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Enantiopure pseudo-C3-symmetric titanium alkoxide with propeller-like chirality.

Authors :
Axe P
Bull SD
Davidson MG
Gilfillan CJ
Jones MD
Robinson DE
Turner LE
Mitchell WL
Source :
Organic letters [Org Lett] 2007 Jan 18; Vol. 9 (2), pp. 223-6.
Publication Year :
2007

Abstract

An enantiopure amine tris(phenolate) ligand containing a single stereogenic center has been used to control the propeller-like chirality of a derived pseudo-C3-symmetric titanium isopropoxide complex with excellent levels of diastereocontrol. [structure: see text].

Details

Language :
English
ISSN :
1523-7060
Volume :
9
Issue :
2
Database :
MEDLINE
Journal :
Organic letters
Publication Type :
Academic Journal
Accession number :
17217270
Full Text :
https://doi.org/10.1021/ol062655w