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The integration of numerous distributed energy sources into the power system offers exciting opportunities to enhance the resilience of distribution networks. It is worth noting that the renewable-to-ammonia system has the potential to alleviate the multi-temporal and spatial imbalance of the power system. Therefore, this paper proposes a mathematical model for a renewable-to-ammonia system, taking into account the material balance and power balance of each unit. Based on this, this paper further explores the optimization scheduling method for flexible ammonia loads in distribution networks. A relaxation method for branch flow models in distribution networks based on second-order cone programming is proposed. An optimization scheduling model for flexible ammonia loads in distribution networks is constructed to minimize network loss. Moreover, considering the environmental advantages of the renewable-to-ammonia system, this paper compares the changes in hydrogen production technologies under different carbon emission constraints. Finally, a case study of the IEEE 33-node system is adopted to verify the effectiveness of the proposed model and method. It indicates that the renewable-to-ammonia system has environmental benefits and can reduce network loss to a certain extent. [ABSTRACT FROM AUTHOR]

This paper navigates the critical role of hydrogen in catalyzing a sustainable energy transformation. This review delves into hydrogen production methodologies, spotlighting green and blue hydrogen as pivotal for future energy systems because of their potential to significantly reduce greenhouse gas emissions. Through a comprehensive literature review and a bibliometric analysis, this study underscores the importance of technological advancements, policy support, and market incentives in promoting hydrogen as a key energy vector. It also explores the necessity of expanding renewable energy sources and international cooperation to secure a sustainable, low-carbon future. The analysis highlights the importance of scalable and cost-effective hydrogen production methods, such as solar-thermochemical and photo-electrochemical processes, and addresses the challenges posed by resource availability and geopolitical factors in establishing a hydrogen economy. This paper serves as a guide for policy and innovation toward achieving global sustainability goals, illustrating the essential role of hydrogen in the energy transition. [ABSTRACT FROM AUTHOR]

As new sources of energy and advanced technologies are used, there is a continuous evolution in energy supply, demand, and distribution. Advanced nuclear reactors and clean hydrogen have the opportunity to scale together and diversify the hydrogen production market away from fossil fuel-based production. Nevertheless, the technical uncertainties surrounding nuclear hydrogen processes necessitate thorough research and a solid development effort. This paper aims to position pink hydrogen for nuclear hydrogen production at the forefront of sustainable energy-related solutions by offering a comprehensive review of recent advancements in nuclear hydrogen production, covering both research endeavors and industrial applications. It delves into various pink hydrogen generation methodologies, elucidating their respective merits and challenges. Furthermore, this paper analyzes the evolving landscape of pink hydrogen in terms of its levelized cost by comparatively assessing different production pathways. By synthesizing insights from academic research and industrial practices, this paper provides valuable perspectives for stakeholders involved in shaping the future of nuclear hydrogen production. [ABSTRACT FROM AUTHOR]

As the global energy landscape transitions towards a more sustainable future, hydrogen has emerged as a promising energy carrier due to its potential to decarbonize various sectors. However, the economic competitiveness of hydrogen production by water electrolysis strongly depends on renewable energy source (RES) availability. Thus, it is necessary to overcome the challenges related to the intermittent nature of RESs. This paper presents a comprehensive techno-economic analysis of complementing green hydrogen production with grid electricity. An evaluation model for the levelized cost of hydrogen (LCOH) is proposed, considering both CO2 emissions and the influence of RES fluctuations on electrolyzers. A minimum load restriction is required to avoid crossover gas. Moreover, a new operation strategy is developed for hydrogen production plants to determine optimal bidding in the grid electricity market to minimize the LCOH. We evaluate the feasibility of the proposed approach with a case study based on data from the Kyushu area in Japan. The results show that the proposed method can reduce the LCOH by 11% to 33%, and increase hydrogen productivity by 86% to 140%, without significantly increasing CO2 emission levels. [ABSTRACT FROM AUTHOR]

While fossil fuels continue to be used and to increase air pollution across the world, hydrogen gas has been proposed as an alternative energy source and a carrier for the future by scientists. Water electrolysis is a renewable and sustainable chemical energy production method among other hydrogen production methods. Hydrogen production via water electrolysis is a popular and expensive method that meets the high energy requirements of most industrial electrolyzers. Scientists are investigating how to reduce the price of water electrolytes with different methods and materials. The electrolysis structure, equations and thermodynamics are first explored in this paper. Water electrolysis systems are mainly classified as high- and low-temperature electrolysis systems. Alkaline, PEM-type and solid oxide electrolyzers are well known today. These electrolyzer materials for electrode types, electrolyte solutions and membrane systems are investigated in this research. This research aims to shed light on the water electrolysis process and materials developments. [ABSTRACT FROM AUTHOR]

This paper presents a comprehensive study on the dynamic simulation modeling of alkaline water electrolyzers. Detailed experimental testing and characteristic analysis reveal that alkaline water electrolyzers have long startup times, rapid dynamic responses, and poor dynamic stability. These characteristics are critical for the development of accurate models and effective strategies. A dynamic simulation model was established in MATLAB R2022b and Simulink, enabling standalone simulation operation and module encapsulation. This model facilitates the construction of hydrogen production clusters and serves as a foundational tool for system strategy research. Simulations of rated current loading and unloading for four electrolyzers over 6 h showed significant differences in startup and operation. Key parameters such as cell voltage, maximum loadable power, hydrogen production efficiency, and energy consumption were analyzed. Temperature simulations indicated significant differences in thermal equilibrium points and cooling modes among the electrolyzers, as determined by structural design and cooling system efficiency. These findings highlight the need for efficiency improvements in high-current density electrolyzers. Overall, the model effectively represents commercial electrolyzer characteristics and offers a reliable tool for future research on control strategies for adapting hydrogen production systems to renewable energy power fluctuations, laying a solid foundation for the optimization of electrolyzer design and operation strategies. [ABSTRACT FROM AUTHOR]

To achieve a more ecologically friendly energy transition by the year 2050 under the European "green" accord, hydrogen has recently gained significant scientific interest due to its efficiency as an energy carrier. This paper focuses on large-scale hydrogen production systems based on marine renewable-energy-based wind turbines and tidal turbines. The paper reviews the different technologies of hydrogen production using water electrolyzers, energy storage unit base hydrogen vectors, and fuel cells (FC). The focus is on large-scale hydrogen production systems using marine renewable energies. This study compares electrolyzers, energy storage units, and FC technologies, with the main factors considered being cost, sustainability, and efficiency. Furthermore, a review of aging models of electrolyzers and FCs based on electrical circuit models is drawn from the literature and presented, including characterization methods of the model components and the parameters extraction methods, using a dynamic current profile. In addition, industrial projects for producing hydrogen from renewable energies that have already been completed or are now in progress are examined. The paper is concluded through a summary of recent hydrogen production and energy storage advances, as well as some applications. Perspectives on enhancing the sustainability and efficiency of hydrogen production systems are also proposed and discussed. This paper provides a review of behavioral aging models of electrolyzers and FCs when integrated into hydrogen production systems, as this is crucial for their successful deployment in an ever-changing energy context. We also review the EU's potential for renewable energy analysis. In summary, this study provides valuable information for research and industry stakeholders aiming to promote a sustainable and environmentally friendly energy transition. [ABSTRACT FROM AUTHOR]

P2A (Power to ammonia) is one of the important ways of large-scale consumption of renewable energy, and one of the important technological routes for the chemical industry to realize low-carbon and clean development. The new off-grid energy power to hydrogen ammonia system lacks the support of large power grids due to the complex mathematical model of the system, more variables, and cumbersome constraints, which leads to model solving difficulties, and the production simulation results obtained suffer from the problems of low economic efficiency and high new energy power abandonment rate. To address the shortcomings of the algorithm, which converges slowly and easily falls into the local optimum when solving the model, this paper applies the Sparrow Search Algorithm (SSA) to the problem of economic optimization of new energy hydrogen synthesis and ammonia system scheduling. Firstly, based on the characteristics of wind and light, the operating characteristics of an electrolyzer, and the characteristics of an electrochemical energy storage device, and taking the economic optimization of the electric hydrogen synthesis ammonia system as the objective function, the economic optimization scheduling model of an off-grid new energy electric hydrogen synthesis ammonia system is established for 24 h production simulation. Secondly, the model is solved based on the sparrow search algorithm, and the speed of solving and the economic benefits of the system are analyzed in comparison with the conventional algorithm. Finally, the proposed off-grid wind-powered hydrogen synthesis ammonia system based on the sparrow search algorithm is verified to achieve the optimal operation of the 24 h production simulation through an actual example in the Daan area of Baicheng City, Jilin Province, which shows that the optimized system has better economic efficiency and the new energy is completely consumed, thus verifying the reasonableness and validity of the algorithm proposed in this article. [ABSTRACT FROM AUTHOR]

Hydrogen produced from renewable energy sources is a valuable energy carrier for linking growing renewable electricity generation with the hard-to-abate sectors, such as cement, steel, glass, chemical, and ceramics industries. In this context, this paper presents a new model of hydrogen production based on solar photovoltaics and wind energy with application to a real-world ceramics factory. For this task, a novel multipurpose profit-maximizing model is implemented using GAMS. The developed model explores hydrogen production with multiple value streams that enable technical and economical informed decisions under specific scenarios. Our results show that it is profitable to sell the hydrogen produced to the gas grid rather than using it for self-consumption for low-gas-price scenarios. On the other hand, when the price of gas is significantly high, it is more profitable to use as much hydrogen as possible for self-consumption to supply the factory and reduce the internal use of natural gas. The role of electricity self-consumption has proven to be key for the project's profitability as, without this revenue stream, the project would not be profitable in any analysed scenario. [ABSTRACT FROM AUTHOR]

This paper presents an assessment of the levelized cost of clean hydrogen produced in Sicily, a region in Southern Italy particularly rich in renewable energy and where nearly 50% of Italy's refineries are located, making a comparison between on-site production, that is, near the end users who will use the hydrogen, and centralized production, comparing the costs obtained by employing the two types of electrolyzers already commercially available. In the study for centralized production, the scale factor method was applied on the costs of electrolyzers, and the optimal transport modes were considered based on the distance and amount of hydrogen to be transported. The results obtained indicate higher prices for hydrogen produced locally (from about 7 €/kg to 10 €/kg) and lower prices (from 2.66 €/kg to 5.80 €/kg) for hydrogen produced in centralized plants due to economies of scale and higher conversion efficiencies. How-ever, meeting the demand for clean hydrogen at minimal cost requires hydrogen distribution pipelines to transport it from centralized production sites to users, which currently do not exist in Sicily, as well as a significant amount of renewable energy ranging from 1.4 to 1.7 TWh per year to cover only 16% of refineries' hydrogen needs. [ABSTRACT FROM AUTHOR]

With the goal of achieving "carbon peak in 2030 and carbon neutrality in 2060", as clearly proposed by China, the transportation sector will face long–term pressure on carbon emissions, and the application of hydrogen fuel cell vehicles will usher in a rapid growth period. However, true "zero carbon" emissions cannot be separated from "green hydrogen". Therefore, it is of practical significance to explore the feasibility of renewable energy hydrogen production in the context of hydrogen refueling stations, especially photovoltaic hydrogen production, which is applied to hydrogen refueling stations (hereinafter referred to "photovoltaic hydrogen refueling stations"). This paper takes a hydrogen refueling station in Shanghai with a supply capacity of 500 kg/day as the research object. Based on a characteristic analysis of the hydrogen demand of the hydrogen refueling station throughout the day, this paper studies and analyzes the system configuration, operation strategy, environmental effects, and economics of the photovoltaic hydrogen refueling station. It is estimated that when the hydrogen price is no less than 6.23 USD, the photovoltaic hydrogen refueling station has good economic benefits. Additionally, compared with the conventional hydrogen refueling station, it can reduce carbon emissions by approximately 1237.28 tons per year, with good environmental benefits. [ABSTRACT FROM AUTHOR]

To solve the problems of low utilization of biomass and uncertainty and intermittency of wind power (WP) in rural winter, an interval optimization model of a rural integrated energy system with biogas fermentation and electrolytic hydrogen production is constructed in this paper. Firstly, a biogas fermentation kinetic model and a biogas hydrogen blending model are developed. Secondly, the interval number is used to describe the uncertainty of WP, and an interval optimization scheduling model is developed to minimize daily operating cost. Finally, a rural integrated energy system in Northeast China is taken as an example, and a sensitivity analysis of electricity price, gas production, and biomass price is conducted. The simulation results show that the proposed strategy can significantly reduce the wind abandonment rate and improve the economy by 3.8–22.3% compared with conventional energy storage under optimal dispatch. [ABSTRACT FROM AUTHOR]

This paper addresses the problem of hydrogen generation from hydrocarbon gases using Steam Methane Reforming (SMR) with byproduct CO2 injected into and stored in a partially depleted oil reservoir. It focuses on the reservoir aspects of the problem using numerical simulation of the processes. To this aim, a numerical model of a real oil reservoir was constructed and calibrated based on its 30-year production history. An algorithm was developed to quantify the CO2 amount from the SMR process as well as from the produced fluids, and optionally, from external sources. Multiple simulation forecasts were performed for oil and gas production from the reservoir, hydrogen generation, and concomitant injection of the byproduct CO2 back to the same reservoir. EOR from miscible oil displacement was found to occur in the reservoir. Various scenarios of the forecasts confirmed the effectiveness of the adopted strategy for the same source of hydrocarbons and CO2 sink. Detailed simulation results are discussed, and both the advantages and drawbacks of the proposed approach for blue hydrogen generation are concluded. In particular, the question of reservoir fluid balance was emphasized, and its consequences were presented. The presented technology, using CO2 from hydrogen production and other sources to increase oil production, also has a significant impact on the protection of the natural environment via the elimination of CO2 emission to the atmosphere with concomitant production of H2. [ABSTRACT FROM AUTHOR]

To reach climate neutrality by 2050, a goal that the European Union set itself, it is necessary to change and modify the whole EU's energy system through deep decarbonization and reduction of greenhouse-gas emissions. The study presents a current insight into the global energy-transition pathway based on the hydrogen energy industry chain. The paper provides a critical analysis of the role of clean hydrogen based on renewable energy sources (green hydrogen) and fossil-fuels-based hydrogen (blue hydrogen) in the development of a new hydrogen-based economy and the reduction of greenhouse-gas emissions. The actual status, costs, future directions, and recommendations for low-carbon hydrogen development and commercial deployment are addressed. Additionally, the integration of hydrogen production with CCUS technologies is presented. [ABSTRACT FROM AUTHOR]

Hydrogen from natural gas reforming can be produced efficiently with a high CO2 capture rate. This can be achieved through oxygen-blown autothermal reforming as the core technology, combined with pressure-swing adsorption for hydrogen purification and refrigeration-based tail gas separation for CO2 capture and recirculation of residual hydrogen, carbon monoxide, and methane. The low-temperature tail gas separation section is presented in detail. The main objective of the paper is to study and quantify the exergy efficiency of this separation process in detail. To achieve this, a detailed exergy analysis is conducted. The irreversibilities in 42 different process components are quantified. In order to provide transparent verification of the consistency of exergy calculations, the total irreversibility rate is calculated by two independent approaches: Through the bottom-up approach, all individual irreversibilities are added to obtain the total irreversibility rate. Through the top-down approach, the total irreversibility rate is calculated solely by the exergy flows crossing the control volume boundaries. The consistency is verified as the comparison of results obtained by the two methods shows a relative deviation of 4 · 10 − 7 . The exergy efficiency of the CO2 capture process is calculated, based on two different definitions. Both methods give a baseline exergy efficiency of 58.38%, which indicates a high degree of exergy utilisation in the process. [ABSTRACT FROM AUTHOR]

This research delineates a pivotal advancement in the domain of sustainable energy systems, with a focused emphasis on the integration of renewable energy sources—predominantly wind and solar power—into the hydrogen production paradigm. At the core of this scientific endeavor is the formulation and implementation of a deep-learning-based framework for short-term localized weather forecasting, specifically designed to enhance the efficiency of hydrogen production derived from renewable energy sources. The study presents a comprehensive evaluation of the efficacy of fully connected neural networks (FCNs) and convolutional neural networks (CNNs) within the realm of deep learning, aimed at refining the accuracy of renewable energy forecasts. These methodologies have demonstrated remarkable proficiency in navigating the inherent complexities and variabilities associated with renewable energy systems, thereby significantly improving the reliability and precision of predictions pertaining to energy output. The cornerstone of this investigation is the deployment of an artificial intelligence (AI)-driven weather forecasting system, which meticulously analyzes data procured from 25 distinct weather monitoring stations across Latvia. This system is specifically tailored to deliver short-term (1 h ahead) forecasts, employing a comprehensive sensor fusion approach to accurately predicting wind and solar power outputs. A major finding of this research is the achievement of a mean squared error (MSE) of 1.36 in the forecasting model, underscoring the potential of this approach in optimizing renewable energy utilization for hydrogen production. Furthermore, the paper elucidates the construction of the forecasting model, revealing that the integration of sensor fusion significantly enhances the model's predictive capabilities by leveraging data from multiple sources to generate a more accurate and robust forecast. The entire codebase developed during this research endeavor has been made available on an open access GIT server. [ABSTRACT FROM AUTHOR]

In this paper, IEC 61511 was used to evaluate the hazards and risks associated with the continuous operation of the hydrolysis reactor system in the copper-chlorine thermochemical hydrogen production cycle, with a specific focus on the application of automated active safety systems and safety integrated systems. The analysis presented herein was performed using a speculative but representative hydrolysis piping and instrumentation diagram (P&ID) for the hydrolysis reaction, which was based on currently published systems as well as experience with experimental hydrolysis reactors. This analysis was then used to inform the design of a set of automated safety systems that provide the redundant operation of critical devices and can bring the hydrolysis to a safe shutdown state if needed. [ABSTRACT FROM AUTHOR]

Nowadays, one of the most important areas in refining the energy sector in the developed countries is the transition to environmentally friendly technologies, and hydrogen energy production is the most promising of them. In this rapidly advancing area, significant progress in creating new technologies for hydrogen fuel generation, transportation, storage, and consumption has been recently observed, while a fast-growing number of research papers and implemented commercial projects related to hydrogen makes it necessary to give their general review. In particular, the combination of the latest achievements in this area is of particular interest with a view to analyzing the possibility of creating hydrogen fuel supply chains. This paper presents an analytical review of existing methods of hydrogen production, storage, and transportation, including their key economic and energy-related characteristics, and proposes an approach to the creation, analysis, and optimization of hydrogen supply chains. A mathematical model has been developed to determine the cost of hydrogen, taking into account the supply chain, including production, transport and storage. Based on the results of modeling in the given scenario conditions for 2030, 2040 and 2050, promising hydrogen supply chains have been established. Under the various scenario conditions, hydrogen production by 2050 is most preferable by the method of steam conversion of methane with a cost of 8.85 USD/kg H2. However, due to the environmental effect, electrolysis also remains a promising technology with a cost of hydrogen produced of 17.84 USD/kg. [ABSTRACT FROM AUTHOR]

Rapid industrialization is consuming too much energy, and non-renewable energy resources are currently supplying the world's majority of energy requirements. As a result, the global energy mix is being pushed towards renewable and sustainable energy sources by the world's future energy plan and climate change. Thus, hydrogen has been suggested as a potential energy source for sustainable development. Currently, the production of hydrogen from fossil fuels is dominant in the world and its utilization is increasing daily. As discussed in the paper, a large amount of hydrogen is used in rocket engines, oil refining, ammonia production, and many other processes. This paper also analyzes the environmental impacts of hydrogen utilization in various applications such as iron and steel production, rocket engines, ammonia production, and hydrogenation. It is predicted that all of our fossil fuels will run out soon if we continue to consume them at our current pace of consumption. Hydrogen is only ecologically friendly when it is produced from renewable energy. Therefore, a transition towards hydrogen production from renewable energy resources such as solar, geothermal, and wind is necessary. However, many things need to be achieved before we can transition from a fossil-fuel-driven economy to one based on renewable energy. [ABSTRACT FROM AUTHOR]

The paper provides an economic model for the assessment of hydrogen production at the site of an existing thermal power plant, which is then integrated into the existing gas grid. The model uses projections of electricity prices, natural gas prices, and CO2 prices, as well as estimates of the cost of building a power-to-gas system for a 25-year period. The objective of this research is to calculate the yellow hydrogen production price for each lifetime year of the Power-to-gas system to evaluate yellow hydrogen competitiveness compared to the fossil alternatives. We test if an incentive scheme is needed to make this technology economically viable. The research also provides several sensitivity scenarios of electricity, natural gas, and CO2 price changes. Our research results clearly prove that yellow hydrogen is not yet competitive with fossil alternatives and needs incentive mechanisms for the time being. At given natural gas and CO2 prices, the incentive for hydrogen production needs to be 52.90 EUR/MWh in 2025 and 36.18 EUR/MWh in 2050. However, the role of hydrogen in the green transition could be very important as it provides ancillary services and balances energy sources in the power system. [ABSTRACT FROM AUTHOR]

Hydrogen is widely considered as the fuel of the future. Due to the challenges present during hydrogen production using conventional processes and technologies, additional methods must be considered, like the use of microorganisms. One of the most promising technologies is dark fermentation, a process where microorganisms are utilized to produce hydrogen from biomass. The paper provides a comprehensive overview of the biological processes of hydrogen production, specifically emphasizing the dark fermentation process. This kind of fermentation involves bacteria, such as Clostridium and Enterobacterium, to produce hydrogen from organic waste. Synthetic microbial consortia are also discussed for hydrogen production from different types of biomasses, including lignocellulosic biomass, which includes all biomass composed of lignin and (hemi)cellulose, sugar-rich waste waters, and others. The use of genetic engineering to improve the fermentation properties of selected microorganisms is also considered. Finally, the paper covers the important aspect of hydrogen management, including storage, transport, and economics. [ABSTRACT FROM AUTHOR]

Hydrogen is known to be the carbon-neutral alternative energy carrier with the highest energy density. Currently, more than 95% of hydrogen production technologies rely on fossil fuels, resulting in greenhouse gas emissions. Water electrolysis is one of the most widely used technologies for hydrogen generation. Nuclear power, a renewable energy source, can provide the heat needed for the process of steam electrolysis for clean hydrogen production. This review paper analyses the recent progress in hydrogen generation via high-temperature steam electrolysis through solid oxide electrolysis cells using nuclear thermal energy. Protons and oxygen-ions conducting solid oxide electrolysis processes are discussed in this paper. The scope of this review report covers a broad range, including the recent advances in material development for each component (i.e., hydrogen electrode, oxygen electrode, electrolyte, interconnect, and sealant), degradation mechanisms, and countermeasures to mitigate them. [ABSTRACT FROM AUTHOR]

The integration of renewable energy sources is crucial for achieving sustainability and environmental preservation. However, their intermittent nature poses challenges to electrical system stability, requiring robust integration strategies. Microgrids emerge as a flexible solution, but their successful deployment requires meticulous planning and intelligent operation to overcome these challenges. This paper presents the development of a reduced-scale laboratory dedicated to researching both hardware and software solutions for intelligent microgrid management. The laboratory was designed to incorporate key components that are becoming increasingly important in the present microgrid context, including renewable energy generation, storage systems, electrolyzers for hydrogen production, and combined heat and power sources. While some equipment consists of commercial models, the battery bank, converter, and supervisory systems were custom-designed to meet the specific requirements of the laboratory. The laboratory has proven itself as a robust tool for conducting studies on microgrids, effectively incorporating essential components, addressing pertinent system issues, and allowing for several tests on converting control algorithms. [ABSTRACT FROM AUTHOR]

The imperative to achieve a climate-neutral industry necessitates CO2-free alternatives for H2 production. Recent developments suggest that plasma technology holds promise in this regard. This study investigates H2 production by methane pyrolysis using a lab-scale plasma furnace, with the primary objective of achieving a high H2 yield through continuous production. The plasma furnace features a DC-transferred thermal plasma arc system. The plasma gas comprises Ar and CH4, introduced into the reaction zone through the graphite hollow cathode. The off-gas is channeled for further analysis, while the plasma arc is recorded by a camera installed on the top lid. Results showcase a high H2 yield in the range of up to 100%. A stable process is facilitated by a higher power and lower CH4 input, contributing to a higher H2 yield in the end. Conversely, an increased gas flow results in a shorter gas residence time, reducing H2 yield. The images of the plasma arc zone vividly depict the formation and growth of carbon, leading to disruptive interruptions in the arc, hence declining efficiency. The produced solid carbon exhibits high purity with a fluffy and fine structure. This paper concludes that further optimization and development of the process are essential to achieve stable continuous operation with a high utilization degree. [ABSTRACT FROM AUTHOR]

Solar hydrogen production technology is a key technology for building a clean, low-carbon, safe, and efficient energy system. At present, the intermittency and volatility of renewable energy have caused a lot of "wind and light". By combining renewable energy with electrolytic water technology to produce high-purity hydrogen and oxygen, which can be converted into electricity, the utilization rate of renewable energy can be effectively improved, while helping to improve the solar hydrogen production system. This paper summarizes and analyzes the research status and development direction of solar hydrogen production technology from three aspects. Energy supply mode: the role of solar PV systems and PT systems in this technology is analyzed. System control: the key technology and system structure of different types of electrolytic cells are introduced in detail. System economy: the economy and improvement measures of electrolytic cells are analyzed from the perspectives of cost, consumption, efficiency, and durability. Finally, the development prospects of solar hydrogen production systems in China are summarized and anticipated. This article reviews the current research status of photovoltaic-photothermal coupled electrolysis cell systems, fills the current research gap, and provides theoretical reference for the further development of solar hydrogen production systems. [ABSTRACT FROM AUTHOR]

Nowadays, with the need for clean and sustainable energy at its historical peak, new equipment, strategies, and methods have to be developed to reduce environmental pollution. Drastic steps and measures have already been taken on a global scale. Renewable energy sources (RESs) are being installed with a growing rhythm in the power grids. Such installations and operations in power systems must also be economically viable over time to attract more investors, thus creating a cycle where green energy, e.g., green hydrogen production will be both environmentally friendly and economically beneficial. This work presents a management method for assessing wind–solar–hydrogen (H2) energy systems. To optimize component sizing and calculate the cost of the produced H2, the basic procedure of the whole management method includes chronological simulations and economic calculations. The proposed system consists of a wind turbine (WT), a photovoltaic (PV) unit, an electrolyzer, a compressor, a storage tank, a fuel cell (FC), and various power converters. The paper presents a case study of green hydrogen production on Sifnos Island in Greece through RES, together with a scenario where hydrogen vehicle consumption and RES production are higher during the summer months. Hydrogen stations represent H2 demand. The proposed system is connected to the main power grid of the island to cover the load demand if the RES cannot do this. This study also includes a cost analysis due to the high investment costs. The levelized cost of energy (LCOE) and the cost of the produced H2 are calculated, and some future simulations correlated with the main costs of the components of the proposed system are pointed out. The MATLAB language is used for all simulations. [ABSTRACT FROM AUTHOR]

This review article provides a comprehensive analysis of the hydrogen landscape, outlining the imperative for enhanced hydrogen production, implementation, and utilisation. It places the question of how to accelerate hydrogen adoption within the broader context of sustainable energy transitions and international commitments to reduce carbon emissions. It discusses influencing factors and policies for best practices in hydrogen energy application. Through an in-depth exploration of key factors affecting hydrogen implementation, this study provides insights into the complex interplay of both technical and logistical factors. It also discusses the challenges of planning, constructing infrastructure, and overcoming geographical constraints in the transition to hydrogen-based energy systems. The drive to achieve net-zero carbon emissions is contingent on accelerating clean hydrogen development, with blue and green hydrogen poised to complement traditional fuels. Public–private partnerships are emerging as catalysts for the commercialisation of hydrogen and fuel-cell technologies, fostering hydrogen demonstration projects worldwide. The anticipated integration of clean hydrogen into various sectors in the coming years signifies its importance as a complementary energy source, although specific applications across industries remain undefined. The paper provides a good reference on the gradual integration of hydrogen into the energy landscape, marking a significant step forward toward a cleaner, greener future. [ABSTRACT FROM AUTHOR]

The present study is focused on improving the technology for deep oil sludge processing by pyrolysis methods, considered to be the most promising technology for their environmentally friendly utilization, in which a significant yield of fuel products is expected. The technology developed by the authors of this study is a two-stage process. The first stage, pyrolysis of oil sludge, was investigated in previous papers. A significant yield of non-condensable gases was obtained. This paper presents a study of the second stage of complex deep processing technology—pyrolysis of non-condensable gases (purified propane) using a stirrer with the help of the developed experimental setup. The expected benefit of using the stirrer is improved heat transfer due to circumferential and radial-axial circulation of the gas flow. The effect of a stirrer on the yield of final target decomposition products—H2-containing mixtures and H2 generated during non-catalytic (medium-temperature) and catalytic pyrolysis of non-condensable gases obtained by pyrolysis of oil sludge are estimated. Ni catalyst was used for catalytic pyrolysis. The study shows that the application of the stirrer leads to increasing in H2-containing mixtures and H2 concentrations. In particular, during the whole reaction time (10 h), the average H2 concentration in pyrolysis gas during catalytic pyrolysis increased by ~5.3%. In this case, the optimum reaction time to produce H2 was 4 h. The peak H2 concentration in the pyrolysis gas at reaction temperature 590 ± 10 °C was: 66.5 vol. % with the stirrer versus 62 vol. % without the stirrer with an error of ±0.4 %. A further increase in reaction time is cost-effective in order to obtain H2-containing mixtures. [ABSTRACT FROM AUTHOR]

Hydrogen production modules (HPMs) play a crucial role in harnessing abundant photovoltaic power by producing and supplying hydrogen to factories, resulting in significant operational cost reductions and efficient utilization of the photovoltaic panel output. However, the output of photovoltaic power is stochastic, which will affect the revenue of investing in an HPM. This paper presents a comprehensive analysis of HPMs, starting with the modeling of their operational process and investigating their influence on distribution system operations. Building upon these discussions, a deterministic optimization model is established to address the corresponding challenges. Furthermore, a two-stage stochastic planning model is proposed to determine optimal locations and sizes of HPMs in distribution systems, accounting for uncertainties. The objective of the two-stage stochastic planning model is to minimize the distribution system's operational costs plus the investment costs of the HPM subject to power flow constraints. To tackle the stochastic nature of photovoltaic power, a data-driven algorithm is introduced to cluster historical data into representative scenarios, effectively reducing the planning model's scale. To ensure an efficient solution, a Benders' decomposition-based algorithm is proposed, which is an iterative method with a fast convergence speed. The proposed model and algorithms are validated using a widely utilized IEEE 33-bus system through numerical experiments, demonstrating the optimality of the HPM plan generated by the algorithm. The proposed model and algorithms offer an effective approach for decision-makers in managing uncertainties and optimizing HPM deployment, paving the way for sustainable and efficient energy solutions in distribution systems. Sensitivity analysis verifies the optimality of the HPM's siting and sizing obtained by the proposed algorithm, which also reveals immense economic and environmental benefits. [ABSTRACT FROM AUTHOR]

In this paper, we investigate the optimization of an oxygen removal system for water electrolysis plants because high oxygen concentrations can be dangerous and compromise the quality of the hydrogen produced. The design of an oxygen removal system was investigated using numerical analysis. The results showed that the diameter of the chamber had a significant effect on the oxygen removal efficiency, and a diameter twice the size of the gas inlet was found to be optimal. The porosity of the catalyst layer also played a crucial role in the efficiency, with a lower porosity resulting in higher removal rates. Additionally, the optimal chamber length was found to be 76.8 D to achieve an oxygen mole fraction of 2.4 ppm after the chamber, which satisfied the safety criterion of 4.0 ppm. These results can aid in the design of oxygen removal systems for water electrolysis plants, providing a more efficient and safer operation. [ABSTRACT FROM AUTHOR]

This paper aims to perform a systematic review, with a bibliometric approach, of the techno-economic evaluation studies of hydrogen production. To achieve this objective, a comprehensive outline of hydrogen production processes from fossil and renewable sources is presented. The results reveal that electrolysis, classified as water splitting, is the most investigated process in the literature since it contributes to a reduction in greenhouse gas emissions and presents other advantages, such as maturity and applicability, energy efficiency, flexibility, and energy storage potential. In addition, the processes of gasification, classified as thermochemical, and steam reforming, classified as catalytic reforming, are worth mentioning. Regarding the biological category, there is a balance between research on photo fermentation and dark fermentation. The literature on the techno-economic evaluation of hydrogen production highlights significant gaps, including a scarcity of comprehensive studies, a lack of emphasis on commercial viability, an absence of sensitivity analysis, and the need for comparative analyses between production technologies. [ABSTRACT FROM AUTHOR]

This research investigated the suitability of air-to-water generator (AWG) technology to address one of the main concerns in green hydrogen production, namely water supply. This study specifically addresses water quality and energy sustainability issues, which are crucial research questions when AWG technology is intended for electrolysis. To this scope, a reasoned summary of the main findings related to atmospheric water quality has been provided. Moreover, several experimental chemical analyses specifically focused on meeting electrolysis process requirements, on water produced using a real integrated AWG system equipped with certified materials for food contact, were discussed. To assess the energy sustainability of AWGs in green hydrogen production, a case study was presented regarding an electrolyzer plant intended to serve as energy storage for a 2 MW photovoltaic field on Iriomote Island. The integrated AWG, used for the water quality analyses, was studied in order to determine its performance in the specific island climate conditions. The production exceeded the needs of the electrolyzer; thus, the overproduction was considered for the panels cleaning due to the high purity of the water. Due to such an operation, the efficiency recovery was more than enough to cover the AWG energy consumption. This paper, on the basis of the quantity results, provides the first answers to the said research questions concerning water quality and energy consumption, establishing the potential of AWG as a viable solution for addressing water scarcity, and enhancing the sustainability of electrolysis processes in green hydrogen production. [ABSTRACT FROM AUTHOR]

The main purpose of this paper is the techno-economic analysis of hydrogen production from biogas via steam reforming in a pilot plant. Process flow modeling based on mass and energy balance is used to estimate the total equipment purchase and operating costs of hydrogen production. The pilot plant installation produced 250.67 kg/h hydrogen from 1260 kg/h biomethane obtained after purification of 4208 m3/h biogas using a heat and mass integration process. Despite the high investment cost, the plant shows a great potential for biomethane reduction and conversion to hydrogen, an attractive economic path with ecological possibilities. The conversion of waste into hydrogen is a possibility of increasing importance in the global energy economy. In the future, such a plant will be expanded with a CO2 reduction module to increase economic efficiency and further reduce greenhouse gases in an economically viable manner. [ABSTRACT FROM AUTHOR]

To address the severity of the wind and light abandonment problem and the economics of hydrogen energy production and operation, this paper explores the problem of multi-cycle resource allocation optimization of hydrogen storage systems for coal–wind–solar power generation. In view of the seriousness of the problem of abandoning wind and photovoltaic power and the economy of hydrogen production and operation, the node selection and scale setting issues for hydrogen production and storage, as well as decision-making problems such as the capacity of new transmission lines and new pipelines and route planning, are studied. This research takes the satisfaction of energy supply as the basic constraint and constructs a multi-cycle resource allocation optimization model for an integrated energy system, aiming to achieve the maximum benefit of the whole system. Using data from Inner Mongolia, where wind abandonment and power limitation are severe, and Beijing and Shanxi provinces, where hydrogen demand is high, this paper analyzes the benefits of the hydrogen storage system for coal–wind–solar power generation, and explores the impact of national subsidy policies and technological advances on system economics. [ABSTRACT FROM AUTHOR]

Hydrogen refueling stations (HRSs) are critical for the popularity of hydrogen vehicles (fuel cell electric vehicles—FCEVs). However, due to high installation investment and operating costs, the proliferation of HRSs is difficult. This paper studies HRSs with on-site electrolytic production and hydrogen storage devices and proposes an optimization method to minimize the total costs including both installation investment and operating costs (OPT-ISL method). Moreover, to acquire the optimization constraints of hydrogen demand, this paper creatively develops a refueling behavior simulation method for different kinds of FCEVs and proposes a hydrogen-demand estimation model to forecast the demand with hourly intervals for HRS. The Jensen–Shannon divergence is applied to verify the accuracy of the hydrogen-demand estimation. The result: 0.029 is much smaller than that of the estimation method in reference. Based on the estimation results and peak-valley prices of electricity from the grid, a daily hydrogen generation plan is obtained, as well as the optimal capacities of electrolyzers and storage devices. As for the whole costs, compared with previous configuration methods that only consider investment costs or operating costs, the proposed OPT-ISL method has the least, 8.1 and 10.5% less, respectively. Moreover, the proposed OPT-ISL method shortens the break-even time for HRS from 11.1 years to 7.8 years, a decrease of 29.7%, so that the HRS could recover its costs in less time. [ABSTRACT FROM AUTHOR]

This paper aims to review existing energy-sector and hydrogen-energy-related legal, policy, and strategy documents in the ECOWAS region. To achieve this aim, current renewable-energy-related laws, acts of parliament, executive orders, presidential decrees, administrative orders, and memoranda were analyzed. The study shows that ECOWAS countries have strived to design consistent legal instruments regarding renewable energy in developing comprehensive legislation and bylaws to consolidate it and to encourage investments in renewable energy. Despite all these countries having a legislative basis for regulating renewable energy, there are still weaknesses that revolve around the law and policy regarding its possible application in green hydrogen production and use. The central conclusion of this review paper is that ECOWAS member states presently have no official hydrogen policies nor bylaws in place. The hydrogen rise presents a challenge and opportunity for members to play an important role in the fast-growing global hydrogen market. Therefore, these countries need to reform their regulatory frameworks and align their policies by introducing green hydrogen production in order to accomplish their green economy transition for the future and to boost the continent's sustainable development. [ABSTRACT FROM AUTHOR]

Disputed supply chains, inappropriate weather and low investment, followed by the Russian invasion of Ukraine, has led to a phenomenal energy crisis, especially in the Horn of Africa. Accordingly, proposing eco-friendly and sustainable solutions to diversify the access of electricity in the Republic of Djibouti, which has no conventional energy resources and is completely energy-dependent on its neighboring countries, has become a must. Therefore, the implementation of sustainable renewable and energy storage systems is nationally prioritized. This paper deals, for the first time, with the exploitation of such an affordable and carbon-free resource to produce hydrogen from wind energy in the rural areas of Nagad and Bara Wein in Djibouti. The production of hydrogen and the relevant CO2 emission reduction using different De Wind D6, Vestas and Nordex wind turbines are displayed while using Alkaline and Proton Exchange Membrane (PEM) electrolyzers. The Bara Wein and Nagad sites had a monthly wind speed above 7 m/s. From the results, the Nordex turbine accompanied with the alkaline electrolyzer provides the most affordable electricity production, approximately 0.0032 $/kWh for both sites; this cost is about one per hundred the actual imported hydroelectric energy price. Through the ecological analysis, the Nordex turbine is the most suitable wind turbine, with a CO2 emission reduction of 363.58 tons for Bara Wein compared to 228.76 tons for Nagad. While integrating the initial cost of wind turbine implementation in the capital investment, the mass and the levelized cost of the produced green hydrogen are estimated as (29.68 tons and 11.48 $/kg) for Bara Wein with corresponding values of (18.68 tons and 18.25 $/kg) for Nagad. [ABSTRACT FROM AUTHOR]

Australia has clear aspirations to become a major global exporter of hydrogen as a replacement for fossil fuels and as part of the drive to reduce CO2 emissions, as set out in the National Hydrogen Strategy released in 2019 jointly by the federal and state governments. In 2021, the Australian Energy Market Operator specified a grid forecast scenario for the first time entitled "hydrogen superpower". Not only does Australia hope to capitalise on the emerging demand for zero-carbon hydrogen in places like Japan and South Korea by establishing a new export industry, but it also needs to mitigate the built-in carbon risk of its export revenue from coal and LNG as major customers, such as Japan and South Korea, move to decarbonise their energy systems. This places hydrogen at the nexus of energy, climate change mitigation and economic growth, with implications for energy security. Much of the published literature on this topic concentrates on the details of what being a major hydrogen exporter will look like and what steps will need to be taken to achieve it. However, there appears to be a gap in the study of the implications for Australia's domestic energy system in terms of energy security and export economic vulnerability. The objective of this paper is to develop a conceptual framework for the implications of becoming a major hydrogen exporter on Australia's energy system. Various green hydrogen export scenarios for Australia were compared, and the most recent and comprehensive was selected as the basis for further examination for domestic energy system impacts. In this scenario, 248.5 GW of new renewable electricity generation capacity was estimated to be required by 2050 to produce the additional 867 TWh required for an electrolyser output of 2088 PJ of green hydrogen for export, which will comprise 55.9% of Australia's total electricity demand at that time. The characteristics of comparative export-oriented resources and their interactions with the domestic economy and energy system are then examined through the lens of the resource curse hypothesis, and the LNG and aluminium industries. These existing resource export frameworks are reviewed for applicability of specific factors to export-oriented green hydrogen production, with applicable factors then compiled into a novel conceptual framework for exporter domestic implications from large-scale exports of green hydrogen. The green hydrogen export superpower (2050) scenario is then quantitatively assessed using the established indicators for energy exporter vulnerability and domestic energy security, comparing it to Australia's 2019 energy exports profile. This assessment finds that in almost all factors, exporter vulnerability is reduced, and domestic energy security is enhanced by the transition from fossil fuel exports to green hydrogen, with the exception of an increase in exposure of the domestic energy system to international market forces. [ABSTRACT FROM AUTHOR]

This work aims to explain aluminum hydrolysis reaction kinetics based on a properly chosen theoretical model with machined aluminum waste chips as well as alkali solutions up to 1M as a promoter and to estimate the overall reaction profit. The purpose of this work is to assess the optimal alkali concentration in the production of small- and medium-scale green hydrogen. To obtain results with better accuracy, we worked with flat Al waste chips, because a flat surface is preferable to maximally increase the time for the created hydrogen bubbles to reach the critical gas pressure. Describing the reaction kinetics, a flat shape allows for the use of a planar one-dimensional shrinking core model instead of a much more complicated polydisperse spheric shrinking core model. We analyzed the surface chemical reaction and mass transfer rate steps to obtain the first-order rate constant for the surface reaction and the diffusion coefficient of the aqueous reactant in the byproduct layer, respectively. We noted that measurements of the diffusion coefficient in the byproduct layer performed and discussed in this paper are rare to find in publications at alkali concentrations below 1M. With our reactor, we achieved a H2 yield of 1145 mL per 1 g of Al with 1M NaOH, which is 92% of the theoretical maximum. In the estimation of profit, the authors' novelty is in paying great attention to the loss in alkali and finding a crucial dependence on its price. Nevertheless, in terms of consumed and originated materials for sale, the conversion of aluminum waste material into green hydrogen with properly chosen reaction parameters has positive profit even when consuming an alkali of a chemical grade. [ABSTRACT FROM AUTHOR]

The global trade and transportation sectors heavily rely on the maritime industry. Still, its dependence on fossil energy sources poses significant environmental challenges and leads to unstable fuel prices that affect the cost of goods transported by sea. This paper aims to evaluate the viability of seaports as energy-intensive entities and explore the feasibility of implementing a Nuclear-Renewable Hybrid Energy System (NRHES). The study presents a case study of the Tanjung Priok Port in Indonesia, focusing on estimating energy consumption, emissions, and the potential impact of carbon taxation on seaport operations. By quantifying these factors, the research provides insights into the energy requirements, environmental effects, and potential costs associated with seaport carbon taxation. A comprehensive analysis of the technical and economic feasibility of implementing an NRHES in the seaport case study is conducted, determining the optimal sizing and composition of components, considering the proportion of nuclear and renewable energy sources. Furthermore, the economic analysis takes into account energy expenses, net present value, cash flow, return on investment, and internal rate of return. The objective of these findings is to provide decision-makers with insights into the advantages and obstacles associated with implementing an NRHES, ultimately contributing to a cleaner and more sustainable future for the maritime sector. [ABSTRACT FROM AUTHOR]

The production of hydrogen as both chemical feed and energy carrier using low-carbon technologies is one of the solutions to reach net-zero emissions. This paper, firstly, reviews the publications on the life-cycle assessment of photovoltaic (PV)-based hydrogen production focused on the carbon footprint. Secondly, it updates the global warming potential (GWP) values of this H2 production process considering the state-of-the-art PV panels for installation in Italy. In the literature, H2 produced in Europe and the rest of the world results in a mean GWP equal to 4.83 and 3.82 kg CO2 eq./kg H2, respectively, in which PV systems contribute the highest share. The average efficiency of PV panels assumed in the literature is lower than the current PV modules. Updating the supply chain, efficiency, and manufacturing energy and material flows of PV modules can decrease the GWP value of the H2 produced by nearly 60% (1.75 kg CO2 eq./kg H2, with use of alkaline electrolyzer) in the Italian context, which can be further reduced with advancements in PV panels or electrolysis efficiency. The study proves that advancement in the PV industry and additional savings in the electrolyzer's electrical demand can further decrease the carbon footprint of PV-based H2. [ABSTRACT FROM AUTHOR]

Green hydrogen is gaining increasing attention as a key component of the global energy transition towards a more sustainable industry. Chile, with its vast renewable energy potential, is well positioned to become a major producer and exporter of green hydrogen. In this context, this paper explores the prospects for green hydrogen production and use in Chile. The perspectives presented in this study are primarily based on a compilation of government reports and data from the scientific literature, which primarily offer a theoretical perspective on the efficiency and cost of hydrogen production. To address the need for experimental data, an ongoing experimental project was initiated in March 2023. This project aims to assess the efficiency of hydrogen production and consumption in the Atacama Desert through the deployment of a mobile on-site laboratory for hydrogen generation. The facility is mainly composed by solar panels, electrolyzers, fuel cells, and a battery bank, and it moves through the Atacama Desert in Chile at different altitudes, from the sea level, to measure the efficiency of hydrogen generation through the energy approach. The challenges and opportunities in Chile for developing a robust green hydrogen economy are also analyzed. According to the results, Chile has remarkable renewable energy resources, particularly in solar and wind power, that could be harnessed to produce green hydrogen. Chile has also established a supportive policy framework that promotes the development of renewable energy and the adoption of green hydrogen technologies. However, there are challenges that need to be addressed, such as the high capital costs of green hydrogen production and the need for supportive infrastructure. Despite these challenges, we argue that Chile has the potential to become a leading producer and exporter of green hydrogen or derivatives such as ammonia or methanol. The country's strategic location, political stability, and strong commitment to renewable energy provide a favorable environment for the development of a green hydrogen industry. The growing demand for clean energy and the increasing interest in decarbonization present significant opportunities for Chile to capitalize on its renewable energy resources and become a major player in the global green hydrogen market. [ABSTRACT FROM AUTHOR]

Using traditional Chinese medicine residue biomass as the raw material and industrial limestone as a carbon absorbent, this paper investigates the production of hydrogen-rich synthesis gas in a pilot-scale calcium looping dual fluidized bed (DFB) system. The study focuses on analyzing the distribution characteristics of temperature and pressure, as well as the operation and control methods of the DFB system. The effects of reaction temperature, material layer height (residence time), water vapor/biomass ratio (S/B), and calcium/carbon molar ratio (Ca/C) on gasification products are examined. The experimental results demonstrate that as the temperature (600–700 °C), S/B ratio (0.5–1.5), Ca/C ratio (0–0.6), and other parameters increase, the gas composition shows a gradual increase in the volume content of H2, a gradual decrease in the volume content of CO, and an initial increase and subsequent decrease in the volume content of CH4. Within the range of operating conditions in this study, the optimal conditions for producing hydrogen-rich gas are 700 °C, an S/B ratio of 1.5, and a Ca/C ratio of 0.6. Furthermore, increasing the height of the material layer in the gasification furnace (residence time) enhances the absorption of CO2 by the calcium absorbents, thus promoting an increase in the volume content of H2 and the carbon conversion rate in the gas. [ABSTRACT FROM AUTHOR]

This paper presents a mathematical programming approach for the strategic planning of hydrogen production from renewable energies and its use in electric power generation in conventional technologies. The proposed approach aims to determine the optimal selection of the different types of technologies, electrolyzers and storage units (energy and hydrogen). The approach considers the implementation of an optimization methodology to select a representative data set that characterizes the total annual demand. The economic objective aims to determine the minimum cost, which is composed of the capital costs in the acquisition of units, operating costs of such units, costs of production and transmission of energy, as well as the cost associated with the emissions generated, which is related to an environmental tax. A specific case study is presented in the Mexican peninsula and the results show that it is possible to produce hydrogen at a minimum sale price of 4200 $/tonH2, with a total cost of $5.1687 × 106 and 2.5243 × 105 tonCO2eq. In addition, the financial break-even point corresponds to a sale price of 6600 $/tonH2. The proposed model determines the trade-offs between the cost and the emissions generated. [ABSTRACT FROM AUTHOR]

Instead of storing the energy produced by photovoltaic panels in batteries for later use to power electric loads, green hydrogen can also be produced and used in transportation, heating, and as a natural gas alternative. Green hydrogen is produced in a process called electrolysis. Generally, the electrolyser can generate hydrogen from a fluctuating power supply such as renewables. However, due to the startup time of the electrolyser and electrolyser degradation accelerated by multiple shutdowns, an idle mode is required. When in idle mode, the electrolyser uses 10% of the rated electrolyser load. An energy management system (EMS) shall be applied, where a storage technology such as a lithium-ion capacitor or lithium-ion battery is used. This paper uses a state-machine EMS of PV microgrid for green hydrogen production and energy storage to manage the hydrogen production during the morning from solar power and in the night using the stored energy in the energy storage, which is sized for different scenarios using a lithium-ion capacitor and lithium-ion battery. The mission profile and life expectancy of the lithium-ion capacitor and lithium-ion battery are evaluated considering the system's local irradiance and temperature conditions in the Australian climate. A tradeoff between storage size and cutoffs of hydrogen production as variables of the cost function is evaluated for different scenarios. The lithium-ion capacitor and lithium-ion battery are compared for each tested scenario for an optimum lifetime. It was found that a lithium-ion battery on average is 140% oversized compared to a lithium-ion capacitor, but a lithium-ion capacitor has a smaller remaining capacity of 80.2% after ten years of operation due to its higher calendar aging, while LiB has 86%. It was also noticed that LiB is more affected by cycling aging while LiC is affected by calendar aging. However, the average internal resistance after 10 years for the lithium-ion capacitor is 264% of the initial internal resistance, while for lithium-ion battery is 346%, making lithium-ion capacitor a better candidate for energy storage if it is used for grid regulation, as it requires maintaining a lower internal resistance over the lifetime of the storage. [ABSTRACT FROM AUTHOR]

There is a significant push to reduce carbon dioxide (CO2) emissions and develop low-cost fuels from renewable sources to replace fossil fuels in applications such as energy production. As a result, CO2 conversion has gained widespread attention as it can reduce the accumulation of CO2 in the atmosphere and produce fuels and valuable industrial chemicals, including carbon monoxide, alcohols, and hydrocarbons. At the same time, finding ways to store energy in batteries or energy carriers such as hydrogen (H2) is essential. Water electrolysis is a powerful technology for producing high-purity H2, with negligible emission of greenhouse gases, and compatibility with renewable energy sources. Additionally, the electrolysis of organic compounds, such as lignin, is a promising method for localised H2 production, as it requires lower cell voltages than conventional water electrolysis. Industrial wastewater can be employed in those organic electrolysis systems due to their high organic content, decreasing industrial pollution through wastewater disposal. Electrocoagulation, indirect electrochemical oxidation, anodic oxidation, and electro-Fenton are effective electrochemical methods for treating industrial wastewater. Furthermore, bioenergy technology possesses a remarkable potential for producing H2 and other value-added chemicals (e.g., methane, formic acid, hydrogen peroxide), along with wastewater treatment. This paper comprehensively reviews these approaches by analysing the literature in the period 2012–2022, pointing out the high potential of using electrolytic cells for energy and environmental applications. [ABSTRACT FROM AUTHOR]

Climate change primarily caused by the greenhouse gases emitted as a result of the consumption of carbon-based fossil fuels is considered one of the biggest challenges that humanity has ever faced. Moreover, the Ukrainian crisis in 2022 has complicated the global energy and food status quo more than ever. The permanency of this multifaceted fragility implies the need for increased efforts to have energy independence and requires long-term solutions without fossil fuels through the use of clean, zero-carbon renewables energies. Hydrogen technologies have a strong potential to emerge as an energy eco-system in its production-storage-distribution-utilization stages, with its synergistic integration with solar-wind-hydraulic-nuclear and other zero-carbon, clean renewable energy resources, and with the existing energy infrastructure. In this paper, we provide a global review of hydrogen energy need, related policies, practices, and state of the art for hydrogen production, transportation, storage, and utilization. [ABSTRACT FROM AUTHOR]

Hydrogen gas (H2) is an energy carrier that does not generate carbon dioxide emissions during combustion, but several processes in use for its production demand high energy inputs associated with fossil fuels and greenhouse emissions. Biological processes, such as dark fermentation (DF), have the potential to remove the dependency on fossil fuels in H2 production. DF is a process that encourages fermentative bacteria to ferment organic substrates to produce H2 as a truly clean energy carrier, but its success depends on removing the presence of competing H2−consuming microorganisms in the inoculum consortia. This paper addresses a strategy to enhance H2 production from different types of substrates by testing inoculum pre-treatment processes to inactivate H2−consuming bacteria, including acid-shock (pH 3), basic-shock (pH 10) and heat-shock (115 °C) methods. Digestate from anaerobic digesters processing sewage sludge was used to produce pre-treated inocula, which were subsequently tested in a batch bio-H2 potential (BHP) test using glucose as a substrate. The results show that heat-shock pre-treatment was the best method, reporting a H2 yield of 191.8 mL-H2/gVS added (the untreated inoculum reported 170.91 mL-H2/gVS added). Glucose conversion data show a high concentration of butyric acid in both treated and untreated inocula during BHP tests, which indicate that the butyrate pathway for H2 production was dominant; shifting this to the formate route could further enhance net H2 production. A standardised inoculum-conditioning method can help to consistently assess the biohydrogen potential of suitable feedstock for DF and maximise H2 yields. [ABSTRACT FROM AUTHOR]

Hydrogen can be considered an innovative fuel that will revolutionize the energy sector and enable even more complete use of the potential of renewable sources. The aim of the paper is to present the challenges faced by companies and economies that will produce and use hydrogen. Thanks to the use of hydrogen in the energy, transport and construction sectors, it will be possible to achieve climate neutrality by 2050. By 2050, global demand for hydrogen will increase to 614 million metric tons a year, and thanks to the use of hydrogen in energy, transport and construction, it will be possible to achieve climate neutrality. Depending on the method of hydrogen production, the processes used and the final effects, several groups can be distinguished, marked with different colors. It is in this area of obtaining friendly hydrogen that innovative possibilities for its production open up. The costs of hydrogen production are also affected by network fees, national tax systems, availability and prices of carbon capture, utilization, and storage installations, energy consumption rates by electrolyzers and transport methods. It is planned that 1 kg of hydrogen will cost USD 1. The study used the desk research method, which made it possible to analyze a huge amount of descriptive data and numerical data. [ABSTRACT FROM AUTHOR]

Hydrogen is emerging as a new energy vector outside of its traditional role and gaining more recognition internationally as a viable fuel route. This review paper offers a crisp analysis of the most recent developments in hydrogen production techniques using conventional and renewable energy sources, in addition to key challenges in the production of Hydrogen. Among the most potential renewable energy sources for hydrogen production are solar and wind. The production of H2 from renewable sources derived from agricultural or other waste streams increases the flexibility and improves the economics of distributed and semi-centralized reforming with little or no net greenhouse gas emissions. Water electrolysis equipment driven by off-grid solar or wind energy can also be employed in remote areas that are away from the grid. Each H2 manufacturing technique has technological challenges. These challenges include feedstock type, conversion efficiency, and the need for the safe integration of H2 production systems with H2 purification and storage technologies. [ABSTRACT FROM AUTHOR]