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Start Over Author "Gatineau, David" Journal journal of organic chemistry
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2. H-Adamantylphosphinates as Universal Precursors of P-Stereogenic Compounds.

Author

Gatineau, David, Duc Hanh Nguyen, Hérault, Damien, Vanthuyne, Nicolas, Leclaire, Julien, Giordano, Laurent, and Buono, Gérard

Subjects
*PHOSPHINATES, *ENANTIOMERS, *STEREOSELECTIVE reactions, *ORGANIC synthesis, *CATALYSIS, *ORGANIC chemistry research
Abstract

A new family of H-adamantjdphosphinates as universal precursors of P-stereogenic Ugands was obtained in one step from commercial chlorophosphines. Both enantiomers of these air- and moisture-stable intermediates can easily be separated by semipreparative chiral HPLC on a gram scale and individually undergo stereoselective transformations to afford each enantiomer of a set of P-stereogenic compounds such as secondary phosphine oxides and boron-protected monophosphines. [ABSTRACT FROM AUTHOR]

Published
2015
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