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1. Microwave-assisted Cu (I) Catalyzed Solvent-free Three Component Coupling of Aldehyde, Alkyne and Amine

Author

Yuhong Ju, Rajender S. Varma, and Chao-Jun Li

Subjects
chemistry.chemical_classification, Solvent free, Chemistry, Organic Chemistry, Alkyne, Microwave assisted, Aldehyde, Computer Science Applications, Catalysis, Coupling (electronics), Drug Discovery, Polymer chemistry, Organic chemistry, Amine gas treating, Microwave
Abstract

Direct Grignard type addition of terminal alkynes to in situ generated imines, from aldehydes and amines, occurs under microwave irradiation using CuBr alone in a one-pot operation. This solventless approach provides ready access to propargylamines and is applicable both to aromatic and aliphatic aldehydes.

Published
2004
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