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Environmental destruction, water crisis, and clean energy are among the very important challenges worldwide based on sustainable development goals. Photocatalytic fuel cell, a potential candidate for converting chemical energy into electrical energy through a pollution-free method, holds promise in addressing these challenges. In this regard, we investigated the response of a photoanode covered with UiO66-NH 2 -TiO 2 /NiF on a porous nickel foam as an attractive electrochemical response to remove antibiotics from aqueous solution and simultaneously produce electricity using a one-step hydrothermal synthesis. Nickel foam with its fine structure provides a suitable space for the interaction of light, catalyst, and efficient mass transfer of reactive molecules. It appears that it can be used as a competitive electrode in fuel cells. In order to investigate the properties of the photocatalyst, structural analyses including XRD, FESEM, FTIR, and UV-vis DRS were utilized. Additionally, polarization and electrochemical tests such as chronoamperometry and EIS were measured to further examine the electrochemical features of the PFC photoanode system. The obtained results under optimal conditions (SMZ concentration = 20 ppm, pH = 6, irradiation time = 120 min) were as follows: removal efficiency of 91.7%, P max  = 16.98 μW/cm 2 , J sc  = 96.75 μA/cm 2 , V oc  = 644 mV. The light-induced current flow in UiO66-NH 2 -TiO 2 /NiF exhibited prominent and reproducible photocurrent responses, indicating efficient and stable charge separation in TiO 2 /NiF composite materials, which is a promising strategy for pollutant removal and simultaneous electricity generation., (© 2023. The Author(s).)

This study explores the influence of inter-dot tunneling effects within a quantum dot molecule on the Fresnel diffraction phenomenon. Our findings indicate that the Fresnel diffraction of the output probe Gaussian field can be manipulated by adjusting the inter-dot tunneling parameter's strength and the characteristics of the coupling field. The inter-dot tunneling effect establishes a closed-loop system, setting conditions for the interference of the applied fields. We specifically examine a Laguerre-Gaussian (LG) coupling field, investigating how its properties-such as strength, value, and sign of the orbital angular momentum (OAM)-impact the Fresnel diffraction of the output probe field. Increasing the inter-dot tunneling parameter and the coupling LG field's strength allows for control over the spatial distribution of the Fresnel diffraction pattern. Notably, the inter-dot tunneling parameter can disturb the symmetry of the diffraction patterns. Additionally, considering a negative OAM for the coupling LG field transforms the diffraction pattern into its inverse shape. This suggests that, in the presence of the inter-dot tunneling effect, the Fresnel diffraction pattern is contingent on the direction of rotation of the helical phase front of the coupling LG field. Our results offer insights into quantum control of Fresnel diffraction patterns and the identification of OAM in LG beams, presenting potential applications in quantum technologies., (© 2024. The Author(s).)

The SOCS1 (Suppressor Of Cytokine Signalling 1) protein is considered a tumour suppressor. Notably, the SOCS1 gene is frequently silenced in cancer by hypermethylation of its promoter. Besides blocking inflammation, SOCS1 tumour suppressor activity involves Met receptor inhibition and enhancement of p53 tumour suppressor activity. However, the role of SOCS1 in colorectal cancer (CRC) remains understudied and controversial. Here, we investigated SOCS1 relevance for CRC by querying gene expression datasets of human CRC specimens from The Cancer Genome Atlas (TCGA), and by SOCS1 gain/loss-of-function analyses in murine and human colon carcinoma cells. Our results show that SOCS1 mRNA levels in tumours were more often elevated than reduced with respect to matched adjacent normal tissue of CRC specimens (n = 41). The analysis of TCGA dataset of 431 CRC patients revealed no correlation between SOCS1 expression and overall survival. Overexpression of SOCS1 in CRC cells triggered cell growth enhancement, anchorage-independent growth and resistance to death stimuli, whereas knockdown of SOCS1 reduced these oncogenic features. Moreover, SOCS1 overexpression in mouse CT26 cells increased tumourigenesis in vivo. Biochemical analyses showed that SOCS1 pro-oncogenic activity correlated with the down-modulation of STAT1 expression. Collectively, these results suggest that SOCS1 may work as an oncogene in CRC.

The city's rapid development would lead to irreversible changes in architectural heritage. As one of the ways to promote sustainable development, world heritage tourism has opened up a new perspective for the protection, inheritance and development of architectural heritage. Taking the study of architectural heritage in the Historic Centre of Macau as an example, employing eye-tracking experiment and semantic differential method (SD method) to explore the relationship between tourists' perceptions of visual elements of architectural heritage, positive emotions, and behavioral intentions. The results show that in terms of visual elements, the architectural style of the wall (p = 0.013 < 0.05, B = 0.165), the proportional balance of the windows (p = 0.047 < 0.05, B = 0.120), the exquisite decoration of the door (p = 0.028 < 0.05, B = 0.125), and the proportional balance of other buildings (p = 0.042 < 0.05, B = 0.121) have a positive impact on tourists' behavioral intention. In terms of positive emotions, positive (p = 0.001 < 0.05, B = 0.177), intense (p = 0.000 < 0.01, B = 0.228), and enthusiastic (p = 0.008 < 0.05, B = 0.156) emotions were positively correlated with behavioral intention. The research results can provide a scientific basis and decisional reference for the protection and tourism development of architectural heritage in the Historic Centre of Macau. [ABSTRACT FROM AUTHOR]

Jharkhand is a minerally prosperous state with geogenic and industrial origins of metals. This study assesses the seasonal variation of pseudo-total metal contents (Cr, Ni, Pb, Zn, Mn, Cu, Fe, Mg, Al) and related contamination and risks in indoor dust, street dust, and soils of four major cities of Jharkhand. Across cities and seasons, Zn, Cu, and Pb were the most common pollutants. Indoor dust showed higher metal concentrations than street dust and soil, suggesting their indoor origins. Geo-accumulation indices indicated significant Cu contamination, followed by Pb and Zn. Street dust exhibited notable enrichment in Zn and Pb in all cities except Dhanbad, where Cu contamination was substantial. Ecological risk indices peaked during summer in street dusts of Ranchi and Bokaro (for Pb) and during monsoons in soils of Jamshedpur and Dhanbad (for Cu). Based on chemical sequential extractions, the mobilities of Mg, Mn, Zn, and Cu were high, while Pb had moderate mobility. The probable sources of immediate concern were vehicles and paints, wire, electroplating, metal casting, and steel manufacturing industries. The findings emphasize the urgent need for implementing stringent regulations to mitigate metal emissions and ensure compliance with environmental standards. [ABSTRACT FROM AUTHOR]

To tackle the challenges of increasing the efficiency of photocatalysts, a ternary magnetic heterojunction photocatalyst containing spinel cobalt and zinc ferrites, and zeolite (CZZ) was designed and fabricated. The physicochemical properties of the novel photocatalyst were verified using characterization techniques such as XRD, FT-IR, FE-SEM, EDS mapping, N2 adsorption-desorption, VSM, PL, and UV–Vis DRS. The CZZ photocatalyst exhibited a significant Cr (VI) reduction rate of 0.1535 min−1, which was 9.27, 5.37 and 3.58 times higher than those of single ZnFe2O4 nanoparticles (0.0166 min−1), CoFe2O4 nanoparticles (0.0286 min−1), and CoFe2O4–ZnFe2O4 (0.0428 min−1) respectively. CZZ showed an excellent reusability after three consecutive cycles of Cr(VI) reduction. The results from the experiments in different aqueous environments displayed that CZZ could be a promising photocatalyst to reduce Cr(VI) in the treatment of actual aqueous matrices. The present study not only provides a highly active catalytic system for the practical removal of Cr(VI) but also paves the way for the fabrication of high-performance heterojunction photocatalysts. [ABSTRACT FROM AUTHOR]

Evaluation of genetic biodiversity for micronutrients is crucial for breeding high-quality crops and addressing the negative impacts of mineral deficiencies. The objectives of this research were to assess genetic variation and the relationship between grain Fe and Zn levels and agronomic traits in a diverse collection of wheat varieties. Additionally, the study aimed to determine the correlation between microsatellite markers (SSR) and micronutrient quantities. A total of 42 genotypes (Iranian commercial cultivars, landraces, and Afghan and Swiss varieties) were evaluated over a two-year period. Fe and Zn levels were measured using two semi quantitative staining assays and atomic absorption spectrophotometry (AAS) facility. Semi-quantitative staining methods and AAS showed high correlations for micronutrient contents. Landraces exhibited higher Fe (63.79 mg/kg) and Zn (44.76 mg/kg) but lower grain yield compared with commercial cultivars. Heritability estimates ranged 53%-79.43%, suggesting that genetic variance played a higher contribution in the phenotypic variation of traits than environmental factors. Notably, Fe content displayed significant correlations with days to maturity. Canonical correlation analysis (CCA) revealed that Zn content was correlated with four agronomic traits. Evaluation of genetic diversity using SSR markers demonstrated high genetic variation among the genotypes tested. The analysis of polymorphism information content (PIC) indicated that SSR primers had an average PIC of 0.75, with the Xgwm192 primer exhibiting higher PIC than others. Several SSR markers revealed association with micronutrient content that can be used in marker-assisted selection (MAS) programs aimed at selection of high micronutrient genotypes. In conclusion, the findings underscored the substantial genetic diversity present in micronutrient levels among global wheat genotypes, the potential of landraces for micronutrients biofortification of wheat cultivars through cross hybridization, the utility of staining methods for screening high/low micronutrient genotypes, and use of microsatellite markers for marker-assisted breeding aiming to micronutrient improvement in breeding programs. [ABSTRACT FROM AUTHOR]

Brazil is one of the world's largest beer producers and also a major food producer. These activities generate a large amount of residues which, if disposed of inappropriately, can have adverse effects on the environment. The objective of this research was to evaluate the potential of using these residues for both mushroom cultivation (traditional use) and the production of mycelium-based composites (innovative use). Mushroom production (Pleurotus sajor-caju) was conducted using only brewer's spent grains (fresh and dried) and also mixed with banana leaves (1:1) or peach palm leaves (1:1), which are residues widely available in the northern region of Santa Catarina, Brazil. The productivity of mushrooms cultivated using fresh and dried brewer's spent grains did not exhibit a statistically significant difference, indicating that this residue can be utilized shortly after its generation in the industrial process, thereby reducing costs associated with production. Combining brewer's spent grains with banana or peach palm leaves resulted in enhanced mushroom production (0.41 and 0.38 g day−1, respectively) compared to using the leaves as a sole substrate. The mushrooms produced contain sugars and a minimal sodium content, and are considered a source of phosphorus. In addition, no toxic elements (Hg and Pb) were present. The mycelium-based composites produced using the residual substrate (after the mushroom harvest) exhibited better mechanical properties (compressive strength = 0.04 MPa, density = 242 kg m−3, and low humidity sorption) than those produced using fresh substrate. The results demonstrate the synergistic effect of combining the two approaches under investigation. The use of brewer´s spent enhance the mushroom productivity and the residual substrate enhance the mechanical properties of mycelium-based composites. The compressive strength, density, and air humidity sorption properties are essential for determining the potential applications of mycelium-based composites. The use of brewer's spent grains mixed with banana leaves demonstrated significant promise for mushroom production and subsequent application in the development of mycelium-based composites. These sequential approaches contribute to waste valorization and the rational utilization of natural resources, as the mycelium-based composites are considered for substitution of synthetic materials, thereby promoting sustainability for future generations. [ABSTRACT FROM AUTHOR]

In this study, natural asphalt was oxidized to synthesize a new nano-structure adsorbent for dye removal. The functionalization of natural asphalt by oxidation introduced new properties that influenced its activity. The process of oxidizing natural asphalt with potassium permanganate resulted in a low-cost adsorbent, which can potentially be a more affordable option compared with synthetic alternatives. Characterization analysis confirmed the enhanced surface area, improving dye interaction and adsorption. The interconnected channels and capillaries of the oxidized natural asphalt facilitated the capillary action drawing in liquids, including dyes. The distinctive porosity of natural asphalt oxide (NA-oxide) was noted, and the experimental results showed that the NA–oxide nanoadsorbent efficiently adsorbed cationic and anionic dyes in water, with maximum capacities of 14.68 mg.g−1, 17.81 mg.g−1 and 16.47 mg.g−1 for methyl orange, methylene blue and Rhodamine B, respectively. The study investigated various parameters, such as concentration, adsorption dose, pH, contact time, and temperature, affecting the dye removal process. Langmuir, Freundlich, and Temkin isotherms along with pseudo-first and pseudo-second-order kinetic equations were applied to assess the adsorption process, indicating that dyes adhered to the pseudo-first-order model and Langmuir isotherm. Analysis of MO, MB, and RhB dyes revealed conformity to Langmuir isotherm and first-order kinetics. Thermodynamic evaluations like ΔH°, ΔS°, and ∆G° displayed the exothermic and spontaneous nature of dye adsorption on the NA-oxide adsorbent. Furthermore, the absorbent displayed remarkable stability with a recovery rate of 98.45% after ten cycles, signifying its potential for enduring effectiveness in dye removal processes. [ABSTRACT FROM AUTHOR]

Soil heavy metals (HMs) pollution is a growing global concern, mainly in regions with rapid industrial growth. This study assessed the concentrations, potential sources, and health risks of HMs in agricultural soils near marble processing plants in Malakand, Pakistan. A total of 21 soil samples were analyzed for essential and toxic HMs via inductively coupled plasma‒optical emission spectrometry (ICP‒OES), and probabilistic health risks were evaluated via Monte Carlo simulation. The concentrations (mg/kg) of Ca (29,250), P (805.5) and Cd (4.5) exceeded the average shale limits of 22,100, 700, and 3.0 mg/kg, respectively, and indices such as Nemerow's synthetic contamination index (NSCI) and the geoaccumulation index (Igeo) categorized the soil sites as moderately polluted. The potential ecological risk index (PERI) indicated considerable to high ecological risk for As and Cd. The deterministic analysis indicated non-carcinogenic risks for children (HI > 1), whereas the probabilistic analysis suggested no significant risk (HI < 1) for both adults and children. Both methods indicated that the total cancer risk for Cr, Ni, Cd, and As exceeded the USEPA safety limits of 1.0E-06 and 1.0E-04. Sensitivity analysis identified heavy metal concentration, exposure duration, and frequency as key risk factors. The study suggested that HM contamination is mainly anthropogenic, poses a threat to soil and human health, and highlights the need for management strategies and surveillance programs to mitigate these risks. [ABSTRACT FROM AUTHOR]

Hypomyelinating leukodystrophy (HLD) is a rare genetic heterogeneous disease that can affect myelin development in the central nervous system. This study aims to analyze the clinical phenotype and genetic function of a family with HLD-7 caused by POLR3A mutation. The proband (IV6) in this family mainly showed progressive cognitive decline, dentin dysplasia, and hypogonadotropic hypogonadism. Her three old brothers (IV1, IV2, and IV4) also had different degrees of ataxia, dystonia, or dysarthria besides the aforementioned manifestations. Their brain magnetic resonance imaging showed bilateral periventricular white matter atrophy, brain atrophy, and corpus callosum atrophy and thinning. The proband and her two living brothers (IV2 and IV4) were detected to carry a homozygous mutation of the POLR3A (NM_007055.4) gene c. 2300G > T (p.Cys767Phe), and her consanguineous married parents (III1 and III2) were p.Cys767Phe heterozygous carriers. In the constructed POLR3A wild-type and p.Cys767Phe mutant cells, it was seen that overexpression of wild-type POLR3A protein significantly enhanced Pol III transcription of 5S rRNA and tRNA Leu-CAA. However, although the mutant POLR3A protein overexpression was increased compared to the wild-type protein overexpression, it did not show the expected further enhancement of Pol III function. On the contrary, Pol III transcription function was frustrated (POLR3A, BC200, and tRNA Leu-CAA expression decreased), and MBP and 18S rRNA expressions were decreased. This study indicates that the POLR3A p.Cys767Phe variant caused increased expression of mutated POLR3A protein and abnormal expression of Pol III transcripts, and the mutant POLR3A protein function was abnormal. [ABSTRACT FROM AUTHOR]

Heavy metal accumulation in agricultural products has become a major concern. Previous studies have focused on the transport of heavy metals from the soil and their accumulation in crops. However, recent studies revealed that wheat leaves, ears, and awns can also transport and accumulate heavy metals. Wheat grains can be influenced by two sources of heavy metals: soil contamination and atmospheric deposition. To comprehend the transport characteristics of heavy metals in soil, atmospheric deposition, and wheat, 37 samples each for wheat rhizosphere soil, wheat roots, stems, leaves, and grains were collected. Fifteen samples of atmospheric dry deposition and atmospheric wet deposition were collected from Linshu County (northern area), China. Based on the test data, the characteristics of heavy metals and their distribution in the study area were analyzed. Migration patterns of heavy metals in crops from different sources were investigated using Pearson correlation and redundancy analysis. Finally, a predictive model for heavy metals in wheat grains was developed using multiple linear regression analysis. Significant disparities in the distribution of heavy metals existed among wheat roots, stems, leaves, and grains. The coefficient of variation of heavy metals in atmospheric deposition was relatively high, indicating discernible spatial patterns influenced by human activities. Notably, a positive correlation was observed between the concentration of heavy metals in wheat grains and atmospheric deposition of Hg, Cd, and Pb. Conversely, Zn and Ni levels in wheat grains were significantly negatively associated with soil Zn, Ni, pH, and OM content. The contribution of heavy metal elements from different sources varied in their impact on the grain's heavy metal content. Specifically, atmospheric deposition was the primary source of Hg and Pb in wheat grains, while Cd, Ni, Cu, and Zn were predominantly derived from soil. Using a multiple linear regression model, we could accurately predict Hg, Pb, Cd, Ni, Zn, and As concentrations in crop grains. This model can facilitate quantitative evaluation of ecological risk of heavy metals accumulation in crops in the study area. [ABSTRACT FROM AUTHOR]

This work describes the study of the removal of a refractory contaminant, i.e., Hexavalent chromium (Cr(VI)) from aqueous systems by a novel adsorbent comprising Cr(VI) tolerant bacteria and zero valent iron nanoparticle (nZVI). A gram-positive, rod-shaped bacteria used in the study were isolated from wastewater (WW) received from the effluent of leather industries. The adsorbents were prepared with bacteria, nZVI alone, and a combination of both. The adsorbent comprising both elements was found to remove Cr(VI) with a higher percentage (93%) and higher capacities (0.58 mg/g) as compared to adsorbent with bacteria (Cr(VI) removal = 63%, qe = 0.163 mg/g) or nanoparticles (Cr(VI) removal = 80%, qe = 0.45 mg/g) alone. The adsorbent worked best at neutral pH, and the removal became saturated after 90 min of incubation. Equilibrium studies with isotherm modeling suggested that the adsorption process follows sips isotherm (R2 = 0.9955), which is expected to bean intra-particle diffusion process before the actual adsorption. Process kinetics was modeled with pseudo-first order, pseudo-second order, and Vermeulen model. The diffusion coefficient determined by fitting the kinetic data to Vermeulen model was found to be 0.0000314 cm2/s. The adsorbent can be tested further for continuous flow processes to find more insights about the usage on a large scale. [ABSTRACT FROM AUTHOR]

This study presents a thorough numerical evaluation of the crashworthiness properties of a new bio-inspired DNA tubes (BIDNATs) with circular, elliptical, and rectangular cross-sections. Deformation and crashworthiness behaviors are evaluated using axial quasi-static crushing simulations by ABAQUS/Explicit (Abaqus 6.14, https://www.3ds.com/products-services/simulia/products/abaqus/). The study compares the performance of conventional tubes with rectangular and elliptical cross-sections to DNA-inspired tubes. Increasing the rotation angle leads to more helices and a pronounced helix angle, resulting in lower initial peak force (IPF). However, lower cross-section aspect ratios generally have higher IPF and specific energy absorption (SEA) values. BIDNATs with rectangular cross-sections and a 540° rotation angle have the lowest SEA and IPF values across all aspect ratios. Notably, for the 110/100 aspect ratio, the SEA of E110/100 is 71% higher than the conventional tube. Overall, BIDNATs with elliptical cross-sections and a 360° rotation angle exhibit higher SEA values and lower IPF values, particularly for a width (W) of 100 mm. Conventional circular and elliptical tubes generally have SEA values exceeding 6 J/g, with only E110/100 surpassing this among DNA-inspired tubes. The NE110/100 tube has the highest SEA, surpassing E110/100 by 54%, while its IPF is 10% greater than DNA-inspired E110/100. It's worth noting that conventional circular and elliptical tubes have higher IPF values compared to their DNA-inspired counterparts. These findings offer valuable insights for engineers and researchers in the design of crash tubes to improve overall vehicle safety for both occupants and pedestrians. [ABSTRACT FROM AUTHOR]

The main purpose of this research endeavor is to reduce lead concentrations in the wastewater of an oil refinery through the utilization of a material composed of oyster shell waste (MIL-100(Fe)/Cygnea/Fe3O4/TiO2. Initially, iron oxide nanoparticles (Fe3O4) were synthesized via solvent-thermal synthesis. It was subsequently coated layer by layer with the organic–metallic framework MIL-100 (Fe) using the core–shell method. Additionally, the solvent-thermal method was utilized to integrate TiO2 nanoparticles into the magnetic organic–metallic framework's structure. Varieties of analytical analysis were utilized to investigate the physical and chemical properties of the synthetic final photocatalyst. Nitrogen adsorption and desorption technique (BET), scanning electron microscopy (SEM), scanning electron diffraction pattern (XRD), and transmission electron microscopy (TEM). Following the characterization of the final photocatalyst, the physical and chemical properties of the nanoparticles synthesized in each step, several primary factors that significantly affect the removal efficiency in the advanced oxidation system (AOPs) were examined. These variables consist of pH, photocatalyst dosage, lead concentration, and reaction temperature. The synthetic photocatalyst showed optimal performance in the removal of lead from petroleum wastewater under the following conditions: 35 °C temperature, pH of 3, 0.04 g/l photocatalyst dosage, and 100 mg/l wastewater concentration. Additionally, the photocatalyst maintained a significant level of reusability after undergoing five cycles. The findings of the study revealed that the photocatalyst dosage and pH were the most influential factors in the effectiveness of lead removal. According to optimal conditions, lead removal reached a maximum of 96%. The results of this investigation showed that the synthetic photocatalyst, when exposed to UVA light, exhibited an extraordinary capacity for lead removal. [ABSTRACT FROM AUTHOR]

Recycling is known as a solution for cigarette filter management, but this may cause the release of trapped pollutants in it. Cigarette smoke toxins and chemicals that trapped in the cigarette filter can accumulate in the recycling leachate. In this study, littered cigarette filters and freshly smoked cigarette filters were recycled and the resulting leachate was analyzed. The results showed that the minimum and maximum Chemical Oxygen Demand (COD) of the studied leachates were 2100 mg/L and 11,300 mg/L, respectively. The maximum temporal variation in the studied leachate quality was 74.28%, but the maximum spatial variation was 314.2%. COD in the freshly smoked sample was 2600–9200 mg/L more than the littered samples. The average concentration of chromium, lead, nickel, and cadmium in littered samples was 0.023, 0.024, 0.045, and 0.019 mg/L, respectively. Environmental conditions such as humidity, the efficiency of the urban cleaning system in reducing the resistance of littered filters, the difference in the quality of the filter and tobacco, and the difference in smoking behaviors were effective in this variation. Reducing the toxicity of cigarette smoke and improving the efficiency of the urban cleaning system can lead to the same quality, but leachate treatment is necessary to reduce the environmental risk. [ABSTRACT FROM AUTHOR]

We study the effects of the uniaxial tensile strain and shear deformation as well as their combinations on the electronic properties of single-layer black phosphorene. The evolutions of the strain-dependent band gap are obtained using the numerical calculations within the tight-binding (TB) model as well as the first-principles (DFT) simulations and compared with previous findings. The TB-model-based findings show that the band gap of the strain-free phosphorene agrees with the experimental value and linearly depends on both stretching and shearing: increases (decreases) as the stretching increases (decreases), whereas gradually decreases with increasing the shear. A linear dependence is less or more similar as compared to that obtained from the ab initio simulations for shear strain, however disagrees with a non-monotonic behaviour from the DFT-based calculations for tensile strain. Possible reasons for the discrepancy are discussed. In case of a combined deformation, when both strain types (tensile/compression + shear) are loaded simultaneously, their mutual influence extends the realizable band gap range: from zero up to the values respective to the wide-band-gap semiconductors. At a switched-on combined strain, the semiconductor–semimetal phase transition in the phosphorene is reachable at a weaker (strictly non-destructive) strain, which contributes to progress in fundamental and breakthroughs. [ABSTRACT FROM AUTHOR]

This study focused on a direct comparison of conventional hydrothermal and microwave treatment during the synthesis of TiO2–Fe3O4 photocatalyst, which is an effective catalyst for decomposing metronidazole. The photocatalyst underwent various characterization analyses, including X-ray diffraction, Raman spectroscopy, transmission electron microscopy, energy dispersive X-ray, and diffuse reflectance spectroscopy. The Raman spectroscopy analysis revealed that the materials obtained through the conventional hydrothermal treatment consisted of separate phases of anatase and magnetite. On the other hand, the materials synthesized using the microwave process showed a noticeable shift in the Eg band (143 cm−1) and its half-width towards higher wavenumbers. This shift is likely due to the introduction of Fe ions into the TiO2 lattice. Additionally, both conventional hydrothermal and microwave synthesis routes produced TiO2–Fe3O4 systems with superparamagnetic properties, as demonstrated by SQUID magnetic measurements. The TEM analysis revealed that the materials synthesized using the microwave process exhibited higher homogeneity, with no noticeable large aggregates observed. Finally, this work proposed a convenient LED photoreactor that effectively utilized the photo-oxidative properties of TiO2–Fe3O4 photocatalysts to remove metronidazole. Combining photoactive TiO2–Fe3O4 catalysts with an energy-efficient LED reactor resulted in a low electrical energy per order (EEO). [ABSTRACT FROM AUTHOR]

This study aims at increasing earthquake preparedness knowledge perception and practice among Nepalese immigrants residing in Japan through an educational intervention. A single arm quasi experimental study was conducted among Nepalese immigrants residing in Japan. An educational intervention was prepared along with a 52 itemed questionnaire. In total, 165 participants responded to our questionnaire. Majority of them were male (67.88%), and the mean age was 32.78 years. Generalized equation model showed that the knowledge score of earthquake preparedness was 4.01 points higher immediately after the intervention [95% CI (2.78–5.24), p-value < 0.001] compared to baseline with a further increase by 7.02 points [95% CI (5.96–8.09), p-value < 0.001] at two weeks follow up. However, the practice score increased only by 2.83 points [95% CI (2.51–3.14), p-value < 0.001] immediately after the intervention with a similar increase at two weeks and 12 weeks follow up period [OR: 2.62, 95% CI (2.29–2.96), p-value < 0.001]. The educational intervention, when conducted in native language, can increase both the knowledge and practice score of earthquake preparedness hence, information related to earthquake preparedness in Nepali languages in the government websites of Japan could potentially increase information seeking behavior of people. [ABSTRACT FROM AUTHOR]

The quality of irrigation water sources can significantly affect the concentrations of heavy metals (HMs) in cultivated vegetables. This study aimed to investigate the effect of various water resources, including treated wastewater effluent (TWE), river water (RW), and well water with chemical fertilizer (WW+F), on the accumulation of heavy metals (HMs) in the three most widely consumed edible vegetables (Coriander, Radish, and Basil) in Iran. A total of 90 samples of edible vegetables, 13 samples of irrigation water, and 10 soil samples were collected to determine HMs concentrations. Iron (Fe), Zinc (Zn), Copper (Cu), Manganese (Mn), Lead (Pb), Cadmium (Cd), Chromium (Cr), Nickel (Ni,) and Arsenic (As) were analyzed by inductively coupled plasma optical emission spectrometry (ICP-OES). Eventually, the Total Target Hazard Quotient (TTHQ) for the toxic metals of As, Pb, and Cd was determined. The results revealed that the TTHQ of toxic metals in vegetables was less than the allowable limits (TTHQ = 1). Also, TWE was the best irrigation water type since the HMs content of vegetables was low. By comparing the results with national and international standards, it can be concluded that the Gharasou RW for irrigation of edible vegetables was inappropriate. [ABSTRACT FROM AUTHOR]

The aim of the study was to compare the shape of the feet, the mobility of the metatarsophalangeal and interphalangeal joints and the flexibility of the calf muscles in older women with hallux valgus versus middle-aged women with and without this deformation to identify the presence of features which correlate particularly strongly with hallux valgus, and on which prophylaxis and conservative treatment should focus. The study involved 201 women: 92 aged 60–84 years with hallux valgus of both toes, 78 aged 38–59 with hallux valgus of both toes, and 31 aged 38–57 years with correctly shaped feet. The intensity of pain in the foot, the valgus angle of the big toe and fifth toe, the longitudinal and transverse arches of the foot, the symmetry of foot load with body weight, toe joint mobility and muscle flexibility were analysed. Both groups of women with hallux valgus differed from women with normal feet in the height of the transverse arch, the extent of dorsal extension in the first metatarsophalangeal joint and plantar flexion in the first interphalangeal joint. Older women were additionally characterised by reduced plantar flexion in the metatarsophalangeal joint of the big toe, limited flexibility of the soleus and gastrocnemius muscles as well as less pain in the toe area than in the foot itself. The most characteristic changes which were observed in older women with hallux valgus are a limited range of motion in the MTP and IP joints of the big toe, a reduced transverse arch and increased restriction of calf muscle flexibility. [ABSTRACT FROM AUTHOR]

Due to several centuries of ongoing mining activities, Middle Spiš (Slovakia) is one of the areas with a damaged environment. The contents of Fe, Mn, Zn, Cu, Ni, Pb, Cd, and Hg were determined in the soils and home-grown vegetables (potatoes, carrots, tomatoes). Except for Pb, the contents of heavy metals in the soils of some plots were higher than the limit values. Based on the values of Contamination factor (Cf), Degree of contamination (Cdeg), Geo-accumulation index (Igeo), and Pollution load index (PLI), very high Fe, Cd, and Hg contamination (Cf ≥ 6), very high soil contamination (Cdeg ≥ 20), extremely heavy Fe and Hg contamination (Igeo > 5), resp. moderately pollution to non-pollution (1 < PLI ≤ 2) was found in all plots. In vegetable samples, the maximum levels were exceeded for Cu, Pb, Hg (potato), Pb (carrot, tomato), and Hg (carrot, plot E). Bioaccumulation factor values BAF > 1 were for Cu (carrots, potatoes). Estimated daily intake values for all heavy metals were lower than their tolerable daily intake. Chronic daily intake of heavy metals ranged 2.495E−06 (Hg)—0.1416 (Fe) mg/kg/day. Based on Hazard index values, potato consumption poses a risk (0.8068–1.3057). The results showed that the monitoring of soils and cultivated production is necessary for the investigated area. [ABSTRACT FROM AUTHOR]

Magnetism in atomically thin functional materials can be an important phenomenon for exploring two-dimensional magneto-optics. Magneto-optical experimental data have revealed significant Kerr signals in insulator thin films. Here, the magneto-optical Kerr effect of oxygen functionalized and doped hexagonal boron nitride (hBN) has been investigated by performing first-principles calculations. We calculated Kerr angle and Kerr ellipticity for functionalized hBN as an attention-drawn material. Moreover, increasing of oxygen doping percentage leads to the introduction of surface plasmon to hBN. Our findings show that the functionalized hBN can tolerate high-temperature conditions, keeping oxygen atoms bridge-bonded. These giant opto/magnetic responses of insulating 2D materials provide a platform for the potential designing of magneto-optical devices. [ABSTRACT FROM AUTHOR]

Owing to their outstanding characteristics, carbon based nanofluids (CbNFs) have been applied to various advanced heat transfer and cooling technologies. It was claimed that these CbNFs can considerably improve the properties of the base working fluids. Among all the thermal characteristics, the thermal conductivity (λ) is regarded as the primary parameter to be considered for the application of nanofluids (NFs). In the present research study we measured for the first time both λ and thermal diffusivity (aT) of very stable fullerene (C60)-based NFs in liquid phase (1,2,3,4-tetrahydronaphthalene and 1,2-dicholorobenzene) by the transient multi-current hot wire technique at atmospheric pressure in a wide range of temperature (254–323 K). Similar to the base liquids (BLs), we observed a slight decrease in λ with an increase in temperature. Additionally, compared to the BLs λ was reduced upon the addition of C60. The results were compared with the predicted ones using different theoretical models. Not much variation in aT was observed between the C60 NFs and the corresponding BLs due partly to the small variation of λ with the addition of C60. [ABSTRACT FROM AUTHOR]

Doxorubicin (DOX) is a potent anti-cancer agent and there have been attempts in developing nanostructures for its delivery to tumor cells. The nanoparticles promote cytotoxicity of DOX against tumor cells and in turn, they reduce adverse impacts on normal cells. The safety profile of nanostructures is an important topic and recently, the green synthesis of nanoparticles has obtained much attention for the preparation of biocompatible carriers. In the present study, we prepared layered double hydroxide (LDH) nanostructures for doxorubicin (DOX) delivery. The Cu–Al LDH nanoparticles were synthesized by combining Cu(NO3)2·3H2O and Al(NO3)3·9H2O, and then, autoclave at 110. The green modification of LDH nanoparticles with Plantago ovata (PO) was performed and finally, DOX was loaded onto nanostructures. The FTIR, XRD, and FESEM were employed for the characterization of LDH nanoparticles, confirming their proper synthesis. The drug release study revealed the pH-sensitive release of DOX (highest release at pH 5.5) and prolonged DOX release due to PO modification. Furthermore, MTT assay revealed improved biocompatibility of Cu–Al LDH nanostructures upon PO modification and showed controlled and low cytotoxicity towards a wide range of cell lines. The CLSM demonstrated cellular uptake of nanoparticles, both in the HEK-293 and MCF-7 cell lines; however, the results were showed promising cellular internalizations to the HEK-293 rather than MCF-7 cells. The in vivo experiment highlighted the normal histopathological structure of kidneys and no side effects of nanoparticles, further confirming their safety profile and potential as promising nano-scale delivery systems. Finally, antibacterial test revealed toxicity of PO-modified Cu–Al LDH nanoparticles against Gram-positive and -negative bacteria. [ABSTRACT FROM AUTHOR]

This manuscript investigates the influence of the chemical activation step order and process parameters on the specific capacitance of activated carbon derived from rice husk. The chemical activation was performed either before or after the carbonization step, using phosphoric acid (H 3 PO 4 ) and potassium hydroxide (KOH) as activating agents. For activation before carbonization, the carbonization process was conducted at various temperatures (600, 750, 850, and 1050 °C). On the other hand, for activation after carbonization, the effect of the volume of the chemical agent solution was studied, with 0, 6, 18, 21, 24, and 30 mL/g of phosphoric acid and 0, 18, 30, 45, 60, and 90 mL/g of 3.0 M KOH solution. The results revealed that in the case of chemical activation before carbonization, the optimum temperature for maximizing specific capacitance was determined to be 900 °C. Conversely, in the case of chemical activation after carbonization, the optimal volumes of the chemical agent solutions were found to be 30 mL/g for phosphoric acid (H 3 PO 4 ) and 21 mL/g for potassium hydroxide (KOH). Moreover, it was observed that utilizing phosphoric acid treatment before the carbonization step leads to an 21% increase in specific capacitance, attributed to the retention of inorganic compounds, particularly silica (SiO 2 ). Conversely, when rice husks were treated with KOH after the carbonization step, the specific capacitance was found to be doubled compared to treatment with KOH prior to the carbonization step due to embedding of SiO 2 and KHCO 3 inorganic constituents. This study provides valuable insights into the optimization of the chemical activation step order and process parameters for enhanced specific capacitance in rice husk-derived activated carbon. These findings contribute to the development of high-performance supercapacitors using rice husk as a sustainable and cost-effective precursor material., (© 2024. The Author(s).)

Sources and levels of heavy metals (HMs) in soil and dust of urban and suburban areas in Riyadh (industrial city) and Mahad AD'Dahab (mining area) cities in Saudi Arabia were reported in this study. Additionally, the concentrations of HMs in different soil particle size fractions (> 250, 63–250 and < 63 µm) were reported. Pollution extent, and ecological and human health risks associated with collected soil and dust samples were explored. Contamination levels of HMs were higher in dust as compared to soil samples at all sites. The average integrated potential ecological risk in dust samples of urban area of Mahad AD'Dahab was 139, and thus characterized as a very-high-risk criterion. Enrichment factor (EF), correlation analyses, and principal component analysis showed that aluminum (Al), cobalt (Co), chromium (Cr), iron (Fe), manganese (Mn), nickel (Ni), titanium (Ti), and zinc (Zn) had mainly the lithogenic occurrence (EF < 2). However, Zn, copper (Cu), and lead (Pb) in Riyadh, and cadmium (Cd), Cu, Zn, and Pb in the Mahad AD'Dahab were affected by industrial and mining activities, respectively, that were of anthropogenic origins (EF > 2). The hazard index values of dust and soil (< 63 µm) samples in both urban and suburban areas in Mahad AD'Dahab were > 1, suggesting non-carcinogenic risk. Therefore, the dust and soil samples from the mined area of Mahad AD'Dahab had a higher pollution levels, as well as ecological and human health risks than those from Riyadh. Hence, the pollution of such residential environments with HMs (especially Cd, Cu, Zn, and Pb) needs to be monitored. [ABSTRACT FROM AUTHOR]

We developed a computational-based model for simulating adsorption capacity of a novel layered double hydroxide (LDH) and metal organic framework (MOF) nanocomposite in separation of ions including Pb(II) and Cd(II) from aqueous solutions. The simulated adsorbent was a composite of UiO-66-(Zr)-(COOH)2 MOF grown onto the surface of functionalized Ni50-Co50-LDH sheets. This novel adsorbent showed high surface area for adsorption capacity, and was chosen to develop the model for study of ions removal using this adsorbent. A number of measured data was collected and used in the simulations via the artificial intelligence technique. Artificial neural network (ANN) technique was used for simulation of the data in which ion type and initial concentration of the ions in the feed was selected as the input variables to the neural network. The neural network was trained using the input data for simulation of the adsorption capacity. Two hidden layers with activation functions in form of linear and non-linear were designed for the construction of artificial neural network. The model's training and validation revealed high accuracy with statistical parameters of R2 equal to 0.99 for the fitting data. The trained ANN modeling showed that increasing the initial content of Pb(II) and Cd(II) ions led to a significant increment in the adsorption capacity (Qe) and Cd(II) had higher adsorption due to its strong interaction with the adsorbent surface. The neural model indicated superior predictive capability in simulation of the obtained data for removal of Pb(II) and Cd(II) from an aqueous solution. [ABSTRACT FROM AUTHOR]

The study aims to solve the problems of limited capacity and difficult recovery of lignite to adsort Cu2+, Zn2+ and Pb2+ in acid mine wastewater (AMD). Magnetically modified lignite (MML) was prepared by the chemical co-precipitation method. Static beaker experiments and dynamic continuous column experiments were set up to explore the adsorption properties of Cu2+, Zn2+ and Pb2+ by lignite and MML. Lignite and MML before and after the adsorption of heavy metal ions were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and Fourier transform infrared spectrometer (FTIR). Meanwhile, the adsorption mechanisms of Cu2+, Zn2+ and Pb2+ by lignite and MML were revealed by combining the adsorption isotherm model and the adsorption kinetics model. The results showed that the pH, adsorbent dosage, temperature, initial concentration of heavy metal ions, and contact time had an influence on the adsorption of Cu2+, Zn2+ and Pb2+ by lignite and MML, and the adsorption processes were more in line with the Langmuir model. The adsorption kinetics experiments showed that the adsorption processes were jointly controlled by multiple adsorption stages. The adsorption of heavy metal ions by lignite obeyed the Quasi first-order kinetic model, while the adsorption of MML was chemisorption that obeyed the Quasi second-order kinetic model. The negative ΔG and positive ΔH of Cu2+ and Zn2+ indicated the spontaneous and endothermic nature reaction, while the negative ΔH of Pb2+ indicated the exothermic nature reaction. The dynamic continuous column experiments showed that the average removal rates of Cu2+, Zn2+ and Pb2+ by lignite were 78.00, 76.97 and 78.65%, respectively, and those of heavy metal ions by MML were 82.83, 81.57 and 83.50%, respectively. Compared with lignite, the adsorption effect of MML was better. As shown by SEM, XRD and FTIR tests, Fe3O4 was successfully loaded on the surface of lignite during the magnetic modification, which made the surface morphology of lignite coarser. Lignite and MML removed Cu2+, Zn2+ and Pb2+ from AMD in different forms. In addition, the adsorption process of MML is related to the O–H stretching vibration of carboxylic acid ions and the Fe–O stretching vibration of Fe3O4 particles. [ABSTRACT FROM AUTHOR]

Nowadays, radiation grafting polymer adsorbents have been widely developed due to their advantages, such as low operating cost, high efficiency. In this research, glycidyl methacrylate monomers were grafted on polypropylene polymer fibers by simultaneous irradiation of gamma-ray with a dose of 20 kGy. The grafted polymer was then modified using different amino groups and tested for adsorption of cobalt ions in an aqueous solution. Finally, the modified polymer adsorbent with a high efficiency for cobalt ions adsorption was synthesized and tested. Different modes of cobalt ions adsorption were tested in other adsorption conditions, including adsorption contact time, pH, different amounts of adsorbent mass, and different concentrations of cobalt ions solution. The adsorbent structure was characterized with FT-IR, XRD, TG and SEM techniques and illustrated having an efficient grafting percentage and adsorption capability for cobalt removing by batch experiments. The optimum conditions were obtained by a central composite design: adsorbent mass = 0.07 g, initial concentration = 40 mg/L, time = 182 min, and pH = 4.5 with ethylenediamine as a modified monomer and high amination percentage. Kinetics and equilibrium isotherms observation described that the experimental data followed pseudo-second-order and Langmuir models, respectively. The maximum adsorption capacity from Langmuir isotherm capacity is obtained equal to 68.02 mg/g. [ABSTRACT FROM AUTHOR]

We investigate the reforming of a plane wave into a periodic waveform in its propagation through a structural asymmetry four-level quantum dot molecule (QDM) system that is induced by an inter-dot tunneling process and present the resulting tunneling-induced Talbot effect. The tunneling process between two neighborhood dots is provided with the aid of a gate voltage. Using a periodic coupling field the response of the medium to the propagating plane probe beam becomes periodic. The needed periodic coupling field is generated with the interference of two coherent plane waves having a small angle and propagating almost parallel to the probe beam direction. In the presence of the tunneling effect of an electron between two adjacent QDs, for the probe beam propagating through the QDM system, the medium becomes transparent where the coupling fields interfere constructively. As a result, the spatial periodicity of the coupling field modulates the passing plane probe beam. We determine the minimum length of the QDM system to generate a periodic intensity profile with a visibility value equal to 1 for the probe field at the exit plane of the medium. It is also shown that by increasing the propagation length of the probe beam through the QDM medium, the profile of the maximum intensity areas becomes sharper. This feature is quantified by considering a sharpness factor for the intensity profile of the probe beam at the transverse plane. Finally, we investigate free space propagation of the induced periodic field and present the Talbot images of the tunneling-induced periodic patterns at different propagation distances for different values of the QDM medium lengths. The presented dynamically designing method of the periodic coherent intensity patterns might find applications in science and technology. For instance, in optical lithography, the need to use micro/nanofabricated physical transmission diffraction gratings, in which preparation of them is expensive and time-consuming, can be eliminated. [ABSTRACT FROM AUTHOR]

Maf1−/− mice are lean, obesity-resistant and metabolically inefficient. Their increased energy expenditure is thought to be driven by a futile RNA cycle that reprograms metabolism to meet an increased demand for nucleotides stemming from the deregulation of RNA polymerase (pol) III transcription. Metabolic changes consistent with this model have been reported in both fasted and refed mice, however the impact of the fasting-refeeding-cycle on pol III function has not been examined. Here we show that changes in pol III occupancy in the liver of fasted versus refed wild-type mice are largely confined to low and intermediate occupancy genes; high occupancy genes are unchanged. However, in Maf1−/− mice, pol III occupancy of the vast majority of active loci in liver and the levels of specific precursor tRNAs in this tissue and other organs are higher than wild-type in both fasted and refed conditions. Thus, MAF1 functions as a chronic repressor of active pol III loci and can modulate transcription under different conditions. Our findings support the futile RNA cycle hypothesis, elaborate the mechanism of pol III repression by MAF1 and demonstrate a modest effect of MAF1 on global translation via reduced mRNA levels and translation efficiencies for several ribosomal proteins. [ABSTRACT FROM AUTHOR]

Optical tweezers have become a powerful tool in the fields of biology, soft condensed matter physics, and nanotechnology. Here, we report the use of recently introduced radial carpet beams (RCBs) in the optical tweezers setup to trap multiple particles. An RCB is produced by diffraction of a plane or Gaussian beam from an amplitude radial grating. Because of the radial symmetry of the grating, all the diffraction orders are propagated along the optical axis and are used for trapping. Based on the number of grating spokes, the produced RCB has a definite number of high-intensity spots on the transverse plane located over a circular ring. These high-intensity spots of the beam provide multi-traps when it passes through an objective lens and have enough gradient force to trap polystyrene and silica particles. Moreover, the diffracted light from the grating has this property to transfer the angular momentum. We show that the multi-trapped birefringent particles could rotate in their own traps when polarization of the trapping RCB to be circular. In addition, the orbital rotation of the particles is simply executable by manually rotating the grating in its plane around the optical axis. [ABSTRACT FROM AUTHOR]

A regional field survey of a total of 109 pairs of soil and rice samples was conducted to evaluate the health risks posed by heavy metals in the Jin-Qu Basin, China. The studied soils are characterized by acid (pH in mean level of 5.5), carbon rich (soil organic matter in mean of 33.6 g kg−1) and mainly contaminated by Cd (42.2% samples exceeded the standard value of 0.3 mg kg−1 (GB15618-2018)). The spatial distributions of Cd, Pb and Zn exhibited similar geographic trends. 34% and 30% of the rice samples containing Cd and Pb exceeded the threshold value of 0.2 mg kg−1 (GB2762-2017), respectively. The risk estimation of dietary intake had a target hazard quotient value of Cd of 0.918 and a hazard index value for rice consumption of 2.141. Totally, Cd and Pb were found to be the main components contributing to the potential health risks posed by non-carcinogenic effects for local inhabitants. [ABSTRACT FROM AUTHOR]

Uziflies (Family: Tachinidae) are dipteran endoparasites of sericigenous insects which cause major economic loss in the silk industry globally. Here, we are presenting the first full mitogenome of Blepharipa sp. (Acc: KY644698, 15,080 bp, A + T = 78.41%), a dipteran parasitoid of Muga silkworm (Antheraea assamensis) found in the Indian states of Assam and Meghalaya. This study has confirmed that Blepharipa sp. mitogenome gene content and arrangement is similar to other Tachinidae and Sarcophagidae flies of Oestroidea superfamily, typical of ancestral Diptera. Although, Calliphoridae and Oestridae flies have undergone tRNA translocation and insertion, forming unique intergenic spacers (IGS) and overlapping regions (OL) and a few of them (IGS, OL) have been conserved across Oestroidea flies. The Tachinidae mitogenomes exhibit more AT content and AT biased codons in their protein-coding genes (PCGs) than the Oestroidea counterpart. About 92.07% of all (3722) codons in PCGs of this new species have A/T in their 3rd codon position. The high proportion of AT and repeats in the control region (CR) affects sequence coverage, resulting in a short CR (Blepharipa sp.: 168 bp) and a smaller tachinid mitogenome. Our research unveils those genes with a high AT content had a reduced effective number of codons, leading to high codon usage bias. The neutrality test shows that natural selection has a stronger influence on codon usage bias than directed mutational pressure. This study also reveals that longer PCGs (e.g., nad5, cox1) have a higher codon usage bias than shorter PCGs (e.g., atp8, nad4l). The divergence rates increase nonlinearly as AT content at the 3rd codon position increases and higher rate of synonymous divergence than nonsynonymous divergence causes strong purifying selection. The phylogenetic analysis explains that Blepharipa sp. is well suited in the family of insectivorous tachinid maggots. It's possible that biased codon usage in the Tachinidae family reduces the effective number of codons, and purifying selection retains the core functions in their mitogenome, which could help with efficient metabolism in their endo-parasitic life style and survival strategy., (© 2022. The Author(s).)

The Merbok Estuary comprises one of the largest remaining mangrove forests in Peninsular Malaysia. Its value is significant as it provides important services to local and global communities. It also offers a unique opportunity to study the structure and functioning of mangrove ecosystems. However, its biodiversity is still partially inventoried, limiting its research value. A recent checklist based on morphological examination, reported 138 fish species residing, frequenting or subject to entering the Merbok Estuary. In this work, we reassessed the fish diversity of the Merbok Estuary by DNA barcoding 350 specimens assignable to 134 species initially identified based on morphology. Our results consistently revealed the presence of 139 Molecular Operational Taxonomic Units (MOTUs). 123 of them are congruent with morphology-based species delimitation (one species = one MOTU). In two cases, two morphological species share the same MOTU (two species = one MOTU), while we unveiled cryptic diversity (i.e. COI-based genetic variability > 2%) within seven other species (one species = two MOTUs), calling for further taxonomic investigations. This study provides a comprehensive core-list of fish taxa in Merbok Estuary, demonstrating the advantages of combining morphological and molecular evidence to describe diverse but still poorly studied tropical fish communities. It also delivers a large DNA reference collection for brackish fishes occurring in this region which will facilitate further biodiversity-oriented research studies and management activities., (© 2021. The Author(s).)

We analyse possibilities to quantitatively evaluate the surface second-order optical nonlinearity in noncentrosymmetric materials based on polarization-resolved analysis of far-field radiation patterns of second-harmonic generation. We analytically demonstrate that for plane-wave illumination the contribution to the second-harmonic signal from the surface of a nonlinear medium exhibits different polarization properties and angular dependencies compared to the contribution from the bulk. In view of this, we optimize the illumination geometry in order to enable the most efficient separation and comparison of both nonlinearities. Furthermore, we consider the illumination of an AlGaAs slab by a tightly-focused linearly-polarized Gaussian beam as an alternative measurement geometry. It is found that the reliable separation of the surface nonlinearity contribution as well as a wide range of detectable values can be achieved with this geometry as well.

Diffraction gratings are important optical components and are used in many areas of optics such as in spectroscopy. A diffraction grating is a periodic structure that splits and diffracts the impinging light beam into several beams travelling in different directions. The diffracted beams from a grating are commonly called diffraction orders. The directions of the diffraction orders depend on the grating period and the wavelength of the impinging light beam so that a grating can be used as a dispersive element. In the diffraction of a plane wave from a conventional grating, the intensities of diffracted beams decrease with increasing order of diffraction. Here, we introduce a new type of grating where in the diffraction of a plane wave, the intensity of a given higher order diffracted beam can be higher than the intensity of the lower orders. We construct these gratings by adding an azimuthal periodic dependency to the argument of the transmission function of a linear phase grating that has a sinusoidal profile and we call them azimuthally-modified linear phase gratings (AMLPGs). In this work, in addition to introducing AMLPGs, we present the generation of varied radial carpet beams over different diffraction orders of an AMLPG with controlled intensity sharing among the generated beams. A radial carpet beam is generated in the diffraction of a plane wave from a radial phase grating. We show that for a given value of the phase amplitude over the host linear phase grating, one of the diffraction orders is predominant and by increasing the value of the phase amplitude, the intensity sharing changes in favor of the higher orders. The theory of the work and experimental results are presented. In comparison with the diffraction of a plane wave from radial phase gratings, the use of AMLPGs provides high contrast diffraction patterns and presents varied radial carpet beams over the different diffraction orders of the host linear phase grating. The resulting patterns over different diffraction orders are specified and their differences are determined. The diffraction grating introduced with controlled intensity sharing among different diffraction orders might find wide applications in many areas of optics such as optical switches. We show that AMLPG-based radial carpet beams can be engineered in which they acquire sheet-like spokes. This feature nominates them for potential applications in light sheet microscopy. In addition, a detailed analysis of the multiplication of the diffraction pattern of an AMLPG by the 2D structure of a spatial light modulator is presented. The presented theory is confirmed by respective experiments. [ABSTRACT FROM AUTHOR]

Fat-tail content of sheep breeds is varied and the molecular mechanisms regulating fat-tail development have not been well characterized. Aiming at better identifying the important candidate genes and their functional pathways contributing to fat deposition in the tail, a comparative transcriptome analysis was performed between fat- (Lori-Bakhtiari) and thin-tailed (Zel) Iranian sheep breeds using RNA-seq. The experiment was conducted on six male lambs (three lambs per each breed) at seven months of age. Four different combinations of aligners and statistical methods including Hisat2 + edgeR, Hisat2 + DESeq2, STAR + edgeR and STAR + DESeq2 were used to identify the differentially expressed genes (DEGs). The DEGs were selected for functional enrichment analysis and protein-protein interaction (PPI) network construction. Module analysis was also conducted to mine the functional sub-networks from the PPI network. In total, 264 genes including 80 up- and 184 down-regulated genes were identified as DEGs. The RNA-Seq results were validated by Q-RT-PCR. Functional analysis of DEGs and the module analysis of PPI network demonstrated that in addition to pathways affecting lipid metabolism, a series of enriched functional terms related to "response to interleukin", "MAPK signaling pathways", "Wnt signaling pathway", "ECM-receptor interaction", "regulation of actin cytoskeleton", and "response to cAMP" might contribute to the deposition of fat in tails of sheep. Overall results using RNA-Seq analysis characterized important candidate genes involved in the fatty acid metabolism and regulation of fat deposition, suggesting novel insights into molecular aspects of fat-tail metabolism in sheep. Selected DEGs should be further investigated as potential markers associated with the fat-tail development in sheep breeds. [ABSTRACT FROM AUTHOR]

The plasma propofol concentration is important information for anaesthetists to monitor and adjust the anaesthesia depth for patients during a surgery operation. In this paper, a stand-alone ion mobility spectrometer (IMS) was constructed for the rapid measurement of the plasma propofol concentrations. Without any sample pre-treatment, the plasma samples were dropped on a piece of glass microfiber paper and then introduced into the IMS cell by the thermal desorption directly. Each individual measurement could be accomplished within 1 min. For the plasma propofol concentrations from 1 to 12 μg mL−1, the IMS response was linear with a correlation coefficient R2 of 0.998, while the limit of detection was evaluated to be 0.1 μg mL−1. These measurement results did meet the clinical application requirements. Furthermore, other clinically-often-used drugs, including remifentanil, flurbiprofen and atracurium, were found no significant interference with the qualitative and quantitative analysis of the plasma propofol. The plasma propofol concentrations measured by IMS were correlated well with those measured by the high performance liquid chromatography (HPLC). The results confirmed an excellent agreement between these two methods. Finally, this method was applied to monitor the plasma propofol concentrations for a patient undergoing surgery, demonstrating its capability of anaesthesia monitoring in real clinical environments. [ABSTRACT FROM AUTHOR]