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Coordination strategy-induced selective C–H amination of 8-aminoquinolines.
- Source :
-
Chemical Communications . 6/25/2017, Vol. 53 Issue 50, p6736-6739. 4p. - Publication Year :
- 2017
-
Abstract
- In this study, we broke through the directing function of the amide group. The coordination interaction between metal and directing-group enhanced the reactivity of the substrate. Using this strategy, we realized the selective amination of 8-aminoquinolines at the C5 position via employing azoles as the source of amine. Various kinds of 8-aminoquinolines and different substituted azoles were compatible to afford the corresponding C–N coupling products. [ABSTRACT FROM AUTHOR]
- Subjects :
- *COORDINATE covalent bond
*AMINATION
*QUINOLINE
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 53
- Issue :
- 50
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 123699118
- Full Text :
- https://doi.org/10.1039/c7cc02601c