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Emerging global environmental pollution issues have caused a reduction in coal utilization, leading to an increased research focus on biomass use as an alternative. However, due to the low heat values of biomass, studies in this field are still in progress. Biomass primarily comprises cellulose, hemicellulose, and lignin. To determine the composition of these three components, the measurement methods recommended by TAPPI (Technical Association of the Pulp and Paper Industry) and NREL (National Renewable Energy Laboratory) are typically employed involving equipment such as HPLC. However, these methods are time consuming. In this study, we proposed a model for predicting cellulose, hemicellulose, and lignin contents based on elemental and industrial analyses. A dataset comprising 174 samples was used to develop this model. This was validated using 25 additional samples. The R2P values for cellulose, hemicellulose, and lignin were 0.6104–0.6362, 0.4803–0.5112, and 0.7247–0.7914, respectively; however, the R2CV values obtained from the validation results were 0.7387–0.7837, 0.3280–0.4004, and 0.7427–0.7757, respectively. The optimal models selected for cellulose, lignin, and hemicellulose were C1, L2, and 100-(C1-L2) or H2, respectively. Our predictions for woody and herbaceous biomass, including torrefied samples, should be applied with caution to other biomass types due to the potential accuracy limitations. To enhance the prediction accuracy, future research should broaden the range of biomass types considered and gather more data specifically related to woody and herbaceous biomass. [ABSTRACT FROM AUTHOR]

The efficient utilization of low-cost carbon feedstocks, such as municipal solid waste (MSW), in biorefineries has become increasingly important for reducing GHG emissions and meeting the growing demand for renewable energy sources. However, MSW as a feedstock presents several challenges, including high moisture content, compositional variability, particle size and shape, density, and ash content. To address these challenges, the potential of mechanical dewatering and high-moisture pelleting processes for densifying MSW fractions, such as paper, cardboard, thin plastic, and thick plastic, into low-cost carbon feedstocks with improved handling and conversion properties were investigated. The effect of these preprocessing technologies on the critical quality attributes (CQAs) of the resulting pellets, including bulk density, durability, and size uniformity, were evaluated. The results showed that with these preprocessing technologies, the paper and cardboard fractions could be pelleted at moisture contents over 40% (w.b.) while achieving >99% durability and >300 kg/m3, while the high moisture plastic fractions were not suitable for pelleting. The thick plastic fraction processed in a screw press was shown to remove up to 30% of the moisture content in a single pass. These findings suggest that these mechanical preprocessing technologies can improve the physical properties of low-cost municipal solid waste fractions for biofuels production. [ABSTRACT FROM AUTHOR]

In recent decades, there has been growing interest in the thermal conversion of various alternative fuels, such as biomass and waste-derived fuels. One of the technological solutions for the so-called direct co-combustion of fuels is to create mixtures of various fuels, called mixed secondary fuel. However, mixed secondary fuel has different properties compared to primary fuels. Due to this, by properly selecting the types and proportions of mixtures, it is possible to eliminate their potentially negative impact on both combustion technology and the natural environment. In this paper, we decided to prepare mixed secondary fuel by mixing sunflower husk pellets with RDF (refuse-derived fuel) in a ratio of 1:1 and then analyze the combustion process of the produced fuel in fluidized bed conditions. The results obtained on the basis of the presented research indicate that the mixed secondary fuel eliminated the impact of alkali metal compounds on reducing the melting point of ash and, consequently, on the combustion process of the mixed secondary fuel. An additional benefit is the reduction of emissions of harmful compounds into the atmosphere occurring during the combustion of municipal waste and compliance with the concept of the circular economy. [ABSTRACT FROM AUTHOR]

Reliable heat and power supply are among the basic household needs nowadays. It is especially topical in rural or distant locations that may be cut off from the energy grid due to extreme weather or other events. Nonetheless, the sustainability of our power production systems has to be considered to sustain our planet's long-term abilities to provide energy resources and a viable environment. Renewable energy resources must be prioritized in rural and remote areas, simultaneously strengthening distributed production ability and self-sufficiency. In this context, the use of the Stirling engine for heat to power generation in households, on the scale of small communities, and by using only renewable resources is becoming increasingly topical. Therefore, this research aims to identify the current state-of-the-art for Stirling engine applications using biomass as a renewable energy source, in the context of sustainability and energy security. The paper summarizes the current research tendencies at the household level in the use of biomass-based Stirling engines for renewable heat and power generation in decentralized energy systems. The methodology applied is a structured literature review and content analysis. The research results corroborate the progress towards the use of renewable resources and towards increased energy efficiency because the keyword and overlay analysis showed more frequent publishing in these areas. The content analysis on two more specific sub-directions of interest, i.e., biomass-fuelled Stirling engine use in households and Stirling engine implications on energy security, showed that though research activity in these directions has increased lately, more profound research is needed, especially on aspects of energy security and independence. The content analysis revealed a lack of in-depth analysis on the effects of Stirling engine use on energy security or energy independence, which is suggested as a topical subject for future research. [ABSTRACT FROM AUTHOR]

During biomass combustion in a grate-fired boiler, each particle undergoes a sequence of different reactions, and the phenomena differ from the conversion of a single, thermally thin, particle. Hence, this paper aims to deepen the understanding of biomass conversion processes and provides valuable insights for advancing biomass-based energy systems. Firstly, the weight loss characteristics of the larger particles of eucalyptus, pine, acacia, and olive samples were investigated at different isothermal temperatures in a purpose-built reactor that simulates the devolatilization process in a controllable manner. As opposed to the thermogravimetric analysis using thermally thin particles, it was concluded that all fuels show that the combustion of large particles does not exhibit separate consecutive conversion stages, due to internal diffusion resistance. Furthermore, it was verified that the devolatilization rate depends mainly on the reactor temperature, and, consequently, the mass-loss profile is independent of the biomass type. In addition to these experiments, the composition of the gases over the devolatilization period was analyzed for the main fuel used in power plants, eucalyptus. Once again, a strong correlation to the reactor temperature was observed, with CO2 and CO always being the main devolatilization products. The temperature dependence of both compounds presented an increase from 8 to 13% between 600 and 800 °C for CO, while the CO2 yield only slightly increased from 11 to 12%. These observations were essential to identify the transport phenomena effect and the gaseous products released during the biomass combustion. [ABSTRACT FROM AUTHOR]

Biomass and renewable resources are becoming substitutes for fossil-based resources, providing opportunities for more sustainable environmental management and reductions in environmental damage. This paper studies the prospects for wood pellet production in Kazakhstan through the lens of business model adjustment in a microenterprise in Kazakhstan. This study focuses on answering the following questions: (1) How do microenterprises propose, create, deliver and capture value through business models in the wood industry? (2) What are the opportunities and challenges relating to these business models in the context of wood pellet production in Kazakhstan? Kazakhstan has a high potential for biomass production, providing a particularly interesting case for analysing how microenterprises can tap into this potential to create value. This paper combines an analysis of bioenergy and forestry trends with a qualitative case study. The analysis of the business model is based on Osterwalder's business model canvas. The value proposition of the enterprise studied herein is to provide a local biomass-based alternative to fossil fuels. The overall growth of wood-based industries in Kazakhstan and the national movement towards renewable energy create favourable prospects for microenterprises engaged in the production of wood pellets; however, these industries are also characterised by high institutional and regulatory dependencies. [ABSTRACT FROM AUTHOR]

This paper addresses the challenge of meeting increasing energy needs by assessing the potential of bioenergy as a sustainable resource option in South Central Texas. Available agricultural crop residues suitable for bioenergy production are evaluated from the 21 counties in South Central Texas Regional Water Planning Area (Region L). The residues produced and available for bioenergy are quantified according to the production areas for each field crop and tree area. Residue-to-product ratios of field crops are determined according to crop type and production quantity. Biomass potential of trees is calculated based on tree density and biomass production per tree. The results demonstrate that the potential productions of utilizable agricultural wastes are in the range of 898.7 t kt–1421.39 kt for Region L. The average annual energy potential is estimated at 19.27 PJ, and ranges between 14.36 and 24.18 PJ. The average potential biomass-based electricity production could compensate significant amount of coal-based electricity generated in the Texas and when agricultural wastes are available. [ABSTRACT FROM AUTHOR]

The development of civilization is related to an increase in energy demand, while its production is still based mainly on fossil fuels. The release of carbon into the environment, which disturbs the balance of the global system, is the consequence of using these fuels. One possible way to reduce the carbon footprint of the energy sector is the widespread use of cover crops' biomass for energy production. The aim of this paper is to critically review the knowledge on the dissemination of catch and cover crops' cultivation in different regions of the world, and the yield, chemical composition and biomethane potential of their biomass. Additionally, the environmental benefits, as well as the challenges and opportunities associated with this biomass use in the energy sector, are considered. The review showed that the aboveground biomass of cover and catch crops is a valuable source for the production of bioenergy in biogas plants. However, the key role of these crops is to prevent soil degradation. Therefore, changes in biomass target use must be preceded by a multi-aspect analysis that allows their impact on the environment to be assessed. [ABSTRACT FROM AUTHOR]

This paper presents research findings on the pelleting process of pine sawdust using bakery waste in a pelletizer. The addition of bakery waste (white wheat–rye bread, whole-grain rye bread, and pumpkin bread) to pine sawdust had a beneficial effect on the kinetic strength of the pellets obtained, an increase of up to approximately three percentage points. The density of pellets with the addition of bakery waste also increased, while the bulk density of the pellets decreased. The addition of bakery waste also had a positive effect on the power demand of the pelletizer. It was reduced from 3.08% (at a 10% addition of white wheat–rye bread) to 22.18% (at a 20% addition of pumpkin bread), compared to the process of compacting pure pine sawdust. In addition, all the pellets containing bakery waste had a lower energy yield (EY) determined based on lower heating value and energy inputs. This index was lower by 53 Wh·kg−1 for pine sawdust pellets with a 10% addition of pumpkin bread. The greatest reduction, on the other hand, was by 173 Wh·kg−1 for pellets, with a 20% addition of white wheat–rye bread. In each case, an increase in the share of bakery additives resulted in a decrease in the energy yield from the pellets obtained. The smallest reduction in EY was found when pumpkin bread was used as an additive (from 53 to 133 Wh·kg−1). Considering all the parameters analyzed characterizing the pellets obtained, it was concluded that the addition of bakery residues to pelletized pine sawdust should not exceed 10%. Further increases in the proportion of bakery waste did not yield relative benefits, due to the deterioration of the energy characteristics of the pellets obtained. [ABSTRACT FROM AUTHOR]

The paper discusses the results of investigations of the change in thermal and emission-related parameters of a heating boiler fueled with biomass after a modification with a proprietary flue gas recirculation system made for this type of equipment. The results provide insight into the combustion process with a multistage flue gas recirculation that materially affected the boiler operation: a reduction in the mass concentration of nitrogen oxides (NOx) by reducing the combustion temperature. The authors also observed a reduction in the emission of particulate matters (PM) and carbon monoxide (CO). For the investigations, the authors used a heating boiler fitted with an automatic fuel feed (timber pellets) and a proprietary patented flue gas recirculation system (Polish patent Pat. 243395) for low power solid fuel heating boilers. Aside from the measurement of the mass concentration of the emitted pollutants, the research focused on the measurements of the temperature inside the combustion chamber, the temperature of the flue gas and the level of oxygen in the flue gas. The aim of the research was to confirm the validity of using the flue gas recirculation technique to reduce emissions of harmful substances from biomass heating boilers, as a technique not previously used for this group of devices. Moreover, the aim of the research was to test an original engineering solution, in the form of a flue gas distribution valve, and investigate its effect on reducing NOx emissions and improving other thermal and emission parameters of the boiler. The obtained research results confirm the validity of the chosen actions and provide a positive premise for the practical use of this technology in solid fuel heating boilers. [ABSTRACT FROM AUTHOR]

Biomass pyrolysis is considered as a thermochemical conversion system that is performed under oxygen-depleted conditions. A large body of literature exists in which thermodynamic equilibrium (TE) and kinetic approaches have been applied to predict pyrolysis products. However, the reliability, accuracy and predictive power of both modeling approaches is an area of concern. To address these concerns, in this paper, two new simulation models based on the TE and kinetic approaches are developed using Aspen Plus, to analyze the performance of each approach. Subsequently, the results of two models are compared with modeling and experimental results available in the literature. The comparison shows that, on the one hand, the performance of the TE approach is not satisfactory and cannot be used as an effective way for pyrolysis modeling. On the other hand, the results generated by the new model based on the kinetic approach suggests that this approach is suitable for modeling biomass pyrolysis processes. Calculation of the root mean square error (RMS), to quantify the deviation of the model results from the experiment results, confirms that this kinetic model presents superior agreement with experimental data in comparison with other kinetic models in the literature. The acquired RMS for the developed kinetic method in this paper varies within the span of 1.2 to 3.2 depending on temperature (400–600 °C) and various feedstocks (pine spruce sawdust, bagasse, wood bark, beech wood and paddy straw). [ABSTRACT FROM AUTHOR]

Formulating energy policies at national, European, and global levels is extremely challenging. The move away from fossil fuels is associated with a variety of technological, economic, and social implications, each of which is subject to dynamic changes and societal scrutiny and can hardly be predicted with certainty. Therefore, a fact-based assessment for the path to a sustainable green energy future is sought out in this paper, using the road-based mobility sector of the Federal Republic of Germany as an example. The analysis performed in this paper is built on publicly accessible, reputable sources like DESTATIS and EUROSTAT. In addition, some very simple calculations were made, e.g., on the potential for wind and photovoltaic energy within Germany. Such an analysis needs to start with the overall energy consumption of any one country. A basic assumption of the paper is that the energy system of the future will be based to a large extent on electricity and its storage in chemical energy. It is assumed that, in addition to hydrogen, liquid energy sources will play a significant role due to the simplicity of their logistics and the subsequent implications on cost. Examples of green, electricity-based fuels with great potential are methanol, methane, and ammonia. Additionally, biomass plays an important role, either for direct use as a fuel or as a source of non-fossil carbon. Today, biofuels, i.e., biodiesel and bioethanol, deliver the largest contribution to climate protection in the EU transport sector. The main goal—the reduction of greenhouse gas emissions—often collides with geopolitical circumstances or national political necessities. This includes, for example, the current world market situation and its national impacts caused by the Russian attack on Ukraine. The prospect for a green, sustainable, and defossilized energy supply are discussed in this context. The paper concludes that a defossilized world energy supply and trade based on renewable electricity and its derivatives, eHydrogen and refuels, and on biomass, is feasible. [ABSTRACT FROM AUTHOR]

This paper presents the application of prediction in the analysis of market price volatility in Polish conditions of wood processing by-products in the form of biomass. The ARIMA model, which takes into account cyclical, seasonal, irregular fluctuations of historical data on the basis of which the forecast and long-term trends of selected wood products were made, was used in predicting prices. Comparisons were made between the ARIMA prediction method and the multiplicative Winters–Holt model. During the period studied (2017–2022), the changes in the market price of biomass were characterized by a wide spread of values. On average, the price of these products increased from 2017 to the end of 2022 by 125%. The price prediction analysis showed seasonal fluctuations in the case of wood chips. The uncertainty in price prediction is due to changes in supply resulting from the influence of global factors. The Diebold–Mariano test of matching accuracy confirms that the price prediction of the analyzed by-product sorts using the ARIMA and WH models is possible. The conclusion reached by comparing these two methods is that each can be used under certain market conditions of certain assortments. In the case of a stable wood product, the choice of the ARIMA model should be resolved, while in the case of price volatile products, WH will be a better choice. The difference between the predicted and actual price with ARIMA ranged from 2.4% to 11.6% and for WH from 3.7% to 29.8%. [ABSTRACT FROM AUTHOR]

Mercury is considered one of the most harmful ecotoxic elements. A main source of its anthropogenic emissions is fuel combustion. For fuels with a high mercury content, costly methods are required to remove mercury from the flue gases. The solution to this problem is to remove mercury from the fuel before combustion. This can be achieved by a mild pyrolysis process. Solid fuel samples with relatively high mercury content were examined. These included waste (refuse-derived fuel, paper, sewage sludge, and rubber), waste wood biomass (hornbeam leaves, pine and spruce bark), and six coal. The mild pyrolysis process was performed at 300 °C in an argon flow of 500 cm3/min. The residence time was 30 min. Proximate and ultimate analysis (including mercury content) was conducted for raw fuels and chars. The process allowed a significant reduction in mercury content from 36 to 97%. Mercury was most easily removed from biomass and waste with the most difficult being from coal. The effectiveness of mercury removal was determined by the type of fuel and its mercury content. The mercury content in the obtained chars was 0.05–3.4 µg Hg/MJ. The use of such chars will meet current EU emission standards and those to be introduced in the future. [ABSTRACT FROM AUTHOR]

In this study, biorefinery as a concept is applied to thermomechanical pulp (TMP)-based paper production to evaluate the possibility of co-production of synthetic natural gas (SNG), electricity and district heating in addition to mechanical pulp and paper. The combined heat and power plant (CHP) associated to TMP is replaced by a biomass-to-SNG (BtSNG) plant. Implementing BtSNG in a mechanical pulp production line might improve the profitability of a TMP mill and also help to commercialize the BtSNG technology by taking into account of some key issues such as biomass availability, heat utilization, etc. A TMP + BtSNG mathematical model is developed with ASPEN Plus. The model prediction shows that the scale of the TMP + BtSNG mill and SNG price are two strong factors for the implementation of BtSNG in a TMP mill. A BtSNG plant associated to a TMP mill should be built at a scale above 100 MW of biomass thermal input. For the case of Swedish economic condition, commercialization of SNG production as a transport biofuel has not matured yet. Political instruments to support commercialization of transport biofuel are necessary. [ABSTRACT FROM AUTHOR]

Integrated whole-boiler process models are useful in the design of biomass and coal-fired boilers, and they can also be used to analyse different scenarios such as low load operation and alternate fuel firing. Whereas CFD models are typically applied to analyse the detail heat transfer phenomena in furnaces, analysis of the integrated whole-boiler performance requires one-dimensional thermofluid network models. These incorporate zero-dimensional furnace models combined with the solution of the fundamental mass, energy, and momentum balance equations for the different heat exchangers and fluid streams. This approach is not new, and there is a large amount of information available in textbooks and technical papers. However, the information is fragmented and incomplete and therefore difficult to follow and apply. The aim of this review paper is therefore to: (i) provide a review of recent literature to show how the different approaches to boiler modelling have been applied; (ii) to provide a review and clear description of the thermofluid network modelling methodology, including the simplifying assumptions and its implications; and (iii) to demonstrate the methodology by applying it to two case study boilers with different geometries, firing systems and fuels at various loads, and comparing the results to site measurements, which highlight important aspects of the methodology. The model results compare well with values obtained from site measurements and detail CFD models for full load and part load operation. The results show the importance of utilising the high particle load model for the effective emissivity and absorptivity of the flue gas and particle suspension rather than the standard model, especially in the case of a high ash fuel. It also shows that the projected method provides better results than the direct method for the furnace water wall heat transfer. [ABSTRACT FROM AUTHOR]

Because of the social, economic, and environmental issues linked with fossil resources, there is a global interest in finding alternative renewable and sustainable resources for energy and materials production. Biomass could be one such renewable material that is available in large quantities. However, biomass physicochemical properties are a challenge for its industrial application. Recently, the torrefaction process was developed to improve the fuel characteristics of biomass. However, in recent days, energy production has slowly been shifting towards solar and wind, and restrictions on thermal power plants are increasing. Thus, there will be a need to find alternative market opportunities for the torrefaction industry. In that regard, there is a quest to find alternative applications of torrefaction products other than energy production. This paper presents a couple of alternative applications of torrefied biomass. Torrefaction process can be used as a biomass pretreatment option for biochemical conversion processes. The other alternative applications of torrefied biomass are using it as a reducing agent in metallurgy, as a low-cost adsorbent, in carbon-black production, and as a filler material in plastics. The use of torrefied biomass in fermentation and steel production is validated through a few laboratory experiments, and the results are looking attractive. The lower sugar yield is the main challenge in the case of the microbial application of torrefied biomass. The lower mechanical strength is the challenge in the case of using it as a reducing agent in a blast furnace. To date, very few studies are available in the literature for all the highlighted applications of torrefied biomass. There is a need for extensive experimental validation to identify the operational feasibility of these applications. [ABSTRACT FROM AUTHOR]

Pyrolysis, a process for extracting valuable chemicals from waste materials, leverages computational fluid dynamics (CFD) to optimize reactor parameters, thereby enhancing product quality and process efficiency. This review aims to understand the application of CFD in pyrolysis. Initially, the need for pyrolysis and its role in biomass valorization are discussed, and this is followed by an elaboration of the fundamentals of CFD studies in terms of their application to the pyrolysis process. The various CFD simulations and models used to understand product formation are also explained. Pyrolysis is conducted using both conventional and microwave-assisted pyrolysis platforms. Hence, the reaction kinetics, governing model equations, and laws are discussed in the conventional pyrolysis section. In the microwave-assisted pyrolysis section, the importance of wavelength, penetration depth, and microwave conversion efficiencies on the CFD are discussed. This review provides valuable insights to academic researchers on the application of CFD in pyrolysis systems. The modeling of pyrolysis by computational fluid dynamics (CFD) is a complex process due to the implementation of multiple reaction kinetics and physics, high computational cost, and reactor design. These challenges in the modeling of the pyrolysis process are discussed in this paper. Significant solutions that have been used to overcome the challenges are also provided with potential areas of research and development in the future of CFD in pyrolysis. [ABSTRACT FROM AUTHOR]

This paper presents a comprehensive method for optimizing the controlling parameters of a biomass boiler. The historical data are preprocessed and classified into different conditions with the k-means clustering algorithm. The first-order derivative (FOD) method is used to compensate for the lag of controlling parameters, the backpropagation (BP) neural network is used to map the controlling parameters with the boiler efficiency and unit load, and the ant colony optimization (ACO) algorithm is used to search the opening of air dampers. The results of the FOD-BP-ACO model show an improvement in the boiler efficiency compared to the predicted values of FOD-BP and the data compared to the historical true values were observed. The results suggest that this FOD-BP-ACO method can also be used to search and optimize other controlling parameters. [ABSTRACT FROM AUTHOR]

Biomass is an excellent renewable organic energy in nature. 5-hydroxymethylfurfural (HMF) is a significant platform chemical derived from biomass. It can be obtained from biomass and has the potential to produce high value-added derivatives. For the past few years, the chemocatalysis pathway has been extensively studied and is the main pathway of HMF transformation. In this paper, the influence factors and reaction mechanisms of different catalyst types on HMF hydrogenation processes were discussed. The latest progress on the efficient catalytic system using hydrogen, alcohol and other hydrogen sources to catalyze HMF was introduced. Future research prospects of catalytic hydrogenation of HMF were also prospected. [ABSTRACT FROM AUTHOR]

In the context of increased energy demands and finding solutions for energetic autonomy, the use of waste base materials has increased in recent years in all areas of research. In this context, waste waters, sludge or slurry, biodegradable materials, second generation effluents, and their byproducts are some of the key substrates of interest to obtain biogas through AD (anaerobe digestion). The goal is to utilize these materials as a base for the generation of renewable energy and thereby make it the main source of energy for households or industries. This paper aims to characterize, from a physical and chemical point of view, wastewater from Timis county as a base substrate material in the co-fermentation process with cereal residual biomass. We aimed to determine the energetic potential of the wastewater and perform preliminary testing at a small and pilot-sized experimental installation for biogas production with Timis wastewater as the main energy carrier. The novelty of the paper stems from the use of a patented pilot installation as our experimental approach, as well as the use of a different comparative scale co-fermentation process for biogas production. The conclusions will be traced relative to the obtained results, and preliminary solutions will be proposed for further avenues on this topic. [ABSTRACT FROM AUTHOR]

Energy is a key driver of all modern economies. Sustainable development is playing an increasingly important role both at regional and local levels. It is a compromise between social and economic needs and the preservation of nature. In the policy of the European Union, the idea of sustainable development and environmental protection is of decisive importance for the implemented programs and economic activities. Contemporary challenges require the transformation of the energy market towards greater use of renewable sources. According to Directive 2009/28/EC of the European Parliament and European Council on promoting energy from renewable sources, Poland has committed itself to achieving a 23% share of renewable energy in gross final energy consumption by 2030. This goal considers total energy consumption in terms of power, engineering, heating, refrigeration, and transport. The aim of this paper was, firstly, an analysis of the share of renewable energy in the European Union over an 18-year period (2004–2021), with particular emphasis on the position of Poland. The second objective was the analysis of renewable energy at the local level in Poland, i.e., at the local government unit (LAU) level. Changes in the share of renewable energy in Poland compared to other European countries were also examined. The study utilized functional analysis of principal components and cluster analysis based on the data from the Central Statistical Office and EUROSTAT. The study found that while Poland does not differ significantly from other countries in using renewable energy, it does fall below the European average. Principal component analysis suggests that Poland responds adequately to European changes in the share of renewable energy in total energy consumption. This dynamic is stable (over 95% explained by the first component) and applies to most countries surveyed. In addition, the authors sought to answer questions relating to the current status of renewable energy sources in Poland, the barriers and challenges facing the introduction of renewable energy in the country, a comparative analysis of Poland's progress in renewable energy with other global counterparts, and an exploration of the future prospects and potential for the development of renewable energy in Poland. The study found that the potential for renewable energy is greatest in the northern areas of Poland, with photovoltaics and wind power plants providing the greatest capacity. Poland's renewable energy potential is very high and will be determined by technological development, political, economic, and social issues. [ABSTRACT FROM AUTHOR]

Microalgae-based technologies have huge potential for application in the environment sector and the bio-energy industry. However, their cost-efficiency has to be improved by drawing on design and operation data for large-scale installations. This paper presents a technical concept of an installation for large-scale microalgae culture on digestate liquor, and the results of a pilot-scale study to test its performance. The quality of non-treated digestate has been shown to be insufficient for direct use as a growth medium due to excess suspended solids, turbidity, and organic matter content, which need to be reduced. To that end, this paper proposes a system based on mechanical separation, flotation, and pre-treatment on a biofilter. The culture medium fed into photobioreactors had the following parameters after the processing: COD—340 mgO2/dm3, BOD5—100 mgO2/dm3, TN—900 mg/dm3, and TP—70 mg/dm3. The installation can produce approx. 720 kgVS/day of microalgal biomass. A membrane unit and a thickening centrifuge (thickener) were incorporated into the design to separate and dehydrate the microalgal biomass, respectively. The total energy consumption approximated 1870 kWh/day. [ABSTRACT FROM AUTHOR]

Using straw and herbaceous crops to replace or augment fossil fuels is becoming popular as access to forest biomass becomes environmentally stricter and more expensive. The low bulk density raw biomass is pre-processed and densified into pellets to facilitate handling and use. Dust is generated during collection, baling and debaling, grinding, drying, and densifying processed herbaceous biomass. Abundant literature deals with dust generated during the industrial handling of woody biomass, grains, and other crops like cotton. But the information on handling herbaceous biomass in the open literature is scarce. This paper reviews the available literature on dust generation from handling and processing of herbaceous biomass. Limited available data shows that herbaceous biomass species have a lower ignition temperature than woody biomass. The paper identifies several crucial pieces of information needed to ensure safety in the handling and pelleting of herbaceous crops. [ABSTRACT FROM AUTHOR]

The utilization of biomass can not only alleviate the energy crisis but also reduce the pollution of fossil fuels to the environment. Biomass gasification is one of the main utilization methods, which can effectively convert biomass into high-value and wide-use gasification gas. However, this process inevitably produces the by-product tar, which affects the yield of syngas. In order to solve this problem, a two-stage process combining biomass pyrolysis and CO2 catalytic reforming is proposed in this paper, which is used to prepare high calorific value syngas rich in H2 and CO and reduce the by-product tar of biomass gasification while realizing the resource utilization of CO2. The effects of the reforming temperature and CO2/C ratio on the gas yield and calorific value of biomass were investigated by catalytic gasification reforming device, and the system energy consumption was analyzed. With the increase of reforming temperature, the yield of CO increased, and the yield of H2 and the calorific value of gas increased first and then decreased. Increasing the CO2/C ratio within a proper range is beneficial to the formation of syngas. When the reforming temperature is 900 °C and the CO2/C ratio is 1, syngas with a high gas calorific value is obtained, which of is 2.75 MJ/kg is obtained. At this time, the yield of H2 and CO reached the maximums, which were 0.46 Nm3/kg and 0.28 Nm3/kg, respectively. Under these conditions, the total energy consumption of the system is 0.68 MJ/kg, slightly more than 0, and does not require too much external heat. [ABSTRACT FROM AUTHOR]

The decarbonization of energy matrices is crucial to limit global warming below 2 °C this century. An alternative capable of enabling zero or even negative CO2 emissions is bioenergy with carbon capture and storage (BECCS). In this sense, the Brazilian sugar–energy sector draws attention, as it would be possible to combine the production of fuel and electricity from renewable biomass. This paper is the final part of a study that aimed to research carbon capture and storage (CCS) in energy systems based on sugarcane. The case studied is CCS in thermal power plants considering two different technologies: the steam cycle based on the condensing–extraction steam turbine (CEST) and the combined cycle integrated to biomass gasification (BIG-CC). The results for the thermal power plant indicate that the CO2 capture costs may be lower than those in cogeneration systems, which were previously studied. The main reasons are the potential scale effects and the minimization of energy penalties associated with integrating the CCS system into the mills. In the best cases, capture costs can be reduced to EUR 54–65 per ton of CO2 for the CEST technology and EUR 57–68 per ton of CO2 for the BIG-CC technology. [ABSTRACT FROM AUTHOR]

Sustainability and resilience are major challenges for the building sector in order to meet energy efficiency and low carbon emissions goals. Based on the defined and quantified targets of the EU climate change policy, Renewable Energy Systems (RESs) are among the top-priority measures for accomplishing the target of decarbonization in buildings. Nevertheless, the choice of the type of RES is not a one-dimensional problem, and the optimal combination may not be unique. The aim of this paper is the energy and environmental evaluation of renewable energy technologies with emphasis on biomass and solar thermal systems for heating applications in residential buildings. More specifically, and aiming at the maximum possible contribution of renewable energy sources in the total final energy consumption for the needs of zero energy buildings, different scenarios are presented based on a Life Cycle Energy Analysis (LCEA) approach. The methodology is based on quantifying the environmental impacts (midpoint analysis), as well as endpoint analysis, in order to define the impact on human health, ecosystem damage, and resource depletion. The LCEA has been conducted, supported by the SimaPro tool, ensuring the environmental impact assessment result. A combination of RES technologies based on solar and biomass are examined and compared to conventional fossil fuel heating systems according to technical, energy, and environmental criteria. Finally, the energy system technologies were compared in correlation to a building's thermal insulation level. The first set of simulations fulfilled the minimum thermal insulation requirements, according to the national energy performance regulation, whilst the second set of simulations was based on increased levels of insulation. The point of this analysis was to correlate the impact of thermal insulation to RES technologies' contribution. The results determined that the best available energy solution, focusing on technical and environmental criteria, is the combination of biomass and solar thermal systems for covering the heating processes in residential buildings. More specifically, the combined biomass–solar system has a lower overall environmental impact, due to the reduction in gaseous pollutant emissions, as well as the reduction in the amount of used fuel. The reduction in the total environmental impact amounts to a percentage of approximately 43%. [ABSTRACT FROM AUTHOR]

The current focus on renewable energy sources and the circular economy favors the thermal conversion of low-quality fuels, such as biomass and waste. However, the main limitation of their usability in the power sector is the risk of slagging, fouling, ash deposition, and high-temperature corrosion. These problems may be avoided or significantly mitigated by the application of aluminosilicate clay minerals as fuel additives. In this paper, the three most commonly occurring aluminosilicates are reviewed: kaolin, halloysite, and bentonite. Their application has been proven to minimize combustion-related problems by bonding alkalis in high-melting compounds, thus increasing ash melting temperatures, reducing ash deposition tendencies, and decreasing the particulate matter emission. Due to excellent sorption properties, aluminosilicates are also expected to fix heavy metals in ash and therefore decrease their emissions into the atmosphere. The application of aluminosilicates as fuel additives may be a key factor that increases the attractiveness of biomass and other low-quality fuels for the power sector. [ABSTRACT FROM AUTHOR]

Recently, biomass has become an increasingly widely used energy resource. The problem with the use of biomass is its variable composition. The most important property that determines the energy content and thus the performance of fuels such as biomass is the heating value (HHV). This paper focuses on selecting the optimal number of input variables using linear regression (LR) and the multivariate adaptive regression splines approach (MARS) to create an artificial neural network model for predicting the heating value of selected biomass. The MARS model selected the input data better than the LR model. The best modeling results were obtained for a network with three input neurons and nine neurons in the hidden layer. This was confirmed by a high correlation coefficient of 0.98. The obtained results show that artificial neural network (ANN) models are effective in predicting the calorific value of woody and field biomass, and can be considered a worthy simulation model for use in selecting biomass feedstocks and their blends for renewable fuel applications. [ABSTRACT FROM AUTHOR]

The pretreatment of biomass through torrefaction is an effective means of improving the fuel quality of woody biomass and its suitability for use in existing facilities burning thermal coal. Densification of torrefied biomass produces a fuel of similar energy density, moisture content, and fixed carbon content to low-grade coals. Additionally, if the torrefaction conditions are optimized, the produced torrefied pellet will be resistant to weathering and biological degradation, allowing for outdoor storage and transport in a manner similar to coal. In untreated biomass, lignin is the primary binding agent for biomass pellets and is activated by the heat and pressures of the pellet extrusion process. The thermal degradation of lignin during torrefaction reduces its binding ability, resulting in pellets of low durability not suitable for transportation. The use of a binding agent can increase the durability of torrefied pellets/briquettes through a number of different binding mechanisms depending on the binder used. This study gives a review of granular binding mechanisms, as they apply to torrefied biomass and assesses a variety of organic and inorganic binding agents, ranking them on their applicability to torrefied pellets based on a number of criteria, including durability, hydrophobicity, and cost. The best binders were found to be solid lignin by-product derived from pulp and paper processing, biomass tar derived from biomass pyrolysis, tall oil pitch, and lime. [ABSTRACT FROM AUTHOR]

The continual generation and discharge of waste are currently considered two of the main environmental problems worldwide. There are several waste management options that can be applied, though anaerobic digestion (AD) process technology seems to be one of the best, most reliable, and feasible technological options that have attracted remarkable attention due to its benefits, including the generation of renewable energy in the form of biogas and biomethane. There is a large amount of literature available on AD; however, with the continuous, progressive, and innovative technological development and implementation, as well as the inclusion of increasingly complex systems, it is necessary to update current knowledge on AD process technologies, process variables and their role on AD performance, and the kinetic models that are most commonly used to describe the process-reaction kinetics. This paper, therefore, reviewed the AD process technologies for treating or processing organic biomass waste with regard to its classification, the mechanisms involved in the process, process variables that affect the performance, and the process kinetics. Gazing into the future, research studies on reduced MS-AD operational cost, integrated or hybrid AD-biorefinery technology, integrated or hybrid AD-thermochemical process, novel thermochemical reactor development, nutrient recovery from integrated AD-thermochemical process, and solid and liquid residual disposal techniques are more likely to receive increased attention for AD process technology of biomass wastes. [ABSTRACT FROM AUTHOR]

Biomass fuels play an important role in the field of fluidized bed combustion, but due to the diversity and uncertainty of fuels, there are usually some problems of high CO emission that cannot be directly solved by combustion adjustment. In this paper, a 75 t/h biomass fluidized bed was taken as the research object. It was observed from the field test that the gas incomplete combustion loss reached 12.13% when mono-combustion of wheat straw was conducted, and the CO concentration in the exhaust gas exceeded 30k ppm. Combined with the CPFD numerical simulation, the combustion characteristics and influence of secondary air layout on CO reduction performance were discussed in detail. The results revealed that the gas temperature gradually increased along furnace height under the initial condition, and the maximum temperature was more than 1000 °C at furnace outlet. The air curtain of the secondary air jets was insufficient, and the wheat straw rose rapidly as it entered into the furnace. By arranging adjacent secondary air ports above each fuel-feeding inlet, the residence time of particles in the furnace could be significantly increased, thus, the furnace temperature distribution was more reasonable and the CO emission was reduced by 58.6%. [ABSTRACT FROM AUTHOR]

The depletion of fossil fuels has led to a search for new methods of fuel and chemical production from biomass. One of the methods of converting biomass into valuable products is the process of pyrolysis. This process has been extensively researched in recent years due to the rising prices of energy and chemicals. This work contains basic information on the pyrolysis process concerning the individual components present in the biomass and the types of biomass used in the pyrolysis process. Particular attention was paid to sewage sludge, the management of which is a big challenge. The influence of the most important process parameters (temperature, heating rate, residence time of the solid and vapor, reaction atmosphere) on the pyrolysis products (char, oil, and gas) was presented. The paper presents an overview of the reactors used in the pyrolysis process, from slow to fast pyrolysis, together with their efficiency, advantages, and disadvantages. The analysis of the application of other thermochemical processes for producing the energy used in the process of pyrolysis and in the drying of the biomass was carried out. Two industrial-scale installations for the pyrolysis of sewage sludge were presented. [ABSTRACT FROM AUTHOR]

Pyrolysis has been applied in the human economy for many years, and it has become a significant alternative to the production of chemical compounds, including biofuels. The article focuses mostly on recent achievements in the technical and processing aspects of pyrolysis. The aim of the review is to present the latest research on the process of waste biomass pyrolysis to fuel production. The paper describes the mechanisms of the pyrolysis process, composition, and properties of the obtained fractions, namely pyrolysis gas, bio-oil, and biochar. Additionally, the technical aspects of the pyrolysis process are mentioned, with particular attention to the construction of the reactors. The process of waste biomass pyrolysis allows for obtaining many chemical compounds (second-generation biofuels). Optimization of the pyrolysis process allows obtaining the desired products that are applied in the chemical industry, energy, and transport. The application of pyrolysis gas, oil, and biochar as valuable chemical compounds are related to the intensifying effects of climate change, biofuel production, and waste management in accordance with the principles of sustainable development. In recent years, there has been large-scale research into the use of renewable energy sources through pyrolysis. This will make it possible to significantly reduce the carbon footprint and produce second-generation biofuels in a sustainable manner. Current research into the mechanisms of pyrolysis processes is promising, and will therefore provide access to clean and low-cost compounds that will have broad applications in the energy, chemical, agricultural, and transportation industries. [ABSTRACT FROM AUTHOR]

Based on current trends and policies aimed at decarbonizing energy systems, the conversion of biomass to bioenergy has the potential to grow rapidly, but such growth depends on the development of efficient, sustainable, and competitive biomass supply chains. As a result, the biomass supply chain has stimulated the interest of a diverse group of researchers across academia, government, and industry, and there is a need to synthesize and categorize the rapidly expanding literature in this field. We conducted a literature review using advanced bibliometric analysis and visualization of 1711 peer-reviewed articles published from January 1992 to August 2022 with the aim of promoting impactful research in both growing and neglected areas of investigation. The results show that there are potential research gaps and opportunities in six critical areas: globalization of supply chain research; incorporation of uncertainty, stochasticity, and risk into supply chain models; investigation of multi-feedstock supply systems; strengthening supply chain resilience; application of inventory control methods; and broader use of machine learning and artificial intelligence in this field. By providing a holistic examination of how biomass-to-bioenergy supply chain research has grown and evolved over this period, our results and subsequent framework and recommendations can aid researchers in developing future studies and can guide stakeholder strategies to identify, diagnose, and address modern challenges that face the bioenergy industry. [ABSTRACT FROM AUTHOR]

Conventional methods used to determine pyrolysis gas composition are based on chemical kinetics. The mechanism of those reactions is often unknown, which makes the calculations more difficult. Solving complex chemical reactions' kinetics involving a nonlinear set of equations is CPU time demanding. An alternative approach is based on the Gibbs free energy minimization method. It requires only the initial composition and operation parameters as the input data, for example, temperature and pressure. In this paper, the method for calculating the pyrolytic gas composition from biogenic fuels has been presented, and the thermogravimetric experimental results have been adopted to determine the total gas yield. The studied problem has been reduced to the optimization method with the use of the Lagrange multipliers. This solution procedure is advantageous since it does not require knowledge of the reaction mechanism. The obtained results are in good agreement with experimental data, demonstrating the usefulness of the proposed method. [ABSTRACT FROM AUTHOR]

Straw is a substantial agricultural by-product for biogas production. Hydrolysis of straw is found to be a rate-limiting step during its anaerobic digestion and could be enhanced by pretreatment. In this paper, the effect of various combinations of particle size reduction, autoclaving, and low-level Fenton reaction was studied on straw for biogas production. Grinding of straw contributed to the maximum increase in the biomethane potential. Only Fenton or only the autoclave process improves the kinetics slightly but does not considerably improve the biomethane potential. Combining autoclaving and low-concentration Fenton pretreatment considerably improves the BMP values. Lignin content, CHNSO elemental analysis, Scanning Electronic Microscopy (SEM), Simon's staining, infrared spectroscopy (DRIFT and ATR), Nuclear magnetic resonance spectroscopy, and wide-angle X-ray diffraction analysis (WAXD) were used to characterize the physical and chemical changes of straw due to pretreatment. Results show a poor correlation between biogas production and the different physical and chemical biomass characteristics. It makes it difficult to explain the outcome of various pretreatment methods applied to biomass. Without further improvement and development of analytical techniques, the prediction of the biomethane potential of a feedstock with the aid of pretreatment can only be considered in case-by-case studies. [ABSTRACT FROM AUTHOR]

A number of measures to diversify its energy supply sources and reduce its dependence on imported energy sources has been taken by the EU. These include pursuing new energy sources, such as renewable energy and liquefied natural gas; increasing the storage capacities; and investing in interconnectors and other infrastructure. However, these actions require long-term adjustment, while there is a need to find an option to meet the energy needs at a moment. One possible option is to utilize seed production wastes for energy production. This research paper aims to investigate the potential of utilizing seed production wastes (SPWs) for energy production in continental Croatia, and assess its feasibility. Eight different SPWs were used in this research, where their energy characteristics were determined and the theoretical thermal potential was calculated if they are used as raw material in the production of thermal energy through biomass and cogeneration power plants, or in biogas power plants. By using the available feedstock, it is theoretically possible to produce a total of 38,051.10 GJ of thermal energy by direct combustion of SPWs and 34,727.91 GJ by combustion of the produced biomethane. The SPWs of oilseed rape and beans contain the highest specific heat potential per hectare. [ABSTRACT FROM AUTHOR]

Agricultural biomass is one of the most important renewable energy sources. As a byproduct of corn, soybean and sunflower production, large amounts of biomass are produced that can be used as an energy source through conversion. In order to assess the quality and the possibility of the use of biomass, its composition and calorific value must be determined. The use of nonlinear models allows for an easier estimation of the energy properties of biomass concerning certain input and output parameters. In this paper, RFR (Random Forest Regression) and SVM (Support Vector Machine) models were developed to determine their capabilities in estimating the HHV (higher heating value) of biomass based on input parameters of ultimate analysis. The developed models showed good performance in terms of HHV estimation, confirmed by the coefficient of determination for the RFR (R2 = 0.79) and SVM (R2 = 0.93) models. The developed models have shown promising results in accurately predicting the HHV of biomass from various sources. The use of these algorithms for biomass energy prediction has the potential for further development. [ABSTRACT FROM AUTHOR]

This paper offers an algorithm to account for potential actions on the efficient production of renewable energy. The algorithm consists of a substantiated choice of a certain type of renewable energy, the evaluation of its potential, and the regulation of the processes of obtaining that renewable energy. Also, potential resources for agricultural biofuel production have been analyzed and it has been determined that there is real biomass potential in Lithuania. It will thus be beneficial to make appropriate managerial decisions on the methods of biofuel processing and consumption, as well as on means of receiving the economic, energy and environmental effects. The total potential of by-product biomass of crop production was determined, and the thermal and electric potential of the crop by-products were calculated. Additionally, the potential for production of gas-like types of fuel (biomethane, biohydrogen, and syngas) from crop by-products was determined. The potential for the production of diesel biofuel from oil crop waste (bran) was also found, and the potential for livestock by-products for receiving gas-like types of fuel (biomethane, biohydrogen) was established. The corresponding thermal and electric equivalents of the potential were found and the potential volumes of the biomethane and biohydrogen production were calculated. The total energy equivalent equals, on average, 30.017 × 106 GJ of the thermal energy and 9.224 × 106 GJ of the electric energy in Lithuania. The total potential of biomethane production (taking into account crop production and animal husbandry wastes) on average equals 285.6 × 106 m3. The total potential of biohydrogen production on average equals 251.9 × 106 m3. The cost equivalents of the energy potential of agrarian biomass have been calculated. The average cost equivalent of the thermal energy could equal EUR 8.9 billion, electric energy—EUR 15.9 billion, biomethane—EUR 3.3 billion and biohydrogen—EUR 14.1 billion. The evaluation of the agricultural biomass potential as a source of renewable energy confirmed that Lithuania has a large biomass potential and satisfies the needs for the production of renewable energy. Thus, it is possible to move to the second step, that of making a decision concerning biomass conversion. [ABSTRACT FROM AUTHOR]

Renewable sources play a crucial role in the decarbonisation process of the current linear economy, aimed at reaching the 2030 climate objectives and fulfilling the EU's long-term strategy of achieving carbon neutrality by 2050. All economic subjects, including households, can contribute to the Green Deal goals. The main goal of this paper is to evaluate households' consumption of energy sources for heating purposes in the Czech Republic in the period 2003–2020 and depict possible drivers of switching to biomass. For this, various data were collected, such as data published by the Czech Statistical Office, ministries, and other national authorities, as well as data from Eurostat. Concerning methods, data analysis, correlation analysis, and regression analysis were used. Different models focus on the substitution effect, rebound effect, and behaviour of different kinds of households. The results show a substitution effect connected with the consumption of coal, electricity, and biomass for heating purposes. Many households substituted coal for biomass in the observed period. On the other hand, the environmental impact of such substitution is not significant, as carbon emissions and emissions of other pollutants are stable. The substitution of fuels should be accompanied by technological change, e.g., improvement of combustion boilers. Moreover, households of pensioners are the key economic subjects with the highest impact on biomass consumption for heating purposes. Against this background we recommend policies to support households in replacing their boilers for more environmentally friendly ones. [ABSTRACT FROM AUTHOR]

The aim of the study is to present the possibilities of simultaneous production of green energy and reduction of pollution in rural areas. Actions taken by small family businesses are in line with the goals of a low-carbon economy. The paper presents the results of research on the possibility of using ecological energy for production and, at the same time, utilizing harmful waste generated in farms in rural areas. Within a month, a medium-sized biogas plant can produce about 35–40 GJ of energy (depending on the input material). Biogas production may be of significant importance from the point of view of environmental protection, especially in the case of overproduction of animal waste and slaughterhouse materials. The production and use of energy generated from agricultural waste give a great opportunity for diversification and an increase in income of family farms. In addition to financial, energy, and environmental gains, we can obtain a very valuable fertilizer that is easily absorbed by plants in field cultivation. Energy efficiency is an important parameter in biogas production. The possibility of reducing pollution in rural areas and the possibility of using digestate as a fertilizer and an innovative addition to biocomposites. [ABSTRACT FROM AUTHOR]

The energy sector is nowadays facing new challenges, mainly in the form of a massive shifting towards renewable energy sources as an alternative to fossil fuels and a diffusion of the distributed generation paradigm, which involves the application of small-scale energy generation systems. In this scenario, systems adopting one or more renewable energy sources and capable of producing several forms of energy along with some useful substances, such as fresh water and hydrogen, are a particularly interesting solution. A hybrid polygeneration system based on renewable energy sources can overcome operation problems regarding energy systems where only one energy source is used (solar, wind, biomass) and allows one to use an all-in-one integrated systems in order to match the different loads of a utility. From the point of view of scientific literature, medium- and large-scale systems are the most investigated; nevertheless, more and more attention has also started to be given to small-scale layouts and applications. The growing diffusion of distributed generation applications along with the interest in multipurpose energy systems based on renewables and capable of matching different energy demands create the necessity of developing an overview on the topic of small-scale hybrid and polygeneration systems. Therefore, this paper provides a comprehensive review of the technology, operation, performance, and economical aspects of hybrid and polygeneration renewable energy systems in small-scale applications. In particular, the review presents the technologies used for energy generation from renewables and the ones that may be adopted for energy storage. A significant focus is also given to the adoption of renewable energy sources in hybrid and polygeneration systems, designs/modeling approaches and tools, and main methodologies of assessment. The review shows that investigations on the proposed topic have significant potential for expansion from the point of view of system configuration, hybridization, and applications. [ABSTRACT FROM AUTHOR]

The consumption of fossil fuels is one of the main drivers of climate change. Lignin derived from biomass is a carbon-neutral raw feedstock, and its conversion into fuels is gaining much attention. The gasification of biomass aims to transform heterogeneous feedstocks into syngas and heat that could be used for various purposes. Lignin is a biomass feedstock of special interest due to its particular properties and its ability to be obtained in abundant quantities as a side product from the paper pulp industry as well as the growing cellulosic ethanol industry. This review explores the existing works regarding lignin gasification from different perspectives and compares the results obtained with other existing thermochemical processes, in addition to providing a perspective on the long-term fate of gasification as a technology compared to other emerging technologies. The analysis indicates that while lignin gasification may grow in importance in the near future due to increased interest in hydrogen production, its potential in emerging applications indicates that lignin may be too valuable to be used purely for energy generation purposes, and applications that take advantage of its inherent chemical compounds are expected to take priority in the long-term. [ABSTRACT FROM AUTHOR]

The current paper proposes a novel multi-generation system, integrated with compound parabolic collectors and a biomass combustor. In addition to analyzing the comprehensive system in a steady state, the feasibility of using nanofluids as heat transfer fluids in the solar cycle and their effect on the overall performance of the system was studied. The multi-generation system is generally designed for generating electricity, cooling, freshwater, drying, hot water, and hydrogen, with the help of six subsystems. These include a double stage refrigeration system, an organic Rankine cycle, a steam Rankine cycle, a dryer, a proton exchange membrane electrolyzer, and a multistage flash distillation system. Two types of nanoparticles (graphene, silver), which have various high-quality properties when used within ethylene glycol, were chosen as absorbing fluids in the solar cycle. The performance parameters of the base case thermodynamic analysis and some of the variable parameters were calculated, and their effect on system performance was determined. According to the results, a spike in solar irradiation, ambient temperature, output temperature of biomass combustor and nanofluids' concentration positively affected the overall system performance. The results also clearly showed an improvement in system performance when using nanofluids as working fluids in solar collectors. [ABSTRACT FROM AUTHOR]

This paper shows a practice to raise the reliability of an electric power system by the installation of distributed generation, taking gasified biomass as fuel. To calculate the reliability index, a probabilistic load flow was used. This index is determined as the fault probability of the system. The resolution of this probabilistic load flow combines the method of cumulants and Gram–Charlier expansion. To achieve the reliability index, simulating a number of contingencies is required; the greater the number of simulated contingencies, the higher the accuracy of the index obtained. This probabilistic technique uses the random variables as starting information, so the two generators and loads are simulated as random variables. The generators of this distributed generation are biomass-fueled gas engines, commonly found in Spain. The simulations carried out on the IEEE 14-bus Test System, including three biomass generators, show that the inclusion of this type of generation improves the overall reliability indices of the electrical system. [ABSTRACT FROM AUTHOR]

The gasification rate of fuel, biomass gasification in particular, is an important parameter which is worth considering in the process of creating a gasifier with a continuous operation process. The gasification of biomass is a complex thermochemical process. The theoretical and practical studies of the gasification rate of biomass are complicated because of a high thermochemical rate of reactions in the functioning zones of a gasifier. The complexity of the study prevents the achievement of the required accuracy of the analytical model of the gasification rate of biomass. The known theoretical models of the gasification rate only partially describe the dynamics of the gasification rate of biomass. Moreover, most scientific studies are focused on establishing the effects of gasifier parameters and the gasification process on the quality indicators of the received gas but not on the gasification rate of fuel. To build an accurate model of the gasification rate the authors propose a series of experimental studies in a well-defined range of the parameters of a gasifier. The paper suggests a simple mathematical model of the gasification rate of biomass, which is proportional to the amount of plant biomass that remained non-gasified. The coefficients of the gasification rate for straw pellets, wood pellets and wood in pieces have been determined. Under a minimal air supply into an active zone of a gasifier (0.00088 m3/s) a coefficient of gasification rate is nearly the same for the test fuel materials and it differs by 4.7% between wood pellets and straw pellets. When the air supply increases, the gap between the coefficients increases as well and it reaches 9.44 × 10−5 c−1 for wood pellets, 1.05 × 10−4 c−1 for straw pellets and 8.64 × 10−5 c−1 for wood in pieces under air supply into an active zone of a gas generator of 0.01169 m3/s. Straw pellets have the highest gasification rate and wood in pieces has the lowest gasification rate. [ABSTRACT FROM AUTHOR]

This paper presents the results of an experimental study of the emission levels of selected greenhouse gases (CO2, CH4, NOx) arising from the combustion of different forms of biomass, i.e., solid biomass in the form of pellets and liquid biomass in the example of engine biofuel (biodiesel). Both types of biomass under study are rape-based biofuels. The pellets are made from rape straw, which, as a waste product, can be used for energy purposes. Additionally, biodiesel contains rape oil methyl esters (FAME) designed to power diesel engines. The boiler 25 kW was used to burn the pellets. Engine measurements were performed on a dynamometer bench on an S-4003 tractor engine. An analyzer Testo 350 was used to analyze the exhaust gas. CO2 emission studies do not indicate the environmental benefits of using any alternative fuels tested compared to their conventional counterparts. In both the engine and boiler tests for NOx emissions, no environmental benefits were demonstrated from the use of alternative fuels. The measured average NOx emission levels for biodiesel compared to diesel were about 20% higher, and for rapeseed straw pellets, they were more than 60% higher compared to wood pellets. Only in the case of engine tests was significantly lower CH4 (approx. 30%) emission found when feeding the engine with rape oil methyl esters. [ABSTRACT FROM AUTHOR]

In this paper, the thermochemical conversion of selectively pre-treated binary blends composed of 30% microwave (MW) pre-treated biomass pellets (wheat straw, wood) and 70% of different origin raw biomass pellets (wheat straw, wood, or peat) was performed using originally developed experimental device with a heat output up to 20 kW. Biomass pellets were pre-treated at temperatures of 200 and 275 °C using a microwave laboratory scale torrefaction of the original construction. It was established that synergistic effects of interaction between the components of binary blends promote an increase in the efficiency of their thermochemical conversion by 5.8–9.4%. It was assumed that synergistic effects of thermochemical conversion can be related to an increase in surface area and porosity of pre-treated pellets. With a focus on different steps and rates of biomass degradation and heat amounts released for different types of blends, the thermal analysis (DTG/DSC) of ground blends in the temperature range of 25–650 °C was performed in air media with the heating rate of 10 °C/min. According to the thermal analysis data, the heat energy yield of ground blends meets the requirements of linear regression based on the additivity principle and the development of synergistic effects during thermochemical conversion of ground blends was not detected. [ABSTRACT FROM AUTHOR]

Many thermal resources are not reasonably used in the chemical industry's production process. To recover the waste heat from organic waste residue-calcium carbonate (CaCO3), which is added to inhibit hydrogen production, an organic Rankine cycle (ORC) system is applied in this research. An ORC system can reuse the low-temperature waste heat that is not fully utilized. In this study, the mathematical model of the biomass ORC power generation system is constructed. Five organic working fluids, R11, R113, R123, R141b, and R245fa, were selected from the physical characteristics and safety of working fluids. The system application case is the low-temperature heat absorption in a chemical industry's production process. The system is simulated by Aspen Plus V11 software, so as to study and analyze the influence of different working fluids and working conditions on the system performance and to obtain the preferred working fluids under different working conditions. At the same time, the economic evaluation and entropy method of the system are evaluated by using the investment profit rate PRI from different angles. It can be found that R11 and R141b have advantages, but R11 does not have advantages in environmental aspects. Through research, it is found that it is difficult to have a working fluid that can adapt to the biomass ORC power generation system under any working conditions. This paper can provide a basis for the subsequent research and selection of working fluids in the biomass ORC system. [ABSTRACT FROM AUTHOR]