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China is the top emitter of greenhouse gases in the world. Pulp and paper industry is one of eight the strictly regulated industries about carbon emission in China. However, estimates of carbon emissions from China's pulp and paper industry have been suffered from remarkable uncertainty. It is summarized that is aroused by the inaccuracy of factors evaluating energy consumption, and the huge gap between the calculation standards for assessing energy consumption in the production process and the actual level recorded in the factories. This paper re-evaluated the carbon emission of China's pulp and paper industry from the perspective of life cycle assessment, and applied more accurate emission factors, taking account of the actual energy consumption of the production process in factories, to estimate the actual carbon emissions in maximum. It is found that the national standards about the energy consumption quota of China's pulp and paper industry is no longer applicable, and the actual energy consumption regulated in the production process is far better than the advanced level given by the national standards. The greenhouse gas emission have been seriously overestimated approximately 12.00%–56.17% by international organizations. • Life Cycle Analysis of the China's pulp and paper Industry is conducted thoroughly. • The pulp flow of China's pulp and paper Industry is analyzed. • Energy regulated in factory is far better than the national standards' required. • Carbon emissions of China's pulp and paper Industry are overestimated. [ABSTRACT FROM AUTHOR]

Variable renewable energy-based power is expected to increase toward a sustainable society, although the power cannot be dispatched effectively due to its intermittent nature. To accelerate renewable energy implementation, we simulated energy flows of paper mills installing wind energy and evaluated their potentials to function as energy hubs for appropriate early-stage design. We targeted 39 Japanese paper mills assumed to have thermal energy storage, wind–thermal energy converters and regional woody biomass installed, and analyzed the amount of power and heat selling and life cycle greenhouse gas emissions. The results for the paper mills were compared with conventional mills to examine effective conditions for greenhouse gas reduction. The amount of power or heat selling depended on the capacity of the paper mill and the installed equipment. Most paper mills could reduce greenhouse gas using thermal energy storage, wind energy, and woody biomass. The paper mill with the highest life cycle greenhouse gas reduction, compared with conventional mills, could achieve a 190% reduction. To function as a cogeneration energy hub, the equipment installed in paper mills should be designed according to the conditions of the paper mills and their regions. • Paper mills have potential as energy hubs by integrating variable renewable energy. • Thermal energy storage and wind–thermal energy converters were studied. • Energy flows and greenhouse gas emissions of paper mills were simulated. • Most mills could provide stable power and/or heat supplies and reduce emissions. [ABSTRACT FROM AUTHOR]

Abstract This study aims at to make a heuristic analysis of energy efficiency performance of Indian paper industry in a non-parametric production theoretic approach. Using the data for 2004–05 to 2013–14, radial and non-radial variants of DEA were employed to estimate energy saving potential and identify the relative position of paper industry across the states. Preliminary analysis in terms of energy intensity scores showed declining trends of energy intensity over the period of analysis for most of the states except states like Assam, Chhattisgarh, Kerala and Punjab where it does not decline much. Assuming a variable returns to scale (VRS) technology under the conditions of inherent heterogeneity and market imperfection, the slack-based measure (SBM) reported a much higher energy saving potential than reported by other measures in the study. Further by taking scale efficiency into account, the study documented the higher contribution of pure energy inefficiency in explaining the total energy inefficiency within the paper industry relative to scale inefficiency. Finally, the study recommends the propagation of energy efficiency program through a market-based and regulatory mechanism along with consolidation and technological advancement of individual units, in order to tap vast energy saving potential and thereby ensure the growth and environmental sustainability. Highlights • The paper examined the energy efficiency performance of Indian paper industry. • Both radial (BCC) and the non-radial (SBM) measures of energy efficiency, were applied. • BCC measure reported an energy saving potential of 16%. • SBM measure reported an energy saving potential of 24%, higher than BCC measure. • Scale efficiency implied the relatively higher contribution of pure energy inefficiency. [ABSTRACT FROM AUTHOR]

The present study investigates the effect on methane production from waste paper when co-digested with macroalgal biomass. Both feedstocks were previously mechanically pretreated to reduce their particle size. The study was planned according two factors: the feedstock to inoculum (F/I) ratio and the waste paper to macroalgae (WP/MA) ratio. The F/I ratios checked were 0.2, 0.3 and 0.4 and the WP/MA ratios were 0:100, 25:75, 50:50, 75:25 and 100:0. The highest methane yield (386 L kg −1 VS added ) was achieved at an F/I ratio of 0.2 and a WP/MA ratio of 50:50. A biodegradability index of 0.87 obtained in this study indicates complete conversion of feedstock at an optimum C/N ratio of 26. Synergistic effect was found for WP/MA 25:75, 50:50 and 75:25 mixing ratios compared with the substrates mono-digestion. [ABSTRACT FROM AUTHOR]

In the present study, a thermodynamic analysis of a cogeneration system in a pulp and paper industry under different operating modes i.e., singular and hybrid with a variable ambient temperature is conducted according to actual operating data. For singular operating mode, the power boiler is only employed using natural gas while for hybrid operating mode, the power boiler with the recovery boiler is employed using natural gas and black liquor as main fuels, respectively. The results show that for hybrid operating mode in comparison with the singular one, the thermal efficiency of turbine and condenser is enhanced by 1.36 and 7.7%, respectively while it is reduced by 2.8% for the power boiler. In addition, the overall thermal efficiency under singular and hybrid operating modes is 87.4 and 53.7%, respectively. For hybrid operating mode, the exergy destruction of power boiler decreases by almost 10% compared with that for the singular operating mode. Also, at hybrid operating mode, the soda is recovered with a mass flow rate of 33 tons/hour that is required for the cooking process in the chemical pulp section and additionally the consumption of natural gas in the power boiler is reduced by 11.8%. [ABSTRACT FROM AUTHOR]

Increasing levels of variable renewable energy require additional flexible resources in the global energy system. In countries with energy-intensive industries, flexibility may be increased through industrial demand side management (IDSM). In most studies, the potential of IDSM is estimated from a technical or theoretical viewpoint. However, IDSM capacity is only utilized if the industry finds it profitable, and thus the economic potential should also be assessed. The focus of this paper is on the intra-day IDSM potential of a paper mill site that is active in the Nordic power market. An optimization model is built to estimate the costs that occur when the paper mill executes regulating power bids, if the original production schedule has been optimized against a spot price forecast. The costs are estimated for different sizes of bids and a marginal cost curve is provided for pricing them. Using this marginal cost curve, the market potential of the case mill site is assessed. It is found that this potential is greatly influenced by the costs of executing regulating power bids. The results indicate that transmission system operators and policy makers should account for economic factors when assessing the potential of market based IDSM. [ABSTRACT FROM AUTHOR]

Long term annual electricity consumption forecasting is very important for country's energy planning. These forecasts are influenced by several factors (political, technological, social, environmental and economic), and brings with itself a high uncertainty degree in its results and difficulties in the evaluation of such factors over them. A methodology that eases to take into account these factors aiming improve the results and help understanding the electricity consumption annual trajectory till the forecast horizon is, therefore, very much useful and desired. So, we propose a modelling structure using the bottom-up approach to cope with these matters and to evaluate the trajectory of long term annual electricity consumption of a sector of the Brazilian industry up to 2050 considering energy efficiency (EE) scenarios. It is important to emphasize that Brazil is a developing country, and to build a bottom-up approach was a challenge, mainly due to the fact that this model is data intensive. In particular, this modelling was applied in the pulp and paper sector. The main goal was to consider technological diffusion scenarios in EE measures, and show the energy savings achieved. The results point an energy savings in the order of 25% when an actual scenario is considered. [ABSTRACT FROM AUTHOR]

In this paper an original and exhaustive mathematical modelling of air impingement drying systems for the production of tissue paper in the Yankee-hoods configurations is reported, which offers the possibility to optimize its energy performance. The model takes into account many detailed operative parameters of the overall drying process with the aim to execute its energy and mass balance and to evaluate its energy performances. The validity of the mathematical model has been assessed by comparison with actual data from an existing tissue paper mill. Finally, the energy performances of two different layouts of the air system have been evaluated and compared. Changing the operative parameters of the drying process, such as air jet temperature and speed and moisture content of the extraction air, it is possible to obtain the same paper production with an energy saving of about 4.5%. In average, the layout with two parallel air circuits assure an energy saving of about 1% with respect to the layout with a single air circuit. [ABSTRACT FROM AUTHOR]

The effects of five commercially available hydrolytic enzyme additives on methane yields from dehydrated paper pulp sludge (DPPS) were determined in 5L pilot-scale reactors operated in semi-continuous mode for 60 days. Methane production was 40% and 43% higher in reactors receiving Novozymes and Novalin additives, respectively, compared to controls. Effects of time of DPPS inclusion on bacterial and archaeal microbial communities were many times larger than effects of enzyme type as enzyme addition did not produce rearrangements larger than random fluctuations observed in reactors receiving only DPPS. The ratio between volatile organic acids and alkalinity signified progressive decrease in process stability until day 45 irrespective of enzyme supplementation. Complementation with clarified pig slurry (1.5% vol.) for subsequent 15 days effectively stabilized process parameters and was sufficient for microbial communities to maintain DPPS hydrolytic capacity and process additional carbon flow derived from hydrolytic activity of enzyme additives. Consequently, initially unadapted full-scale biogas plant inoculum was capable of significantly increased methane yields from DPPS. Based on annual DPPS availability in EU the potential for additional energy recovery was estimated to be in the range of nearly 1 TJ. [ABSTRACT FROM AUTHOR]

The waste biomass has immense opportunities and plenty of potentials to be an efficient source of renewable energy. Initially, native unripe coconut husk (NCH) was used as raw material for fluidized bed gasification. Then NCH was treated with paper and pulp waste water to impregnate metals present in it for getting enhanced H 2 yield in fuel gas. Humidified air was used as gasifying medium, which served the purpose of introducing water vapour to take part in the gasification process. Then after, gasification medium was retrofitted with CO 2 , which enhanced both the higher heating value (HHV), and CO and H 2 content in the fuel gas. This research serves the dual benefit of energy generation and waste minimization. HHV of unripe coconut husk was investigated and found to be 20.95 MJ/kg. H 2 yield and HHV from impregnated coconut husk (ICH) were obtained as 55.55 vol % and 5.24 MJ/Nm3, respectively at HER 0.1 and gasification temperature of 850 °C in case of fluidized bed gasification. The GC-MS analysis of fuel oil obtained from ICH gasification was done to get the information about high yield of fuel gas as promise product of fluidized bed gasification. • Humidified air fluidized bed gasification of coconut husk with CO 2 was performed. • Paper and pulp wastewater was used for metals impregnation onto coconut husk. • Hydrogen content increased in humidified air gasification of treated coconut husk. • CH 4 in fuel gas decreased for humidified air with CO 2 resulting in decrease of HHV. • GC-MS fuel oil analysis resulted less number of elements showing higher gas yield. [ABSTRACT FROM AUTHOR]

Production of transportation fuels from biorefineries via biomass gasification has been suggested as a way of introducing renewable alternatives in the transportation system with an aim to reduce greenhouse gas emissions to the atmosphere. By co-locating gasification-based processes within heat demanding industries, excess heat from the gasification process can replace fossil or renewable fuels. The objective of this study was to compare the heat integration potential of four different gasification-based biorefinery concepts with a chemical pulp and paper mill. The results showed that the choice of end-product which was either methanol, Fischer-Tropsch crude, synthetic natural gas or electricity, can have significant impact on the heat integration potential with a pulp and paper mill and that the heat saving measures implemented in the mill in connection to integration of a gasification process can increase the biomass resource efficiency by up to 3%-points. Heat saving measures can reduce the necessary biomass input to the biorefinery by 50% if the sizing constraint is to replace the bark boiler with excess heat from the biorefinery. A large integrated gasification process with excess steam utilisation in a condensing turbine was beneficial only if grid electricity is produced at below 30% electrical efficiency. [ABSTRACT FROM AUTHOR]

Magazines and newspapers, as two kinds of municipal solid waste, were investigated as the fuel feedstock in a hybrid direct carbon fuel cell. These carbon sources, together with a reference carbon source-activated charcoal, were characterized by such techniques as X-ray diffraction spectra, X-ray photoelectron spectroscopy, and thermal gravimetric analysis, among others. The results indicate that the carbon from magazine waste paper was more abundant in calcite and magnesium calcite, with more oxidation degree of carbon and higher thermal reactivity, compared with the other two carbon sources. Then, the cell performance fed with such carbon sources was tested in a homemade device. The cell fed with magazine waste paper carbon showed the highest performance among the three carbon sources, with a peak power density of 172 mW/cm 2 at 650 °C. The cell performance results indicated that waste paper carbon sources, with a surface containing certain inherent impurities (calcite and magnesium calcite) and a high oxidation degree of carbon, could favor the thermal gasification of carbon fuel, and thus considerably enhance cell performance, especially for the operating temperatures below 700 °C. This study demonstrated that waste paper carbon sources could be promising fuel feedstock for hybrid direct carbon fuel cells. [ABSTRACT FROM AUTHOR]

The Swedish pulp and paper industry (PPI) must increase energy efficiency to remain competitive on the global market, which has experienced entries from countries with cheaper energy and raw material supplies. Interactions among variables for energy use, production, energy management, electricity price and firm characteristics (FC), in different types of mills, i.e., pulp, paper and integrated mills, in Sweden from 2006 to 2015 indicate that correlations among the studied variables were different in different types of mills. This difference between types of mills seemed to originate partly from varying accessibility to production residue that could be used for energy. For all types of mills, variation of electricity prices did not correlate significantly with energy efficiency during the study period. The studied FC were firm's age, number of employees, number of companies in company group, net sales and profit for the year. Energy efficiency was more affected by the variables characterizing energy and production compared to the variables representing FC. This study also suggested presence of possible discrepancies between FC that were perceived as barriers to energy management towards energy efficiency, according to previous studies, and what was shown by the data combining variables representing energy use, production and FC. [ABSTRACT FROM AUTHOR]

A kind of wood pulp fiber paper (WPFP) was proposed as candidate for the matrix of desiccant wheel. Silica gel was coated on WPFP by impregnation method and the corresponding coating ratio was obtained and analyzed. Then the thermal conductivity, pore structure and adsorption/desorption performances of WPFP coated with silica gel were tested and analyzed. The results indicated that the WPFP has high coating ratio for silica gel due to its hydrophilic characteristic. The thermal conductivity of WPFP coated with silica gel after the first coating increases obviously compared with raw WPFP and reaches to 0.1292 W/(m⋅K). In addition, the WPFP coated with silica gel after the first coating has high specific surface area and its maximal adsorption quantity for water vapor can be 0.240 g/g. Finally, the DCOP of the desiccant wheel using WPFP as matrix obtained by numerical simulation can be 1.75 under the given working condition that the temperature of regeneration air is set as 90 °C and the inlet condition of process air is set as 34.3 °C and 56.2% RH. It is indicated that the desiccant wheel using WPFP as matrix can meet the requirement of air dehumidification and save energy by 7.35% simultaneously. • Novel desiccant wheel using WPFP with high coating ratio as matrix was proposed. • WPFP belongs to hydrophilic material and has high coating ratio for silica gel. • The water vapor adsorption quantity of WPFP can be fitted well by D-A equation. • The DCOP of the desiccant wheel with WPFP as matrix can be 1.75. [ABSTRACT FROM AUTHOR]

Abstract: In this study, a pulp and paper mill (PPM) in the SEKA Papermaking Plant in İzmit, Turkey, is analysed through energy and exergy balances. The plant utilises recycled waste paper for papermaking. This type of raw material input makes the process highly sophisticated. The pulping uses strictly mechanical processes, such as digestion, separation by screening and hydrocyclone, and refining. The milling, as an integrated process, provides the final operations necessary to prepare the conditions required for the end-product by stock-preparation, wiring, rolling, and drying by dewatering, pressing, and evaporation. The possibility of making the entire process more thermodynamically efficient is discussed by calculating the energy and exergy losses for all the mechanical and physical sub-processes. The study shows that the energy efficiencies for each of the mechanical and physical steps in the PPM vary between 34% and 97.4%, whereas the exergy efficiencies vary between 30.2% and 94.2%. In conclusion, based on the results from the energy and exergy flow analyses, the exergy output can be improved through more efforts directed primarily to further measurements toward more efficient energy utilisation in the PPM. [Copyright &y& Elsevier]

This paper evaluates the environmental impacts of different alternatives for handling of sludge from paper and pulp mills in Sweden, using Life Cycle Assessment (LCA). The common practice of incineration of biosludge with energy recovery followed by landfilling of ash (System A) was compared with the alternative of digesting sludge anaerobically to produce biogas using different digestate residue management options. The digestate produced from anaerobic digestion (AD) was assumed to be incinerated for heat energy recovery in System B or pyrolyzed for biochar production in System C to be mixed with forest soils. The impact categories considered in this work are climate change, non-renewable energy use, mineral extraction, aquatic ecotoxicity, carcinogens and non-carcinogens. The LCA results demonstrate that the two proposed systems significantly reduce the environmental impacts of biosludge management relative to incineration. An 85% reduction in the aquatic ecotoxicity impact is achieved in System C, due to the reduced mobility of heavy metals in biochar relative to ash. System C, on the whole, outperformed the other two, leading the authors to the recommendation that the use of pulp and paper mill biosludge in biogas-biochar production systems is preferable to merely recovering energy from it. • Anaerobic digestion (AD)-pyrolysis and AD-incineration were modelled as biosludge treatment technologies. • Immobilization of the heavy metals in biochar significantly reduced aquatic ecotoxicity. • The lowest carcinogens and non-carcinogens impacts were offered by the AD-pyrolysis system. • From an environmental point of view, biogas-biochar is preferable to merely energy recovery. [ABSTRACT FROM AUTHOR]

The P&P (pulp and paper) industry in Taiwan is highly energy intensive and there is much product diversification. Taiwan has extremely limited coal and petroleum resources and imports 98% of its energy supply. Increased energy utilization efficiency to reduce energy consumption is necessary for industry in order to implement energy audit recommendations. This work summarizes the energy-saving potential of 118 firms from 2009 to 2013 as determined by on-site energy audits, as well as the energy savings implemented in 2011 by 72 firms in Taiwan's P&P industry, according to data from the on-line Energy Declaration System. It is found that the total of the energy-saving potential and the implemented energy savings are 168.3 and 762.1 TJ, respectively. The results of this study can serve as a reference for current P&P operations and as a base case for stimulating changes in energy utilization. [ABSTRACT FROM AUTHOR]

Abstract: This work analyzed the energy flow of the pulp and paper industry in Taiwan. The potential technology options that were examined focus on how to capture some of the energy currently lost in the processes and then identifying the areas with energy-saving potential that could also have large impacts across a variety of industries. In addition, the energy-saving potential of these options was evaluated. The energy-saving potential of the pulp and paper industry would be around 6939.9 KLOE/M. The greatest energy-saving potential lies with improving energy distribution and equipment efficiency, which would together potentially comprise 86.8% of total energy conservation. This analysis can serve as a benchmark for current pulp and paper making operations, and as a base case for stimulating changes toward more efficient energy utilization in the pulp and paper industry. [Copyright &y& Elsevier]

This study shows a comparative techno-economic analysis of the integration of biomass gasification for generation of producer gas to be used in electricity production and to replace natural gas in the lime kilns of the pulp and paper industry. Three study cases with alternative configurations of the energy system integrating biomass gasification were analysed, including or not the co-generation of electricity and thermal energy, namely: i) Case I, for generation of electricity from residual forest biomass (RFB) in an integrated gasification combined cycle system, ii) Case II, generation of producer gas by RFB gasification for replacement of natural gas in the burners of a lime kiln, and iii) Case III, as an integration of Cases I and II for combined production of electricity and heat. Residual forest biomass from eucalyptus logging activities for feedstock processing for the pulp and paper industry was considered as fuel for direct (air) gasification in bubbling fluidized bed. The analysis made is supported on review reports, namely, the evaluation of the existing literature on investment projects in biomass power plants, and on experimental investigation for determining the composition of the producer gas from gasification of the selected feedstock. An economic model was developed that combines the net present value, internal rate of return and payback period. The main results of the energy system analysis show that the net electricity generation is between 72 and 83 GWh/year, while the production of CaO in the lime kiln supported by combustion of producer gas, is 82.12 kt/year, and a global energy efficiency between 21.70 and 34.17 % is achieved for the analysed configurations of the energy system. The results of the economic analysis show a positive NPV, an IRR greater than the discount rate and a PBP less than the useful life of the plant. The sensitivity analysis shows quite favorable investment projections given the low probability that the NPV will reach negative values and compromise the economic viability of the project. • The technical-economic viability of the forest biomass residues gasification is addressed. • Integration of IGCC concepts in the pulp and paper industry is reviewed. • The opportunities and drawbacks of IGCC in the pulp and paper industry are discussed. • Replacement of natural gas for producer gas for electricity generation and lime production is analysed. • A Monte Carlo sensitivity analysis is performed. [ABSTRACT FROM AUTHOR]

Abstract: The objective of this paper is to estimate the energy saving potential in China's paper industry by determining energy intensity under different scenarios. Cointegration model and stability test are applied to formulate the equilibrium equation. Results show that energy price, industry structure, profit margin and technology have significant impact as they are negatively correlated to changes in energy intensity. Three scenarios (BAU (business as usual), intermediate and active) are designed to estimate the future trend of energy intensity in paper industry. In 2010, the energy intensity (energy consumption per unit of value added) was 4 tce/10,000 RMB, and by the scenarios it is expected to considerably decline. According to the BAU (business as usual) scenario, the energy intensity will decrease to 2.56, 1.43 and 0.70 tce/10,000 RMB by 2015, 2020 and 2025, respectively. With respect to the intermediate scenario it is expected to drop further to 0.44 tce/10,000 RMB. Yet by the active scenario, the energy intensity is expected to considerably decline to 0.36 tce/10,000 RMB by 2025. Using the BAU forecast as a baseline, the quantity of energy savings is estimated to be 185.6 billion tce by 2025. Considering this important potential, we also provided some policy suggestions. [Copyright &y& Elsevier]

In this paper an approach for analysing the potential for implementation of different technology pathways for the European pulp and paper industry (PPI) is presented. The approach is based on detailed technical research and aggregates the knowledge from previous studies to incorporate the whole European PPI. Thus, the potential for different technology pathways can be estimated on a European level whilst still considering important characteristics of individual mills. The usefulness of the approach was exemplified by applying it to a case study of the potential for introduction of carbon capture and storage (CCS) within the European PPI. The results from the case study show that for the European PPI, CCS has an up-hill road in order to be a viable, large scale alternative for reduction of CO2 emissions. If CCS is to be introduced in large scale within the European PPI, large biomass-based point sources of CO2 emissions need to be included when planning for CCS infrastructure and also the infrastructure needs to be built out for clusters emitting <20 MtCO2/yr. [ABSTRACT FROM AUTHOR]

Abstract: Paper production is an energy-intensive process and accounted for about 9% of industrial energy demand in Germany in 2008. There have only been slow improvements in energy efficiency in the paper industry over the past twenty years. Policies can accelerate the progress made, but knowledge about the remaining efficiency potentials and their costs is a prerequisite for their success. We assess 17 process technologies to improve energy efficiency in the German pulp and paper industry up to 2035 using a techno-economic approach. These result in a saving potential of 34 TJ/a for fuels and 12 TJ/a for electricity, which equal 21% and 16% of fuel and electricity demand, respectively. The energy savings can be translated into mitigated CO2 emissions of 3 Mt. The larger part of this potential is found to be cost-effective from a firm''s perspective. The most influential technologies are heat recovery in paper mills and the use of innovative paper drying technologies. In conclusion, significant saving potentials are still available, but are limited if we assume that current paper production processes will not change radically. Further savings would be available if the system boundaries of this study were extended to e.g. include cross-cutting technologies. [Copyright &y& Elsevier]

Abstract: Co-liquefaction of secondary pulp/paper-mill sludge (solids concentration: 1.6 wt%) and waste newspaper with a total solids concentration of 11.3 wt% was investigated with and without the addition of catalysts in a 75 ml Parr High-Pressure reactor at temperatures of 250–380 °C for 20 min. The yield of heavy oil (HO) without catalyst was between 16.7 and 28.0 wt% within this temperature range, and peaked at 350 °C. The addition of HCO2H, FeS, or KOH at 5 wt% of the total solids (on a dry basis) was found to enhance the HO yield at 300 °C, particularly HCO2H, which increased the yield of HO from 24.9 to 34.4 wt%. More interestingly, synergistic effects between secondary pulp/paper-mill sludge and waste newspaper were observed in the co-liquefaction operations. For example, the HO yield attained was 26.9 wt% at 300 °C in the co-liquefaction of the mixture of 33 wt% sludge and 67 wt% waste newspaper, and was noted to be 9 wt% and 6 wt% higher than the yields obtained from liquefaction of sludge and waste newspaper alone, respectively. The HOs from liquefaction or co-liquefaction at 300 °C for 20 min exhibited significantly higher energy contents (HHV ≥ 30 MJ/kg), almost doubled those (˜16 MJ/kg) of the original feedstocks. [Copyright &y& Elsevier]

This paper presents a comparison between four gasification-based biorefineries integrated with a pulp and paper mill. It is a continuation of 'Transportation fuel production from gasified biomass integrated with a pulp and paper mill - Part A: Heat integration and system performance'. Synthesis into methanol, Fischer-Tropsch crude or synthetic natural gas, or electricity generation in a gas turbine combined cycle, were evaluated. The concepts were assessed in terms of GHG (greenhouse gas) emissions and economic performance. Net annual profits were positive for all biofuel cases for an annuity factor of 0.1 in the year 2030; however, the results are sensitive to biofuel selling prices and CO 2,eq charge. Additionally, GHG emissions from grid electricity are highly influential on the results since all biofuel processes require external power. Credits for stored CO 2 might be necessary for processes to be competitive, i.e. storage of separated CO 2 from the syngas conditioning has an important role to play. Without CO 2 storage, the gas turbine case is better than, or equal to, biofuels regarding GHG emissions. Efficiency measures at the host mill prior to heat integration of a gasification process are beneficial from the perspective of GHG emissions, while having a negative impact on the economy. [ABSTRACT FROM AUTHOR]

Urgent need for waste disposal and renewable energy have opened up promising pathways for renewable and sustainable fuel production to substitute traditional fossil fuels. In this study, catalytic co-pyrolysis of waste paper (WP) and polyvinyl chloride (PVC) as typical municipal solid wastes was experimentally investigated towards hydrogen-rich syngas production. Results indicated the maximum H 2 yield (429 μmol·g cat −1·min−1) was obtained with 60% PVC weight ratio under 900 °C which was higher than single component pyrolysis. Higher hydrogen yield (681.76 μmol·g cat −1·min−1) appeared over Fe/CeO 2 –CaO under the optimal conditions compared to that of Ru/ZSM-5-CaO (445.54 μmol·g cat −1·min−1). From the calculated non-isothermal kinetic parameters, both catalysts could reduce activation energies. Proper porous structure and CaO content in the catalyst could enhance hydrogen production via carbon species fixation. • Catalytic co-pyrolysis of waste paper and PVC blends for hydrogen production is firstly investigated. • Enhanced interactions of PVC/waste paper during pyrolysis was found for H 2 production. • Non-isothermal kinetics were implemented to evaluate catalytic co-pyrolysis. • High H 2 yield was obtained over Fe/CeO 2 –CaO for its pore structure and sorption enhancing effect. [ABSTRACT FROM AUTHOR]

A new process for the production of bioethanol from paper mill sludge (PMS) is described in this work. PMS biomass feedstock was processed via the simultaneous saccharification and fermentation (SSF) with and without accelerants. The enzymatic hydrolysis and fermentation were first evaluated, and the energy demand was 2.2 MJ/L of produced ethanol. When the enzymatic hydrolysis and fermentation were combined, the energy demand was reduced to 1.0 MJ/L ethanol, the sugars production increased, and the overall capital cost of the process decreased. The sugar yield was improved by adding accelerant and selecting the optimal fiber recovery method. The accelerant improved the enzymatic hydrolysis via a pathing/bridging mechanism. The SSF with the chemical fiber recovery method coupled with accelerant addition would be the best process configuration. Upon this combination, the glucose profile was enhanced from 9.8 g/L to 17.0 g/L. The sludge fiber conversion by SSF was improved by selecting an efficient fiber recovery method combined with the accelerant addition. SSF in chemical fiber recovery with accelerant addition was the best process by a 10% improvement of ethanol yield. The proposed process configuration offers a lower cost and sustainable process and contributes to the circular economy of zero waste discharges. • A combined SSF process using PMS feedstock to produce bioethanol was developed. • The energy saving in an integrated process was 1.2 MJ/L ethanol. • The optimal fiber recovery from paper mill sludge was achieved via acid treatment. • The optimal fiber recovery increased fractional glucose by 27%. • The cationic accelerant improved the enzymatic hydrolysis by 10% due to the patching mechanism. [ABSTRACT FROM AUTHOR]

This article presents results of a pulsed UV laser method for the simultaneous reduction of graphite oxide (GO) and patterning of reduced graphene oxide (rGO). This direct laser writing method was applied to the fabrication of graphene-based, in-plane interdigitated micro-supercapacitors (μ-SCs), prepared on free-standing GO paper (10 μm thick). The electrochemical performance of μ-SCs was studied using two different electrolytes (KOH and NaCl). The results from cyclic voltammetry measurements exhibited typical electrical double layer behavior, with specific capacitances of 9.3 μF/cm2 and 13.8 μF/cm2 (at a scan rate of 10 mV/s) for KOH and NaCl electrolytes, respectively. The μ-SCs exhibited good performance, with retention of 95% of the original capacitance values after 3400 charge-discharge cycles. When compared to devices obtained by conventional lithographic techniques, the laser fabrication of planar μ-SCs is faster, cost-effective and scalable. We believe this one-step and environmentally friendly laser-assisted method to be a good alternative for the fabrication of flexible energy storage devices. • Direct laser writing is used to design the interdigitated electrode for μ-supercapacitor. • Direct laser writing on GO paper is simple, chemical free and room temperature technique. • The laser parameters are optimized to complete photothermal reduction of GO paper. • GO paper-based μ-supercapacitors reveal excellent electrochemical performance. [ABSTRACT FROM AUTHOR]

Abstract: In this study the possibilities of making a cost-effective heat exchanger retrofit in a simulated thermo mechanical pulp and paper mill are analysed using advanced composite curves. The use of advanced composite curves is a fairly new method developed in Chalmers University, and they have not previously been used to analyse a mechanical pulp and paper mill. The simulated mill used as an example in this study has one TMP (thermo mechanical pulping) line, one paper machine, debarking and auxiliary systems. The results show that the advanced curves give valuable information on the system and provide guidance as to where to look for improvement potential. The relative costs of different improvements are in line with traditional knowledge of improvement costs. [Copyright &y& Elsevier]

Thin, lightweight, stackable, solid-state supercapacitors are in great demand in the electronics industry because of their use in miniaturized devices. Herein, we report a simple and novel strategy to fabricate ultra-thin, lightweight, and stackable symmetric supercapacitors using MnO 2 -incorporated carbon nanotube (CNT)-web paper. SEM and TEM analyses revealed a uniform nanometer-scale coating of MnO 2 on the individual fibers of the CNT-web paper after simple deposition at room temperature. The network structure of free-standing conductive CNT-web paper provides a short diffusion path, allowing for complete utilization of MnO 2 in the charge storage process. A MnO 2 /CNT-web paper electrode showed an excellent areal capacitance of 135 mF cm −2 at 5 mV s −1 with a remarkable capacitance retention of 95% after 10,000 cycles. A symmetric solid-state supercapacitor containing MnO 2 /CNT-web paper displayed a high areal capacitance of 57 mF cm −2 with an energy density of 0.018 mWh cm −2 and a capacitance retention as high as 86% after 10,000 cycles. In addition, the voltage and capacitance were tripled by simply stacking three symmetric supercapacitors and connecting them in series and in parallel, respectively. We are optimistic that the excellent performance of the ultra-thin CNT-web paper-based supercapacitors demonstrated here will facilitate the development of compact supercapacitor banks in the near future. [ABSTRACT FROM AUTHOR]

The preparation and application of heteroatom doped carbons have attracted lots of attention in the past years. In the current work, a facile synthesis of nitrogen doped carbon with filter paper as the carbon source and urea as the nitrogen source was presented. Filter paper was first impregnated with urea solution, and was then carbonized and activated. The carbons' physical and chemical properties were studied. For the application in CO 2 adsorption, impacts from porous characteristics and nitrogen doping were discussed and differentiated. The results suggested that nitrogen doping was beneficial to the improvement of CO 2 uptake, but suitable porous properties were the most important factors. Nitrogen doping showed more significant effects on enhancing the adsorption heat and selectivity. The research of carbonaceous CO 2 adsorbent should focus on nitrogen doped carbons with high porosity. • Urea loaded filter paper is used as starting material for nitrogen doped carbon. • Effects of nitrogen doping and porous structure on CO 2 adsorption are studied. • CO 2 uptake at 273 K and 1 bar reaches 5.12 mmol/g. • Nitrogen doping has obvious effects on CO 2 adsorption heat and selectivity. [ABSTRACT FROM AUTHOR]

In this study, the methane production potential of paper industry waste sludge (PPWS) was investigated using consortium of hydrolytic enzymes (CHE) mediated poly3hydroxybutyrate (P3HB) method. Initially, P3HB was extracted from municipal aerated waste sludge (MARWS) by optimizing extraction time and dimethyl carbonate dosage. Maximum of P3HB (910 mg/g) was extracted at 60 min of extraction time and 4 mL of dimethyl carbonate dosage. Then, the influence of extracted P3HB dosage (5–120 mg) on methane production from PPWS was examined. 75 mg of P3HB dosage was exhibited higher methane production (153 mL/g VS) when compared to other P3HB dosage. Further, CHE mediated pretreatment was performed by varying CHE dosage and temperature. At optimized CHE dosage (2.5 mL) and temperature (45 °C), maximum of chemical oxygen demand (COD) liquefaction, suspended solids reduction (SSR) and lignin removal were found respectively to be 23.7%, 18% and 61% which was higher than control (COD liquefaction (0.9%), SSR (0.5%) and lignin removal (0.7%)). Also, biomethane potential assay was carried out in which CHE mediated P3HB method attained higher methane production (280 mL/g VS) when compared to CHE method (217 mL/g VS) and control (47 mL/g VS). • Biopolyester was extracted by varying extraction time and dimethyl carbonate dose. • The extracted biopolyester was identified as P3HB. • P3HB dose had a significant impact on methane production from PPWS. • Maximum of COD liquefaction and SSR were noticed in CHE pretreatment study. • Higher methane production was attained by CHE mediated P3HB method. [ABSTRACT FROM AUTHOR]

The reaction kinetics of drying, pyrolysis and combustion of paper sludge have been determined in a thermogravimetric analyzer (TGA). The effects of heating rate (5–30 K min−1) and sample weight (10–50 mg) on drying and pyrolysis of paper sludge have been determined. The kinetic parameters of char combustion are determined at the isothermal conditions (723–1173 K). For dehydration, pyrolysis and combustion of paper sludge, temperature can be divided into drying (−470 K), pyrolysis [low (470–660 K), medium (660–855 K)] and combustion (>855 K) ranges. From the kinetic parameters (frequency factor and activation energy) of water decomposition, two major degradable compounds are found and the experimental thermogravimetric curves predicted by those parameters. For char combustion, the reaction order is found to be unity. The char combustion is well expressed by the shrinking core model with chemical reaction controlling and the activation energy is changed from 24.3 to 10.14 kJ mol−1 K−1 at 873 K. [Copyright &y& Elsevier]

Using the two criteria of potential CO2 reduction and cost of CO2 reduction, technical energy measures in Swedish pulp and paper mills are investigated. Principal CO2-reducing measures analysed are: decreased specific energy utilisation, fuel switch, and CO2 capture and sequestration. Among the investigated measures, conventional technologies for electricity conservation and improved electrical conversion efficiency in existing systems for cogeneration of heat and power are identified as the most cost-effective alternatives that also have large CO2 reduction potentials. For commercially available technologies, the results indicate an accumulated reduction potential of up to 8 MtCO2/y (14% of the Swedish net emissions). If emerging technologies for black liquor gasification (BLG) with pre-combustion CO2 capture and sequestration are considered, the CO2 reduction potential increases by up to 6 MtCO2/y (10% of the Swedish net emissions). Commercialised BLG, CO2 capture and reliable CO2 sequestration technologies are identified as important potential contributors to Swedish compliance with Kyoto Protocol targets, especially in a scenario of nuclear power closure. [Copyright &y& Elsevier]

Abstract The paper drying process has the highest level of energy consumption in the pulp and paper production process. Analysis and optimization of the energy system during the paper drying process is critical for improving the energy efficiency of the entire paper mill. In the existing model for the paper drying process, the solution requires accurate boundary conditions such as the air temperature and humidity of the pocket area and the cylinder surface temperature, which are very difficult to obtain in the papermaking process. This can result in significant deviations between the model solution and the actual production process. This paper focuses on the single-tier dryer cylinder-based paper drying process that has been widely used with high-speed papermaking machines in recent years. A mathematical model is proposed based on real-time data. The verification via industrial production demonstrates that the proposed model is reliable for the paper drying process. Based on the simulation results, two optimization operations have been proposed. The energy consumption decreases from 1.51 t steam/t paper to 1.44 t steam/t paper, 4.6% of the steam and 1.26 × 106 RMB can be saved for a medium-scale paper mill with the annual production capacity of 105 t paper. Highlights • Mathematical model for the single-tier cylinder based paper drying process is proposed. • Both the steam-condensate system and the paper drying process are considered. • The simulation results are verified by the industrial data from a papermaking enterprise. [ABSTRACT FROM AUTHOR]

A facile strategy is designed for the fabrication of flexible and free-standing ternary CoSnO 3 /graphene/carbon nanotubes (CoSnO 3 /GN/CNTs) composite papers through a simple filtration, followed by annealing process. The CoSnO 3 /GN/CNTs composite papers with high flexibility and tailorability can be easily fabricated. The CoSn(OH) 6 nanoparticles/graphene oxide/carbon nanotubes (CoSn(OH) 6 /GO/CNTs) composite papers obtained by a simple filtration method are transformed into CoSnO 3 /GN/CNTs composite papers after a thermal treatment process. In this unique composite structure, CoSnO 3 nanoparticles (nanocubes and nanoboxes) are embedded homogenously into the 3D framework of graphene and carbon nanotubes, respectively, in which offers not only a 3D conductive network and a dual restriction on the aggregation of CoSnO 3 nanoparticles, but also accommodates the large volume expansion of CoSnO 3 nanoparticles. When used directly as binder- and conductive agent-free anodes for lithium-ion batteries, the CoSnO 3 /GN/CNTs composite papers exhibit superb electrochemical properties including extraordinary reversible capacities, superior rate capabilities and stable cycle performances compared to CoSnO 3 nanoparticles and GN/CNTs paper, suggesting a new pathway for the rational engineering of anode materials. [ABSTRACT FROM AUTHOR]

Abstract: The Scandinavian mechanical pulp and paper industry has been facing great challenges during the past decades, mainly because of declining demand for newsprint, and higher prices on raw material and energy. One way of increasing profitability is to produce more value-added products besides the production of pulp and paper. In this study, integration potentials of three possible future biomass gasification-based energy mills with an existing thermo-mechanical pulp (TMP) mill, co-located with a sawmill, have been evaluated. The product gas was utilized for electricity production in a gas turbine, for production of methanol or for production of Fischer–Tropsch (FT) liquids. Integration of the energy mills showed good potential as the TMP mill constitutes a heat sink for which the excess heat from the energy mills can be utilized all year round. However, since there is little excess heat from the TMP mill at the required level to be utilized for biomass drying, for example, heat integration is typically one way. It has also been shown that integration of biomass gasification with a TMP mill results in larger CO2 emissions reduction than stand-alone operation. Still, compared to co-firing biomass in a coal power plant, the energy mills all have lower potentials for CO2 emissions reduction. [Copyright &y& Elsevier]

In order to explore hydrothermal carbonization (HTC) behavior of municipal solid wastes (MSW), four typical components, waste textile, wood, paper and food, were employed to perform HTC and co-HTC process. The experiments were conducted at 240 ○C and 90 min with a 1:12 solid/liquid ratio, where blending ratios of 1:3, 1:1 and 3:1 with waste textile were investigated. As expected, the increase of fixed carbon and carbon content improved the fuel potential of hydrochar. The synergistic index (SI) analysis clearly indicated that significant synergistic effects occurred during co-HTC process. Specifically, all the SI values of hydrochar yield from co-HTC of waste textile with wood and paper were negative, while all SI values of hydrochar yield for waste textile with food were positive. Particularly, the SI values of fuel ratio for all hydrochars were positive which suggested co-HTC could promote to enhance the coalification degree of hydrochars. However, the undesirable increment of O content for hydrochars (derived from 75%waste textile-25% waste food and 50%waste textile-50% waste food) decreased the high heating value. The combustion behavior and nth-order kinetic model analysis showed that hydrochars derived from co-HTC rendered a more stable and lasting combustion profile. Image 1 • The synergistic index indicated that significant synergistic effects occurred during co-HTC. • The SI values of hydrochar yield from co-HTC of WT with WW and WP were negative. • The SI values of fuel ratio for all hydrochars were positive suggesting enhanced coalification degree. • Hydrochars derived from co-HTC rendered a more stable and lasting combustion profile. [ABSTRACT FROM AUTHOR]

Abstract: This study investigates heat integrated production of FT (Fischer–Tropsch) crude, where excess heat from the FT crude plant is delivered to a typical Scandinavian pulp and paper mill that produces fine paper. The sizes of FT crude plants are quantified, when the amount of excess heat from the FT plant exactly matches the heating demand otherwise satisfied by the bark boiler at the mill, considering a number of development pathways at the mill, including various degrees of steam savings and biorefinery options, such as lignin extraction. Performance of integrated production is compared with that of an FT stand-alone plant on the basis of wood fuel-to-FT crude efficiency, GHG (greenhouse gas) emissions balances and FT crude production cost. The results show that there exists a heat integration opportunity for an FT crude plant ranging from 0 up to 350 MW (LHV) of wood fuel depending on the development pathway for the mill. The results indicate higher overall efficiency and a generally lower production cost for the heat integrated, co-located production. Heat integrated production has a larger potential to contribute to GHG emission mitigation, assuming a future generation of grid electricity emitting equal to or less than an NGCC (natural gas combined cycle) power plant. [Copyright &y& Elsevier]

Paper mill sludge (PMS) can be efficiently utilized to produce fuels and chemicals. However, wastewater is usually generated during the de-ashing step of the PMS for fibrous materials recovery. Per process requirements, the wastewater stream must be treated which results in an increase in the overall process production cost. Therefore, this research aims at reusing the wastewater produced during the de-ashing step as a substitute for freshwater addition during the conversion of PMS into ethanol. The advantages of this approach include reducing the amount of wastewater produced and enhancing the overall efficiency of the process. It will contribute to the circular economy of zero waste discharges. The results showed that 30% of the process wastewater can be recycled without affecting the enzymatic hydrolysis and ethanol fermentation. Hence, the amount of wastewater that needs to be treated is reduced by 30% resulting in a cost reduction of 22.5%. The results also showed that wastewater recycling minimized the energy demands in the distillation and evaporation units by 1206 kJ/kg. The energy reduction is due to the increase of metals and total soluble solids in the broth stream after fermentation. This process configuration enhanced the process economy, saved energy and managed waste streams. • Reuse of wastewater in the paper mill sludge conversion. • A certain degree of recycling has no impact on the glucose yield. • Wastewater recycling reduced the energy demand of the process by 1251 kJ/kg metric tons wastewater. • Cost-saving of wastewater treatment by 22.5% when a 30% recycling degree achieved. [ABSTRACT FROM AUTHOR]

A highly flexible and free-standing, porous Mn 3 O 4 nanorod/reduced graphene oxide (pMn 3 O 4 NR/rGO) paper was prepared by a two-step process: vacuum filtration and thermal treatment. The MnOOH nanorod/graphene oxide (MnOOH NR/GO) paper obtained by a simple filtration method is transformed into pMn 3 O 4 NR/rGO paper after a thermal reduction process. A unique lamellar structure was achieved with pMn 3 O 4 NR homogeneously intercalated within the GO layers. In the hybrid structure, graphene nanosheets provide a conductive pathway and act as the buffer layers to prevent the pulverization of pMn 3 O 4 NRs during reaction. Therefore, when used as the anode in lithium ion batteries, this pMn 3 O 4 NR/rGO paper exhibits a first high discharge capacity of 943 mA h g −1 , which quickly stabilizes and remains at 573 mA h g −1 even after 100 cycles at 100 mA h g −1 , which is much higher than the discharge capacity of the corresponding pristine graphene paper (183 mA h g −1 ). [ABSTRACT FROM AUTHOR]

In this work, an analysis of co-pyrolysis municipal solid waste and paper sludge with additive (MgO) were investigated by TG-FTIR and Py-GC/MS. The proportions of paper sludge in the blends were 10%, 30% and 50%, respectively. The pyrolysis characteristics, the yields of pollutants (CO, SO 2 , NO, HCl) and CO 2 , the products and chemical composition, the kinetic behaviors and the distribution activation energy model were investigated. After adding paper sludge, the sums of pollutants reduced, the amount of aliphatic hydrocarbons decreased and oxygenates compounds increased. After adding MgO, the results showed that the residue mass decreased, the emission of pollutants reduced, the ratio of aliphatic hydrocarbons became larger, the ratio of oxygenates compounds became smaller, and the activation energy reduced. According to the beforementioned results, the 30% percentage of paper sludge in the mixture with MgO might be the most suitable ratio for co-pyrolysis. [ABSTRACT FROM AUTHOR]

Coconut husk was treated with pulp and paper industry wastewater for impregnating metal constituents present in it. The present work was focused on humidified air as an alternative to steam for generation of hydrogen-rich fuel gas in an updraft fixed-bed gasification column. A series of experiments were performed to see the effect of temperature, air/humidified air and CO 2 addition on gas yield and composition. Furthermore, some experiments were also conducted by varying impregnation temperature at the optimum condition to see the effect of impregnation temperature on gas yield and calorific value. The gross calorific value (GCV) of coconut husk C 53.84 H 77.80 O 43.99 N was estimated as 23.21 MJ/kg. The fuel gas production was found in the range from 0.68 to 2.89 Nm 3 /kg for native and from 0.83 to 3.13 Nm 3 /kg for impregnated coconut husk. The GCV of fuel gas yield was found to be maximum of 12578 kJ/Nm 3 for impregnated coconut husk at impregnation temperature of 105 °C, retrofitted with CO 2 in humidified air. The concentration of hydrogen was found maximum for impregnated coconut husk. The present gasification process not only provides feasibility of green energy but also renders to reduce the pressure of the environmental pollution created by the unutilized coconut husk. [ABSTRACT FROM AUTHOR]

Abstract: The paper industry is, with about 6% of the total worldwide industrial energy use, an energy-intensive industry. The drying section is with approximately 50% the largest energy consumer in a paper mill, energy use in this section is mainly heat use. Several options to decrease heat use in conventional multi-cylinder drying sections are investigated, calculating the effect on energy use. Optimization measures include a) decreasing the amount of water evaporation by applying additives in higher consistencies and by lowering the water viscosity, b) decreasing the heat use of water evaporation by increasing the dew point temperature of the dryer and c) increasing the amount of heat recovery by using exhaust air to not only pre-heat the incoming air but also to increase process water temperatures. These could all be achieved by retrofitting and/or choosing different processing conditions in existing factories. The combined thermal heat saving potential due to the optimization actions is 1.3GJh/t paper (or 32% of the drying section’s heat use) as compared to the reference situation. [ABSTRACT FROM AUTHOR]

Accurate understanding of the marginal energy-saving costs of energy-using entities is critical for regulatory authorities to formulate and implement energy-saving policies. This article brings out an easy-to-operate analytical framework to measure the marginal energy-saving cost and construct energy conservation supply curve with the help of data envelopment analysis and quantitative model. Furthermore, taking China's pulp and paper industry as an example, the authors discuss the difference of economic costs between industry energy-saving task assignment with and without considering the difference of marginal energy-saving costs of different energy using entities with the help of linear programming model. The main empirical results are as follow. First, there is a big difference in the industrial marginal energy-saving costs in different provinces. The difference between the highest and lowest energy-saving costs is twice as large. Second, the optimal energy-saving task assignment based on an accurate energy conservation supply curve can help to save nearly 35% of total economic cost. • An alternative method of measuring energy conservation cost is provided. • An optimal energy saving task assignment model is constructed. • The problem of trade-off between efficiency and equity in policy making is discussed. [ABSTRACT FROM AUTHOR]

In this study, through orthogonal experiments design, the influences of ultrasonic pretreatment (frequency, power and treatment time) on co-pyrolysis and catalytic pyrolysis of municipal solid waste and paper mill sludge were explored. The differential thermogravimetry curves became steeper and the peak values were larger after pretreatment, which made the pyrolysis reaction rapidly and the volatile separated out timely. However, the change of pyrolysis characteristics was not obvious after adding MgO. The catalytic effect of MgO increased with the increase of sludge ratio. After pretreatment, the average activation energy of the samples had an overall increasing trend, but the change was small. MgO had a decreasing effect on activation energy, and with the increasing proportion of sludge the degree of reduction became significant. In addition, high ultrasonic frequency had a negative effect on reducing activation energy. • Study on the co-pyrolysis of municipal solid waste and paper mill sludge. • The differential thermogravimetry curves became steeper after pretreatment. • Distributed activation energy model was used to calculate the kinetic parameters. • The average activation energy had a minor increasing trend after pretreatment. • High ultrasonic frequency had a negative effect on reducing activation energy. [ABSTRACT FROM AUTHOR]

Abstract: The success of any process improvement study depends on the quality of the available data and the way in which the plant-specific characteristics are incorporated in the applied conceptual models; in the context of process integration studies these issues are directly related to the rules followed during the data extraction stage. Improving energy efficiency in a pulp and paper Kraft mill requires the identification of the most promising heat recovery network retrofit projects. In a retrofit analysis using pinch technology/process integration methods, only the process streams associated to the existing heat exchangers and some outlet streams (such as wastewater/effluent streams and vents) with high potential for heat recovery are usually included, while the energy exchanged through non-isothermal stream mixing (NIM) or direct heat transfer (DHT) is often assumed fixed and is not considered in the analysis. Relaxing this assumption requires extracting more data to represent the DHT design configuration that exists in the plant. However, different data extraction options can be considered to represent the DHT configuration depending on the associated process/operation constraints. This work describes a systematic procedure to extract and analyse the impacts of DHT on the overall energy efficiency of a Kraft process with a specific focus on mixing along the pulp line and in water tanks. [Copyright &y& Elsevier]

Among the various waste-to-energy conversion methods, gasification is a technically feasible option for municipal solid waste valorization, meeting current emission limits and reducing landfill disposal burden. This work investigates the potential of paper rich (⁓ 76 % wt.) commercial refuse-derived fuel (RDF) having high ash content (⁓ 17 % wt.) for gasification and co-gasification in downdraft gasifier. The ash formed from RDF, with higher proportion of alkaline earth metals (Ca and Mg) and lower proportion of alkali metals (Na and K), can effectively avoid agglomeration and clinker formation during gasification. The producer gas obtained from RDF gasification reports a maximum lower heating value of 4.34 MJ/Nm3at an equivalence ratio of 0.34 with corresponding cold gas efficiency of 59.24%.Co-gasification of RDF with biomass was examined as a strategy to reduce overall ash content of the mixture, using sawdust. Co-gasification has exhibited a synergy between RDF and sawdust when the RDF fraction in feedstock is at the higher side. A maximum lower heating value of 4.65 MJ/Nm3 was obtained during the co-gasification and the tar yield reduced from 13.6 g/Nm3to 8.8 g/Nm3 when RDF in the feed increased from 25% to 75% (w/w). • Investigates potential of paper-rich RDF for gasification and co-gasification. • Absence of agglomeration and clinker formation during gasification and co-gasification. • Producer gas with LHV and CGE of 4.34 MJ/Nm3 and 59.24%, respectively from RDF gasification. • RDF has exhibited synergy with biomass at higher RDF fraction during co-gasification. • Reduction in tar content with increase in RDF fraction during co-gasification. [ABSTRACT FROM AUTHOR]

This work reports an innovative simulation method for effectively utilizing paper-mill sludge based on the co-gasification approach for energy-enriched renewable fuel production. An Aspen plus-based co-gasification model was developed to simulate and examine the synergetic effects of biomass and paper-mill sludge co-gasification. Initially, the model was validated using experimental data from the reported literature and found good agreement regarding gasification and co-gasification approaches. Sensitivity analysis of biomass gasification revealed that the maximum H 2 content of 29.6% and CO (36.0%), LHV (7.8 MJ/Nm3), 72.2% (CCE) was obtained at optimal (850 °C: temperature; 1 bar: pressure; 0.2: ER) conditions. Further, the H 2 proportion enhanced, and CO declined to 38.8 and 30.7% at the same operating conditions, respectively, with a co-gasification ratio of 50% compared to 0% (H 2 : 29.6% and CO: 36.0%). However, with increasing the co-gasification ratio beyond 20%, the CO content started to follow upward trends; at the same CGR, the H 2 , LHV, and CCE observed were 36.0%, 7.76 MJ/Nm3, and 65.2%, respectively. Hence, the developed co-gasification model can provide vital information for large-scale gasifier design, operating decisions, and optimization using different biomass blends. • Biomass and PMS utilization to produce renewable fuel. • Co-gasification parametric effects evaluation on product yield. • Increasing the proportion of PMS in feedstock mixture increases H 2 content. • 20% PMS co-gasification provided consistency with reported literature. [ABSTRACT FROM AUTHOR]

This work reports the charge storage ability of Ni x Co 1-x (OH) 2 nanosheet-carbon nanofoam paper (CNFP) composites prepared by electrodeposition for high areal capacity supercapacitor electrodes. The Ni x Co 1-x (OH) 2 film grew through instantaneous nucleation, uniformly covered CNFP, and displayed a porous morphology composed of a nanosheet percolation network. The electrochemical response of the Ni x Co 1-x (OH) 2 films was tuned by varying the Co to Ni ratios. The optimized Ni x Co 1-x (OH) 2 stoichiometry resulted in Ni 0.33 Co 0.67 (OH) 2 -CNFP electrodes displaying areal capacity/capacitance values of 1.52 C cm −2 /2.03 F cm −2 at 2.1 mA cm −2 , resulting from the contribution of the double layer capacity of CNFP with the redox capacity of Ni x Co 1-x (OH) 2 . A two electrode cell composed of CNFP as negative electrode and Ni x Co 1-x (OH) 2 -CNFP as positive electrode presented a high areal capacity value of 0.73 C cm −2 at 7.2 mA cm −2 . [ABSTRACT FROM AUTHOR]

Abstract: Energy conservation is a central concern of the current industrial world, where increasing efficient energy usage is the only way of reducing a high energy demand. In the present study the optimization of a pulp and paper mill with a cogeneration plant has been carried out. The optimization was realized with a methodology which includes exergy, exergoeconomics, thermoeconomics and pinch analysis. The proposed methodology was useful in determining not only the best plant operating conditions but also establishing the components or subsystems with the highest irreversibilities. As a result of the study, operation changes in the recovery boiler, the turbogenerator, the thermal treatment and the deaerator were realized. Due to the higher irreversibility in the actual evaporator line, a new line of evaporators was proposed. Also, an innovative heat recycling technology as to the use of heat transformers was proposed in order to reduce waste heat discharged to the atmosphere. The results obtained with the proposed methodology, which integrates the different optimization methods, allowed reaching higher efficiencies and lower operational costs than those obtained with the optimization methods working separately. [Copyright &y& Elsevier]