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Hydroformylation of 1-heptene by a [Rh(NBD)Cl]2/PPh3 system. A kinetic approach
- Source :
- Transition Metal Chemistry; February 1982, Vol. 7 Issue: 1 p44-49, 6p
- Publication Year :
- 1982
-
Abstract
- A kinetic study of the hydroformylation of 1-heptene by a [Rh(NBD)Cl]<subscript>2</subscript>/PPh<subscript>3</subscript> system, taking into account possible gas-liquid mass-transfer restrictions, is presented. The catalytic activity in different solvents is evaluated. With Me<subscript>2</subscript>CO as solvent, the kinetic Equation (1) is obtained. $$Rate = - dC/dt = k' C^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} {\text{C}}_{{\text{Rh}}} ^{{1 \mathord{\left/ {\vphantom {1 4}} \right. \kern-\nulldelimiterspace} 4}} ({\text{P}}_{{\text{H}}_2 } /{\text{P}}_{{\text{CO}}} )^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} $$
Details
- Language :
- English
- ISSN :
- 03404285 and 1572901X
- Volume :
- 7
- Issue :
- 1
- Database :
- Supplemental Index
- Journal :
- Transition Metal Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs15351887
- Full Text :
- https://doi.org/10.1007/BF00623808