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We present an evaluation of aircraft observations of the carbon and greenhouse gases (CO2, CH4, N2O, and CO) using a direct-absorption pulsed quantum cascade laser spectrometer (QCLS) operated during the HIPPO and CalNex airborne experiments. The QCLS made continuous 1Hz measurements with 1-sigma Allan precisions of 20, 0.5, 0.09, and 0.15 ppb for CO2, CH4, N2O, and CO, respectively, over >500 flight hours on 79 research flights. The QCLS measurements are compared to two vacuum ultraviolet (VUV) CO instruments (CalNex and HIPPO), a cavity ring-down spectrometer (CRDS) measuring CO2 and CH4 (CalNex), two broadband non-dispersive infrared spectrometers (NDIR) measuring CO2 (HIPPO), two onboard gas chromatographs measuring a variety of chemical species including CH4, N2O, and CO (HIPPO), and various flask-based measurements of all four species. QCLS measurements are tied to NOAA and WMO standards using an in-flight calibration system and mean differences when compared to NOAA CCG flask data over the 59 HIPPO research flights were 100, 1, 1, and 2 ppb for CO2, CH4, N2O, and CO, respectively. The details of the end-to-end calibration procedures and the data quality-assurance and quality-control (QA/QC) are presented. Specifically, we discuss our practices for the traceability of standards given uncertainties in calibration cylinders, isotopic and surface effects for the long-lived greenhouse gas tracers, interpolation techniques for in-flight calibrations, and the effects of instrument linearity on retrieved mole fractions. [ABSTRACT FROM AUTHOR]

The ultrafast electronic dynamics of pyrazine (C4N2H4) were studied by time-resolved photoelectron imaging (TRPEI) using the third (3ω, 4.7 eV) and fifth harmonics (5ω, 7.8 eV) of a femtosecond Ti:sapphire laser (ω). Although the photoionization signals due to the 5ω - 3ω and 3ω - 5ω pulse sequences overlapped near the time origin, we have successfully extracted their individual TRPEI signals using least squares fitting of the observed electron kinetic energy distributions. When the 5ω pulses preceded the 3ω pulses, the 5ω pulses predominantly excited the S4 (ππ*, ¹B1u+¹B2u) state. The photoionization signal from the S4 state generated by the time-delayed 3ω pulses was dominated by the D3(²B2g) ω S4 photoionization process and exhibited a broad electron kinetic energy distribution, which rapidly downshifted in energy within 100 fs. Also observed were the photoionization signals for the 3s, 3pz, and 3py members of the Rydberg series converging to D0(²Ag). The Rydberg signals appeared immediately within our instrumental time resolution of 27 fs, indicating that these states are directly photoexcited from the ground state or populated from S4 within 27 fs. The 3s, 3pz, and 3py states exhibited single exponential decay with lifetimes of 94 ± 2, 89 ± 2, and 58 ± 1 fs, respectively. With the reverse pulse sequence of 3ω - 5ω, the ultrafast internal conversion (IC) from S2(ππ*) to S1(nπ*) was observed. The decay associated spectrum of S2 exhibited multiple bands ascribed to D0, D1, and D3, in agreement with the 3ω-pump and 6ω-probe experiment described in our preceding paper [T. Horio et al., J. Chem. Phys. 145, 044306 (2016)]. The electron kinetic energy and angular distributions from S1 populated by IC from S2 are also discussed. [ABSTRACT FROM AUTHOR]

Here we compare the global‐scale morphology of Earth's the Far‐Ultraviolet (FUV) emissions observed by NASA's Global‐scale Observations of Limb and Disk (GOLD) mission to those modeled using the Global Airglow (GLOW) code with atmospheric parameters provided by Thermosphere‐Ionosphere‐Electrodynamics General Circulation Model (TIEGCM). The O 5S oxygen (135.6 nm) and N2 Lyman‐Birge‐Hopfield (LBH) emissions are observed over the Western hemisphere every 30 min by the GOLD instrument. The FUV brightness of the thermosphere‐ionosphere is expected to vary in systemic ways with respect to geophysical parameters, solar energy input from above, and terrestrial weather input from below. In this paper we examine the O 5S oxygen emission and the N2 LBH emission brightnesses with local time, latitude, season, tides, geomagnetic activity, and solar activity based on GOLD observations and GLOW modeling. Early GOLD observations indicate that the model effectively reproduces the brightness variations with local time and latitude but is biased low in magnitude. However, the TIEGCM is unable to accurately represent the extraordinary nighttime equatorial ionization anomaly observed by GOLD. It is also expected from these results that the signal from geomagnetic storms may obscure tidal signals. Plain Language Summary: In January 2018, a FUV instrument, the Global‐scale Observations of Limb and Disk (GOLD), was launched as a NASA mission of opportunity aboard a geostationary satellite and scientific operations began in October of 2018. GOLD views the entire disk of the Earth every 30 min, allowing the separation of geophysical variability in both space and time. This allows an unprecedented test of global models. Here, we model the Earth's upper atmosphere using the Thermosphere‐Ionosphere‐Electrodynamics General Circulation Model (TIEGCM), which produces temperature and the densities of the major chemical components of the neutral atmosphere, ionized plasma densities, and neutral air temperatures. These atmospheric temperatures and densities are used to calculate the Earth's upper atmosphere emissions in the Far‐Ultraviolet (FUV) with the Global Airglow (GLOW) model. The calculated emission rates are then used to compute the expected FUV signals as observed from geostationary orbit. In this paper, we show how the FUV brightness varies with local time, season, atmospheric activity, and solar activity. Of particular interest is that the GLOW model excels at producing FUV brightnesses that match the local time and latitude trends of the daytime observations; however, the model fails to adequately portray the extraordinary nighttime phenomena observed by GOLD. Key Points: The Global‐scale Observations of Limb and Disk (GOLD) instrument observes the Earth in the Far‐Ultraviolet (FUV) from a geostationary orbitGLOW adequately calculates the FUV brightness for various local times, latitudes, solar forcing, and lower atmospheric forcingGLOW calculations indicate the oxygen brightness varies by ±45 R and the effective temperature varies by more than 80 K due to tides [ABSTRACT FROM AUTHOR]

Second-order-derivative plus fourth-order-derivative gravity is the ultraviolet completion of second-order-derivative quantum Einstein gravity. While it achieves renormalizability through states of negative Dirac norm, the unitarity violation that this would entail can be postponed to Planck energies. As we show in this paper, the theory has a different problem, one that occurs at all energy scales, namely that the Dirac norm of the vacuum of the theory is not finite. To establish this, we present a procedure for determining the norm of the vacuum in any quantum field theory. With the Dirac norm of the vacuum of the second-order-derivative plus fourth-order-derivative theory not being finite, the Feynman rules that are used to establish renormalizability are not valid, as is the assumption that the theory can be used as an effective theory at energies well below the Planck scale. This lack of finiteness is also manifested in the fact that the Lorentzian path integral for the theory is divergent. Because the vacuum Dirac norm is not finite, the Hamiltonian of the theory is not Hermitian. However, it turns out to be P T symmetric. When one continues the theory into the complex plane and uses the P T symmetry inner product, viz. the overlap of the left-eigenstate of the Hamiltonian with its right-eigenstate, one then finds that for the vacuum this norm is both finite and positive, the Feynman rules now are valid, the Lorentzian path integral now is well behaved, and the theory now can serve as a low energy effective theory, one that we show to have a real classical gravity limit. Consequently, the theory can now be offered as a fully consistent, unitary and renormalizable theory of quantum gravity. [ABSTRACT FROM AUTHOR]

Flashover discharge occurs on spacecraft solar array with inverted potential gradient. The flashover discharges have been measured with an electron beam. However, it is difficult to charge the coupon surface uniformly. In this paper, ultraviolet light was used to achieve a uniform surface charging. The discharge current waveforms and surface potentials were measured with changing uniform surface potential. From these test results, the current waveform was calculated with a ladder circuit model. This model shows that the surface potential neutralization pattern is the same as that obtained with the experimental results. [ABSTRACT FROM PUBLISHER]

This contribution is a survey of the available experimental radiation data measured in the VUV range related to hypersonic atmospheric entry. The objective is to identify the datasets already gathered during aerothermodynamics studies for preparing Mars, Venus, and sample return missions. The final goal is to identify the most valuable datasets for comparisons with future data measured in the European shock-tube ESTHER. Due to the limited number of studies covering VUV radiation in relation to space exploration missions, the review has been extended to domains such as nuclear fusion, exobiology, chemical and process engineering. [ABSTRACT FROM AUTHOR]

Metamaterials and periodic structures operating under high-power excitations are susceptible to breakdown. It was recently demonstrated that a localized breakdown created in a given region of a periodic structure can facilitate breakdown in other regions of the structure where the intensity of the incident electromagnetic fields may not be high enough to cause breakdown under normal circumstances. It was also demonstrated that this phenomenon is due to the generation of vacuum ultraviolet radiation at the location of the initial discharge, which propagates to the neighboring regions (e.g., other unit cells in a periodic structure) and facilitates the generation of a discharge at a lower incident power level. In this paper, we present the results of an experimental study conducted to determine the effective range of this physical phenomenon for periodic structures that operate in air and in pure nitrogen gas at atmospheric pressure levels. It is demonstrated that when breakdown is induced in a periodic structure using a high-power pulse with a frequency of 9.382 GHz, duration of 0.8 is, and peak power level of 25 kW, this phenomenon is highly likely to happen in radii of approximately 16-17 mm from the location of the initial discharge under these test conditions. The results of this study are significant in designing metamaterials and periodic structures for high-power microwave applications as they suggest that a localized discharge created in such a periodic structure with a periodicity less than 16-17 mm can spread over a large surface and result in a distributed discharge. [ABSTRACT FROM AUTHOR]

Solvated electrons (eaq−) generated by atmospheric pressure plasmas in contact with liquids are a key source of plasma-induced liquid chemistry that enable applications in biotechnology and nanoparticle synthesis. In this paper, we report liquid phase reactive species concentrations near an anodic plasma-liquid interface as described by a fluid model. In particular, the interfacial structures and plasma-induced reactive species in NaCl and AgNO3 solutions as generated by a pulsed plasma are highlighted. The results show that the magnitude and the penetration depth of the eaq− concentration in AgNO3 solution are smaller than that in the NaCl solution due to the scavenger reactions of eaq− by Ag+ and NO3−. The early products of the plasma-induced Ag+ reduction are also presented, and the impact of the current density, the pulse width, and the AgNO3 concentration on the silver reduction is analyzed. It is further shown that a typical OH radical flux present in such plasmas can highly impact the eaq− concentration and the Ag+ reduction while the impact of vacuum ultraviolet radiation, H, and H2O2 is less pronounced. [ABSTRACT FROM AUTHOR]

Photoabsorption measurements of NO bands have been made by vacuum-ultraviolet Fourier transform spectrometry with a resolution of 0.12 cm-1 in the wavelength region of 166.2–196.2 nm. Accurate line positions are obtained for the δ(υ,0) bands with υ=2, 3, the ε(υ,0) bands with υ=2, 3, and the β(υ,0) bands with υ=10,12,14. Absolute term values are found for the corresponding upper levels C(2,3), D(2,3), and B(10,12,14). Accurate rotational line integrated cross sections have also been obtained for the lines in these bands. Integrated cross sections reported in our earlier papers [J. Chem. Phys. 109, 1751 (1998); 112, 2251 (2000); 115, 3719 (2001); 116, 155 (2002); 117, 10621 (2002); 119, 8373 (2003)] have been revised, and the results reported here comprise the δ(υ,0) bands with υ=0–3, the ε(υ,0) bands with υ=0–3, the β(υ,0) bands with υ=6,7,9–12,14, and the γ(3,0) band. For each band, the band oscillator strength is obtained from the sum of the line strengths of all rotational lines, and these are compared with other published values. [ABSTRACT FROM AUTHOR]

Free electron LASer in Hamburg is the first free electron laser user facility operating in the vacuum ultraviolet and soft X-ray wavelength range. Many user experiments require knowledge of the spatial and temporal coherence properties of the radiation. In this paper, we present a theoretical analysis of the coherence properties of the radiation for the fundamental and for the higher odd frequency harmonics. We show that temporal and spatial coherence reach their maxima close to the free electron laser (FEL) saturation but may degrade significantly in the post-saturation regime. We also find that the pointing stability of short FEL pulses is limited due to the fact that nonazimuthal FEL eigenmodes are not sufficiently suppressed. We discuss possible ways for improving the degree of transverse coherence and the pointing stability. [ABSTRACT FROM AUTHOR]

An absorption has been detected at 1699.8 cm-1 in the midinfrared spectrum of the vacuum ultraviolet photolysis products of 1,3-butadiene (C4H6) trapped in Ar at 10 K, which on the basis of extensive13 C-substitution experiments is shown to belong to the C4 carbon chain. The behavior of the new band correlates closely with the ν2, C[larger_closed_square]C stretching vibration of linear C4 at 1543.4 cm-1 identified in an earlier paper. It is argued that the 1699.8 cm-1 absorption is a combination band involving the C[larger_closed_square]C stretching vibration and a bending mode of C4, with a cis-bent structure. [ABSTRACT FROM AUTHOR]

We have studied the electrical and optical characteristics of an air-cooled argon excimer vacuum-ultraviolet lamp (λ *** 126 nm) excited by a dielectric barrier discharge powered by: 1) pulsed or 2) sinusoidal high-voltage drivers from 32 to 100 kHz. Compared to sinusoidal excitation, pulsed excitation gives nearly *** 2x higher vacuum-ultraviolet (VUV) output and electrical-to-VUV conversion efficiency at high pressure (800-900 mbar). Visually, the pulse-driven plasma is spatially homogeneous, whereas for sinusoidal excitation the plasma becomes filamentary at higher pressure and/or frequency. Spectral emission is highly monochromatic with most of the output in the desired VUV band (λ = 115-140 nm). With the lamp running at pressure >700 mbar and power loadings >1.6 W/cm³, a sharp spike in VUV output was consistently seen at turn-on. We believe that transient phenomena or favorable initial conditions may be partly responsible for this VUV spike, although the equilibrium VUV output appears to be limited due to thermal dissipation, gas heating, and associated loss of gas from the active region. We propose that we may be observing the same intrinsic VUV spiking phenomena as reported in liquid nitrogen-cooled Xe, Kr, and Ar excimer lamps by Gerasimov et al. More importantly, we believe ours is the first such observation reported for an excimer VUV lamp operating near room temperature. This VUV spiking behavior raises the prospect that designs with improved thermal management may achieve even higher VUV power and efficiency. [ABSTRACT FROM AUTHOR]

Recently, a silicon-based ultrashallow-junction \p^+\- \n photodiode (B-layer diode) has been reported, with very high and very stable sensitivity in the vacuum-ultraviolet and extreme-ultraviolet spectral ranges. However, the ultrashallow nature of the junction leads to a high series resistance of the photodiode if no conductive capping layers are used. In a recent paper by Shi , a study on the relation between the sensitivity and the series resistance of the B-layer diodes, which can be large due to the shallow-junction depth, was presented. In this paper, an extensive analysis of the photodiode electrical and optical performance parameters and their interrelation is given. The influence of the series resistance on the response time of the photodiode for different illumination patterns is studied theoretically and also experimentally verified. It has been proven by modeling, simulations, and experiments that the time constant of the photodiode does not change significantly with the illumination spot area. This effect is due to temporary variations, going in opposite directions, of the equivalent series resistance, and the junction capacitance values found at the first instant a photogenerated charge are locally stored in the photodiode p-n junction. Also, the dependence of the degradation of the sensitivity on the incident wavelength and the diode vertical stack is examined through analysis and experimentation. [ABSTRACT FROM AUTHOR]

Abstract-In this paper, thick-film ceramic-sheet panel as a dielectric-barrier microdischarge-plasma source has been fabricated, and the behaviors of the positive column in the counterelectrode structure have been experimentally observed according to various electrode gaps from 200 to 500 μm. The minimum gap distance between the electrodes, which directly affects the generation of the positive column, was suggested based on the infrared (IR) emission characteristics from the microdischarge plasma. Considering the experimental observations, it is confirmed that the IR efficiency remarkably increases when an efficient positive column is produced at the electrode gaps over 400 μm. [ABSTRACT FROM AUTHOR]

The first stages of planet formation usually occur when the host star is still in a (relatively) dense star-forming region, where the effects of the external environment may be important for understanding the outcome of the planet formation process. In particular, star-forming regions that contain massive stars have strong far-ultraviolet (FUV) and extreme ultraviolet (EUV) radiation fields, which can induce mass-loss from protoplanetary discs due to photoevaporation. In this paper, we present a parameter-space study of the expected FUV and EUV fields in N -body simulations of star-forming regions with a range of initial conditions. We then use recently published models to determine the mass-loss due to photoevaporation from protoplanetary discs. In particular, we focus on the effects of changing the initial degree of spatial structure and initial virial ratio in the star-forming regions, as well as the initial stellar density. We find that the FUV fields in star-forming regions are much higher than in the interstellar medium, even when the regions have stellar densities as low as in the Galactic field, due to the presence of intermediate-mass, and massive, stars (>5 M⊙). These strong radiation fields lead to the destruction of the gas component in protoplanetary discs within 1 Myr, implying that gas giant planets must either form extremely rapidly (<1 Myr), or that they exclusively form in star-forming regions like Taurus, which contain no intermediate-mass or massive stars. The latter scenario is in direct tension with meteoritic evidence from the Solar system that suggests the Sun and its protoplanetary disc was born in close proximity to massive stars. [ABSTRACT FROM AUTHOR]

A laser-produced plasma source for extreme-ultraviolet (EUV) lithography conventionally uses a diffraction grating on the collection mirror for spectral purity filtering via diffractive scattering of infrared (IR) radiation. This paper proposes an alternative approach in which an EUV-blazed diffraction grating diverts in-band EUV radiation into the intermediate-focus aperture, rather than diverting IR out of the aperture. The full out-of-band spectrum, from long-wave IR to vacuum ultraviolet, can be fully excluded by this method regardless of whether the radiation is undiffracted or diffractively scattered by the grating. Much of the out-of-band radiation--especially the IR--is undiffracted, and this radiation can be efficiently returned to the plasma via retroreflection to enhance IR-to-EUV conversion. Plasma-emitted radiation that does not intercept the collection mirror can also be recycled back to the plasma via retroreflection to further boost EUV output. [ABSTRACT FROM AUTHOR]

This paper presents an in-depth overview of the present status and novel developments in the field of plasma processing of low dielectric constant (low-k) materials developed for advanced interconnects in ULSI technology. The paper summarizes the major achievements accomplished during the last 10 years. It includes analysis of advanced experimental techniques that have been used, which are most appropriate for low-k patterning and resist strip, selection of chemistries, patterning strategies, masking materials, analytical techniques, and challenges appearing during the integration. Detailed discussions are devoted to the etch mechanisms of low-k materials and their degradation during the plasma processing. The problem of k-value degradation (plasma damage) is a key issue for the integration, and it is becoming more difficult and challenging as the dielectric constant of low-k materials scales down. Results obtained with new experimental methods, like the small gap technique and multi-beams systems with separated sources of ions, vacuum ultraviolet light, and radicals, are discussed in detail. The methods allowing reduction of plasma damage and restoration of dielectric properties of damaged low-k materials are also discussed. [ABSTRACT FROM AUTHOR]

The double photoionization of HI molecules has been investigated using vacuum ultraviolet synchrotron radiation in the energy range between 27 and 35 eV. The product ions have been detected by the use of time-of-flight mass spectrometry and the threshold energy for HI2+ and H++I+ formation has been determined. These results have been interpreted by the use of a theoretical model which has been previously applied by us to HBr2+ and HCl2+. On the basis of the reliability of such a model, an assessment of the systematic trends of the bond features along the HX2+ (X=F, Cl, Br, I) homologous series is given in this paper. In particular, the increase of the stability of these dications, in their lowest electronic states, when going towards the heavier molecules, has been rationalized considering the systematic variation of the charge transfer coupling between the H–X2+ and the H+–X+ states. [ABSTRACT FROM AUTHOR]

In synchrotron radiation and electron storage rings, photon-stimulated gas desorption is a major contributor to gas load, leading to vacuum degradation and compromising the stability and quality of the beamline. Therefore, it is imperative to investigate the underlying mechanisms of photon-stimulated gas desorption to enhance the reliability of the experiments. In this paper, a theoretical model for analyzing the process of photon-stimulated desorption is presented, and the equations are solved numerically by considering the evacuation, bulk diffusion, thermal outgassing, adsorption, and desorption of surface gas molecules. The modified model can predict the yield of H 2 gas desorption induced by photon stimulation when synchrotron radiation is directed vertically onto various sample surfaces, utilizing the coupled multi-physics solution. The calculated results are consistent with the experimental measurements obtained from the Shanghai Synchrotron Radiation Facility. The results show that the photodesorption yield is related to the amount of surface-adsorbed molecules, which explains the observed decrease in the photodesorption yield with increasing accumulated photon dose. Furthermore, the study provides a theoretical approach to predicting the pressure evolution of photon-stimulated desorption. • A theoretical model for the analysis of photon-stimulated desorption (PSD) process is presented. • Reveals the mechanism underlying the decrease in the PSD yield with increasing accumulated photon dose. • Methods for predicting the evolution of pressure in the vacuum chamber before and after synchrotron radiation. • Methods for reducing the error between the tested PSD yield and the intrinsic PSD yield. [ABSTRACT FROM AUTHOR]

The low-lying electronic states of silicon dimer (Si 2 ) and its cation (Si 2 + ) have been studied by single-photon photoelectron spectroscopy combining a flow-tube reactor, vacuum-ultraviolet synchrotron radiation, and a double imaging photoelectron/photoion spectrometer. The energy range covered in this study (7.0−9.5 eV) allowed to observe several photoionising transitions involving the three lowest electronic states of Si 2 ( X 3 Σ g − , D 3 Π u , a 1 Δ g ) and five of the six lowest states of Si 2 + ( X + 4 Σ g − , a + 2 Π u , b + 2 Δ g , c + 2 Σ g − , and e + 2 Π u ). Using ab initio calculations and Franck-Condon simulations, several electronic transitions are identified which bring new elements in the description of the dense electronic landscapes of the silicon dimer and its cation. Interestingly, one of the most intense transitions is spin-forbidden ( X + 4 Σ g − ← a 1 Δ g ) and is most probably observed through autoionisation processes by spin interactions. [ABSTRACT FROM AUTHOR]

Context. The evolution of amorphous hydrocarbon materials, a-C(:H), principally resulting from ultraviolet (UV) photon absorptioninduced processing, are likely at the heart of the variations in the observed properties of dust in the interstellar medium. Aims. The consequences of the size-dependent and compositional variations in a-C(:H), from aliphatic-rich a-C:H to aromatic-rich a-C, are studied within the context of the interstellar dust extinction and emission. Methods. Newly-derived optical property data for a-C(:H) materials, combined with that for an amorphous forsterite-type silicate with iron nano-particle inclusions, a-SilFe, are used to explore dust evolution in the interstellar medium. Results. We present a new dust model that consists of a power-law distribution of small a-C grains and log-normal distributions of large a-SilFe and a-C(:H) grains. The model, which is firmly anchored by laboratory-data, is shown to quite naturally explain the variations in the infrared (IR) to far-ultraviolet (FUV) extinction, the 217 nm UV bump, the IR absorption and emission bands and the IR-mm dust emission. Conclusions. The major strengths of the new model are its inherent simplicity and built-in capacity to follow dust evolution in interstellar media. We show that mantle accretion in molecular clouds and UV photo-processing in photo-dominated regions are likely the major drivers of dust evolution. [ABSTRACT FROM AUTHOR]

Highlights • SnTe as capping layer coatings in the vacuum and extreme ultraviolet spectral regions. • Design and fabrication of VUV quarter wave plates (QWP) based on SnTe/Al bilayer. • Extreme ultraviolet (EUV) improved facility for ellipsometric measurements. • Studying the polarimetric properties of SnTe/Al sample at the wavelength of (121.6 nm). • Angle-dependence phase retarder properties of SnTe/Al also reported in this study. Abstract Vacuum ultraviolet and extreme ultraviolet polarized light plays a significant role in many applications from materials science and solar physics investigations to optical components development. In this paper, we study the optical performances and the quarter wave retarder properties of aluminum coating capped with SnTe/Al thin film. The measurements have been performed by using a reflectometer properly improved for ellipsometric characterizations. The specimen has been fully characterized at hydrogen Lyman–alpha line (121.6 nm) by deriving the reflectance and the ellipsometric parameters, i.e. the ratio r and the phase difference δ. We found that the SnTe/Al bilayer behaves as phase retarder, although the performances differ from the ideal case. In fact, the polarimetric analysis combined with the optical test at different wavelengths allowed to identify carbon contamination on the top layer and a mild oxidation of the aluminum coating that affect the optical throughput. [ABSTRACT FROM AUTHOR]

ISSIS imager has been thought as an open purpose instrument within the World Space Observatory (WSO) international space mission. The highest priorities of ISSIS, an instrument to be developed by Spain, are to guarantee high spatial resolution and high sensitivity down to the far ultraviolet (FUV). The paper displays the capacities of GOLD for multilayer deposition and FUV reflectometry, among other metrologies, for ISSIS optical elements. Deposition of coatings for ISSIS-WSO will be carried out in a new UHV system with a 75-cm diameter deposition chamber. The purpose of the new laboratory is the deposition of coatings satisfying the constraints for FUV space optics. The first target coating to be developed in this new laboratory is Al protected with MgF, with optimum reflectance down to ∼120 nm. GOLD's existing reflectometer is able to characterize flat pieces both by transmittance and reflectance, and the latter from near-normal to grazing incidence, in the range from 12 to 200 nm. Other metrologies that will be available at GOLD for ISSIS's coatings and filters include optical thickness of filters to assure parfocality, filter wedge, and coating and filter scattering. [ABSTRACT FROM AUTHOR]

In this paper we present our system design and methodology for making absolute quantum efficiency (QE) measurements through the vacuum ultraviolet (VUV) and verify the system with delta-doped silicon CCDs. Delta-doped detectors provide an excellent platform to validate measurements through the VUV due to their enhanced UV response. The requirements for measuring QE through the VUV are more strenuous than measurements in the near UV and necessitate, among other things, the use of a vacuum monochromator, good dewar chamber vacuum to prevent on-chip condensation, and more stringent handling requirements. [ABSTRACT FROM AUTHOR]

The effects of pH value, VUV intensity, initial dye concentration, initial H2O2 concentration, and TiO2 loading dose on the degradation of three azo dyes: acid Orange 8, acid Blue 29, and acid Blue 113 were studied to explore and compare the treatment efficiencies among the adopted AOPs. It was found that pH played an important role in the degradation of dyes using VUV irradiation. For VUV/H2O2, VUV/TiO2, and VUV/TiO2/H2O2 processes, the decoloration rates of the three azo dyes were more efficient under acidic conditions relative to alkaline conditions. The degradation rates of dyes increased with increasing concentrations of H2O2, but reaction rates were retarded at high concentrations of H2O2 because the H2O2 compound acted as a scavenger of the hydroxyl radical. In this paper, three azo dyes were decomposed efficiently by VUV irradiation only demonstrating the effectiveness of VUV direct photolysis. [ABSTRACT FROM AUTHOR]

This paper studies the near transform-limited high-resolution tunable far-ultraviolet light which is generated by narrow-band tunable light both theoretically and experimentally. It shows the theoretical work about conversion efficiency of sum-frequency, which is restricted by phase-matching angle, walk-off angle and phase distortion and so on, and sets experiment to check this work successfully. Also the origin of chirp of dye laser is analysed. [ABSTRACT FROM AUTHOR]

Most of the mass of the interstellar medium is in neutral phases that are heated by far-ultraviolet radiation from star forming regions. The gas, in turn, emits line radiation in the infrared and submillimeter that potentially has great diagnostic value. In this paper, we will review the physical processes (including heating, cooling, gas phase and grain surface chemistry) that give rise to this line emission and present diagnostic diagrams. We will also discuss several examples where models of neutral gas emission have been used to interpret line emission, including observations of H2O and O2 in molecular clouds and an example which points out the caution that must be used when applying the diagnostics to kiloparsec-sized regions in other galaxies. [ABSTRACT FROM AUTHOR]

Plasma-based technology is of great importance for a range of industrial applications. However, due to the complexity of gas-phase and surface chemical reactions, the underlying plasma chemistry is still poorly understood, leading to a growing demand for experimental setups on plasma diagnostics. In this paper, we report an apparatus that combines tunable synchrotron vacuum ultraviolet (VUV) photoionization with molecular-beam mass spectrometry for detecting ionic and neutral species formed in the processes of plasma discharge. The products including reactive intermediates such as enols can be identified unambiguously with the measurements of photoionization mass spectrometry (PIMS) and photoionization efficiency spectra. The tunable VUV PIMS has been proven as an ideal and sensitive tool for a comprehensive understanding of plasma chemistry. [ABSTRACT FROM AUTHOR]

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Synchrotron radiation circular dichroism (SRCD) spectroscopy is emerging as an important new tool in structural molecular biology. Previously we had shown that in lower-flux SRCD instruments, such as UV1 at ISA and beamline 3.1 at the SRS, vacuum ultraviolet (VUV) radiation damage to proteins was not evident after exposure over a period of hours. No effects were detected in either the protein primary or the secondary structures. However, with the development of high-flux beamlines, such as CD12 at the SRS, this issue has been revisited because of changes observed in the SRCD spectra of consecutive scans of protein samples obtained on this high-flux beamline. Experiments have been designed to distinguish between two different possible mechanisms: (i) photoionization causing free radicals or secondary electrons producing degradation of the protein, and (ii) local heating of the sample resulting in protein denaturation. The latter appears to be the principal source of the signal deterioration. [ABSTRACT FROM AUTHOR]

The paper deals with the results of experimental investigation of spectrally averaged group reflectivities R(Δλ) in a vacuum ultraviolet (hν ∼ 10 to 70 eV) spectral range of commercial samples of high-temperature dielectric materials (α-Al2O3, SiO2, BNC) under conditions of a prethreshold (prior to the beginning of developed surface evaporation) power density of probing radiation. [ABSTRACT FROM AUTHOR]

Direct imaging of the magnetosphere by instruments on the IMAGE spacecraft is supplemented by simultaneous observations of the global aurora in three far ultraviolet (FUV) wavelength bands. The purpose of the multi-wavelength imaging is to study the global auroral particle and energy input from the magnetosphere into the atmosphere. This paper describes the method for quantitative interpretation of FUV measurements. The Wide-Band Imaging Camera (WIC) provides broad band ultraviolet images of the aurora with maximum spatial resolution by imaging the nitrogen lines and bands between 140 and 180 nm wavelength. The Spectrographic Imager (SI), a dual wavelength monochromatic instrument, images both Doppler-shifted Lyman-a emissions produced by precipitating protons, in the SI-12 channel and 01135.6 nm emissions in the SI-13 channel. From the SI-12 Doppler shifted Lyman-a images it is possible to obtain the precipitating proton flux provided assumptions are made regarding the mean energy of the protons. Knowledge of the proton (flux and energy) component allows the calculation of the contribution produced by protons in the WIC and SI-13 instruments. Comparison of the corrected WIC and SI-13 signals provides a measure of the electron mean energy, which can then be used to determine the electron energy flux. To accomplish this, reliable emission modeling and instrument calibrations are required. In-flight calibration using early-type stars was used to validate the pre-flight laboratory calibrations and determine long-term trends in sensitivity. In general, very reasonable agreement is found between in-situ measurements and remote quantitative determinations. [ABSTRACT FROM AUTHOR]

A novel high-frequency driving scheme was proposed in this paper to improve the luminous efficiency of a plasma display. High-frequency oscillating waveform was applied to the address electrodes of the conventional three-electrodes ac-type plasma display panel during the sustaining period. More vacuum ultraviolet rays were generated by the high-frequency waveform so that the luminance and luminous efficiency could be enhanced. From experiments on an 8.5-in panel, the luminance was improved and the luminous efficiency was enhanced more than 40%. [ABSTRACT FROM AUTHOR]

This study employed a vacuum ultraviolet synchrotron radiation source and reflectron time‐of‐flight mass spectrometry (TOF‐MS) to investigate the photoionization and dissociation of styrene. By analyzing the photoionization mass spectrum and efficiency curve alongside G3B3 theoretical calculations, we determined the ionization energy of the molecular ion, appearance energy of fragment ions, and relevant dissociation pathways. The major ion peaks observed in the photoionization mass spectra of styrene correspond to C8H8+, C8H7+ and C6H6+. The ionization energy of styrene is measured as 8.46 ± 0.03 eV, whereas the appearance energies of C8H7+ and C6H6+ are found to be 12.42 ± 0.03 and 12.22 ± 0.03 eV, respectively, in agreement with theoretical values. The main channel for the photodissociation of styrene molecular ions is the formation of benzene ions, whereas the dissociation channel that loses hydrogen atoms is the secondary channel. Based on the experimental results and empirical formulas, the required dissociation energies (Ed) of C8H7+, C8H6+ and C6H6+ are calculated to be (3.96 ± 0.06), (4.00 ± 0.06) and (3.76 ± 0.06) eV, respectively. Combined with related thermochemical parameters, the standard enthalpies of formations of C8H8+, C8H7+, C8H6+ and C6H6+ are determined to be 964.2, 1346.3, 1350.2 and 1327.0 kJ/mol, respectively. Based on the theoretical study, the kinetic factors controlling the styrene dissociation reaction process are determined by using the Rice–Ramsperger–Kassel–Marcus (RRKM) theory. This provides a reference for further research on the atmospheric photooxidation reaction mechanism of styrene in atmospheric and interstellar environments. [ABSTRACT FROM AUTHOR]

Results are presented of research aimed at creating a compact source of soft X-ray and vacuum ultraviolet radiation through the collision of a powerful plasma flow with a gas jet. In experiments that were carried out, a pulsed electrodynamic accelerator generated a hydrogen plasma flow with an energy constant of ≈50 kJ and duration of 10–15 μs. The flow, with a density of ≈6 × 1015 cm–3, moved at a velocity of (2‒4) × 107 cm/s in a longitudinal magnetic field with an induction of up to 2 T and interacted with a flat supersonic gas jet. The maximum molecular density of the gas, nitrogen or neon, in the jet reached 1017 cm–3. The formation of a compact emitting plasma layer with a thickness of 3–5 cm, moving along the path of the hydrogen plasma flow at a speed of approximately 3 × 106 cm/s was demonstrated. In several experiments, a tungsten plate was used as an obstacle to confine the motion of the emitting plasma along the magnetic field, localizing the interaction region between the plasma flow and the gas jet within the diagnostic control zone. Soft X-ray obscurography and spectroscopy were used to obtain data regarding the radiation generation from the interaction zone of the hydrogen plasma flow and the gas jet. The results of measuring the radiation energy from the formed plasma are presented: ≈2 kJ in the case of a nitrogen jet and ≈ 3 kJ in the case of a neon jet. Numerical modeling of the line radiation from multi-charged ions and subsequent comparison of calculated and experimental data allowed estimating the electron temperature of the nitrogen and neon plasmas formed during the interaction of the hydrogen plasma flow with the gas jet at a level of ≥40 eV. [ABSTRACT FROM AUTHOR]

Carbon 1s excitation of methane, CH4, has been studied in the gas phase using the ion trap integrated with the photon–ion instrument at PETRA III/DESY and soft X-rays from the beamline P04. The created photoions are stored within the ion trap so that in further steps the photoions can undergo reactions with neutral methane molecules. The ionic photoproducts as well as reaction products created thereby are mass-over-charge analyzed by an ion time-of-flight spectrometer. Besides the photoions, product ions with up to three carbon atoms are found. In contrast to experiments using vacuum ultraviolet radiation, especially highly reactive product ions with a small number of hydrogen atoms such as C 2 H 2 + and C 2 H 3 + are found, which are important precursors for larger hydrocarbons such as C6H6. Possible production routes of the product ions are analyzed on the basis of a model that considers the probabilities for photofragmentation and the first subsequent chemical reaction step. The model indicates that the high degree of fragmentation by photons with energies around 280 eV is favoring these products. The results of the measurements show that the products like C 2 H 2 + and C 2 H 3 + can be generated by a single collision of the ionization product with neutral methane. The results suggest that soft X-rays might be important for chemical reactions in planetary atmospheres, which has usually not been taken into account. However, due to the high degree of fragmentation and large cross sections involved, they can have a large influence even when the corresponding photon flux is rather small. [ABSTRACT FROM AUTHOR]

The C2 carbon cluster is found in a large variety of environments including flames, electric discharges, and astrophysical media. Due to spin-selection rules, assessing a complete overview of the dense vibronic landscape of the C 2 + cation starting from the ground electronic state X Σ g + 1 of the neutral is not possible, especially since the C 2 + ground state is of X + Σ g − 4 symmetry. In this work, a flow-tube reactor source is employed to generate the neutral C2 in a mixture of both the lowest singlet X Σ g + 1 and triplet a 3Πu electronic states. We have investigated the vibronic transitions in the vicinity of the first adiabatic ionization potential via one-photon ionization with vacuum ultraviolet synchrotron radiation coupled with electron/ion double imaging techniques. Using ab initio calculations and Franck-Condon simulations, three electronic transitions are identified and their adiabatic ionization energy is determined E i ( a + 2 Π u ← X 1 Σ g + ) = 12.440 (10) eV, E i ( X + 4 Σ g − ← a 3 Π u ) = 11.795 (10) eV, and Ei(a+2Πu ← a3Πu) = 12.361(10) eV. From the three origin bands, the following energy differences are extracted: ΔE(a − X) = 0.079(10) eV and ΔE(a+ − X+) = 0.567(10) eV. The adiabatic ionization potential corresponding to the forbidden one-photon transition X+ ← X is derived and amounts to 11.873(10) eV, in very good agreement with the most recent measurement by Krechkivska et al. [J. Chem. Phys. 144, 144305 (2016)]. The enthalpy of formation of the doublet ground state C 2 + cation in the gas phase is determined at 0 K, Δ f H 0 (0 K) ( C 2 + ( Π u 2 )) = 2019.9 (10) kJ mol−1. In addition, we report the first experimental ion yield of C2 for which only a simple estimate was used up to now in the photochemistry models of astrophysical media due to the lack of experimental data. [ABSTRACT FROM AUTHOR]

The materials of the article outline the features of the use of ultraviolet LED systems in industry, and propose a solution for their use in the grain processing and compound feed industry. Ultraviolet light (UV) is a well-researched and widely used means of decontamination and disinfection of surfaces, air, water, and food. Usually, far ultraviolet radiation (or ultraviolet C, UVC) with a wavelength of 254 nm is used, which corresponds to the peak absorption of wave energy by the DNA of a living cell. There is a mathematical mechanism for calculating the parameters of radiation in relation to its effect on microorganisms: a curve describing the microbial death depending on the increase in the radiation dose received by the bacteria and formulae for the relationship between the three main parameters (dose, radiation flux and exposure duration). Ultraviolet lamps (tubes) are commonly used, on the basis of which a large number of emitters have been developed for different needs. There are also emitters for grain and feed disinfection in use, but only outside of industrial production lines. Ultraviolet irradiation is not used directly on manufacturing lines so far. However, it can be used to reduce the microbial burden of a feed or food product prior to packaging the finished product. For this purpose, ultraviolet light-emitting diodes (LEDs) available on the world market today can be used. However, their use faces difficulties: ultraviolet LEDs emit wavelengths longer than lamps (at about 275 nm or more), which requires an increase in the duration of irradiation, which is undesirable for industrial processing of products directly on the line. However, the small size of the UVC LEDs will allow them to be installed in grain processing and feed mills inside equipment (magnetic separators, gravity feeders, etc.) with appropriate protection against damage by moving material. In addition, suspended emitters of any configuration can be placed above belt conveyors that move material at a certain speed. This approach will require certain measures to control the efficiency of irradiation (requires microbiological studies) and to protect personnel from the harmful effects of ultraviolet rays (means of personal and collective protection, measurement of radiation intensity). [ABSTRACT FROM AUTHOR]

This paper describes a method for transferring a nanoscale pattern from a cyclic olefin polymer (COP) mold to the surface of UV curable polydimetylsiloxane (PDMS) on a glass substrate. The PDMS is first deposited on the patterned mold by spin-coating and photocuring. Vacuum ultraviolet (VUV) radiation is then used to activate the surface of both the PDMS and the glass substrate before bringing them into contact. Once a bond has been formed, the COP mold is peeled away, leaving the patterned PDMS on the glass substrate. Bonding tests were first carried out to determine the optimum VUV irradiation dose to form a permanent bond. The effectiveness of the proposed method was then demonstrated by transferring a periodic nanoscale pattern. Microscopic examination of the original and transferred patterns revealed that successful reproduction was achieved. A spectroscopic analysis was also performed to clarify the mechanism involved in the bonding process. The results suggested that VUV irradiation caused oxidation of the PDMS surface and the formation of OH groups. When the PDMS and the glass substrate were brought into contact, a dehydration reaction took place which caused the formation of siloxane ( O Si O ) bonds between the two materials. The proposed method offers the advantages of being simple and allowing deformation-free transfer of very fine patterns. It can also be applied to a wide range of nanoscale fabrication tasks. [ABSTRACT FROM AUTHOR]

The present paper is focused on the use of a vacuum ultraviolet absorption spectrometer (VUV) for gas chromatography (GC), within the context of flow modulated comprehensive two-dimensional gas chromatography (FM GC × GC). The features of the VUV detector were evaluated through the analysis of petrochemical and fatty acids samples. Besides responding in a predictable fashion via Beer’s law principles, the detector provides additional spectroscopic information for qualitative analysis. Virtually all chemical species absorb and have unique gas phase absorption features in the 120–240 nm wavelength range monitored. The VUV detector can acquire up to 90 full range absorption spectra per second, allowing its coupling with comprehensive two-dimensional gas chromatography. This recent form of detection can address specific limitations related to mass spectrometry ( e.g., identification of isobaric and isomeric species with very similar mass spectra or labile chemical compounds), and it is also able to deconvolute co-eluting peaks. Moreover, it is possible to exploit a pseudo-absolute quantitation of analytes based on pre-recorded absorption cross-sections for target analytes, without the need for traditional calibration. Using this and the other features of the detector, particular attention was devoted to the suitability of the FM GC × GC-VUV system toward qualitative and quantitative analysis of bio-diesel fuel and different kinds of fatty acids. Satisfactory results were obtained in terms of tailing factor (1.1), asymmetry factor (1.1), and similarity (average value 97%), for the FAMEs mixtures analysis. [ABSTRACT FROM AUTHOR]

There is growing theoretical and observational evidence that protoplanetary disc evolution may be significantly affected by the canonical levels of far-ultraviolet (FUV) radiation found in a star-forming environment, leading to substantial stripping of material from the disc outer edge even in the absence of nearby massive stars. In this paper, we perform the first full radiation hydrodynamic simulations of the flow from the outer rim of protoplanetary discs externally irradiated by such intermediate strength FUV fields, including direct modelling of the photon-dominated region which is required to accurately compute the thermal properties. We find excellent agreement between our models and the semi-analytic models of Facchini et al. (2016) for the profile of the flow itself, as well as the mass-loss rate and location of their 'critical radius'. This both validates their results (which differed significantly from prior semianalytic estimates) and our new numerical method, the latter of which can now be applied to elements of the problem that the semi-analytic approaches are incapable of modelling. We also obtain the composition of the flow, but given the simple geometry of our models we can only hint at some diagnostics for future observations of externally irradiated discs at this stage. We also discuss the potential for these models as benchmarks for future photochemical-dynamical codes. [ABSTRACT FROM AUTHOR]

Polyetheretherketone (PEEK) is the material of choice in several applications ranging from the automotive industry to medicine, but the surface properties are usually not adequate. A standard method for tailoring surface properties is the application of gaseous plasma. The surface finish depends enormously on the processing parameters. This article presents a review of strategies adapted for improved wettability and adhesion of PEEK. The kinetics of positively charged ions, neutral reactive plasma species, and vacuum ultraviolet radiation on the surface finish are analyzed, and synergies are stressed where appropriate. The reviewed articles are critically assessed regarding the plasma and surface kinetics, and the surface mechanisms are illustrated. The directions for obtaining optimal surface finish are provided together with the scientific explanation of the limitations of various approaches. Super-hydrophilic surface finish is achievable by treatment with a large dose of vacuum ultraviolet radiation in the presence of oxidizing gas. Bombardment with positively charged ions of kinetic energy between about 100 and 1000 eV also enable high wettability, but one should be aware of excessive heating when using the ions. [ABSTRACT FROM AUTHOR]

In this paper, the design, construction, and test procedure of a closing switch prototype based on thyristors is described. In particular, details are given about the design criteria and about the triggering board architecture, which is a high side biased, self supplied unit using the electrical energy derived from a local snubber network for the gate drive. The structure guarantees a hard firing gate pulse for the required high dI/dt application. Further, the results of the prototype tests are presented and discussed. The stack assembly has a holding voltage of 6.5 kV and is used for switching a series resonant circuit with a ringing frequency of 12 kHz for a pulsed inductive vacuum ultraviolet source. Maximum current amplitudes of 13 kA and pulse energies of more than 600 J were switched during the test procedure. [ABSTRACT FROM AUTHOR]

Advances in free electron lasers (FELs) which generate high energy photons are expected to open novel nonlinear optics in the x-ray and vacuum ultraviolet (VUV) regions. In this paper, we report a new method for performing VUV-FEL focusing experiments. A VUV-FEL was focused with Kirkpatrick-Baez optics on a multilayer target, which contains fused silica as a fluorescent material. By measuring the fluorescence, a 5.6×4.9 μm2 focal spot was observed in situ. Fluorescence was used to measure the saturable absorption of VUV pulses in the tin layer. The transmission increases nonlinearly higher with increasing laser intensity. [ABSTRACT FROM AUTHOR]

193 nm photoresist patterns printed by optical lithography are known to present significant linewidth roughness (LWR) after the lithographic step that is partially transferred into the underlayers during plasma etching processes. In this study, we identify the factors that impact the photoresist pattern sidewalls roughness during plasma exposure. Among them, plasma vacuum ultraviolet light (110–210 nm) is shown to be the main contributor to the LWR decrease induced by plasma etching processes. In this paper, we also demonstrate the strong correlation between LWR obtained after plasma exposure and the surface roughening mechanisms taking place on top of the resist patterns. [ABSTRACT FROM AUTHOR]

We proposed and demonstrated an optical dry etching method for transferring a pattern on a photomask to a surface of plastics by decomposing the irradiated area using the high energy of vacuum ultraviolet light (VUV) at room temperature and pressure. Two kinds of wavelengths of 160 nm and 172 nm were used as the vacuum ultraviolet light, and the patterning performances for polymethyl methacrylate (PMMA) and polycarbonate (PC) were compared. As a result, it was revealed that proportional relationships were obtained between the etching rate and the irradiation dose for both wavelengths, and the cross-sectional profiles were anisotropic. In addition, both PMMA and PC were etched at a wavelength of 160 nm, whereas PC could not be etched at a wavelength of 172 nm, suggesting that it correlates with the bond dissociation energies of the molecular bonds of the materials and the energies of the photons. Furthermore, by combining this method with the optical bonding method that we had previously developed to bond surfaces irradiated with VUV, we have demonstrated a method for fabricating microfluidic devices by irradiating only with VUV. This paper shows that this technique is a new microfabrication method suitable for simple and mass production of plastic materials. [ABSTRACT FROM AUTHOR]

This work presents a computational study of the atmospheric pressure plasma of the COST jet source in He + 0.1% N2 buffer gas, incorporating the treatment of the VUV resonant radiation from He atoms at a wavelength of 58.4 nm. The plasma is driven by single- and multi-frequency waveforms at various peak-to-peak voltages between 400 V and 685 V. The simulations, which include the photoemission of electrons from the electrodes as well as the photoionization of the N2 molecules indicate that these processes, induced by the VUV radiation, have relatively little influence on the discharge characteristics due to other more efficient charged particle production mechanisms, e.g., Penning ionization. While the plasma characteristics are computed along one spatial dimension perpendicular to the electrodes, the tracing of the VUV photons is executed in the real 3D geometry of the plasma source to allow the computation of the VUV photon flux leaving the device through the orifice. Photon fluxes up to ≈ 5 Ă— 1 0 15 cmâˆ'2 sâˆ'1, corresponding to an energy flux of ≈18 mW cmâˆ'2 are found at multi-frequency operation. [ABSTRACT FROM AUTHOR]

The paper has investigated the process of measuring power illumination for vacuum ultraviolet radiation by means of the solution of potassium iodide as a photochemical actinometer. We have investigated the formation of triiodide-ion when radiated the solution of light with wavelength 185 nm. It has been shown that obtaining hydroxyl radicals OH at this wavelength is determined by the formation of I. The quantum yield of the process constitutes 0.165. Measuring the concentration of the obtained I we determined power illumination of a quartz lamp DRB-20 (wavelength 185 nm), which constitutes 49.2 × 10 E/s. [ABSTRACT FROM AUTHOR]