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Three-dimensional metal-organic framework based on pentanuclear manganese clusters as building blocks.
- Source :
- Journal of Coordination Chemistry; Jun/Jul2016, Vol. 69 Issue 11-13, p1792-1801, 10p, 6 Diagrams, 2 Charts, 5 Graphs
- Publication Year :
- 2016
-
Abstract
- A rare 3-D Mn–organic framework, [(CH3)2NH2]3[Mn5(btc)4(Ac)(H2O)4]·5H2O (1), based on pentanuclear manganese clusters as building blocks has been prepared and structurally characterized by EA, IR, TGA, PXRD, and single-crystal X-ray diffraction. Structural analysis indicates the pentanuclear manganese cluster in1has a bow-like configuration, which is the first found to act as secondary building unit in the field of metal–organic framework. Gas adsorption measurements reveal that1can absorb a considerable amount of N2and CO2. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 69
- Issue :
- 11-13
- Database :
- Complementary Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 116661961
- Full Text :
- https://doi.org/10.1080/00958972.2016.1193167