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1. Coordination strategy-induced selective C–H amination of 8-aminoquinolines.

Author

Yi, Hong, Chen, Hong, Bian, Changliang, Tang, Zilu, Singh, Atul K., Qi, Xiaotian, Yue, Xiaoyu, Lan, Yu, Lee, Jyh-Fu, and Lei, Aiwen

Subjects
*COORDINATE covalent bond, *AMINATION, *QUINOLINE
Abstract

In this study, we broke through the directing function of the amide group. The coordination interaction between metal and directing-group enhanced the reactivity of the substrate. Using this strategy, we realized the selective amination of 8-aminoquinolines at the C5 position via employing azoles as the source of amine. Various kinds of 8-aminoquinolines and different substituted azoles were compatible to afford the corresponding C–N coupling products. [ABSTRACT FROM AUTHOR]

Published
2017
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