas and electricity consumption, differentiating between family groups; homes with children; homes with elderly; and homes without either. Both regression and Lasso regression analyses are used to analyse data from a 2019 UK-based survey of 4358homes (n = 1576 with children, n = 436 with elderly, n = 2330 without either). Three models (building, occupants, behaviour) were tested against electricity and gas consumption for each group. Results indicated that homes without children or elderly consumed the least energy. Property Type emerged as the strongest predictor in the Building Model (except for homes with elderly), while Current Energy Efficiency was less significant, particularly for homes with elderly occupants. Homeownership and number of occupants were the most influential factors in the Occupants Model, though this pattern did not hold for homes with elderly. Many occupant and behaviour variables are often considered 'unregulated energy' in calculations such as SAP and are thus typically disregarded. However, this study found these variables to be significant, especially as national standards improve. The findings suggest that incorporating occupant behaviour into energy modelling could help reduce the energy performance gap. [ABSTRACT FROM AUTHOR]

The oxide and halide perovskite materials with a ABX3 structure exhibit a number of excellent properties, including a high dielectric constant, electrochemical properties, a wide band gap, and a large absorption coefficient. These properties have led to a range of applications, including renewable energy and optoelectronics, where high-performance catalysts are needed. However, it is difficult for a single structure of perovskite alone to simultaneously fulfill the diverse needs of multiple applications, such as high performance and good stability at the same time. Consequently, perovskite nanocomposites have been developed to address the current limitations and enhance their functionality by combining perovskite with two or more materials to create complementary materials. This review paper categorizes perovskite nanocomposites according to their structural composition and outlines their synthesis methodologies, as well as their applications in various fields. These include fuel cells, electrochemical water splitting, CO2 mitigation, supercapacitors, and optoelectronic devices. Additionally, the review presents a summary of their research status, practical challenges, and future prospects in the fields of renewable energy and electronics. [ABSTRACT FROM AUTHOR]

The primary goal of this paper is to study a few advantages of bulk nanoparticles of Cu-doped SnO2 using the solid-state reaction method. Many innovative methods were employed to evaluate the special tuning of the bandgap and other structural and morphological properties of the material. X-ray diffractometer (XRD) confirmed that tin oxide has a rutile-type tetragonal-shaped structure with space group P42 / mnm. The average crystallite size was calculated which was found to increase from 53 to 80 nm by increasing the Cu-doping from x = 0 to x = 0.30. SEM images specified that nanoparticles are inhomogeneous and densely close to each other and the average particle size was found to be in the range of ~225–430 nm. Transmission electron microscopy (TEM) images showed the grains present in a few cubic and spherical shapes and grain size was increased (~20–90 nm) with doping of copper in the SnO2 lattice. UV–Vis spectroscopy showed that the band gap increased from 3.531 to 3.701 eV for pure SnO2 and Cu-doped SnO2, respectively. XPS identified the electronic state of Sn as well as Cu atoms as 4 + and 2 + , respectively. Raman spectroscopy showed that only three vibrational modes, i.e., A1g, B2g and doubly degenerate Eg, exist in a sample. [ABSTRACT FROM AUTHOR]

Exploration of compounds featuring multiple anions beyond the single-oxide ion, such as oxyhalides and oxyhydrides, offers an avenue for developing materials with the prospect of novel functionality. In this paper, we present the results for a mixed anion layered material, ScHX2 (X: Br, I) based on density functional theory. The result predicted the ScHX2 (X: Br, I) monolayers to be stable and semiconducting. Notably, the electronic and mechanical properties of the ScHX2 monolayers are comparable to well-established 2D materials like graphene and MoS2, rendering them highly suitable for electronic devices. Additionally, these monolayers exhibit an ability to adjust their band gaps and band edges in response to strain and substrate engineering, thereby influencing their photocatalytic applications. [ABSTRACT FROM AUTHOR]

BiOBr with different preferred growth orientation facets would show a different photocatalytic performance. When decorated in situ with metallic Bi nanoparticles, Bi/BiOBr would commonly display an enhanced photocatalytic performance. In this paper, the BiOBr nanoplates with preferred growth orientation (102) facet and (110) facet were first synthesized using a hydrothermal method. Then, some metallic Bi nanoparticles were modified in situ onto the (110)BiOBr nanoplates, which was expected to show a much more enhanced photocatalytic performance. All samples were characterized using XRD, FE-SEM, TEM, N2 adsorption–desorption, UV–vis and XPS. FE-SEM and TEM images showed that the grain size of the metallic Bi particles was about 5 nm to 10 nm. UV–vis spectra showed that, after some metallic Bi nanoparticles were modified on (110)BiOBr nanoplates, the light absorbance in the visible light region at 400–700 nm became stronger and their optical band gap became larger. N2 adsorption–desorption tests showed that the Bi(x)/(110)BiOBr nanosheets possessed larger specific surface areas than that of the (102)BiOBr and (110)BiOBr nanoplates. The XPS results showed that Bi(x)/(110)BiOBr contained more oxygen vacancies and a more negative value of the conduction band minimum. The photocatalytic performance of (102)BiOBr, (110)BiOBr and Bi(x)/(110)BiOBr were tested in the photocatalytic degradation of rhodamine B under visible light irradiation for 2 h; their photocatalytic efficiency was 45%, 75% and 80%, respectively. In comparison to (102)BiOBr, (110)BiOBr exhibited much higher photocatalytic activity, while for Bi(x)/(110)BiOBr, despite the surface Plasmon resonance effect, a larger specific surface area and more oxygen vacancies, the enhancement of the efficiency was limited, which might have resulted from the larger optical band gap. [ABSTRACT FROM AUTHOR]

In order to alleviate the structural vibrations induced by traffic loads, in this paper, a phonon crystal plate with functionally graded materials is designed based on local resonance theory. The vibration damping performance of the phonon crystal plate is studied via finite element numerical simulation and the band gap is verified via vibration transmission response analysis. Finally, the engineering application mode is simulated to make it have practical engineering application value. The results show that the phonon crystal plate has two complete bandgaps within 0~150 Hz, the initial bandgap frequency is 0.00 Hz, the cut-off frequency is 128.32 Hz, and the internal ratio of 0~100 Hz is 94.13%, which can effectively reduce the structural vibration caused by traffic loads. Finally, stress analysis of the phonon crystal plate is carried out. The results show that phonon crystals of functionally graded materials can reduce stress concentration through adjusting the band gap. The phonon crystal plate designed in this paper can effectively suppress the structural vibration caused by traffic loads, provides a new method for the vibration reduction of traffic infrastructure, and can be applied to the vibration reduction of bridges and their auxiliary facilities. [ABSTRACT FROM AUTHOR]

The primary objective of this paper is to conduct a comparative analysis of diverse Electromagnetic Band Gap (EBG) antennas in terms of their suitability for Wi-Fi applications operating at 5 GHz. Wi-Fi primarily operates within the 2.4 GHz and 5 GHz frequency bands, with the 5 GHz band offering higher data rates and reduced interference compared to the 2.4 GHz band. Furthermore, its larger number of available channels makes it an optimal choice for environments with high user density. The antennas in this study are designed with dimensions of 28.11x32.40x1.6 mm³ (length x width x height) using RT/Duroid 5880 substrate, which has a thickness of 1.6 mm and a relative permittivity (εr) of 2.2. The integration of Electromagnetic Band Gap structures in antenna designs has gained substantial attention due to their unique properties that enhance antenna performance characteristics. The paper presents sixteen distinct EBG antennas, all designed using CST software. These antennas incorporate various EBG shapes, such as Fork, L-shape, C-shape, Hash, and Z-shape, positioned on a rectangular patch and in the ground plane. The study's results reveal that the Hash EBG on the patch offers superior performance compared to other EBG types. As a result, the Hash EBG on the patch, alongside various Z-shaped EBGs on the ground plane, is assessed for different antenna performance parameters, including return loss, radiation patterns, and gain. Finally, a diagonal Z-shaped EBG antenna is designed, simulated, and tested. The antenna return loss at 5.2GHz is –48 dB The proposed antenna achieved a peak gain of 7.3 dB at 5.2GHz. The proposed antenna exhibits omnidirectional properties. The antenna shows an efficiency of 90% at the resonant frequency. The experimentally measured results of the designed diagonal EBG antenna have shown satisfactory agreement and are consistent with the simulated results. The findings of this research contribute to a better understanding of EBG antennas potential for Wi-Fi applications in the 5 GHz frequency band. [ABSTRACT FROM AUTHOR]

Spray pyrolysis technique has been applied to deposit a broad range of thin films, which are used in various devices such as solar cells, sensors, and solid oxide fuel cells. Spray pyrolysis is one of the most common, inexpensive, simple, and quite versatile methods used for synthesizing submicron and sphericalshaped luminescent materials multicomponent oxide thin films. In this paper, spray pyrolysis TiO2 thin films has been deposited on glass substrates and kept at different temperature to reveal its optical properties by the help of UV-visible spectroscopy. Refractive index (n) of TiO2 thin films as wide semiconductor has been calculated using optical energy gap (Eg). The calculated values of refractive index from the new relations have been compared with the values reported by different researchers; an excellent agreement has been obtained between them. The material identification was confirmed from X-ray diffraction techniques and first derivative of transmission spectra’s has been plotted that gives band gap value of films respectively. [ABSTRACT FROM AUTHOR]

This paper studies the radial alternating material phononic crystal (RAM-PnC). By simulating the band gap structure of the phononic crystal, a complete acoustic band gap was verified at the resonant frequency of 175.14 MHz, which can prevent the propagation of elastic waves in a specific direction. The proposed alternately arranged radial phononic crystal structure is applied to the thin-film piezoelectric-on-silicon (TPOS) MEMS resonator. The finite element simulation method increases the anchor quality factor (Qanchor) from 60,596 to 659,536,011 at the operating frequency of 175.14 MHz, which is about 10,000 times higher. The motion resistance of the RAM-PnC resonator is reduced from 156.25 Ω to 48.31 Ω compared with the traditional resonator. At the same time, the insertion loss of the RAM-PnC resonator is reduced by 1.1 dB compared with the traditional resonator. [ABSTRACT FROM AUTHOR]

As a layered material with single/multi-atom thickness, two-dimensional transition metal sulfide WS2 has attracted extensive attention in the field of science for its excellent physical, chemical, optical, and electrical properties. The photoelectric properties of WS2 are even more promising than graphene. However, there are many existing preparation methods for WS2, but few reports on its direct growth on tungsten films. Therefore, this paper studies its preparation method and proposes an innovative two-dimensional material preparation method to grow large-sized WS2 with higher quality on metal film. In this experiment, it was found that the reaction temperature could regulate the growth direction of WS2. When the temperature was below 950 °C, the film showed horizontal growth, while when the temperature was above 1000 °C, the film showed vertical growth. At the same time, through Raman and band gap measurements, it is found that the different thicknesses of precursor film will lead to a difference in the number of layers of WS2. The number of layers of WS2 can be controlled by adjusting the thickness of the precursor. [ABSTRACT FROM AUTHOR]

The wave equation revealing the wave propagation in chiral phononic crystals, established through force equilibrium law, conceals the underlying physical information, such as the essence of the motion coupling and the inertial amplification effect. This has led to a controversy over the bandgap mechanism. In this article, we theoretically unveil the reason for this controversy, and put forward an alternative approach from wave behavior to formulate the wave equation, offering an alternative pathway to articulate the bandgap physics directly. Based on the physics revealed by our theory method, we identify the obstacles in coupled acoustic and optic branches to widen and lower the bandgap. Then we introduce an approach based on spherical hinges to decrease the barriers, for customizing the bandgap frequency and width. Finally, we validate our proposal through numerical simulation and experimental demonstration. The wave equation established for chiral phononic crystals based reveals only the coupling of acoustic and optic branches, hiding the complexity of the bandgap physics. The alternative method proposed in this paper allows direct observation of the essential physics, and enables to decouple acoustic and optic branches for the manipulation of band gaps. [ABSTRACT FROM AUTHOR]

Context: The key factor in designing heat-resistant energetic materials is their thermal sensitivity. Further research and prediction of thermal sensitivity remains a great challenge for us. This study is based on first-principles calculations and establishes a theoretical model, which comprehensively considers band gap, density of states, and Young's modulus to obtain a empirical parameter Ψ. A quantitative relationship was established between the new parameter and the thermal decomposition temperature. The value of Ψ is calculated for 10 energetic materials and is found to have a strong correlation with the experimental thermal decomposition temperature. This further proves the reliability of our model. Specifically, the larger the value of Ψ, the higher the thermal decomposition temperature, and the more stable the energetic material will be. Therefore, to some extent, we can use the new parameter Ψ calculated by the model to predict thermal sensitivity. Methods: Based on first-principles, this paper used the Cambridge Serial Total Energy Package (CASTEP) module of Materials Studio (MS) for calculations. The Perdew-Burke-Ernzerhof (PBE) functionals in Generalized Gradient Approximation (GGA) method as well as the Grimme dispersion correction was used in this paper. [ABSTRACT FROM AUTHOR]

The monolithic integration of gallium phosphide (GaP), with its green band gap, high refractive index, large optical non-linearity, and broad transmission range on silicon (Si) substrates, is crucial for Si-based optoelectronics and integrated photonics. However, material mismatches, including thermal expansion mismatch and polar/non-polar interfaces, cause defects such as stacking faults, microtwins, and anti-phase domains in GaP, adversely affecting its electronic properties. Our paper presents a structural and defect analysis using scanning transmission electron microscopy, high-resolution transmission electron microscopy, and scanning nanobeam electron diffraction of epitaxial GaP islands grown on Si nanotips embedded in SiO2. The Si nanotips were fabricated on 200 mm n-type Si (001) wafers using a CMOS-compatible pilot line, and GaP islands were grown selectively on the tips via gas-source molecular-beam epitaxy. Two sets of samples were investigated: GaP islands nucleated on open Si nanotips and islands nucleated within self-organized nanocavities on top of the nanotips. Our results reveal that in both cases, the GaP islands align with the Si lattice without dislocations due to lattice mismatch. Defects in GaP islands are limited to microtwins and stacking faults. When GaP nucleates in the nanocavities, most defects are trapped, resulting in defect-free GaP islands. Our findings demonstrate an effective approach to mitigate defects in epitaxial GaP on Si nanotip wafers fabricated by CMOS-compatible processes. [ABSTRACT FROM AUTHOR]

Seismic surface waves carry significant energy that poses a major threat to structures and may trigger damage to buildings. To address this issue, the implementation of periodic barriers around structures has proven effective in attenuating seismic waves and minimizing structural dynamic response. This paper introduces a framework for seismic surface wave barriers designed to generate multiple ultra-low-frequency band gaps. The framework employs the finite-element method to compute the frequency band gap of the barrier, enabling a deeper understanding of the generation mechanism of the frequency band gap based on vibrational modes. Subsequently, the transmission rates of elastic waves through a ten-period barrier were evaluated through frequency–domain analysis. The attentional effects of the barriers were investigated by the time history analysis using site seismic waves. Moreover, the influence of the soil damping and material damping are separately discussed, further enhancing the assessment. The results demonstrate the present barrier can generate low-frequency band gaps and effectively attenuate seismic surface waves. These band gaps cover the primary frequencies of seismic surface waves, showing notable attenuation capabilities. In addition, the soil damping significantly contributes to the attenuation of seismic surface waves, resulting in an attenuation rate of 50%. There is promising potential for the application of this novel isolation technology in seismic engineering practice. [ABSTRACT FROM AUTHOR]

In this paper, a modified Josephson junction model is proposed, which splits the two-dimensional electron gas by inserting a middle superconductor strip into a conventional Josephson junction. This modification enhances the superconducting proximity effect, thus avoiding the appearance of a soft gap and inducing a stable Majorana zero-energy mode. Through numerical simulation, the impact of the middle superconductor strip with different widths on the energy band structure is studied, and a significant increase in the topological energy gap is found. In addition, the modified system maintains a robust topological gap even at a strong in-plane magnetic field. [ABSTRACT FROM AUTHOR]

An epoxy-based metamaterial plate structure with local resonance is designed in this paper. The bandgap of the bending wave ranges from 36.46Hz to 110.55Hz. Through the optimization design of the oscillators in the plate structure, the starting bandgap moves to 19.79Hz, and the band gap width is 72Hz. The dispersion curve and frequency response function were calculated by finite element method (FEM). On this basis, the plane wave expansion method formula of the structural model was derived, and the equivalent model of spring-mass model was established. The results show that the calculation results of the three methods of the epoxide metamaterial plate structure were basically consistent, and the correctness of these methods was verified mutually. The methods derived in this paper bring great convenience and diversity to the application of plate structure. The article proposes a low-frequency wide bandgap thick plate structure model. [ABSTRACT FROM AUTHOR]

Due to a wide band gap and large exciton binding energy, zinc oxide (ZnO) is currently receiving much attention in various areas, and can be prepared in various forms including nanorods, nanowires, nanoflowers, and so on. The reliability of ZnO produced by a single dopant is unstable, which in turn promotes the development of co-doping techniques. Co-doping is a very promising technique to effectively modulate the optical, electrical, magnetic, and photocatalytic properties of ZnO, as well as the ability to form various structures. In this paper, the important advances in co-doped ZnO nanomaterials are summarized, as well as the preparation of co-doped ZnO nanomaterials by using different methods, including hydrothermal, solvothermal, sol-gel, and acoustic chemistry. In addition, the wide range of applications of co-doped ZnO nanomaterials in photocatalysis, solar cells, gas sensors, and biomedicine are discussed. Finally, the challenges and future prospects in the field of co-doped ZnO nanomaterials are also elucidated. [ABSTRACT FROM AUTHOR]

This paper introduces a structural design which has superior energy harvesting ability. The proposed structure is based on the ability of most periodic structures to prohibit elastic waves from propagating in a specific frequency range of the phonon band gap. By leading into acoustic black hole (ABH) units and utilizing the energy concentration characteristics of the ABH structure, the filtering effect can be made more significant. These two characteristics can produce significant strain and energy localization, which is conducive to energy harvesting. In this paper, we obtained ABH unit capable of producing broadband gaps by adjusting the geometric parameters of the ABH structure, and chose a cantilever as the research object for energy harvesting, by applying a piezoelectric patch on the unit located near the fixed end to gain a broader application in the actual situation. The results show that the beam combining the energy concentration characteristics of band gap and ABH structure has a significant improvement in energy harvesting efficiency. Optimization on the parameters of ABH unit shows that the band gap characteristic of the periodic ABH structure can further optimize the energy harvesting efficiency of practical energy harvesters, and opens up a new possibility of energy harvesting of ABH structure. [ABSTRACT FROM AUTHOR]

A variable-speed pump-turbine is the core component of a hydraulic storage and energy generation station. When the pump-turbine operates at a constant speed, its response to the power grid frequency is poor. In order to improve the hydraulic efficiency of the pumped storage unit, variable-speed units are used. However, there has been no numerical study on the effect of the rotational flow characteristics within the gap of a variable-speed pump-turbine. This paper calculates the flow characteristics within the gap of a variable-speed pump-turbine under three typical pump modes (maximum head minimum flow condition, minimum head maximum flow condition, and maximum speed condition). The research results indicate that the rotational speed significantly affects the pressure distribution, velocity distribution, and turbulent kinetic energy distribution within the crown and band gaps. The higher the speed, the larger the area of the high-pressure region before the runner inlet compared to other operating conditions, and similarly, the low-pressure area after the runner outlet is also larger than in other operating conditions. The change in speed mainly affects the internal flow field of the crown gap, with the most noticeable changes occurring in the pressure and flow velocity at the inlet and outlet of the crown gap. There is a clear trend of pressure drop and velocity increase within the gap as the speed increases. However, with the increase in speed, the pressure distribution and flow velocity within the band gap remain almost the same. In addition to speed changes, it is observed that the pressure within the gap and the flow velocity within the passages are also related to the head, especially in the condition of maximum head, where this relationship becomes more noticeable. [ABSTRACT FROM AUTHOR]

Context: In this paper, we systematically studied the effects of non-metallic element (B, C, N, O, F) doping and biaxial stretching on the photoelectric properties of ZrS2/ZrSe2 heterostructures by using the first-principles calculation method based on density functional theory. The results show that the p-type doping is realized by B, C, and N atom doping, and the n-type doping is realized by O and F atom doping. The doping of B and C atoms produces impurity energy levels in the band gap, which affects the conductivity of the heterostructure. The band gap of N and O atom–doped heterostructures increases under tensile strain, but it is still a direct band gap. The analysis of the optical properties of the heterostructures shows that the doping of non-metallic atoms can adjust the optical absorption rate and reflectivity of the heterostructures. Under the action of tensile strain, the optical properties of the doped heterostructures have changed significantly in the low-energy region. This article provides a theoretical basis for the future application of ZrS2/ZrSe2 heterostructures. Method: This paper uses the first-principles calculation method based on density functional theory. The PBE exchange-correlation functional based on generalized gradient approximation (GGA) is selected for the specific calculation, and the crystal structure is geometrically optimized by the ultrasoft pseudopotential method. It is verified that when the cutoff energy of the ZrS2/ZrSe2 heterostructure is 500 eV, the K-point grid is selected to be 10 × 10 × 2 with the lowest energy, so the cutoff energy is selected to be 500 eV. The K-point grid is selected to be 10 × 10 × 2. The convergence limits for structural optimization are as follows: the maximum force between atoms is 0.01 eV/Å, the convergence threshold of the maximum energy change is set to 10−9 eV/atom, and the convergence threshold of the maximum displacement is 0.001 Å. In order to avoid the influence of atomic periodic motion between different atomic layers, a vacuum layer of 20 Å is added in the vertical direction. Considering the interaction of vdW between the interfaces, the DFT-D2 method is used to verify. The optical properties were calculated by the random phase approximation method, and the K-point grid was selected as 12 × 12 × 2. [ABSTRACT FROM AUTHOR]

A novel terahertz polarization isolator using a two-dimensional square lattice tellurium rod array is numerically investigated at the interesting band of 0.22 THz in this short paper. The isolator is designed by inserting six hexagonal tellurium rods into a fully polarized photonic crystals waveguide with high efficiency of −0.34 dB. The TE and TM photonic band gaps of the 7 × 16 tellurium photonic crystals are computed based on the plane wave expansion method, which happen to coincide at the normalized frequency domain from 0.3859(a/λ) to 0.4033(a/λ), corresponding to the frequency domain from 0.2152 to 0.2249 THz. The operating bandwidth of the tellurium photonic crystals waveguide covers 0.2146 to 0.2247 THz, calculated by the finite element method. The six hexagonal tellurium rods with smaller circumradii of 0.16a serve to isolate transverse electric waves and turn a blind eye to transverse magnetic waves. The polarization isolation function and external characteristic curves of the envisaged structure are numerically simulated, which achieves the highest isolation of −33.49 dB at the central frequency of 0.2104 THz and the maximum reflection efficiency of 98.95 percent at the frequency of 0.2141 THz. The designed isolator with a unique function and high performance provides a promising approach for implementing fully polarized THz devices for future 6G communication systems. [ABSTRACT FROM AUTHOR]

Configuration-controllable metamaterials are a kind of metamaterials whose bandgaps can be effectively adjusted through configuration control, but the configuration changes also produce initial stress. In this paper, the distribution of the initial stress of the configuration-controllable metamaterial under axial displacement and the influence of initial stress on the band gap characteristics of the structure were analyzed using numerical and experimental methods. The results show that initial stress has a significant influence on the bandgap characteristics, and the position and width of the bandgap change with the magnitude of the initial stress. The bandgap distribution of the structure after considering the initial stress is more consistent with the reported experimental results. The influence of initial stress on bandgap cannot be ignored. When the compressive loading displacement is 10 mm, the frequency range of the first bandgap is 262 Hz–310 Hz and that of the second bandgap is 394 Hz–405 Hz. And the frequency range of the first and second bandgaps will be converted into 254 Hz–291 Hz and 391 Hz–400 Hz when considering initial stress. The initial stress generated by compression deformation reduces the frequency of the structural bandgap. The beginning and ending frequencies of the first bandgap will move toward low frequencies, and the first bandgap will close when the compression displacement reaches 30 mm. The initial stress generated by tensile deformation increases the frequency of the structural bandgap. The beginning and ending frequencies of the first bandgap move toward high frequencies, and the bandgap will close when the tensile displacement is 30 mm. [ABSTRACT FROM AUTHOR]

Phononic crystals (PCs) play an important role in the reduction of vibration within a targeted frequency range. Most research of the one-dimensional PCs focuses on the properties or applications of the flexural band gaps; however, practically, the broadband environmental excitations also induce the torsional vibration. Hence, this paper studies a two-degrees-of-freedom local resonance (2DOF-LR) phononic crystal, which can both suppress the propagation of flexural and torsion waves in the same frequency range. To improve the computational efficiency, the Timoshenko theory with a modified transfer matrix (MTM) approach is used for flexural vibration band structure analysis. Through the finite element method (FEM), the vibration attenuation characteristics of the structure within the band gaps are verified. A comprehensive study is conducted to investigate the effects of geometric and material parameters on the attenuation characteristics of the phononic crystal. Finally, a prototype of the proposed phononic crystal is fabricated for the vibration experiment. It is worth noting that a novel experimental setup using the lever principle is designed in this paper to verify the torsional band gap. The frequency ranges of the experimental vibration attenuation match well with the numerical results. [ABSTRACT FROM AUTHOR]

Silicon carbide is changing power electronics; it is enabling massive car electrification owing to its far more efficient operation with respect to mainstream silicon in a large variety of energy conversion systems like the main traction inverter of an electric vehicle (EV). Its superior performance depends upon unique properties such as lower switching and conduction losses, safer high-temperature operation and high-voltage capability. Starting briefly with a description of its physics, more detailed information is then given about some key manufacturing steps such as crystal growth and epitaxy. Afterwards, an overview of its inherent defects and how to mitigate them is presented. Finally, a typical EV's propulsion inverter is shown, proving the technology's effectiveness in meeting requirements for mass electrification. Foreword: In recent years, SiC has drawn the attention of a growing number of power electronics designers as the material has good prospects for reducing environmental impacts on a global basis. The goal of this paper, based on the author's contribution to the introduction of the technology at STMicroelectronics, is to show the potential of silicon carbide in enabling massive car electrification. The company's SiC MOSFETs, tailored to the automotive industry, are enabling visionary EV makers to pave the way for sustainable e-mobility. The intent of this paper is to describe, for a large crowd of readers, how SiC features can accelerate such a transition by quantifying the benefits they bring in terms of improved efficiency in an EV electric powertrain. The paper also has the ambition to highlight the material's physics and to give an overview of its production processes, starting from the crystal growth for realizing substrates to the main epitaxy techniques. Some space has been devoted to the analysis of the main crystal defects not present in silicon and whose nature poses new challenges in terms of manufacturing yields and screening. Finally, some insights into the market evolution and on the transition to 200 mm wafers are given. [ABSTRACT FROM AUTHOR]

Heterostructure engineering is an effective technology to improve photo-electronic properties of two dimensional layered semiconductors. In this paper, based on first principles method, we studied the structure, stability, energy band, and optical properties of ZnSe/SnSe heterostructure change with film layer. Results show that all heterostructures are the type-II band arrangement, and the interlayer interaction is characterized by van der Waals. The electron concentration and charge density difference implies the electron (holes) transition from SnSe to monolayer ZnSe. By increasing the layer of SnSe films, the quantum effects are weakened leading to the band gap reduced, and eventually show metal properties. The optical properties also have obvious change, the excellent absorption ability of ZnSe/SnSe heterostructures mainly near the infrared spectroscopy. These works suggest that ZnSe/SnSe heterostructure has significant potential for future optoelectronic applications. [ABSTRACT FROM AUTHOR]