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1. Enantiopure pseudo-C3-symmetric titanium alkoxide with propeller-like chirality.

Author

Axe P, Bull SD, Davidson MG, Gilfillan CJ, Jones MD, Robinson DE, Turner LE, and Mitchell WL

Subjects
Crystallography, X-Ray, Ligands, Magnetic Resonance Spectroscopy methods, Models, Molecular, Molecular Structure, Sensitivity and Specificity, Stereoisomerism, Organometallic Compounds chemistry, Titanium chemistry
Abstract

An enantiopure amine tris(phenolate) ligand containing a single stereogenic center has been used to control the propeller-like chirality of a derived pseudo-C3-symmetric titanium isopropoxide complex with excellent levels of diastereocontrol. [structure: see text].

Published
2007
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