1. Analysis of the composition of a mixture of249Bk+249Cf on the basis of x rays
- Author
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G. V. Buklanov and Yu. P. Kharitonov
- Subjects
Crystallography ,Nuclear Energy and Engineering ,Period (periodic table) ,Isotope ,Chemistry ,Yield (chemistry) ,General Engineering ,Analytical chemistry ,Composition (visual arts) ,Radiation - Abstract
The results of the study enable us to conclude the following: the β decay of249Bk is accompanied by an L series of x rays from the daughter product Cf. The yield of this radiation is low: ω(Lα+Lβ+ Lγ) ≈ 10−4 (β disintegration)−1, but because of the high specific β activity of249Bk, 1 μg of this isotope emits ∼3.7·105 x-ray quanta per minute. This enables us to detect a fairly small amount of Bk (∼0.01 μg) on the basis of x rays in a period of 5–10 min. The rapid accumulation of the daughter product249Cf does not interfere with the determination of the249Bk on the basis of x rays. Even when the mixture contains equal numbers of Bk and Cf nuclei, the ratio of the Lα lines corresponding to them is 0.46. Therefore the composition of a mixture of249Bk+249Cf can be determined on the basis of x rays over broad ranges of variation of the relative concentrations of Bk+Cf, roughly from 0.03 to 80. It is important to note that for relative measurements it is not necessary to prepare special specimens, since x rays with energies of 15–20 keV are not strongly absorbed in the solution and in the walls of the chemical vessel.
- Published
- 1980
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