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Your search keyword '"Zheng, Shou-Tian"' showing total 1 results
Start Over Author "Zheng, Shou-Tian" Topic metal-organic frameworks Journal journal of coordination chemistry
1 results on '"Zheng, Shou-Tian"'

1. Three-dimensional metal-organic framework based on pentanuclear manganese clusters as building blocks.

Author

Li, Xin-Xiong, Wei, Kun-Yu, Zhuang, Ting-Ting, Xia, Wei, Chen, Jing-Yu, Zhang, Rong-Tao, and Zheng, Shou-Tian

Subjects
METAL-organic frameworks, MANGANESE clusters, SINGLE crystals, X-ray diffraction, GAS absorption & adsorption
Abstract

A rare 3-D Mn–organic framework, [(CH3)2NH2]3[Mn5(btc)4(Ac)(H2O)4]·5H2O (1), based on pentanuclear manganese clusters as building blocks has been prepared and structurally characterized by EA, IR, TGA, PXRD, and single-crystal X-ray diffraction. Structural analysis indicates the pentanuclear manganese cluster in1has a bow-like configuration, which is the first found to act as secondary building unit in the field of metal–organic framework. Gas adsorption measurements reveal that1can absorb a considerable amount of N2and CO2. [ABSTRACT FROM AUTHOR]

Published
2016
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