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The present work deals with analyzing the effect of silicon dioxide on mechanical and thermal stability of hybrid polymer composite. Compression molding is adopted to develop the hybrid composite with constant 0.5 wt.% of graphene and varying wt.% of silicon dioxide (2, 4 & 6 wt.%). Modified hummers method is used to synthesis graphene by chemical exfoliation of graphene from graphite flakes. Mechanical properties of developed composite is investigated using tensile, flexural, impact and interlaminar shear testing follow by fracture surface analysis of tested samples. Thermal stability is examined by thermogravimetric analysis and functional group confirmation is carried out using Fourier transform infrared spectroscopy (FTIR). Investigation over mechanical properties of fabricated composite reveals that addition of silicon dioxide up to 4 wt.% depicted higher flexural and tensile strength. Increment in silicon dioxide percentage improves the toughness of composite. FTIR results confirms the presence of asymmetric stretching vibrations due the after effect of hybrid fillers. Thermogravimetric analysis results depict that incorporation silicon dioxide increases the activation of energy of matrix from ~ 24.2 to 31.5 kJ/mol. [ABSTRACT FROM AUTHOR]

To simultaneously endow thermal conductivity, high glass transition temperature (Tg) and healing capability to glass fiber/epoxy (GFREP) composite, dynamic crosslinked epoxy resin bearing reversible β-hydroxyl ester bonds was reinforced with boron nitride nanosheets modified glass fiber cloth (GFC@BNNSs). The in-plane heat conduction paths were constructed by electrostatic self-assembly of polyacrylic acid treated GFC and polyethyleneimine decorated BNNSs. Then, the GFC@BNNSs were impregnated with the mixture of lower concentration (3-glycidyloxypropyl) trimethoxysilane grafted BN micron sheets, 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate and hexahydro-4-methylphthalic anhydride, which accounted for establishing the through-plane heat transport pathways and avoiding serious deterioration of mechanical performances. The resultant GFREP composite containing less boron nitride particles (17.6 wt%) exhibited superior in-plane (3.29 W·m−1·K−1) and through-plane (1.16 W·m−1·K−1) thermal conductivities, as well as high Tg of 204 °C (Tg of the unfilled epoxy=177 °C). The reversible transesterification reaction enabled closure of interlaminar cracks within the composite, achieving decent healing efficiencies estimated by means of tensile strength (71.2%), electrical breakdown strength (83.6%) and thermal conductivity (69.1%). The present work overcame the disadvantages of conventional thermally conductive composites, and provided an efficient approach to prolong the life span of thermally conductive GFREP laminate for high-temperature resistant integrated circuit application. [ABSTRACT FROM AUTHOR]

Recently, the utilization of hybrid basalt/glass fiber reinforced polymer (HBGFRP) nanocomposites has increased significantly in structural applications due to their light weight nature, superior strength-to-weight ratio, and excellent mechanical, chemical, and thermal properties. This study aims to investigate the effects of various drilling parameters and filler weight content on delamination and surface roughness on HBGFRP nanocomposites filled with combination of multi-walled carbon nanotubes (MWCNTs) and nano-silica particles (SiO2) in equal weight proportions of 0%, 1%, and 2%. These nanocomposite laminates were fabricated using the manual lay-up method followed by compression molding with a novel stacking order of fibers 01B/02G/02B/02G/02B/02G/01B consisting of 12 layers.. In this work, the Box-Benkhen Design of Response Surface Methodology (RSM) was employed to optimize the drilling parameters, including spindle speed, feed rate, drill diameter, and weight content of MWCNTs + SiO2. The nanocomposites containing 1.0wt. % MWCNTs + SiO2 demonstrated the most significant reduction in the delamination factor, achieving a 24% reduction. The lowest delamination factor recorded was 1.29, obtained with a spindle speed of 1350 rpm, a feed rate of 0.1 mm/rev, a drill diameter of 6 mm, and the addition of 1.0wt. % MWCNTs + SiO2. Increasing the spindle speed resulted in a further reduction in the delamination factor. The surface roughness measured was 1.213 µm, indicating a relatively smooth surface. It was evident that increase in feed rate and drill diameter corresponded to increase in both delamination factor and surface roughness. [ABSTRACT FROM AUTHOR]