1. 1/60 Sec Time-Resolved High-Resolution Electron Microscopy of Step-Diffusion of Tungsten Atoms on MgO (001) Surfaces
- Author
-
H. Kimata, Nobuo Tanaka, and T. Kizuka
- Subjects
0303 health sciences ,Materials science ,020209 energy ,Analytical chemistry ,chemistry.chemical_element ,02 engineering and technology ,General Medicine ,Tungsten ,03 medical and health sciences ,High resolution electron microscopy ,chemistry ,0202 electrical engineering, electronic engineering, information engineering ,Diffusion (business) ,030304 developmental biology - Abstract
Surface-diffusion process of atoms is one of the important factors for understanding various types of surface-related phenomena such as thin-film growth and catalysis reaction[l]. Development of field ion microscope (FIM) was a great breakthrough for the study of the process in atomic level. The diffusion process of Rh and Re atoms on tungsten surfaces was quantitatively studied, and the barrier potential (Ed) and the pre-exponential factor (D0) were successfully determined[2]. Recent development of scanning tunneling microscope (STM) has also enabled us to measure directly the moving of Pb and Sb-atoms on Ge and Si (111) surfaces[3, 4]. The time-resolution of these methods is, however, not sufficient to trace the diffusion process in detail.In previous papers, we reported the first experiment of tracing the diffusion process of tungsten(W)-atoms on terrace-regions of MgO (001) surfaces in the time-resolution of 1/60 s.using dynamic high resolution electron microscopy[5,6]. The values Ed=0.18 eV and Do=1.5x10−14 cm2/s were successfully determined from the video-tape images. In the present study, we have observed diffusing atoms along the surface-steps and studied the phenomena quantitatively.
- Published
- 1996