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Your search keyword '"A. Oro, Luis"' showing total 24 results
Start Over Author "A. Oro, Luis" Journal transition metal chemistry
24 results on '"A. Oro, Luis"'

18. Hydroformylation of 1-heptene by a [Rh(NBD)Cl]2/PPh3 system. A kinetic approach

Author

Royo, Miguel, Melo, Francisco, Manrique, Antonio, and Oro, Luis

Abstract

A kinetic study of the hydroformylation of 1-heptene by a [Rh(NBD)Cl]2/PPh3 system, taking into account possible gas-liquid mass-transfer restrictions, is presented. The catalytic activity in different solvents is evaluated. With Me2CO as solvent, the kinetic Equation (1) is obtained. $$Rate = - dC/dt = k' C^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} {\text{C}}_{{\text{Rh}}} ^{{1 \mathord{\left/ {\vphantom {1 4}} \right. \kern-\nulldelimiterspace} 4}} ({\text{P}}_{{\text{H}}_2 } /{\text{P}}_{{\text{CO}}} )^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} $$

Published
1982
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23. Five coordinate complexes of the type Rh(SnCl3)(NBD)L2

Author

Usón, Rafael, Oro, Luis A., Reyes, Josefa, Carmona, Daniel, and Lahuerta, Pascual

Abstract

Several new rhodium complexes of general formulation Rh(SnCl3)(NBD)L2 (L=P(OMe)3, P(OMe)2Ph, P(OMe)Ph2, P(OEt)3, P(OEt)2Ph, P(OEt)Ph2, P(O-i-Pr)3, P(OPh)3) have been prepared and characterized by elemental analysis and by i.r. and n.m.r. spectroscopy. The complexes show low or no conductivity in acetone solution and react with carbon monoxide (1 atm).

Published
1983
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